MATERIAL SAFETY DATA SHEET
Page 1 of 6
303-1008
Prepared according to the WHMIS, ANSI, NOHSC, ACC, OSHA & 2001/58/EC standards. Revision 1.1 11/01/06
CHEMICAL RESPONSE CARD:
1. PRODUCT IDENTIFICATION
303 HIGH TECH FABRIC GUARD鈩?
1.1 Product Name:
RESPONSE
TEAM PPE:
See ingredients listed in section 2
1.2 Chemical Name:
None reported by the manufacturer
1.3 Synonyms:
WHMIS:
303 HIGH TECH FABRIC GUARD
1.4 Trade Names:
Water Repellent For Fabrics 3
HEALTH:
1.5 Product Use:
2
303 Products, Inc. FLAMMABILITY:
1.6 Manufacturer's Name:
REACTIVITY: 0
10801 Starwood Drive, Palo Cedro, CA 96073
1.7 Manufacturer鈥檚 Address:
PERSONAL PROTECTION: B
+1 (530) 549-5617
1.8 Business Phone:
CHEMTREC +1 (800) 424-9300 / +1 (703) 527-3887
1.9 Emergency Phone:
2. IDENTIFICATION OF RISKS
Flammable liquid. This product is classified as a hazardous substance and as dangerous
2.1 Hazard Identification:
goods according to the classification criteria of NOHSC and the ADG Code (Australia). In
the event of an exposure or medical inquiry involving this product, please contact a
physician or local poison control center, who may seek advice from CHEMTREC or the U.S.
manufacturer, and show them this Material Safety Data Sheet.
INHALATION: YES SKIN & EYES: YES INGESTION: YES
2.2 Routes of Entry:
EYES: Possible irritation and burning sensation.
2.3 Effects of Exposure:
SKIN: Prolonged or repeated exposure may result in irritation, dermatitis & defatting.
INGESTION: Possible gastrointestinal irritation, nausea, vomiting or diarrhea.
INHALATION: Exposure may cause respiratory tract irritation in some sensitive individuals.
EYES: Irritation and burning sensation.
2.4 Symptoms of Exposure:
SKIN: Possible irritation and dermatitis (rash), characterized by red, dry, itching skin.
INGESTION: Gastrointestinal discomfort, nausea, vomiting, and headache.
INHALATION: Nausea, dizziness, shortness of breath or drunken behavior.
EYES: Irritation and burning sensation.
2.5 Acute Health Effects:
SKIN: Possible irritation and dermatitis (rash).
INGESTION: Possible gastrointestinal irritation, nausea, vomiting or diarrhea.
INHALATION: Exposure may cause respiratory tract irritation in some sensitive individuals.
Chronic exposure may lead to central nervous system complications, blood changes
2.6 Chronic Health Effects:
(aplastic anemia, a rare occurrence that is potentially fatal), and dermatitis. Animal
studies have indicated the potential for liver and kidney damage.
None reported by the manufacturer.
2.7 Target Organs:
None reported by the manufacturer.
2.8 Toxicological Properties:
3. COMPOSITION & INGREDIENTS
EXPOSURE LIMITS IN AIR (mg/m3)
COMPOSITION CAS No. RTECs No. EINECS No. % ACGIH 鈥? ppm OSHA 鈥? ppm OTHERS
TLV STEL PEL STEL IDLH
Petroleum Distillates 64742-48-9 NA 265-150-3 NA NA NA NA NA NA
MATERIAL SAFETY DATA SHEET
Page 2 of 6
303-1008
Prepared according to the WHMIS, ANSI, NOHSC, ACC, OSHA & 2001/58/EC standards. Revision 1.1 11/01/06
4. FIRST AID
EYES: Flush eyes thoroughly with copious amounts of water for at least 20 minutes, holding
4.1 First Aid:
eyelids open to ensure complete flushing. Seek immediate medical attention.
SKIN: Remove contaminated clothing and wash affected areas with soap and water. If
irritation persists, seek prompt medical attention. Launder clothing before reuse.
INGESTION: Do not induce vomiting. Call a physician or poison control center for
assistance & instructions. Seek immediate medical attention. If vomiting occurs
spontaneously, keep victim鈥檚 head lowered (forward) to reduce the risk of aspiration.
INHALATION: Remove victim to fresh air at once. If breathing is difficult, provide
supplemental oxygen. If breathing has stopped, provide artificial respiration. Seek
immediate medical attention. Provide treatment, keeping victim warm & quiet.
Persons with pre-existing skin disorders or eye problems or impaired kidney function may
4.2 Medical Conditions
Aggravated by
be more susceptible to the effects of the substance.
