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MSDS Material Safety Data Sheet
CAS

8042-47-5
59-02-9

File Name: 8042-47-5.asp

Commercial Food Equipment Service Association                                                  P_0000316436        D_0000342590




Duopac庐 Oil 90
Material Safety Data Sheet
Lyondell Lubricants
MSDS No. 669340003
12000 Lawndale Avenue
Hazard Rankings
P.O. Box 2451
Revision Date 10/16/2001
Houston, TX 77252-2451
HMIS NFPA
IMPORTANT: Read this MSDS before handling or disposing of this product and pass this information on to Health Hazard 0 0
employees, customers and users of this product.
Fire Hazard 1 1
Emergency Overview Reactivity 0 0
Physical State Liquid.
* = Chronic Health Hazard
Color Odor
Colorless. Odorless.
Not expected to present a hazard under anticipated conditions of use. Protective Equipment
If liquid material is swallowed, contact a physician.
Do not induce vomiting. Minimum Requirements
See Section 8 for Details
If liquid material enters the lungs, it can cause severe damage.
Spills may create a slipping hazard.




SECTION 1: IDENTIFICATION

Trade Name Technical Contact
Duopac庐 Oil 90 (918) 495-5933

Product Number (918) 495-4700
669340003 Medical Emergency
CAS Number CHEMTREC Emergency
8042-47-5 (800) 424-9300
(United States Only)

Product Family White Mineral Oil
Synonyms Technical-grade White Oil;
High-quality Packaging Oil;
Former Lyondell Lubricants Product Code: 16394;
CITGO SAP Product Code No.: 669340003


SECTION 2: COMPOSITION
Concentration (%)
Component Name(s) CAS Registry No.
1) White Mineral Oil 8042-47-5 100
2) di a tocopherol (Vitamin E) (Stabilizer) 59-02-9 <0.1


SECTION 3: HAZARDS IDENTIFICATION
Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS.

Major Route(s) of Entry Not applicable.
Signs and Symptoms of Acute Exposure

Inhalation No significant adverse health effects are expected to occur upon short-term exposure.
Eye Contact Minimal eye irritation may result from short-term contact with liquid, mist, and/or vapor.
Skin Contact No significant irritation is expected to occur upon short-term exposure.

MSDS No. Revision Date
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Duopac庐 Oil 90

Ingestion If swallowed, no significant adverse health effects are anticipated. Ingestion can cause a laxative effect. If
liquid material enters into the lungs, it can cause severe damage.
Chronic Health Effects No significant signs or symptoms indicative of any adverse health effects are expected to occur.
Summary
Conditions Aggravated None known.
by Exposure

Target Organs No target organ effects are anticipated.

Carcinogenic Potential This product does not contain any components at concentrations above 0.1% which are considered
carcinogenic by OSHA, IARC or NTP.
OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present, the product does not exhibit the
hazard as defined in the OSHA Hazard Communication Standard (29 CFR 1910.1200).

OSHA Health Hazard Classification OSHA Physical Hazard Classification

Explosive Pyrophoric
Irritant Toxic Combustible

Oxidizer Water-reactive
Sensitizer Highly Toxic Flammable

Carcinogenic Organic Peroxide Unstable
Corrosive Compressed Gas



SECTION 4: FIRST AID MEASURES
Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific
information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS.
Inhalation Vaporization is not expected at ambient temperatures. This material is not expected to cause
inhalation-related disorders under anticipated conditions of use. In case of overexposure, move the
person to fresh air.
Eye Contact Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water while
occasionally lifting and lowering eyelids. Seek medical attention if excessive tearing, redness, or pain
persists.
Skin Contact Remove contaminated shoes and clothing. Wipe off excess material. Wash exposed skin with mild
soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists.
Thoroughly clean contaminated clothing before reuse. Discard contaminated leather goods. If material
is injected under the skin, seek medical attention immediately.
Ingestion Do not induce vomiting. If spontaneous vomiting is about to occur, place victim鈥檚 head below knees. If
victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth
to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention
immediately.
Notes to Physician This material presents a significant aspiration hazard. Aspiration may produce chemical pneumonitis.
Induction of emesis is not recommended because of the potential for aspiration. Treatment may involve
careful gastric lavage if performed soon after ingestion or in patients who are comatose or at risk of
convulsing. Protect airway by placement in Trendelenburg and left lateral decubitus position or by
cuffed endotracheal intubation. Subcutaneous or intramuscular injection requires prompt surgical
debridement.


