MATERIAL SAFETY DATA SHEET
MSDS # F3
SINCLAIR JET FUELS
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
TRADE NAME: Jet Fuel
APPLICATIONS: Fuel
SYNONYMS: Commercial Jet Fuel, Jet A, Turbine Fuel, Aviation Fuel, JP - 8
CAS REGISTRY #: #50854-94-9, 8008-20-6
CHEMICAL FAMILY: Liquid Hydrocarbon
EMERGENCY PHONE: CHEMTREC 鈥? (800) 424-9300 or (703) 527-3887 (collect)
SUPPLIER: Sinclair Oil Corporation
P.O. Box 30825
Salt Lake City, Utah 84130
TELEPHONE / FAX: (888) 340-3466 / (801) 524-2740
2. COMPOSITION, INFORMATION ON INGREDIENTS
COMPONENTS: CAS# Typical wt.%
Jet Fuel (kerosene) 8008-20-6 100
Jet Fuel 50854-94-9 100
Cyclohexane 110-82-7 3.5
Benzene 71-43-2 0.9
Toluene 108-88-3 0.8
Xylene 1330-20-7 0.9
Naphthalene 91-20-3 0.5
3. HAZARDS IDENTIFICATION
APPEARANCE: Colorless
PHYSICAL STATE: Liquid
ODOR: Kerosene odor
EMERGENCY OVERVIEW: Can cause irritation to the eyes, skin and respiratory tract. Combustible liquid and vapor. Harmful or
fatal if swallowed. May cause lung damage if aspirated. Toxic to aquatic organisms.
POTENTIAL HEALTH EFFECTS: Trauma and burns secondary to explosions and fires can result. In enclosed spaces, oxygen
may be displayed by vapors or consumed by combustion. Incomplete combustion will produce carbon monoxide and other toxic
gases.
INHALATION: Overexposure may cause weakness, headache, nausea, confusion, blurred vision, drowsiness and other central
nervous system effects. Extremely high-level exposure may result in dizziness, irregular heartbeat, coma, collapse and death.
EYE CONTACT: Contact may cause eye irritation. Naphthalene vapor causes eye irritation.
SKIN CONTACT: Contact may irritate or burn skin. Absorption through the skin may cause symptoms of intoxication.
INGESTION: Based on acute toxicity studies in animals, Jet Fuel is practically non-toxic by ingestion. If aspirated (liquid enters
lung) following ingestion, severe lung irritation and pulmonary edema (swelling of lung tissue) may occur. Aspiration may also
result in central nervous system depression or excitement. Serious, permanent lung damage may result. Nausea, vomiting,
diarrhea and abdominal pain may occur following ingestion.
CARCINOGENICITY: Possible cancer hazard.
4. FIRST AID MEASURES
INHALATION: Remove from further exposure. If unconsciousness occurs, seek immediate medical assistance. If breathing stops,
use mouth-to-mouth resuscitation.
EYE CONTACT: Flush immediately with water for at least 15 minutes. Seek medical attention promptly.
SKIN CONTACT: Discard contaminated leather articles.Wash contact areas with soap and water. Launder contaminated clothing
before reuse.
INGESTION: DO NOT INDUCE VOMITING. Get medical assistance promptly. (Note to Physician: Material, if aspirated into
lungs, may cause chemical pneumonitis. Treat appropriately.)
5. FIRE FIGHTING MEASURES
FLASH POINT (掳F): 110潞F - 130潞F (closed cup)
FLAMMABLE LIMITS: LEL 鈥? 0.6 UEL 鈥? 5.6
AUTOIGNITION TEMPERATURE: 440潞F - 560潞F
FLAMMABILTY CLASSIFICATION: Combustible Liquid
GENERAL HAZARD: Incomplete burning can produce carbon monoxide. Vapors will be released above the flash point and when
mixed with air, the mixture can burn or explode in confined spaces, if exposed to sources of ignition.
FIRE FIGHTING INSTRUCTIONS: Use foam, dry chemical, CO2, water fog or vaporizing liquid (Halon). Keep personnel removed
from and upwind of fire. Cool adjacent structures and storage drums with water spray. Prevent runoff from fire control dilution
entering streams or drinking water supply. Run off may create fire and/or explosion hazard in sewers.
FIRE FIGHTING EQUIPMENT: HAZARDOUS COMBUSTION PRODUCTS: Use of SCBA in enclosed or confined spaces, or as
other wise needed (Bunker gear).
