MATERIAL SAFETY DATA SHEETS Page 1 of 1
SECTION I: SUBSTANCE IDENTIFICATION AND COMPANY INFORMATION
EMERGENCY TELEPHONE NO: 1.800.535.5053
MANUFACTURER'S NAME: ENTITY BEAUTY INC.
INTERNATIONAL EMERGENCY TELEPHONE: 1.352.323.3500
INFORMATION CONTACT: INFOTRAC
ADDRESS: 4700 MILLENNIA BLVD., SUITE 150 ENTITY'S FORMULA NUMBER: CONFIDENTIAL
ORLANDO, FL 32839 PRODUCT CODE:
FAMILY: PRIMER
PRODUCT TYPE: NAIL
TRADE NAME: NAIL PRIMER
NAIL PRIMER ISSUED: FEBRUARY 7, 2005
PRODUCT USE:
SECTION II: COMPOSITION AND INGREDIENT INFORMATION
SAFETY PHRASES: S7/9, S16, S24/25, S33, S37/39, S45 RISK PHRASES: R11, R20/22, R36/37/38 HAZARD SYMBOLS: XN, F
INGREDIENTS:
CAS No. EINECS U. S. INCI European INCI Exposure OSHA Limits ACGIH
VPEL / PEL TLV /STEL
79-41-4 201-204-4 Methacrylic Acid Methacrylic Acid 20 ppmTWA/70mg/m3Skin 20 ppmTWA/70mg/m3 8hr.TWASkin
SECTION III: HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW - This information is based on findings from related or similar materials.
? Flammable liquid!
? May cause skin irritation.
? May cause eye irritation.
? Avoid prolonged or repeated breathing of gases, vapors or mists.
? Please read entire MSDS for additional information.
Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry: Inhalation, skin and ingestion
Eye: CORROSIVE. Splashes may cause severe irritation, Direct Contact may cause severe burns,
destruction of eye tissue and possible permanent injury or blindness.
Skin: CORROSIVE. May cause burns with permanent skin damage
Ingestion: CORROSIVE Causes irritation, a burning sensation of the mouth, throat and will cause damage to the
gastrointestinal tract and adominal pain..
Inhalation: CORROSIVE. Corrosive to the respiratory tract.
Sub-Chronic Effects: Significant exposure to this chemical may adversely affect people with chronic disease or may cause
damage to the respiratory system, skin and eyes.
NOTE: Refer to Section 11, Toxicological Information for Details
SECTION IV: FIRST AGE MEASURES
First Aid for Eye Flush eyes with water for 15 minutes, including under eyelids. SEEK MEDICAL ATTENTION
IMMEDIATELY.
First Aid for Skin Remove contaminated clothing and launder before reuse. Wash affected skin areas with soap and
water. SEEK MEDICAL ATTENTION IMMEDIATELY.
First Aid for Inhalation Remove to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped, give
artificial respiration. SEEK MEDICAL ATTENTION IMMEDIATELY..
First Aid for Ingestion If individual is drowsy or unconscious. do not give anything by mouth; place individual on the left
side with the head down. Give 1-3 glasses of water to dilute stomach contents. Call poison Control
Center immediately. If possible, do not leave individual unattended. SEEK MEDICAL ATTENTION
IMMEDIATELY..
MATERIAL SAFETY DATA SHEETS Page 2 of 2
SECTION V: FIRE FIGHTING METHODS
Flash Point (癋/癈) Flammable Limit (vol. %) Auto-ignition Temperature (vol. %)
TAG Closed: 149篎/ ?篊 1.6-8.7 No Data
Method:
Extinguishing Media: Use CO2, dry chemcial for small fires, or alcohol type aqueous film forming foam.
Fire Fighting If potential for exposure to vapors or products of combustion, wear complete personal protective
Instructions: equipment including self contained breathing apparatus, with full face operated in
pressure demand. Fight fire from a safe distance/protected location.
Unusual Hazards: Flammable. When exposed to heat and flame, material is a fire explosion hazard. Vapor is heavier than air
and can travel considerable distance to source of ignition and flash back. Material creates a special hazard if
it floats on water.
