AQ 191 A
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
SECTION I: PRODUCT INFORMATION
Sikadur庐 32 Hi-Mod
PRODUCT: PART A REVISION DATE: March 28, 2007
USAGE: HIGH-MODULUS, HIGH-STRENGTH, EPOXY BONDING ADHESIVE
MANUFACTURER: SIKA CANADA INC.
601, avenue Delmar
Pointe Claire, QC
H9R 4A9
(514) 697-2610
EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666
TDG CLASSIFICATION: Not Regulated WHMIS Classification: D2B,B3
UN NUMBER: Not Applicable Class: Not Applicable
Packaging Group: Not Applicable
SECTION II: HAZARDOUS INGREDIENTS
Hazardous ingredients % T.L.V. # CAS LD50 (mg/kg) LC50
(species, route) (species, route)
DIGLYCIDYL
60-100 Not Available 25085-99-8 > 5000 (rat, oral) Not Available
BISPHENOL A RESIN
DISTILLATE (PETRO-
LEUM), CATALYTIC
> 2622 (rat, oral)
REFORMER
1-5 Not Available 68477-31-6 Not Available
> 2000 (rabbit,
FRACTIONATOR
skin)
RESIDUE, LOW
BOILING
SECTION III: PHYSICAL CHARACTERISTICS
Physical State: Liquid Boiling Point: Not Established
Appearance and Odor: Amber color with ether odor Freezing Point: Not Established
Density: 1.1 g/ml
Odor Threshold: Not Established Water Solubility: No
Evaporation Rate: Not Applicable pH: Not Applicable
Vapor Density: Not Established % volatility: Not Applicable
Vapor Pressure: Not Established Water/Oil Distribution: Not Established
AQ 191 A
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART A
SECTION IV: FIRE AND EXPLOSION HAZARDS
Flammability: Combustible TDG Flammability Class: Not Regulated
If Yes, under what conditions: Fire, spark Flammable upper limits (% vol.): Not Applicable
Flammable lower limits (% vol.): Not Applicable
Extinguishing methods: Foam, dry chemical Flash Point (method used): 105潞C
products, CO2, water Auto-ignition temperature: Not Established
hose. Dangerous Combustion Products: Carbon oxides,
phenol.
Special Methods: Fire fighters must wear
usual protective clothing Protect from mechanical impact: No
and respiratory
Protect from static discharge: No
equipment. A water hose
may be used to cool the
containers and dissipate
the vapors.
SECTION V: REACTIVITY DATA
Chemical stability: Yes, but Dangerous decomposition products: Phenol, carbon
excessive heat oxides.
will degrade the
resin.
If not, under what conditions: Polymerization Risks: May polymerize
at very high
temperatures.
Incompatibility with other material: Yes
If Yes, which ones: Base, Strong
Acid, and
oxidizer.
AQ 191 A
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART A
SECTION VI: TOXICOLOGICAL PROPERTIES
ROUTE OF ENTRY / CONTACT
Eyes: May cause eye irritations. Carcinogenicity: No
Skin: May be irritating to the skin, may cause Toxic effects
sensitization. on reproduction: No
Inhalation: May irritate lungs, may cause an allergic Teratogenicity: No
reaction.
Mutagenicity: No
Ingestion: May cause irritation of the gastro-
intestinal system.
Product with synergistic
effects: Not Established
Exposure limits:
Diglycidyl bisphenol Not available
A resin:
Distillate (petroleum), Not available
catalytic reformer
fractionator鈥檚 residue,
low boiling
An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems.
AQ 191 A
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART A
SECTION VII: PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT OTHERS
Gloves: Chemical resistant gloves. Ventilation: Sufficient ventilation required
Respiratory equipment: Not necessary under normal use. Procedure in case
of leaks: Absorb with sand or other
Eyes: Safety glasses absorbent material. Residue may
be removed with steam or hot
Shoes: Ordinary water and soap. All precautions
should be taken when cleaning
Clothing: Rubber Apron the spill with solvent.
Other: No Handling and Equipment
Methods: Avoid skin, eye and clothing
contact
Warehouse
Requirements: Keep all containers closed in a
cool, dry area. Keep away from
heat and open flame
.
Special Shipping
Instructions: See TDG class
Waste Disposal: Dispose of sand and rinse water
according to municipal, provincial
or federal laws for disposal of
chemicals.
AQ 191 A
Page 5 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART A
SECTION VIII: FIRST AID
Skin: Remove and clean contaminated clothing.