SECTION 5: FIRE FIGHTING MEASURES
NFPA Flammability NFPA Class-IIIB combustible material. Slightly combustible!
Classification
Flash Point Method OPEN CUP: >177掳C (>351掳F) (Cleveland.).
Lower Flammable Limit Upper Flammable Limit
No data. No data.
Autoignition Temperature Not available.



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Duopac庐 Oil 90

Hazardous Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and trace oxides of sulfur
Combustion Products and/or nitrogen.
Special Properties This material can burn but will not readily ignite. This material will release vapors when heated above
the flash point temperature that can ignite when exposed to a source of ignition. In enclosed spaces,
heated vapor can ignite with explosive force. Mists or sprays may burn at temperatures below the flash
point.
Use dry chemical, foam, Carbon Dioxide or water fog.
Extinguishing Media

Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained
breathing apparatus to protect against potential hazardous combustion or decomposition products and
oxygen deficiencies.


SECTION 6: ACCIDENTAL RELEASE MEASURES
Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific
information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal
Considerations in Section 13 of this MSDS.
Do not touch damaged containers or spilled material unless wearing appropriate protective equipment.
Slipping hazard; do not walk through spilled material. Stop leak if you can do so without risk. For small
spills, absorb or cover with dry earth, sand, or other inert non-combustible absorbent material and place
into waste containers for later disposal. Contain large spills to maximize product recovery or disposal.
Prevent entry into waterways or sewers. In urban area, cleanup spill as soon as possible. In natural
environments, seek cleanup advice from specialists to minimize physical habitat damage. This material
will float on water. Absorbent pads and similar materials can be used. Comply with all laws and
regulations.


SECTION 7: HANDLING AND STORAGE
Handling Avoid water contamination and extreme temperatures to minimize product degradation. Empty
containers may contain product residues that can ignite with explosive force. Do not pressurize, cut,
weld, braze solder, drill, grind or expose containers to flames, sparks, heat or other potential ignition
sources. Consult appropriate federal, state and local authorities before reusing, reconditioning,
reclaiming, recycling or disposing of empty containers and/or waste residues of this product.
Storage Keep container closed. Do not store with strong oxidizing agents. Do not store at temperatures above
120掳 F or in direct sunlight for extended periods of time. Consult appropriate federal, state and local
authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or
waste residues of this product.


SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of mists
and/or vapors below the recommended exposure limits (see below). An eye wash station and safety
shower should be located near the work-station.
Personal Protective Personal protective equipment should be selected based upon the conditions under which this material
Equipment is used. A hazard assessment of the work area for PPE requirements should be conducted by a
qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum
requirements for personal protective equipment. For certain operations, additional PPE may be
required.




Safety glasses equipped with side shields should be adequate protection under most conditions of use.
Eye Protection
Wear goggles and/or face shield if splashing or spraying is anticipated. Wear goggles and face shield if
material is heated above 125掳F (51掳C). Have suitable eye wash water available.


MSDS No. Revision Date
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Duopac庐 Oil 90

Use gloves constructed of chemical resistant materials such as neoprene or heavy nitrile rubber if
Hand Protection
frequent or prolonged contact is expected. Use heat-protective gloves when handling product at
elevated temperatures.
Use clean and impervious protective clothing (e.g., neoprene or Tyvek庐) if splashing or spraying
Body Protection
conditions are present. Protective clothing may include long-sleeve outer garment, apron, or lab coat.
If significant contact occurs, remove oil-contaminated clothing as soon as possible and promptly
shower. Launder contaminated before reuse or discard. Wear heat protective boots and protective
clothing when handling material at elevated temperatures.
Vaporization is not expected at ambient temperatures. Therefore, the need for respiratory protection is
Respiratory Protection
not anticipated under normal use conditions and with adequate ventilation. If elevated airborne
concentrations above applicable workplace exposure levels are anticipated, a NIOSH-approved organic
vapor respirator equipped with a dust/mist prefilter should be used. Protection factors vary depending
upon the type of respirator used. Respirators should be used in accordance with OSHA requirements
(29 CFR 1910.134).
General Comments Use good personal hygiene practices. Wash hands and other exposed skin areas with plenty of mild
soap and water before eating, drinking, smoking, use of toilet facilities, or leaving work. DO NOT use
gasoline, kerosene, solvents, or harsh abrasive skin cleaners. Since specific exposure
standards/control limits have not been established for this product, the "Oil Mist, Mineral" exposure
limits shown below are suggested as minimum control guidelines.
Occupational Exposure Guidelines

