Material Safety Data Sheet Page 1 of 5
Material Name: DuraForm AF
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Hazardous Materials
DuraForm庐 AF Identification System
Product/Trade Name:
(HMIS):
Chemical Family: Polyamide/Aluminum Powder Blend
(Degree of hazard: 0 = low, 4 = extreme);
Material for SLS庐 (selective laser sintering) systems
Product Use: Health 1
Flammability 2
Physical Hazards 2
Personal Protection:
Dust mask, skin, eye protection
Manufacturer:
In the U.S./Canada
Manufacturer Contact 3D Systems, Inc.
26081 Avenue Hall
Valencia, CA 91355 U.S.A.
For Information Phone: 970.257.4700 or
Toll-free Phone: 800.793.3669
Emergency 800.424.9300 - Chemtrec
II. COMPOSITION INFORMATION
Component Information/Information on Non-
CAS # Component Percent
Hazardous Components
25038-74-8 Polyamide powder 40-70 This product is considered to be hazardous according to
7429-90-5 Aluminum powder 30-60 29CFR 1910.1200 (Hazard Communication Standard).
III. HAZARDS IDENTIFICATION
Emergency Overview
Product may form explosive dust/air mixtures if high concentration of product dust is suspended in air. Damp air can increase risk of
explosion. This product is irritating to the eyes, respiratory system and skin. Product is harmful when inhaled; it may affect the lungs.
Avoid contact with eyes.
Potential Health Effects:
Eyes: This product causes irritation, redness, swelling and pain. It can cause conjunctivitis with repeated exposure.
Skin: This product can cause irritation to the skin. Symptoms might include reddening, pain and swelling.
Ingestion: Ingestion can cause gastrointestinal irritation, vomiting, diarrhea and/or nausea.
Inhalation: This product is irritating to the respiratory system. Symptoms might include coughing, difficulty breathing and nasal
irritation. This product can cause metal fume fever with resulting flu-like symptoms. Can cause lung damage.
Medical Conditions Aggravated by Exposure
None known.
IV. FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately.
Skin: Wash affected area with mild soap and water. Remove contaminated clothing. If irritation persists, get medical attention.
Wash contaminated clothing before reuse.
Ingestion: If ingested, get immediate medical attention. DO NOT INDUCE VOMITING.
Inhalation: Move affected person to fresh air. Give artificial respiration if not breathing, and get medical attention immediately.
MSDS 鈥? DuraForm AF 鈥? P/N 24127-S02-01鈥? ENGLISH
Material Safety Data Sheet Page 2 of 5
Material Name: DuraForm AF
V. FIRE FIGHTING MEASURES
NFPA Ratings
2
Flash Point: >360 潞F (183 潞C) Method Used: NA 0 = Minimal
1 = Slight
Upper Flammable Limit (UFL): NA Lower Flammable Limit (LFL): NA 1 2 2 = Moderate
Auto Ignition: NA Flammability Classification: NA 3 = Serious
Rate of Burning: NA 4 = Severe
General Fire Hazards: Dusts can form an explosive mixture with air. Damp air and moisture can increase this risk. Product can burn
violently in presence of oxidizing substances and certain metal oxides. Reactions with strong acids and alkalis
can cause release of flammable hydrogen gas.
Hazardous Combustion Products: Thermal decomposition products include oxides of aluminum. Reactions with strong acids and alkalis
cause release of flammable hydrogen gas.
Extinguishing Media: Dry chemical. Do not use water.
Fire Fighting Equipment/Instructions: Wear full protective clothing, including helmet, self-contained positive-pressure or pressure-
demand breathing apparatus, protective clothing and facemask. Do not use water. Do not get water inside container. Move
container from area if it can be done without risk. Do not use foam or halogenated extinguishing media as pressure may cause
dusting. Avoid inhalation of material or combustion by-products. Dust accumulation from this product can present an explosion
hazard in the presence of an ignition source. For additional information, refer to National Fire Protection Association (NFPA)
pamphlet #654, 鈥淧revention of Fire and dust Explosion in the Chemical, Dye, Pharmaceutical and Plastics Industry鈥?.
VI. ACCIDENTAL RELEASE MEASURES
Containment Procedures: Stop the flow of material, if this is without risk. Ventilate contaminated area. Eliminate sources of ignition.
Avoid contact with water. Avoid the generation of dusts during clean-up.