Wash immediately with plenty of soap and water.
Consult a physician if required.
Eyes: Rinse with water for at least 15 minutes.
Consult a physician immediately.
Inhalation: In the case of overexposure, evacuate to fresh air.
Consult a physician if required.
Ingestion: Drink plenty of water. Do not induce vomiting.
Do not give anything by mouth to an unconscious person.
See a physician immediately.
SECTION IX: PREPARATION INFORMATION
Prepared By : Steve Gosselin
Telephone # : (514) 697-2610
Fax # : (514) 694-2792
Notice To Reader
The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable
as of the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's
current Technical Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone
number listed in Section 1 of this MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE.
SIKA SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE
RESPONSIBLE FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL
PROPERTY RIGHTS HELD BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sikacanada.com or 514-697-2610.
AQ 191 A
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
SECTION I: PRODUCT INFORMATION
Sikadur庐 32 Hi-Mod
PRODUCT: PART B REVISION DATE: March 28, 2007
USAGE: HIGH-MODULUS, HIGH-STRENGTH, EPOXY BONDING ADHESIVE
MANUFACTURER: SIKA CANADA INC.
601, avenue Delmar
Pointe Claire, QC
H9R 4A9
EMERGENCY TELEPHONE NUMBER: CANUTEC (collect) (613) 996-6666
TDG CLASSIFICATION: Paint related liquid WHMIS Classification: D2A, E, B3
UN NUMBER: 3066 Class: 8
Packaging Group: III
SECTION II: HAZARDOUS INGREDIENTS
Hazardous ingredients % T.L.V. # CAS LD50 (mg/kg) LC50
(species, route) (species, route)
OEL RUSSIA STEL 5
4000 mg/m3 rat
BENZYL ALCOHOL 5-10 100-51-6 1230 (oral, rat)
mg/m3, skin
ACGIH LEP-TWA
SILICA SAND 15-40 14808-60-7 Unknown Unknown
0.05 mg/m3
NONYL PHENOL 5-10 Not Available 84852-15-3 580 (oral, rat) Not Available
ACGIH LEP-TWA 10
ppm
NAPHTALENE 1-5 91-20-3 Not Available Not Available
ACGIH LEP-STEL
15 ppm
> 2622 (oral, rat)
PETROLEUM
10-30 Not Available 68477-31-6 Not Available
> 2000 (skin,
DISTILLATE
rabbit)
1635 (oral, rat)
TRI DIMETHYLAMINO > 0.5 mg/L
METHYL PHENOL 2, 4, 1-5 5 ppm, skin. 90-72-2 1350 (skin,
(inh. 4 h, rat)
6 rabbit)
AMINE AND EPOXY
10-30 Not Available Not Available Not Available Not Available
RESIN COPOLYMER
SECTION III: PHYSICAL CHARACTERISTICS
Boiling Point: Not Established
Physical State: Liquid
Freezing Point: Not Established
Appearance and Odor: Amber color with amine odor
Density: 1.5 g/ml
Water Solubility: Partial
Odor Threshold: Not Established
pH: Not Established
Evaporation Rate: Not Applicable
% volatility: 0
Vapor Density: Not Applicable
Water/Oil Distribution: Not Established
Vapor Pressure: Not Applicable
AQ 191 A
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART B
SECTION IV: FIRE AND EXPLOSION HAZARDS
Flammability: Combustible TDG Flammability Class: None
If Yes, under what conditions: Fire, spark. Flammable upper limits (% vol.): Not Established
Flammable lower limits (% vol.): 1.1
105oC
Flash Point (method used):
Extinguishing methods: Foam, dry chemical products, Auto-ignition temperature: Not Established
CO2, water hose. Dangerous Combustion Products: Carbon oxides,
nitrogen oxides,
aldehyde,
ketone.
Special Methods: Fire fighters must wear usual
protective clothing and Protect from mechanical impact: No
respiratory equipment. A
Protect from static discharge: No
water hose may be used to
cool the containers and
dissipate the vapors.
SECTION V: REACTIVITY DATA
Chemical stability: Yes Dangerous decomposition products: Carbon oxides,
If not, under what conditions: nitrogen oxides,
aldehyde,
ketone.
Incompatibility with other material: Yes Polymerization Risks: No
If Yes, which ones: Acid, strong oxidizer,
aldehyde, ketone,
acrylate
AQ 191 A
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART B
SECTION VI: TOXIC PROPERTIES
ROUTE OF ENTRY / CONTACT
Eyes: May cause eye irritations. May cause severe Carcinogenicity: NTP: no. OSHA: no
burns. May cause blindness. According to the IARC the
silica sand is a probable
cause of cancer (D2A).