Substance Applicable Workplace Exposure Levels
ACGIH (United States).
1) Oil Mist, Mineral
TWA: 5 mg/m3
STEL: 10 mg/m3
OSHA (United States).
TWA: 5 mg/m3


SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Color Colorless. Odor Odorless.
Physical State Liquid.
Vapor >1 (Air = 1)
Specific Gravity 0.85 (Water = 1) pH Not applicable.
Density
Melting/Freezing Not available.
Not available.
Boiling Point/Range
Point
Vapor Pressure Viscosity (cSt @ 40掳C) 16
<0.01 kPa (<0.1 mmHg) (at 20掳C)

Solubility in Water Volatile
Insoluble in cold water. Negligible volatility
Characteristics
Additional Properties Gravity, 潞API (ASTM D287) = AP 32.9 @ 60潞 F
Density = AP 7.17 Lbs/gal.
Viscosity (ASTM D2161) = AP 90 SUS @ 100潞 F


SECTION 10: STABILITY AND REACTIVITY
Hazardous Polymerization Not expected to occur.
Chemical Stability Stable.

Conditions to Avoid Keep away from extreme heat, sparks, open flame, and strongly oxidizing conditions.

Materials Incompatibility Strong oxidizers.

Hazardous No additional hazardous decomposition products were identified other than the combustion products
Decomposition Products identified in Section 5 of this MSDS.




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Duopac庐 Oil 90



SECTION 11: TOXICOLOGICAL INFORMATION
For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this
MSDS.
Toxicity Data White Mineral Oil:
ORAL (LD50): Acute: >5000 mg/kg [Rat].
DERMAL (LD50): Acute: >2000 mg/kg [Rabbit].
White Mineral Oil:
Low-viscosity and High-viscosity White Mineral Oils:
ORAL (LD50), Acute: >5000 mg/kg [Rat].
DERMAL (LD50), Acute: >2000 mg/kg [Rabbit].
DRAIZE EYE, Acute: Non-irritating [Rabbit].
DRAIZE DERMAL, Acute: Non-irritating [Rabbit].
BUEHLER, Acute: Non-sensitizing [Guinea Pig].
28-Day DERMAL, Sub-Chronic: Non-irritating [Rabbit].
104-Week DERMAL, Chronic: No skin tumors at site of application [Mouse].
MUTAGENICITY:
Modified Ames Assay: Negative [Salmonella typhimurium].
in-vitro Lymphoma Assay: Negative or no toxicity [Mouse].

Lifetime mouse skin painting studies indicated that white mineral oils are not mutagenic or
carcinogenic. Mineral oil mists derived from highly refined oils are reported to have low acute and
sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high
concentrations of mineral oil mists well above applicable workplace exposure levels include lung
inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute
studies involving exposures to lower concentrations of mineral oil mists at or near current work place
exposure levels produced no significant toxicological effects. In long term studies (up to two years) no
carcinogenic effects have been reported in any animal species tested.


SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity Analysis for ecological effects has not been conducted on this product. However, if spilled, this product
and any contaminated soil or water may be harmful to human, animal, and aquatic life. Also, the
coating action associated with petroleum and petroleum products can be harmful or fatal to aquatic life
and waterfowl.
Environmental Fate An environmental fate analysis has not been conducted on this specific product. Plants and animals
may experience harmful or fatal effects when coated with petroleum-based products. Petroleum-based
(mineral) lube oils will normally float on water. In stagnant or slow-flowing waterways, an oil layer can
cover a large surface area. As a result, this oil layer might limit or eliminate natural atmospheric oxygen
transport into the water. With time, if not removed, oxygen depletion in the waterway might be enough
to cause a fish kill or create an anaerobic environment.