Clean-Up Procedures: Wear appropriate protective equipment and clothing, including a ground strap, during clean-up. Vacuum the
dry powder into a closed container with internally and externally explosion-proof vacuum equipment with
appropriate electrical classification per National Electrical Code, Article 502 or use non-sparking tools. .
Avoid the generation of dusts during clean-up. Avoid contact with water. Place material in an appropriate
container for disposal.
Evacuation Procedures: Keep unnecessary personnel away.
Special Procedures: NA
VII. HANDLING AND STORAGE
Handling Procedures: Avoid dust accumulation of this material to reduce potential explosions hazard. Use non-sparking tools when
opening or closing containers. Use spark-proof, bonded, and grounded conveying and processing equipment to
prevent static charge build-up. Keep this product from heat, sparks, or open flame.
Storage Procedures: Keep this material in a cool, dry, well-ventilated place. Avoid dust accumulation of this material. Eliminate all
sources of ignition. Avoid contact with water or moisture. If possible, store under inert atmosphere. Keep
separate from incompatible materials.
VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
A: General Product Information: Follow all applicable exposure limits.
B: Component Exposure Limits
Aluminum powder (7429-90-5)
3
ACGIH: 10 mg/m TWA (metal dust)
OSHA: 15 mg/m3 TWA (respirable dust)
NIOSH: 10 mg/m3 TWA (respirable dust)
Engineering Controls
Use explosion proof local exhaust ventilation. Ventilation should effectively remove and prevent buildup of any dust generated from the
handling of this product.
MSDS 鈥? DuraForm AF 鈥? P/N 24127-S02-01鈥? ENGLISH
Material Safety Data Sheet Page 3 of 5
Material Name: DuraForm AF
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face: Wear chemical goggles.
Skin: Use impervious gloves and apron.
Respiratory: If ventilation cannot effectively keep dust concentrations below established limits, appropriate NIOSH approved
respiratory protection must be provided.
General: An eye wash fountain is recommended.
IX. PHYSICAL AND CHEMICAL PROPERTIES
Appearance ...................................White powder with mild scent Odor ...........................................Mild
Physical State................................Powder PH..............................................NA
Vapor Pressure .............................< 2 Pa @ 20掳C Vapor Density ............................NA
Boiling Point ..................................>200掳C Melting/Freezing Point ...............NA
Solubility (H2O) .............................insoluble @ 20掳C Bulk Density ...............................0.5- 0.7 g/mL depending on settling
Percent Volatile .............................<1% Molecular Weight .......................NA
X. CHEMICAL STABILITY AND REACTIVITY
Chemical Stability: Dust can react with air and/or water. Reaction can release toxic, flammable, corrosive or explosive gas.
Conditions to Avoid: Avoid dispersion of dust in air. Avoid contact with water. Avoid ignition sources where dust is produced.
Avoid strong acids, oxidizing agents, and other incompatible materials.
Incompatibility: Acids, combustible materials, oxidizing materials, metals, bases, halogens, halocarbons, reducing agents,
alcohols.
Hazardous Decomposition: Oxides of aluminum, hydrocarbon gases, carbon dioxide, carbon monoxide and other toxic fumes can be
released at high temperatures or upon burning.
Hazardous Polymerization: Will not occur.
XI. TOXICOLOGICAL INFORMATION
Acute and Chronic Toxicity
A: General Product Information: Inhalation of aluminum powder can cause metal fume fever, a flu-like illness generally lasting 24
hours or less. It can also damage the lungs.
B: Component Analysis - LD50/LC50: NA
Carcinogenicity
A: General Product Information: None.
B: Component Carcinogenicity: None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP
XII. ECOLOGICAL INFORMATION
Ecotoxicity
A: General Product Information: The ecological assessment of this material is based on an evaluation of its components. This product
is classified as not dangerous to the environment.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity: No ecotoxicity data are available for this product's components.
Environmental Fate: No information available for product.
MSDS 鈥? DuraForm AF 鈥? P/N 24127-S02-01鈥? ENGLISH
Material Safety Data Sheet Page 4 of 5
Material Name: DuraForm AF
XIII. DISPOSAL CONSIDERATIONS
US EPA Waste Number & Descriptions
A: General Product Information: This product has not been classified as a whole. Aluminum powder is classified as follows: D001,
D003.
B: Component Waste Numbers: No EPA Waste Numbers are applicable for this product's components.
Disposal Instructions: Avoid disposal. If possible, completely utilize product. Dispose of unused product in accordance with applicable
federal, state, provincial, or local regulations.