Skin: May be irritating to the skin, may cause severe
burns, can be absorbed by skin. Contact may
cause necrosis, dermatitis, allergic reactions, Toxic effects
on reproduction: No
and sensitization.
Inhalation: Vapors of this product may cause irritation. Teratogenicity: No
Ingestion: May cause severe burns to the mouth, throat, Mutagenicity: Yes (the in vivo tests
stomach, vomiting, dizziness, diarrhea, proved to be positive)
damages to the lungs, and death.
Product with synergistic
An over-exposure may cause breathing difficulty, vomiting, effects: Not Established
headaches, nausea, damages to the lungs, sensitization and
dizziness. May aggravate skin, eyes, lungs, and respiratory or
allergic problems.
Exposition Limits :
Benzyl Alcohol: OEL Russia: STEL 5 mg/m3, skin
Silica Sand: ACGIH TLV-TWA 0.05 mg/m3
Naphthalene: ACGIH TLV-TWA 10 ppm,
ACGIH TLV-STEL15 ppm
Tri(dimethylaminomethyl)-2,4,6 phenol: 5 ppm, skin
An acute or chronic exposure will increase the toxic effects mentioned in this section and may aggravate respiratory
problems.
AQ 191 A
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART B
SECTION VII: PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENT OTHERS
Gloves: Chemical resistant gloves. Ventilation: Sufficient ventilation required
Respiratory equipment: Not necessary under normal use. Procedure in case
of leaks: Absorb with sand or other
Eyes: Full face mask or safety glasses absorbent material.
Shoes: Leather Handling and Equipment
methods: Avoid skin, eye and clothing
Clothing: Rubber Apron contact
Other: Eye wash station, shower Warehouse
Requirements: Keep all containers closed in a
cool, dry and well ventilated
area. Keep away from heat and
open flame.
Special Shipping
Instructions: See TDG class
Waste Disposal: Dispose of sand and rinse water
according to municipal,
provincial or federal laws for
disposal of chemicals.
AQ 191 A
Page 5 of 5
MATERIAL SAFETY DATA SHEET
Sika Canada Inc. Date: 99/09/30
Appr: S.G.
Sikadur庐 32 Hi-Mod
PRODUCT: PART B
SECTION VIII: FIRST AID
Skin: Remove contaminated clothing and shoes.
Wash immediately with plenty of soap and water.
Throw away shoes that were soiled on the inside.
Wash clothing before re-wearing.
Consult a physician if required.
Eyes: Rinse eyes immediately with plenty of water for several minutes, while holding
eyelids wide open, to ensure a proper wash.
The eye rinse within the first minute is essential to ensure maximum protection.
Consult a physician immediately.
Inhalation: In the case of overexposure, evacuate to fresh air.
Consult a physician if required.
Ingestion: Drink plenty of water. Do not induce vomiting.
Do not give anything by mouth to an unconscious person.
See a physician immediately.
SECTION IX: PREPARATION INFORMATION
Prepared By : Steve Gosselin
Telephone # : (514) 697-2610
Fax # : (514) 694-2792
Notice To Reader
The information contained in this Material Safety Data Sheet applies only to the actual Sika Canada product identified and described herein. This
information is not intended to address, nor does it address the use or application of the identified Sika product in combination with any other material,
product or process. All of the information set forth herein is based on technical data regarding the identified product that Sika believes to be reliable as of
the date hereof. Prior to each use of any Sika product, the user must always read and follow the warnings and instructions on the product's current
Technical Data Sheet, product label and Material Safety Data Sheet for each Sika product, which are available at web site and/or telephone number
listed in Section 1 of this MSDS.
SIKA MAKES NO WARRANTIES EXPRESS OR IMPLIED AND ASSUMES NO LIABILITY ARISING FROM THIS INFORMATION OR ITS USE. SIKA
SHALL NOT BE LIABLE UNDER ANY LEGAL THEORY FOR SPECIAL OR CONSEQUENTIAL DAMAGES AND SHALL NOT BE RESPONSIBLE
FOR THE USE OF THIS PRODUCT IN A MANNER TO INFRINGE ON ANY PATENT OR ANY OTHER INTELLECTUAL PROPERTY RIGHTS HELD
BY OTHERS.
All sales of Sika products are subject to its current terms and conditions of sale available at www.sikacanada.com or 514-697-2610.
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