MATERIAL SAFETY DATA SHEET
BULK CLEANERS-SOLVENT BASED
6/20/05
PRODUCTS COVERED: BN-CQ, BP-C, BS-A, BS-H, BS-X, ZBP-X (On Label, BP-X in catalog)
SECTION I MANUFACTURER
Crest Industries, Inc., 1337 King Road, Trenton, MI 48183 Phone: (734) 479-4141 FAX: (734) 479-4040
24 HOUR EMERGENCY TELEPHONE (CHEMTEL): (800) 255-3924 INTERNATIONAL CALLS: (813) 248-0585
SECTION II PRODUCTS
Stock Numbers of Ingredi- HMIS RATING Solubility Volatile
Number Product Name on Label ents in Products HFR Appearance and Odor % in Water Volume %
BN-CQ Non-Chlorinated Brake Kleaner-
Quick Drying 4, 6 330 Clear liq., mild solvent <1 100
BP-C PrimaClean 6 330 Clear liq., alcohol odor 100 100
BS-A Acry-Solv Solvent Cleaner 2,8,9 230 Clear liquid, mild solvent <1 100
BS-H Hi-Solv Super Strength
Solvent Cleaner 2,6,8,9 330 Clear liq., mild solvent 10 to 12 100
BS-X Super-Solv Extra Strength
Solvent Cleaner 2,6,8,9 330 Clear liq., alcohol odor 19 to 21 100
ZBP-X Prep-Flex 1,3,5,7 330 Clear liq., strong solvent <1 100
SECTION III HAZARDOUS INGREDIENTS
Exposure Limits* Flash Vapor Pres- Evap. Rate Boiling Flammable Autoig-
in ppm (parts Point sure (mm Hg (n-Butyl Point Limits in % nition Pt.
Ingredients CAS Number per million) F C at 20 C) Acetate=1) F C Lower Upper F C
1. Ethylene Glycol
Monobutyl Ether 111-76-2 25 A, O (skin) 165 74 0.9 0.1 340 171 -NA- -NA-
2. Ethyl Benzene 100-41-4 100 A 59 15 7 0.5 277 136 1.0 6.7 810 432
3. Ethylene Glycol Mono-
propyl Ether 2807-30-9 Not Established 120 49 1.0 0.2 301 149 Unknown Unknown
4. Hexsolv (Light Petro-
leum Distillate) 64741-84-0 50 A, 500 O -6 -21 106 8.8 148 64 1.0 7.0 433 223
5. Isobutanol 78-83-1 50 A, 100 O 85 29 8.8 0.6 227 108 1.7 11.0 800 427
6. Isopropyl Alcohol 67-63-0 400 A, O 53 12 31 1.7 180 82 2.0 12.0 750 399
7. Toluene 108-88-3 50 A Skin, 200 O 45 7 38 1.5 230 110 1.2 7.0 896 480
8. VM&P Naphtha 8032-32-4 300 A 40 4 45 2.0 235 113 0.9 7.0 480 249
9. Xylene (Mixed Isomers) 1330-20-7 100 A, O 80 27 10 0.8 281 138 1.0 6.4 810 432
*A means ACGIH TLV, O means OSHA PEL. Other abbreviations: > means greater than, < means less than, NA means Not Applicable.
**See NOTE in SECTION VI.
SECTION IV PHYSICAL DATA NOTE: Prolonged and/or repeated overexposure to 4. Hexsolv
Evaporation Rate: See SECTIONS II, III Vapor Density: Heavier than (containing n-Hexane) may cause Peripheral Neuropathy (damage
air Solubility in Water (Wt%): See SECTION II Volatile Volume %: to nerve tissue of the arms or legs) resulting in muscular weak-
See SECTION II Approximate Boiling Point: See SECTIONS II, III ness and loss of sensation in some or all of the following: fingers,
Product Density (water=1): All less than. hands, arms, toes, feet or legs.
Appearance and Odor: See SECTION II NOTE: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRAT-
SECTION V FIRE AND EXPLOSION DATA ING AND INHALING ANY SOLVENT VAPORS MAY BE HARMFUL
Flammability Class: Extremely Flammable: BN-CQ OR FATAL!
Flammable: BP-C, BS-A, BS-H, BS-X, ZBP-X. SKIN CONTACT:
Flash Point (Tag Closed Cup Method): See SECTIONS II, III Acute Exposure: Repeated or prolonged skin contact with cleaners
Approximate Flammable Limits: See SECTIONS II, III can result in dry, defatted and cracked skin causing increased suscepti-
Autoignition Temperature: See SECTIONS II, III bility to infection. Skin irritation may develop into contact dermatitis.