Exposure:
5. FIRE & EXPLOSION HAZARDS
50 掳C (122 掳F) TCC
5.1 Flashpoint & Method:
5.2 Autoignition
NA
Temperature:
Not Determined Not Determined
5.3 Flammability Limits: Lower Explosive Limit (LEL): Upper Explosive Limit (UEL):
5.4 Fire & Explosion
Flammable.
Hazards:
CO2, dry chemical or other appropriate fire extinguishing media,
5.5 Extinguishing Methods:
alcohol foam.
Flammable. Keep containers cool until well after the fire is out. Prevent
5.6 Firefighting Procedures:
runoff from fire control or dilution from entering sewers, drains, drinking
water supply, or any natural waterway. Firefighters should wear full-
face, self-contained breathing apparatus (MSHA/NIOSH approved or
the equivalent) and impervious clothing.
6. SPILLS & LEAKS
Secure spill area, remove or minimize all sources of ignition, and maximize ventilation.
6.1 Spills:
Stop spill or leak at source if safely possible. Deny entry to all unprotected individuals.
Individuals involved in the cleanup must wear appropriate personal protective
equipment. Recover free liquid or cover with inert absorbent material and place into
appropriate container(s) for disposal. If necessary, dike well ahead of the spill to prevent
runoff into drains, sewers or any natural waterway or drinking supply.
7. STORAGE & HANDLING
Use normal hygiene practices. Avoid breathing vapors. Avoid direct skin contact. Wash
7.1 Work & Hygiene
Practices:
hands thoroughly after using this product and before eating, drinking, or smoking. Good
personal hygiene practices, such as washing any skin contact areas and removing
contaminated clothing, are recommended.
Keep away from spark, flame and other sources of ignition. Follow all label instructions.
7.2 Storage & Handling:
Keep container closed when not in use.
Keep this and all chemical out of reach of children.
7.3 Special Precautions:
8. EXPOSURE CONTROL & PERSONAL PROTECTION
8.1 Ventilation &
Explosion-proof local exhaust to maintain exposure limits below those listed in Section 2.
Engineering Controls:
When in enclosed areas or when exposure exceeds limits listed in Section 2, use
8.2 Respiratory Protection:
NIOSH./MSHA approved chemical cartridge respirator with organic vapor (OV) cartridge.
Chemical goggles should be used when handling any chemical product.
8.3 Eye Protection:
Solvent-proof gloves recommended to prevent/reduce exposure.
8.4 Hand Protection:
As required to prevent/reduce exposure.
8.5 Body Protection:
MATERIAL SAFETY DATA SHEET
Page 3 of 6
303-1008
Prepared according to the WHMIS, ANSI, NOHSC, ACC, OSHA & 2001/58/EC standards. Revision 1.1 11/01/06
9. PHYSICAL & CHEMICAL PROPERTIES
0.80 - 0.90
9.1 Density:
鈮? 150 掳C
9.2 Boiling Point:
鈮? 1.0 掳C
9.3 Melting Point:
鈮? 0.1 (water = 1.0)
9.4 Evaporation Rate:
0.5 mm Hg
9.5 Vapor Pressure @ 20掳C:
NA
9.6 Molecular Weight:
Clear to white liquid
9.7 Appearance & Color:
Solvent odor
9.8 Odour Threshold:
Insoluble in water
9.9 Solubility:
NA
9.10 pH:
NA
9.11 Viscosity:
9.12 Coefficient Oil/Water
NA
Distribution:
Vapor Density 5.3 (Air = 1.0)
9.13 Additional Information:
10. STABILITY & REACTIVITY
Stable under normal conditions.
10.1 Stability:
10.2 Decomposition
Heat and carbon oxides (carbon monoxide, carbon dioxide0
Products:
Will not occur.
10.3 Polymerization:
Open flames, sparks, high heat, and close proximity to incompatible substances.
10.4 Conditions to Avoid:
10.5 Incompatible
Strong acids, alkalies or oxidizing agents.
Substances:
11. TOXICOLOGICAL INFORMATION
No general or specific toxicity data has been reported by the manufacturer other than
11.1 Toxicity Data:
the information presented in Section 2. However, good personal hygiene practices, such
as washing any skin contact areas and removing contaminated clothing, are
recommended.
See section 2.5
11.2 Acute Toxicity:
See section 2.6
11.3 Chronic Toxicity:
No. This products contains less than 3% Dimethyl Sulfoxide (DMSO).
11.4 Suspected Carcinogen:
This product is not expected to cause reproductive harm to humans.
11.5 Reproductive Toxicity:
This product is not expected to cause mutagenic effects in humans.
