Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe
SAFETY DATA SHEET
Fast Adhesive (104112)
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
: Fast Adhesive (104112)
Product name and/or code
: Evercoat
Manufacturer
a Division of Illinois Tool Works Inc.
6600 Cornell Road
Cincinnati, Ohio USA
Phone: 1-513-489-7600
: marketing@evercoat.com
e-mail address of person
responsible for this SDS
: CHEMTEL, INC: 1-800-255-3924
Emergency telephone
number (with hours of
operation)
: Fast Adhesive
Product use
2. HAZARDS IDENTIFICATION
The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
: F; R11
Classification
C; R34
Xi; R37
R43
N; R59
: Highly flammable.
Physical/chemical hazards
: Causes burns. Irritating to respiratory system. May cause sensitisation by skin
Human health hazards
contact.
: Dangerous for the ozone layer.
Environmental hazards
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances
Directive 67/548/EEC.
Chemical name CAS % EC number Classification
number
methyl methacrylate 80-62-6 25 - 50 201-297-1 F; R11 [1] [2]
Xi; R37/38
R43
Methacrylic acid 79-41-4 5 - 12.5 Xn; R21/22 [1]
C; R35
Carbon Tetrachloride 56-23-5 0-1 Carc. Cat. 3; [1]
R40
T; R23/24/25,
R48/23
N; R59
R52/53
See section 16 for the full text of the R-phrases
declared above
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
Page: 1/7
: 4/16/2008.
Date of issue/Date of
revision
Fast Adhesive (104112)
3. COMPOSITION/INFORMATION ON INGREDIENTS
Occupational exposure limits, if available, are listed in section 8.
4. FIRST AID MEASURES
First-aid measures
: In all cases of doubt, or when symptoms persist, seek medical attention. Never give
General
anything by mouth to an unconscious person.
: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
Inhalation
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Give nothing by mouth. If unconscious, place in recovery position
and seek medical advice.
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
Skin contact
water or use recognised skin cleanser. Do not use solvents or thinners.
: Check for and remove any contact lenses. Immediately flush eyes with running water
Eye contact
for at least 15 minutes, keeping eyelids open.
: If swallowed, seek medical advice immediately and show the container or label.
Ingestion
Keep person warm and at rest. Do not induce vomiting.
5. FIRE-FIGHTING MEASURES
: Recommended: alcohol-resistant foam, CO2, powders, water spray.
Extinguishing media
Not to be used : water jet.
: Fire will produce dense black smoke. Exposure to decomposition products may
Recommendations
cause a health hazard. Appropriate breathing apparatus may be required. Cool
closed containers exposed to fire with water. Do not release runoff from fire to
sewers or waterways.
6. ACCIDENTAL RELEASE MEASURES
: Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
Personal precautions
Refer to protective measures listed in sections 7 and 8.
: Contain and collect spillage with non-combustible, absorbent material e.g. sand,
Spill
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Do not allow to enter drains or
watercourses. Preferably clean with a detergent. Avoid using solvents. If the product
contaminates lakes, rivers, or sewers, inform the appropriate authorities in
accordance with local regulations.
Note: see section 8 for personal protective equipment and section 13 for waste disposal.
7. HANDLING AND STORAGE
: Vapours are heavier than air and may spread along floors. Vapours may form
Handling
explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapours in air and avoid vapour concentrations higher than the
occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving
container with bonding strap. Operators should wear antistatic footwear and clothing
and floors should be of the conducting type.
Keep container tightly closed. Keep away from heat, sparks and flame. No sparking
tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this preparation. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
Page: 2/7
: 4/16/2008.
Date of issue/Date of
revision
Fast Adhesive (104112)
7. HANDLING AND STORAGE
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking.
Put on appropriate personal protective equipment (see section 8).
Never use pressure to empty. Container is not a pressure vessel. Always keep in
containers made from the same material as the original one.
Comply with the health and safety at work laws.
: Store in accordance with local regulations. Observe label precautions. Store in a
Storage
cool, well-ventilated area away from incompatible materials and ignition sources.
Keep away from: oxidising agents, strong alkalis, strong acids.
No smoking. Prevent unauthorised access. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage.
Do not empty into drains.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
: Provide adequate ventilation. Where reasonably practicable, this should be achieved
Engineering measures
by the use of local exhaust ventilation and good general extraction. If these are not
sufficient to maintain concentrations of particulates and solvent vapours below the
OEL, suitable respiratory protection must be worn.
Occupational exposure limits
Ingredient name
methyl methacrylate ACGIH TLV (United States, 1/2006). Notes: Refers to Appendix
A -- Carcinogens. 2000 Adoption.
STEL: 100 ppm 8 hour(s).
TWA: 50 ppm 8 hour(s).
Personal protective equipment
: If workers are exposed to concentrations above the exposure limit, they must use
Respiratory system
appropriate, certified respirators.
: Personnel should wear antistatic clothing made of natural fibres or of high-
Skin and body
temperature-resistant synthetic fibres.
Hands
Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has
occurred.
: Use safety eyewear designed to protect against splash of liquids.
Eyes
Environmental exposure controls
Do not allow to enter drains or watercourses.
9. PHYSICAL AND CHEMICAL PROPERTIES
Liquid.
Physical state :
Off-white.