SECTION 13: DISPOSAL CONSIDERATIONS
Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility
of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and
residues at the time of disposition.
Conditions of use may cause this material to become a "hazardous waste", as defined by federal or
state regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous
waste" at the time of disposal. Transportation, treatment, storage and disposal of waste material must
be conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State
and/or local regulations may be more restrictive. Contact the RCRA/Superfund Hotline at (800)
424-9346 or your regional US EPA office for guidance concerning case specfic disposal issues.




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Duopac庐 Oil 90



SECTION 14: TRANSPORT INFORMATION
DOT Status Not a U.S. Department of Transportation regulated material.
Proper Shipping Name Not regulated.
Hazard Class Not regulated. Packing Group(s) Not applicable.
UN/NA ID Not regulated.
Reportable Quantity A Reportable Quantity (RQ) has not been established for this material.
Emergency Response Guide Not applicable.
Placards No.
HAZMAT STCC No. Not assigned.

MARPOL III Status Not a DOT "Marine Pollutant"
per 49 CFR 171.8.




SECTION 15: REGULATORY INFORMATION
TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory.
SARA 302/304 The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to
Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning
Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4
and 40 CFR 355. No components were identified.
SARA 311/312 The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to this
subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40 CFR 370.2. This
material would be classified under the following hazard categories:
No SARA 311/312 hazard categories identified.
SARA 313 This product contains the following components in concentrations above de minimis levels that are listed as toxic
chemicals in 40 CFR Part 372 pursuant to the requirements of Section 313 of SARA: No components were
identified.
CERCLA The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires
notification of the National Response Center concerning release of quantities of "hazardous substances"
equal to or greater than the reportable quantities (RQ's) listed in 40 CFR 302.4. As defined by CERCLA, the
term "hazardous substance" does not include petroleum, including crude oil or any fraction thereof which is
not otherwise specifically designated in 40 CFR 302.4. This product or refinery stream is not known to
contain chemical substances subject to this statute. However, it is recommended that you contact state and
local authorities to determine if there are any other reporting requirements in the event of a spill.

CWA This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of
1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining
shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center
at (800) 424-8802.
California This product is not known to contain the any components for which the State of California has found to
Proposition 65 cause cancer, birth defects or other reproductive harm.
New Jersey Petroleum Oil
Right-to-Know Label

Additional Regulatory Federal Hazardous Substances Act, related statutes, and Consumer Product Safety Commission regulations, as
defined by 16 CFR 1500.14(b)(3) and 1500.83(a)(13): This product contains "Petroleum Distillates" which may
Remarks
require special labeling if distributed in a manner intended or packaged in a form suitable for use in the household
or by children. Precautionary label dialogue should display the following: DANGER: Contains Petroleum
Distillates! Harmful or fatal if swallowed! Call Physician Immediately. KEEP OUT OF REACH OF CHILDREN!




MSDS No. Revision Date
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Duopac庐 Oil 90



SECTION 16: OTHER INFORMATION
Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product.
REVISION INFORMATION
Version Number 1.1
Revision Date 10/16/2001
Print Date Printed on 10/16/2001.
ABBREVIATIONS

AP = Approximately EQ = Equal > = Greater Than < = Less Than NA = Not Applicable ND = No Data NE = Not
Established
ACGIH = American Conference of Governmental Industrial Hygienists AIHA = American Industrial Hygiene Association
IARC = International Agency for Research on Cancer NTP = National Toxicology Program
NIOSH = National Institute of Occupational Safety and Health OSHA = Occupational Safety and Health Administration
NPCA = National Paint and Coating Manufacturers Association HMIS = Hazardous Materials Information System
NFPA = National Fire Protection Association EPA = Environmental Protection Agency

DISCLAIMER OF LIABILITY


THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE
INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME
INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE
SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS
A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR
OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR
PURPOSE.

THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL
AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND
EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH
HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT.


***** END OF MSDS *****

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