Extinguishing Media: Foam, carbon dioxide, dry chemical Chronic Exposure: Exposure to small amounts of cleaners over long
Special Fire Fighting Procedures: Full protective equipment, including periods of time may cause some or all of the symptoms as in acute expo-
self-contained breathing apparatus, is recommended because highly sure to cleaners.
toxic gasses may be generated by combustion or thermal decomposition. EYE CONTACT:
Water from fog nozzles may be used to cool closed containers to prevent Acute Exposure: Irritation of the eyes with itching, burning, redness
pressure build up (containers may leak or burst when heated). and even permanent tissue damage if gotten directly into the eyes and
Unusual Fire and Explosion Hazards: Vapors are heavier than air and not flushed out immediately.
may travel along the ground or be moved by ventilation and ignited by Chronic Exposure: Irritation of the eyes with itching, burning, red-
pilot lights, other flames, sparks, heaters, electric motors, smoking or ness.
other ignition sources at locations far from material handling point. At INGESTION:
elevated temperatures [130 F (54 C) or over] containers may vent, rup- Acute Exposure: Irritation to the mouth, and if swallowed, to the
ture or burst. esophagus, stomach tissue and digestive tract. If swallowed, vomiting
SECTION VI HEALTH HAZARD DATA may cause breathing of liquid solvent resulting in chemical pneumonia.
PRIMARY ROUTES OF EXPOSURE: Inhalation, Skin contact, Eye Chronic Exposure: Unknown.
contact. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None
SIGNS AND SYMPTOMS OF EXPOSURE: specifically known to Crest Industries, Inc. but it is possible that eye, res-
INHALATION: piratory tract, skin, liver, kidney, blood cell formation, nervous system and
Acute Exposure: Solvent vapors at concentrations above the TLV brain diseases may be aggravated by overexposure to the products on
can irritate the respiratory tract (nose, throat, lungs) causing a burning this MSDS.
sensation, runny nose, sore throat, coughing, chest discomfort (tight- SECTION VII EMERGENCY AND
ness). May cause central nervous system depression with the following FIRST AID PROCEDURES
progressive symptoms: headache, dizziness, nausea, staggering gait, INHALATION: Move to an area free from risk of further exposure. Ad-
confusion, unconsciousness, cessation of breathing and death. minister oxygen or artificial respiration as needed. Obtain medical atten-
tion.
Chronic Exposure: Reports have associated repeated and
EYE CONTACT: Flush with clean, lukewarm water (low pressure) for at
prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Symptoms include: loss of memory, loss of least 15 minutes while lifting eyelids. Refer person to physician for imme-
diate attention.
intellectual ability and loss of coordination.
BULK CLEANERS SOLVENT BASED 6/20/05 page 2
SKIN CONTACT: Remove contaminated clothing immediately. SECTION IX REACTIVITY DATA
Wash affected areas thoroughly with soap and water. Wash contami- STABILITY: Stable under normal room conditions.
nated clothing thoroughly before reuse. Seek medical attention if irritation HAZARDOUS POLYMERIZATION: Will not occur.
develops or persists. INCOMPATIBILITY (Materials to Avoid): Strong oxidizers.
INGESTION: DO NOT INDUCE VOMITING! Consult physician, hospi- HAZARDOUS DECOMPOSITION PRODUCTS: By high heat and fire:
tal emergency room or poison control center immediately. Have list of carbon dioxide, carbon monoxide, hydrocarbon fumes, smoke.
ingredients available. SECTION X SPILL OR LEAK PROCEDURES
NOTES TO PHYSICIAN: STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR
Inhalation: Treat as for solvent vapor inhalation. Bronchodilators, ex- SPILLED: Put on protective equipment including respiratory protection.
pectorants and antitussives may help. Prevent further spillage. Evacuate nonessential personnel. Remove all
Eyes: May cause conjunctivitis. Stain for evidence of corneal injury. sources of ignition and ventilate the area. Keep spill from reaching sew-
Skin: Treat as any contact dermatitis. ers and waterways. Cover the spill with sawdust, vermiculite, Fuller's
Ingestion: Treat as for solvent ingestion. Inducing vomiting is contra- Earth or other absorbent material. Collect material with non-sparking
indicated because of the possibility of chemical pneumonia caused by tools and put in a tightly sealed container. Remove container to a safe
aspiration of solvent liquid. place.