Hazardous Decomposition Products: May produce carbon monoxide
6. ACCIDENTAL RELEASE MEASURES
LAND SPILL: Treat spill as an oil spill. Eliminate all sources of ignition. Remove leaking containers to a safe area. Contain and
remove by mechanical means. Guard against contamination of water supplies. Spilled material, made solid by using an inert
substance, may be scraped up from the ground. Report spills to appropriate authorities. Dispose of in accordance with Federal,
State, and Local regulations.
WATER SPILL: Treat spill as an oil spill. Spill may be removed from water with boom and vacuuming equipment. Report spills to
appropriate authorities. Dispose of in accordance with Federal, State, and Local regulations.
7. HANDLING AND STORAGE
HANDLING / STORAGE: Ground and bond all transfer and storage equipment. Drums must be grounded/bonded/equipped with
self-closing valves, pressure vacuum bungs and flame arrestors. Do not use as a cleaner or solvent. Do not siphon by mouth.
Store away from ignition sources in a cool area. Containers should be labeled: FLAMMABLE - VAPOR HARMFUL. When
handling, use non-sparking tools and equipment.
NOTE: Make sure Tanker is grounded before loading.
8. EXPOSURE CONTROLS, RESPIRATORY & PERSONAL PROTECTION
ENGINEERING CONTROLS: Provide ventilation sufficient to prevent exceeding recommended exposure limit or build-up of
explosive concentrations of vapor in air. Use explosion-proof equipment. Use away from all ignition sources.
PERSONAL PROTECTION:
PROTECTIVE CLOTHING: Use full-face shield, chemical goggles, impervious gloves, and boots.
RESPIRATOR: Approved respiratory protection must be used when vapor or mist concentrations are unknown or exceed
the TLV. Avoid prolonged or repeated breathing of vapor or mists.
OCUPATIONAL EXPOSURE LIMITS
COMPONENT LIMIT TWA STEL CEILING NOTATION OTHER
200mg/M3
Jet Fuel (Kerosene) ACGIH_TLV A3 Skin, CNS
Cyclohexane OSHA_PEL 300ppm
Cyclohexane ACGIH_TLV 100ppm CNS
Benzene OSHA_PEL 1ppm 5ppm
Benzene OSHA_Z2 10ppm 25ppm
Benzene ACGIH_TLV 0.5ppm 2.5ppm A1 Skin
Toluene OSHA_PEL 200ppm 300ppm
Toluene ACGIH_TLV 50ppm A4 Skin, CNS
Xylene OSHA_PEL 100ppm
Xylene ACGIH_TLV 100ppm 150ppm A4 Irritation
Naphthalene OSHA_PEL 10ppm
Naphthalene ACGIH_TLV 10ppm 15ppm A4 Skin
A1= Confirmed Human Carcinogen
A3= Confirmed Animal Carcinogen with Unknown Relevance to Humans
A4= Not Classified as a Human Carcinogen
CNS= Central Nervous System
Skin= Absorption through the skin may contribute to overall exposure
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE: Liquid
COLOR: Colorless
DENSITY/SPECIFIC GRAVITY (g/ml): 0.77 鈥? 0.84
VAPOR DENSITY (air=1): 4.5
VAPOR PRESSURE: <1 PSIA
BOILING POINT/RANGE: 360潞F
SOLUBILITY IN WATER: No
VISCOSITY: N/A/F
pH : N/A
FREEZING POINT: -40潞F
10. STABILITY AND REACTIVITY
GENERAL: This product is stable
INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Strong acids, alkalis and oxidizers. Also avoid heat, sparks, flame
and static electricity.
HAZARDOUS DECOMPOSITION: Incomplete burning can produce carbon monoxide.
11. TOXICOLOGICAL INFORMATION
SYSTEMIC: Petroleum-derived fuels and fuel oils are complex and variable mixtures of hydrocarbons. In general, the more
viscous the mixture, the less toxic it will be. At high level exposures, humans experience multiple organ failures, some of which
may be due to hypoxia and secondary to the failure of other organ systems. In humans鈥? kidney failure has been noted only at high,
acute levels of exposures, and appears reversible. Liver enzymes may be transiently elevated. At lower level exposures, most
acute health effects are reversible. Inhalation, ingestion and dermal contact can expose people. Frequently, people are exposed
by combined dermal and inhalation exposure.
ACUTE:
Inhalation: : Headaches, confusion, disorientation, blurred vision occur with inhalation. Higher exposures may cause
hallucinations, CNS excitation, drowsiness, CNS depression. Seizure and coma occur from very high exposures and
death may result from respiratory depression. ECG changes, cardiac arrhythmias, tachycardia, shock and cardiovascular
collapse can occur. Pneumonia, pulmonary edema and hemorrhages can occur.