SECTION VI: ACCIDENTAL RELEASE MEASURES
Spill or Release Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it, wash spill material
Procedures into retaining containers. Place containers in a well ventilated area. Consult an expert on disposal of
recovered material and ensure conformity to local disposal regulations. Keep unnecessary and
unprotected personnel from entering. Contain and recover liquid when possible. Use non-sparking tools and
equipment. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry
sand, earth), and place in a chemical waste container. Do not use combustible materials, such as sawdust. Do
not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in
excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is
(800) 424-8802. EU Regulations require the consultation of Directive 98/24/EC. If a leak or spill has not
ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills
away from exposures.
SECTION VII: HANDLING AND STORAGE
Handling: Wash hands thoroughly before eating, drinking or smoking. Keep containers cool and dry. Store below
below 120 degrees F in a tightly closed container well ventilated area. Keep away from heat, light and
ignition sources. Avoid breathing high vapor concentrations. Avoid prolonged or repeated contact
with skin. Store out of direct sunlight. Use non-sparking tools. Wash thoroughly after handling.
Storage: Store in tightly closed container in a cool, dry, isolated, well ventilated areaaway from heat, source of
ignition and incomatibles. Store out of direct sunlight. Store in original container. Use only adequate
ventilation. Ground lines and equipment used during transfer to reduce the possibility of static spark-
initiated fire of explosion. Do not eat or drink or smoke in area of use or storage.
SECTION VIII: EXPOSURE CONTROLS / PERSONAL PROTECTIVE EQUIPMENT
Engineering Facilities storing or ultilizing this material should be equipped with an eye facility and safety shower. Use
Controls: process enclosures local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits. Use explosion-proof ventilation equipment.
Personal Protective Equipment
General: To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that a
hazard assessment in accordance with the OSHA PPE Standard (29CFR1910.132), or European Standard
EN166 be conducted before using this product . Provide eye wash stations and safety showers. Wear
impervious clothing to prevent ANY contact with this product, such as gloves, apron, boots, or whole
body suit. Nitrile rubber is better than PVC.
MATERIAL SAFETY DATA SHEETS Page 3 of 3
Eye/ Face Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also
Protection: permit other type of safety glasses.
Skin Protection: Use impermeable clothing to prevent ANY contact with this product, such as gloves, apron, boots, or whole
body suit. Neoprene and Nitrile rubber is better than PVC..
Respiratory A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be
Protection: permissible under certain limited circumstances where airborne concentrations are expected to exceed
exsposure limits. Protection provided by air purifying respirators is limited. Wear a NIOSH/MSHA or
European Standard EN 149 approved full-facepeice airline respirator in the positive pressure mode with
emergency escape provisions. Follow OSHA repsirator regulations found in 29 CFR 1910.134 or Eurpean
Standard EN 149.
SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor & Odor Threshold PH Specific Gravity Viscosity % Volatile
N/DA N/DA N/A (H2O = 1): N/A N/DA
Octanol/Water Solubili
Boiling Point/ Decomposition Partitioning Vapor ty In
Vapor Pressure Evaporation Rate Ignition
Freezing Point Coefficient Water
Temperature Density
Log Po/w (20癈)
N/DA N/DA N/DA N/DA N/DA N/DA N/A N/DA
Flash Point(癋/癈) Flammable Limit (vol. %) Auto-ignition Temperature(vol. %)
LEL: 1.6 % ; UEL: 8.7 %
149癋/? 篊 ?癋/435篊
SECTION X: STABILITY AND REACTIVITY
Stability: Stable Incompatibility (Materials to Avoid):
Oxidizing Agent i.e. Hydrogen peroxide , Nitric Acid ,
Hazardous Decomposition Products: Carbon Monoxide Perchloric Acid, Chromium Trioxide
Conditions to Avoid: Will not occur
Hazardous Polymerization:
Heat, flames, ignition sources, and incompatibles
SECTION XI: TOXICOLOGICAL INFORMATION
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation ?skin Irritation - Eye
No Data No Data No Data No Data
No Data
Sensitization Mutagenicity Sub-chronic Toxicity
No Data No Data No Data
SECTION XII: ECOLOGICAL INFORMATION
Acute Toxicity to Fish Acute Toxicity to Acute Toxicity to Algae Toxicity to Sewage Bacteria
Bioconcentration
Invertebrates
The LC50/96-hour values N/ DA N/ DA N/ DA N/ DA
for fish are over 100 mg/l.