SECTION VIII EMPLOYEE PROTECTION WASTE DISPOSAL METHOD: Follow all federal, state and local envi-
RECOMMENDATIONS ronmental control regulations. Incineration of the liquid material is the
EYE PROTECTION: Wear safety glasses, splash goggles or face preferred method.
shield. Contact lenses should not be worn. RCRA STATUS: Since these products are ignitable and toxic, they are
SKIN PROTECTION: Cover as much of the skin as possible with ap- hazardous when discarded.
propriate clothing. Wear solvent resistant gloves. SECTION XI SPECIAL PRECAUTIONS &
VENTILATION AND RESPIRATORY PROTECTION: If exhaust venti- STORAGE DATA
lation sufficient to keep the airborne concentrations of solvents below STORAGE TEMPERATURE
their respective TLV's is not possible, an OSHA/MSHA approved TC23C MINIMUM / MAXIMUM: 50 F (10 C) / 120 F (49 C)
Respirator or TC19C Air Supplied Respirator must be used. Observe RECOMMENDED SHELF LIFE: One year
OSHA regulations (29 CFR 1910.134) for respirator use. NOTE: THERE PRECAUTIONS TO BE TAKEN IN HANDLING, STORAGE AND
MUST ALWAYS BE ENOUGH VENTILATION TO KEEP VAPOR USE: Keep away from heat, sparks and open flame. Do not store in
CONCENTRATION BELOW THE LOWER FLAMMABLE LIMIT! temperatures above 120 F (49 C) or in direct sunlight. Do not inhale
OTHER PROTECTIVE MEASURES: Eyewash stations should be vapors. Avoid contact with skin and eyes. Wash hands after use and
available. Educate and train employees in safe use of products. Follow all before eating, drinking, smoking or using the toilet. Employee education
label instructions. and training in the safe use and handling of these materials are required
under the OSHA Hazard Communication Standard (29 CFR
1910.1200).
KEEP OUT OF THE REACH OF CHILDREN!
SECTION XII FEDERAL EPA REGULATION COMPLIANCE INFORMATION EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT of 1986
1) Section 313 Supplier Notifi- HAZARDOUS INGREDIENTS IN BULK CLEANERS-SOLVENT BASED
cation: Chemicals marked with APPROXIMATE PERCENTAGES BY WEIGHT
an * in the following tables are Ingredients (Chemicals) CAS Number BN-CQ BPC BSA BSH BSX ZBPX
subject to the Toxic Chemical 1. Ethylene Glycol Monobutyl Ether 111-76-2 >1
Release Inventory Reporting *2. Ethyl Benzene 100-41-4 06 05 04
Requirements using EPA FORM 3. Ethylene Glycol Monopropyl Ether 2807-30-9 >1
R (40 CFR Part 372). 4. Hexsolv 64741-84-0 82
2) Section 312: All the chemi- 5. Isobutanol 78-83-1 >1
cals listed are subject to Emer- 6. Isopropyl Alcohol 67-63-0 18 100 11 20
gency and Hazardous Chemical *7. Toluene 108-88-3 >1
Inventory Forms and Community 8. VM&P Naphtha 8032-32-4 67 61 56
Right-to-Know Reporting Re- *9. Xylene (Mixed Isomers) 1330-20-7 27 23 20
quirements: Tier I and Tier II Re- Physical Hazard-Fire 100 100 100 100 100 100
ports (40 CFR Part 370). Physical Hazard-Pressure Release NOT A HAZARD
NOTE: This information must be Health Hazard-Acute ALL ARE 100%
included in all MSDSs that are Health Hazard-Chronic ALL ARE 100%
copied and distributed for prod- Physical Hazard-Reactivity NOT A HAZARD
ucts covered by this MSDS.
SECTION XIII VOLATILE ORGANIC COMPOUND known to the state of California to cause cancer, birth defects or repro-
(V. O. C.) CONTENT ACCORDING TO THE ductive toxicity without first giving clear and reasonable warning to such
FEDERAL EPA individuals of such an exposure". The following warning applies for the
BN-CQ BP-C BS-A BS-H BS-X ZBP-X Toluene containing products: BSA, BSH, BSX, and ZBPX
Percent by Weight 100 100 100 100 100 100 WARNING: These products contain a chemical known to the state of
Pounds per Gallon 5.8 6.6 6.5 6.5 6.5 7.2 California to cause birth defects and other reproductive harm. NOTE:
Grams per Liter 695 791 779 779 779 863 BSA, BSH and BSX contain only trace amounts of Toluene (less than
SECTION XIV CALIFORNIA PROPOSITION 65 1%) but it is enough to require the warning.
WARNINGS SECTION XV OZONE DEPLETION IN THE
According to the California Safe Drinking Water and Toxic Enforcement UPPER ATMOSPHERE
Act (PROPOSITION 65) "No person in the course of doing business No ozone depleting chemicals are present in these products.
shall knowingly and intentionally expose any individual to a chemical
DISCLAIMER: The information contained in this MSDS is believed to be accurate and reliable as of the date indicated. Crest Indus-
tries, Inc. assumes no legal responsibility and makes no representation, warranty or guarantee, expressed or implied, as to the com-
pleteness or accuracy of the information. It is offered solely for your consideration, investigation and verification. The user is ultimately
responsible for the safe use of the material in accordance with applicable federal, state, provincial and local laws and regulations.
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