Mutagenicity:
This product is not expected to cause embryotoxic effects in humans.
Embryotoxicity:
This product is not expected to cause teratogenic effects in humans.
Teratogenicity:
This product is not expected to cause reproductive harm in humans.
Reproductive Toxicity:
NA
11.6 Irritancy of Product:
11.7 Biological Exposure
NA
Indices:
11.8 Medical
Treat symptomatically.
Recommendations:
12. ECOLOGICAL INFORMATION
The manufacturer has not reported detailed studies on the environmental fate of the
12.1 Environmental Stability:
material. However, prudent practice would dictate the material not be allowed to enter
the environment.
12.2 Effect on Plants &
The manufacturer has not reported any plant and animal effects.
Animals:
The manufacturer has not reported any aquatic life effects.
12.3 Effect on Aquatic Life:
MATERIAL SAFETY DATA SHEET
Page 4 of 6
303-1008
Prepared according to the WHMIS, ANSI, NOHSC, ACC, OSHA & 2001/58/EC standards. Revision 1.1 11/01/06
13. DISPOSAL CONSIDERATIONS
Dispose of in accordance with federal, state & provincial hazardous waste laws.
13.1 Waste Disposal:
Refer to manufacturer/supplier for information on recovery/recycling. If the material is
13.2 Special Considerations:
unsuitable for recycling or reclamation, enclosed-controlled incineration is
recommended unless otherwise prohibited by local ordinance or other statute.
14. TRANSPORTATION INFORMATION
NOT REGULATED per 49 CFR 搂173.150(f)
14.1 49 CFR (GND):
CONSUMER COMMODITY, 9, ID8000 (鈮? 0.5 L)
14.2 IATA (AIR):
UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, LTD QTY (>0.5 L, 鈮? 5.0 L)
UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III (> 5.0 L)
UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, LTD QTY (鈮? 5.0 L)
14.3 IMDG (OCN):
UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III (> 5.0 L)
MARK PACKAGE 鈥淟IMITED QUANTITY鈥? or 鈥淨UANTIT脡 LIMIT脡E鈥? or
14.4 TDGR (Canada GND):
鈥淟TD QTY鈥? or 鈥淨UANT LT脡E鈥?
UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, ADR, LTD QTY (鈮? 5.0 L)
14.5 ADR/RID (EU):
UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, ADR (> 5.0 L)
UN1268, DESTILADOS DE PETROLEO, N.E.P., 3, III, CANTIDAD LIMITADA (鈮? 5.0 L)
14.6 MEXICO (SCT):
UN1268, DESTILADOS DE PETROLEO, N.E.P., 3, III (> 5.0 L)
15. REGULATORY INFORMATION
15.1 SARA Reporting
This product does not contain any substances subject to SARA reporting requirements.
Requirements:
15.2 SARA Threshold Planning Quantity:
Not applicable.
15.3 TSCA Inventory Status:
All chemical substances of this product are listed on the TSCA inventory or are otherwise exempt from inventory status.
15.4 CERCLA Reportable Quantity (RQ):
Not applicable.
15.5 Other Federal Requirements:
Not applicable.
15.6 Other Regulations
Class B2 Flammable Liquid. This product has been classified according to the hazard
criteria of the CPR and the MSDS contains all of the information required by the CPR.
The components of this product are listed on the DSL/NDSL. None of the
components of this product are listed on the Priorities Substances List.
15.7 State Regulatory Information:
Ingredients in this mixture are not found on any state criteria lists.
15.8 67/548/EEC Requirements:
The primary component of this product is listed in Annex I of EU Directive 67/548/EEC:
Naphtha: (Low-Boiling Point Hydrogen Treated) Flammable, Irritant (F, Xi), R: 10-
36/37/38 - Flammable. Irritating to eyes, respiratory system and skin. S: 2-23-24/25-26-
37/39-51 鈥? Keep out of the reach of children. Do not breathe vapors. Avoid contact
with skin and eyes. In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear suitable gloves and eye/face protection. Use
only in well-ventilated areas.
MATERIAL SAFETY DATA SHEET
Page 5 of 6
303-1008
Prepared according to the WHMIS, ANSI, NOHSC, ACC, OSHA & 2001/58/EC standards. Revision 1.1 11/01/06
16. OTHER INFORMATION
16.1 Other Information:
This product has been classified according to the hazard criteria of the U.S. Occupational Safety & Health
Administration's hazard Communication Standards and Health Canada's Controlled Products Regulations
(CPR) and the MSDS contains all of the information required by the CPR. The components of this product
are listed on the DSL/NDSL. None of the components of this product are listed on the priorities substances
list.