Coordination and concentration deficits have been reported in humans after one hour of exposure. Fatigue, depressed
mood, lack of initiative and sleep disturbances have been reported in factory workers. Attention and sensorimotor speed
were impaired and EEG changes were noted. Workers may complain of palpitations and heaviness in the chest.
Ingestion: Central nervous system, cardiovascular, and respiratory effects have been reported with acute exposures to
various hydrocarbon fuels and oils similar to those reported with inhalation. Nausea, vomiting, cramping and diarrhea
may occur.
Eye: Conjunctivitis and burning, watery eyes have been reported in acute exposures to various hydrocarbon fuels and
oils.
Skin: Mild erythema to full thickness chemical burns have occurred after prolonged exposure to various hydrocarbon fuels
and oils. High levels of skin exposure resulted in death of animals.
CHRONIC: Chronic exposure results in kidney damage in male rats. However, this damage appears to be related to a protein
produced in large amounts in male rats, but not in humans or female rats. Occupational exposures in petroleum refining are
considered Group 2A (probably carcinogenic) by IARC.
Naphthalene, a component of Jet Fuel, can cause hemolytic anemia, especially in those with a deficiency of Glucose-6 phosphate
dehydrogenase (G6PD). Cataracts and other ocular effects have been reported after oral ingestions.
Contains benzene, which is suspected to cause cancer in humans and also can be toxic to the blood and blood forming organs.
12. DISPOSAL INFORMATION
RCRA: Disposal of this product or material contaminated with this material may be regulated under RCRA due to the characteristic
of ignitability.
EPA Hazard Class: Acute Hazard/Chronic Hazard/Fire Hazard
Dispose of in accordance with Federal, State, and Local regulations.
13. TRANSPORT INFORMATION
DOT (Department of Transportation):
PROPER SHIPPING NAME: Fuel, Aviation, Turbine Engine (Jet-A), JP-8
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN 1863 PG III
NAERG96 NUMBER: 128
14. REGULATORY INFORMATION
CERCLA (Comprehensive Environmental Response Compensation and Liability Act): Naphthalene, Benzene, and Toluene are
hazardous substances under RCRA and therefore are subject to emergency notification requirements.
SARA TITLE III (Superfund Amendments and Reauthorization Act): Naphthalene and Toluene are subject to SARA Title III,
Sections 311 and 312, which require MSDS reporting and Hazardous Chemical Inventory reporting.
Naphthalene and Toluene are also subject to SARA Title III, Section 313, which requires Chemical Release reporting.
The following components are subject to OSHA 29CFR1910.1200 Hazard Communication Standard:
Benzene* 1
Cyclohexane 2
Naphthalene 2
Toluene 2
Xylene 2
(1)* Benzene has been identified by NIOSH, IARC, NTP as a human carcinogen. Refer to 29CFR1910.1000 Table Z-2 and
29CFR1910.1028 for information.
(2) Consult MSDS or NIOSH Occupational Guidelines for more information.
15. OTHER INFORMATION
NFPA 704/HMIS:
Health 鈥? 0 Flammability 鈥? 2 Reactivity 鈥? 0
(0 = insignificant, 1 = slight, 2 = moderate, 3 = high, 4 = extreme)
REVISION SUMMARY:
Complete review of MSDS, December 2005.
THIS PRODUCT MATERIAL SAFETY DATA SHEET PROVIDES HEALTH AND SAFETY INFORMATION. THE
PRODUCT SHOULD BE USED IN APPLICATIONS CONSISTENT WITH THIS PRODUCT LITERATURE. FOR
ANY OTHER USES, EXPOSURES SHOULD BE EVALUATED SO THAT APPROPRIATE HADLING PRACTICES
AND TRAINING PROGRAMS CAN BE ESTABLISHED TO ENSURE SAFE WORKPLACE OPERATIONS.
THIS MATERIAL SAFETY DATA SHEET IS PROVIDED IN GOOD FAITH AND MEETS THE REQUIREMENTS OF
THE HAZARDOUS COMMUNICATION PROVISIONS OF SARA TITLE III AND 29CFR1910.1200(g) OF THE OSHA
REGULATIONS. THE ABOVE INFORMATION IS BASED ON REVIEW OF AVAILABLE INFORMATION
SINCLAIR BELIEVES IS RELIABLE AND IS SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. SINCLAIR
DOES NOT GUARANTEE ITS COMPLETENESS OR ACCURACY. SINCE CONDITIONS OF USE ARE OUTSIDE
THE CONTROL OF SINCLAIR, SINCLAIR DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, AND ANY
LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA. NOTHING
HEREIN IS INTENDED TO PERMIT INFRINGEMENT OF VALID PATENTS AND LICENSES.
DATE: December 2005
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