Colour :
Flash point : Open cup: 10癈 (50癋)
3 to 3.5
pH :
1.03
Relative density :
Vapour density : >1 [Air = 1]
Insoluble in the following materials: cold water and hot water.
Solubility :
Page: 3/7
: 4/16/2008.
Date of issue/Date of
revision
Fast Adhesive (104112)
10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions (see section 7).
Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.
Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong
acids.
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product/ingredient name Result Species Dose Exposure
methyl methacrylate LD50 Rat 1328 mg/kg -
Intraperitoneal
LD50 Oral Rat 7872 mg/kg -
LD50 Rat 7088 mg/kg -
Subcutaneous
: Not available.
Conclusion/Summary
Chronic toxicity
: Not available.
Conclusion/Summary
Carcinogenicity
: Not available.
Conclusion/Summary
Mutagenicity
: Not available.
Conclusion/Summary
Teratogenicity
: Not available.
Conclusion/Summary
Reproductive toxicity
: Not available.
Conclusion/Summary
12. ECOLOGICAL INFORMATION
There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 15 for details.
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
methyl methacrylate Mortality Acute LC50 Fish 96 hours
232.2 mg/L
Mortality Acute LC50 191 Fish 96 hours
mg/L
Mortality Acute LC50 Fish 96 hours
160.2 mg/L
Mortality Acute LC50 Fish 96 hours
159.1 mg/L
Mortality Acute LC50 150 Fish 96 hours
mg/L
Mortality Acute LC50 130 Fish 96 hours
mg/L
: Not available.
Conclusion/Summary
Biodegradability
: Not available.
Conclusion/Summary
Page: 4/7
: 4/16/2008.
Date of issue/Date of
revision
Fast Adhesive (104112)
13. DISPOSAL CONSIDERATIONS
Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
: The classification of the product may meet the criteria for a hazardous waste.
Hazardous waste
14. TRANSPORT INFORMATION
Ta s ot i i u e' pe s s always transport in closed containers that are upright and secure. Ensure that
rn p rw t n s r rmie :
h s
persons transporting the product know what to do in the event of an accident or spillage.
Land - road/railway
: UN1247
UN number
Transport document name : METHYL METHACRYLATE MONOMER, STABILIZED
:3
ADR/RID Class
: 339
HI/Kemler number
: II
Packing group
ADR/RID Label :
3
Sea
UN1247
UN number :
METHYL METHACRYLATE, MONOMER, STABILIZED
Proper shipping name :
Not available.
Special provisions :
3
IMDG Class :
II
Packing group :
IMDG Label :
3
: No.
Marine pollutant
: F-E, S-D
Emergency schedules
(EmS)
Air
: UN1247
UN number
: Methyl methacrylate monomer, stabilized
Proper shipping name
: Not available.
Special provisions
:3
ICAO/IATA Classification
: II
Packing group
The "viscosity exemption" provisions do not apply to air transport.
ICAO/IATA label :
3
Inland waterways
UN1247
UN number :
METHYL METHACRYLATE MONOMER, STABILIZED
Proper shipping name :
3
ADNR Classification :
II
Packing group :
Page: 5/7
: 4/16/2008.
Date of issue/Date of
revision
Fast Adhesive (104112)
14. TRANSPORT INFORMATION
ADNR Label :
3
15. REGULATORY INFORMATION
: The product is classified and labelled for supply in accordance with the Directive
EU regulations
1999/45/EC as follows:
Hazard symbol or symbols :
Highly flammable, Corrosive, Dangerous for the environment
: R11- Highly flammable.
Risk phrases
R34- Causes burns.
R37- Irritating to respiratory system.
R43- May cause sensitisation by skin contact.
R59- Dangerous for the ozone layer.
: S26- In case of contact with eyes, rinse immediately with plenty of water and seek
Safety phrases
medical advice.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S45- In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S59- Refer to manufacturer/supplier for information on recovery/recycling.
: methyl methacrylate
Contains
Methacrylic acid
: Europe inventory: All components are listed or exempted.
Europe inventory
: T ei omai c na e i tis ftd t s e t o s o c n t t teu e'
h n r t n o ti d n h aey aa h e d e n t o st e h s r
f o n s i u s
Industrial use
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.
16. OTHER INFORMATION
:1
CEPE Classification
: R11- Highly flammable.
Full text of R-phrases
R40- Limited evidence of a carcinogenic effect.
referred to in sections 2 and
R23/24/25- Toxic by inhalation, in contact with skin and if swallowed.
3 - Europe
R48/23- Toxic: danger of serious damage to health by prolonged exposure through
inhalation.
R21/22- Harmful in contact with skin and if swallowed.
R34- Causes burns.
R35- Causes severe burns.
R37- Irritating to respiratory system.
R37/38- Irritating to respiratory system and skin.
R43- May cause sensitisation by skin contact.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R59- Dangerous for the ozone layer.
The information in this Safety Data Sheet is required pursuant to EU Directive 91/155/EEC and its amendments.
: 4/16/2008.
Date of issue/Date of
revision
Version : 1.1
Indicates information that has changed from previously issued version.
Notice to reader
Page: 6/7
: 4/16/2008.
Date of issue/Date of
revision
Fast Adhesive (104112)
16. OTHER INFORMATION
The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.
Page: 7/7
: 4/16/2008.
Date of issue/Date of
revision
|