MATERIAL SAFETY DATA SHEETS Page 4 of 4
Chemical Fate Information
When released into the soil, this material is expected to quickly evaporate. When released into the soil, this material
Biodegradability
may leach into groundwater. When released into the soil, this material may biodegrade to a moderate extent. When
released to water, this material is expected to quickly evaporate. When released into the water, this material is
expected to have a half-life between 1 and 10 days. When released into water, this material may biodegrade to a
moderate extent. This material is not expected to significantly bioaccumulate.
N/ DA
Chemical Oxygen Demand
SECTION XIII: DISPOSABLE CONSIDERATION
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual vapors may explode on ignition; do
not cut, drill, or weld on or near the container. Mix with compatible chemical which is less flammable and incinerate.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use
or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal
regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. For EU Member States, please refer to
any relevant Community provisions relating to waste. In their absence, it is useful to remind the user that national or regional provisions may be in force.
SECTION XIV: TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Proper Shipping Name: Methacrylic acid, stabilized, 8, UN2531, PG II
Identification Number: UN2531
Marine Pollutant: No
Special Provisions: IB2, T7, TP1, TP18, TP30
Emergency Response Guidebook (ERG) #: 153P
IATA (DGR):
Proper Shipping Name: Methacrylic acid, stabilized, 8, UN2531, PG II
Class or Division: 8
UN or ID Number: UN2531
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Methacrylic acid, stabilized, 8, UN2531, PG II
Class or Division: 8
UN or ID Number: UN2531
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information:
SECTION XV: REGULATORY INFORMATION
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following HAP's or ODS: ?NONE
Clean Water Act: Priority Pollutant Methacrylic Acid
The following ingredients are listed as hazardous pollutants under the CWA:
None of the ingredients are listed as primary pollutants nor are they listed as toxic pollutants.
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and / or other applications as an
indirect food-packaging additive.
Occupational Safety and Health Act This product is considered to be hazardous under the OSHA Hazard Communication Standard. It's hazards are:
? Immediate (acute) health hazard
? Fire hazard
SARA Title III: Section 302 This product contains no chemicals regulated under Section 302 as extremely hazardous substances.
MATERIAL SAFETY DATA SHEETS Page 5 of 5
SARA Title III: Section 304 This product contains chemicals regulated under Section 304 as extremely hazardous chemicals for emergency
Methacrylic Acid
release notification ("CERCLA" List):
SARA Title III: Section 311-312: This product is considered to be hazardous under the OSHA Hazard Communication Standard and is regulated
under Section 311-312 (40 CFR 370). It's hazards are:
? Immediate (acute) health hazard
? Fire hazard
?br>
SARA Title III: Section 313: Methacrylic Acid
TSCA Section 8(b): Inventory: This product contains chemicals listed on the TSCA inventory or otherwise complies with TSCA
premanufacture notification requirements.
State Regulations
CA Right-to-Know Law: Methacrylic Acid
California No Significant Risk Rule:
MA Right-to-Know Law: Methacrylic Acid
NJ Right-to-Know Law: Methacrylic Acid
PA Right-to-Know Law: Methacrylic Acid
FL Right-to-Know Law: Methacrylic Acid
MN Right-to-Know Law: Methacrylic Acid
International Regulations
CDSL: Canadian Inventory Methacrylic Acid
(on Canadian Transitional List)
EINECS: European Inventory: Nail Primer:
? HAZARD SYMBOLS: Xn, F: Harmful, Highly Flammable
? RISK PHRASES: R11, highly flammable, R20/22: Harmful by inhalation and if swallowed, R36/37/38:
Irritating to eyes, respiratory system and skin
? SAFETY PHRASES: S7/9: keep container tightly closed and in a well ventilated place, S16: keep away
from sources of ignition- no smoking, S24/25: avoid contact with skin and eyes, S33: take
precautionary measures against static discharges, S37/39: wear suitable gloves and eye/face
protection, S45: In case of accident or if you feel unwell, seek medical advise immediately (show the
label where possible)
SECTION XVI: OTHER INFORMATION
Hazard Rating System (Pictograms)
NFPA: HMIS:
3
1
1
3 2
2
The information presented herein was obtained from sources considered to be reliable. However, this information is provided without any warranty,
expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and other reasons, we assume no
responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected with the handling, storage, use or disposal of
the product. This MSDS was prepared expressly for this product. Use the materials only as directed. If the product is used as a component of another
product, the information contained within the MSDS may not be applicable. If one could have any concerns with or problems understanding this MSDS
form, please direct all questions to INFOTRAC, Chemical Emergency Resources System at 1(800) 535-5053.
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