16.2 Terms & Definitions:
See last page of this Material Safety Data Sheet.
16.3 Disclaimer:
This Material Safety Data Sheet complies with U.S. OSHA鈥檚 Hazard Communication Standard, 29 CFR
搂1910.1200 and Health Canada's Workplace Hazardous Materials Information System (WHMIS. To the best
of ShipMate's or 303 Products' knowledge, the information contained herein is reliable and accurate as of
this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any
type, either expressed or implied, are provided. The information contained herein relates only to the
specific product. For additional information regarding use, storage and handling or disposal, contact the
manufacturer.
16.4 Prepared for:
303 Products, Inc.
10801 Starwood Drive
Palo Cedro, CA 96073-0966
Phone: +1 (530) 549-5617
Web: http://www.303products.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Blvd, Suite 201
Torrance, CA 90504
Phone: +1 (310) 370-3600
Fax: +1 (310) 370-5700
E-mail: shipmate@shipmate.com
Web: http://www.shipmate.com/
MATERIAL SAFETY DATA SHEET
Page 5 of 6
303-1008
Prepared according to the WHMIS, ANSI, NOHSC, ACC, OSHA & 2001/58/EC standards. Revision 1.1 11/01/06
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION: NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
CAS No. Chemical Abstract Service Number
FLAMMABILITY LIMITS IN AIR:
EXPOSURE LIMITS IN AIR:
Autoignition Minimum temperature required to initiate combustion
Temperature in air with no other source of ignition
ACGIH American Conference on Governmental Industrial Hygienists
LEL Lower Explosive Limit - lowest percent of vapor in air, by
TLV Threshold Limit Value
volume, that will explode or ignite in the presence of
OSHA U.S. Occupational Safety and Health Administration
an ignition source
PEL Permissible Exposure Limit
UEL Upper Explosive Limit - highest percent of vapor in air,
IDLH Immediately Dangerous to Life and Health
by volume, that will explode or ignite in the presence of
an ignition source
FIRST AID MEASURES:
CPR Cardiopulmonary resuscitation - method in which a person HAZARD RATINGS:
whose heart has stopped receives manual chest
compressions and breathing to circulate blood and provide 0 Minimal Hazard
oxygen to the body. 1 Slight Hazard FLAMMABILITY
REACTIVITY
2 Moderate Hazard
HMIS庐
HAZARDOUS MATERIALS IDENTIFICATION
3 Severe Hazard
SYSTEM: HMIS
4 Extreme Hazard
HEALTH
HEALTH, FLAMMABILITY & REACTIVITY RATINGS: ACD Acidic
ALK Alkaline
0 Minimal Hazard
FLAMMABILITY COR Corrosive
1 Slight Hazard SPECIAL
W Use No Water HEALTH
PRECAUTIONS
2 Moderate Hazard
REACTIVITY OX Oxidizer
3 Severe Hazard
4 Extreme Hazard PERSONAL PROTECTION TOXICOLOGICAL INFORMATION:
NCCHL44T 漏 NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808
PERSONAL PROTECTION RATINGS: LD50 Lethal Dose (solids & liquids) which kills 50% of the
exposed animals s
LC50 Lethal concentration (gases) which kills 50% of the
A G exposed animal
ppm Concentration expressed in parts of material per
B H million parts
TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
C I
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or
TC, TCo, LClo, & LCo toxic effects
D J IARC International Agency for Research on Cancer
NTP National Toxicology Program
E K RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
TLm Median threshold limit
Consult your supervisor or S.O.P. for
F X special handling directions. log KOW or log KOC Coefficient of Oil/Water Distribution
REGULATORY INFORMATION:
WHMIS Canadian Workplace Hazardous Material Information System
Face Shield &
DOT U.S. Department of Transportation
Safety Glasses Splash Goggles Gloves
Eye Protection
TC Transport Canada
EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
Boots Full Suit Dust Respirator
Synthetic Apron NDSL Canadian Non-Domestic Substance List
PSL Canadian Priority Substances List
TSCA U.S. Toxic Substance Control Act
Full Face
Dust & Vapor Airline Hood/Mask
EU European Union (European Union Directive 67/548/EEC)
Vapor Respirator Respirator
Respirator or SCBA
EC INFORMATION:
Note: the dotted circle indicates that this respiratory protective
equipment is required for high concentrations or for large
volume spills or releases of product.
OTHER STANDARD ABBREVIATIONS:
NA Not Available
C E F N O T+ Xi Xn
NR No Results
NE Not Established Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
ND Not Determined
ML Maximum Limit
SCBA Self-Contained Breathing Apparatus
|