MATERIAL SAFETY DATA SHEET
Manufacturer's Name: Transportation Emergencies:
NPCA HAZARDOUS MATERIALS IDENTIFICATION
Call Chemtrec SYSTEM
1-800-424-9300
Masterchem庐Industries, Inc. RATING IDENTIFICATION
4=EXTREME HEALTH 2
Emergency Telephone No.
3135 Old Highway M 3=HIGH FLAMMABILITY 3
1-800-325-3552 2=MODERATE REACTIVITY 0
Imperial, MO 63052 1=SLIGHT CHRONIC HEALTH
Medical Emergencies:
Company Code: MTER 0=MINIMAL SEE SECTION V
1-866-303-6951
Issue Date: February 8, 1999
SECTION I 鈥? PRODUCT IDENTIFICATION
Hammerite庐 -Smooth White Quick Dry Metal Finish
PRODUCT NAME:
PRODUCT NUMBER: 46260
PRODUCT CLASS: BRUSH GRADE PAINT
SECTION II A-HAZARDOUS INGREDIENTS
CAS OCCUPATIONAL
VAPOR LISTED AS A
REGISTRY %W CHEMICAL NAME(S) EXPOSURE
PRESSURE CARCINOGEN
NO. LIMITS
TLV PEL
1330-20-7 16.50 Xylene (Mixed Isomers) 100 ppm 100 ppm 9 mm Hg @ 25掳C No
Acetone
67-64-1 4.30 750 ppm 750 ppm 231 mm Hg @ 25掳C No
71-36-3 1.15 N-Butanol 50 ppm 50 ppm 6.3 mm Hg @ 25掳C No
64742-95-6 3.45 C8 to C10 Aromatic Solvent 80 ppm - 8 mm Hg @ 25掳C No
100-41-4 4.13 Ethyl Benzene 125 ppm 5 ppm 2B
10 mm Hg @ 25掳C
SECTION II B - OTHER INGREDIENTS
68783-94-8 45-65 Styreneated Alkyd Copolymer 鈥? 鈥? 鈥? No
13463-67-7 15-25 Titanium Dioxide 鈥? 鈥? 鈥? No
SECTION III - PHYSICAL DATA
APPEARANCE: White, Medium Viscosity Liquid ODOR: Characteristic Aromatic Hydrocarbon
VAPOR DENSITY: 鈱? HEAVIER
BOILING RANGE: 133掳- 344掳 F LIGHTER THAN AIR
FASTER 鈱LOWER THAN ETHER 41.7% VOLATILE VOLUME: 9.74 POUNDS WT/GAL
EVAPORATION RATE:
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLAMMABILITY CLASSIFICATION: OSHA FLASH POINT: Less than LEL: 1.0 DOT: Consumer Commodity ORM-D
1B 50掳F PMCC UEL: 12.8 Limited Quantity
EXTINGUISHING MEDIA:
DRY CHEMICAL 鈱? FOAM 鈱? CO2 鈱?
ALCOHOL FOAM WATER FOG OTHER
UNUSUAL FIRE AND EXPLOSION HAZARDS: Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode
when exposed to extreme heat. During emergency conditions, overexposure to combustion products may cause a health hazard. Symptoms may not be
immediately apparent. Obtain medical attention. Vapors may be ignited by static electricity or friction sparks.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment, including self-contained breathing apparatus, should be used to protect
firefighters from any hazardous combustion products.
SECTION V - HEALTH HAZARD DATA
EFFECTS OF OVEREXPOSURE: Inhalation: Anesthetic, irritation of the respiratory tract or acute nervous system depression characterized by the
following progressive steps; headache, dizziness, staggering gait, confusion, unconsciousness, or coma. Skin or eye contact: Primary irritant.
MEDICAL CONDITIONS PRONE TO AGGRAVATION BY EXPOSURE: Reports have associated repeated and prolonged occupation
overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents
may be harmful or fatal.
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PRIMARY ROUTE(S) OF ENTRY:
DERMAL 鈱? INHALATION 鈱? INGESTION 鈱?
EMERGENCY AND FIRST AID PROCEDURES: Inhalation: Remove to fresh air. If respiration has stopped restore breathing. Treat
symptomatically. Consult a physician. Splash (eyes): Flush immediately with large amounts of water for at least 15 minutes. Take to physician for
medical treatment. Splash (skin); Wash affected areas with soap and water. Remove contaminated clothing. Consult a physician if irritation persists.
Ingestion: Drink 1 or 2 glasses of water to dilute. Do not induce vomiting. Consult physician or poison control center immediately. Treat
symptomatically.
SECTION VI - REACTIVITY DATA
STABLE 鈱?
STABILITY: UNSTABLE
WILL NOT OCCUR 鈱?
HAZARDOUS POLYMERIZATION: MAY OCCUR
HAZARDOUS DECOMPOSITION PRODUCTS: May produce fumes when heated to decomposition, as in welding or fire. Fumes may contain:
carbon monoxide, carbon dioxide, hydrocarbons and other products of combustion.
CONDITIONS TO AVOID: High temperatures or high humidities. Heat, sparks or open flame.
INCOMPATIBILITY: (MATERIALS TO AVOID) Peroxides or strong oxidizing agents.
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Limit spread of spill or leak. Remove all sources of ignition and
ventilate area. Soak up with inert absorbent material. Use non-sparking tools when removing wet absorbent. See Section VIII for required protective
measures. Keep material out of sewers and/or drains.
WASTE DISPOSAL METHOD: Dispose of in accordance with all local, state and federal regulations. Dry paint and empty containers may be
landfilled. Full or partially full containers should be treated as hazardous waste which requires disposal at an approved hazardous waste site or incinerator.
SECTION VIII-SAFE HANDLING AND USE INFORMATION
RESPIRATORY PROTECTION: If you experience eye watering, headaches or dizziness, increase fresh air or wear respiratory protection
(NIOSH/MSHA TC 23C or Equivalent) or leave the area.
VENTILATION: Open doors and windows to provide ventilation of sufficient volume and pattern to keep air contaminant concentrations below
occupational exposure limits as shown in Section II A.
PROTECTIVE GLOVES: Required, rubber or neoprene to prevent skin contact.
EYE PROTECTION: Use safety eyewear including slash guards or side shields.
OTHER PROTECTIVE EQUIPMENT: Wear protective clothing. Remove and wash contaminated clothing before re-use.
HYGIENIC PRACTICES: Wash hands before eating or using the washroom. Smoke in smoking areas only.
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store away from extreme heat, fire, or open flame. Store in accordance with
OSHA 1910.106. Store in well ventilated areas.
OTHER PRECAUTIONS: DO NOT TAKE INTERNALLY. Avoid breathing vapors. Avoid contact with skin and eyes. Store away from any source
of ignition. Keep containers tightly closed and in an upright position to prevent leakage. Do not remove or deface label. Keep out of the reach of
children.
DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy
of this data or the results to be obtained from the use thereof. The product is no more hazardous than its component parts pursuant to 29CFR
1910.1200 (D). The technical information on this MSDS sheet is based upon information submitted by manufacturers and additional
information furnished by distributor's chemical suppliers and manufacturers. Vendor assumes no responsibility for injury to vendee or third
persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally,
vendor assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable
safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.
PREPARED BY: Mr. William R. Benton DATE PREPARED: May 7, 2003
NAME AND TITLE: W.R. Benton, MSDS Coordinator SUPERSEDES: August 15, 2000 S-WHT-B
(Signature Available upon Request)
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