XIV. TRANSPORT INFORMATION
US DOT RID/ADR IMDG IATA IMO Canada TDG
Shipping Name Not Regulated
Hazard Class:
UN Number:
Packing Group:
XV. REGULATORY INFORMATION
US FEDERAL
TSCA:...........................................................................All materials are listed on the TSCA Inventory
SARA 302 EHS List (40 CFR 355 Appendix A): ...........None of the components are listed
SARA 313 (40 CFR 372.65): ........................................Aluminum, dust or fume (7429-90-5) 1.0 % de minimis concentration
CERCLA (40 CFR 302.4): ............................................None of the components are listed
STATE RIGHT-TO-KNOW STATUS
The following components appear on one or more of the following state hazardous substances lists:
Component CA Prop. 65 MA MN NJ PA RI
Aluminum Powder (7429-90-5) Yes Yes Yes Yes Yes Yes
Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component Minimum Concentration
Aluminum Powder (7429-90-5) 1 % (English Item 47, French Item 197)
Component Analysis - Inventory
Component/CAS EC # EEC CAN TSCA NLP
Polyamide powder / 25038-74-8 - No DSL Yes No
Aluminum powder / 7429-90-5 231-072-3 EINECS DSL Yes No
MSDS 鈥? DuraForm AF 鈥? P/N 24127-S02-01鈥? ENGLISH
Material Safety Data Sheet Page 5 of 5
Material Name: DuraForm AF
XVI. ADDITIONAL INFORMATION
MSDS Creation Date: .... January 6, 2005
MSDS Revision #: ......... 1
MSDS Revision Date:.... May 18, 2005
Reason for Revision: ..... update transportation information
For more information: .... www.3dsystems.com
800.793.3669 (Toll-free in the US GMT-07:00; N. America, Mon 鈥? Fri, 6:00 a.m. to 6 p.m.)
970.257.4700 (Outside the U.S. GMT-07:00; N. America, Mon 鈥? Fri, 6:00 a.m. to 6 p.m.)
+49 (0) 6151 357-357 (Europe GMT+01:00; Mon 鈥? Fri, 08:00 a.m. - 17:00 p.m. MEZ)
DISCLAIMER OF LIABILITY: The following supersedes any provision in your company鈥檚 forms, letters, and papers. 3D Systems, Inc. makes no warranty
whether expressed or implied, including warranties of merchantability or of fitness for a particular purpose for this product. No statements or
recommendations contained in the product literature are to be construed as inducements to infringe any relevant patent now or hereafter in existence.
Under no circumstances shall 3D Systems, Inc. be liable for incidental, consequential, or other damages from alleged negligence, breach or warranty,
strict liability or any other theory, arising out of the use or handling of this product. The sole liability of 3D Systems, Inc. for any claims arising out of the
manufacture, use or sale of its products shall be for the buyer鈥檚 purchase price.
漏 Copyright 2005 by 3D Systems, Inc. All rights reserved. Subject to change without notice. DuraForm and SLS are registered trademarks of 3D
Systems, Inc., and the 3D Systems logo is a trademark of 3D Systems, Inc.
Key/Legend
ACGIH = American Conference of Governmental Industrial mg/Kg = milligrams per Kilogram
Hygienists mg/L = milligrams per Liter
CAS = Chemical Abstracts Service mg/m3 = milligrams per Cubic Meter
CERCLA = Comprehensive Environmental Response, MSHA = Mine Safety and Health Administration
Compensation, and Liability Act
NA = Not Applicable or Not Available
CFR = Code of Federal Regulations
NIOSH = National Institute for Occupational Safety and Health
CPR = Controlled Products Regulations
NJTSR = New Jersey Trade Secret Registry
DOT = Department of Transportation
NTP = National Toxicology Program
DSL = Domestic Substances List
OSHA = Occupational Safety and Health Administration
EINECS = European Inventory of Existing Commercial Chemical
SARA = Superfund Amendments and Reauthorization Act
Substances
STEL = Short Term Exposure Limit
EPA = Environmental Protection Agency
TDG = Transport Dangerous Goods
IARC = International Agency for Research on Cancer
TSCA = Toxic Substances Control Act
IATA = International Air Transport Association
WHMIS = Workplace Hazardous Materials Information System.
IDL = Ingredients Disclosure List
MSDS 鈥? DuraForm AF 鈥? P/N 24127-S02-01鈥? ENGLISH
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