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MSDS Material Safety Data Sheet
CAS

64742-48-9
68476-85-7

File Name: 64742-48-9.asp

Commercial Food Equipment Service Association                                    P_0000017371     D_0000337517




DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 1 of 7
DOW CORNING(R) 316 SILICONE RELEASE SPRAY

1. IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY

24 Hour Emergency Telephone: (989) 496-5900
Dow Corning Corporation
South Saginaw Road Customer Service: (989) 496-6000
Midland, Michigan 48686 Product Disposal Information: (989) 496-6315
CHEMTREC: (800) 424-9300

MSDS No.: 01895371 Revision Date: 2002/01/22

Generic Description: Hydrocarbon aerosol propellant
Physical Form: Aerosol
Color: Colorless
Odor: Solvent odor.

NFPA Profile: Health 1 Flammability 4 Instability/Reactivity 0

Note: NFPA = National Fire Protection Association
2. OSHA HAZARDOUS COMPONENTS

CAS Number Wt % Component Name

64742-48-9 40.0 - 70.0 Hydrotreated heavy petroleum naphtha

68476-85-7 30.0 - 60.0 Liquified petroleum gas (LPG)

The above components are hazardous as defined in 29 CFR 1910.1200.

3. EFFECTS OF OVEREXPOSURE

Acute Effects

Eye: Slightly irritating.

Skin: No significant irritation expected from a single short-term exposure.

Inhalation: Vapor may irritate nose and throat. Overexposure by inhalation may cause
drowsiness, dizziness, confusion or loss of coordination.

Oral: Aspiration of liquid while vomiting may injure lungs seriously.

Prolonged/Repeated Exposure Effects

Skin: Repeated or prolonged contact may cause defatting and drying of skin which may result
in skin irritation and dermatitis.

Inhalation: Gas may suffocate by reducing the amount of air (oxygen) available for
breathing.Exposures to high concentrations may cause cardiac
sensitization.Overexposure by inhalation may injure the following organ(s):Nervous
system.

Oral: No known applicable information.
Commercial Food Equipment Service Association P_0000017371 D_0000337517




DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 2 of 7
DOW CORNING(R) 316 SILICONE RELEASE SPRAY

Signs and Symptoms of Overexposure

No known applicable information.

Medical Conditions Aggravated by Exposure

No known applicable information.

The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar
compositions, component data and/or expert review of the product. Please refer to Section 11 for the detailed toxicology
information.
4. FIRST AID MEASURES

Eye: Immediately flush with water for 15 minutes.

Skin: Remove from skin and wash thoroughly with soap and water or waterless cleanser.
Get medical attention if irritation or other ill effects develop or persist.

Inhalation: Remove to fresh air. Get immediate medical attention.

Oral: Get immediate medical attention. Only induce vomiting at the instructions of a
physician. Never give anything by mouth to an unconscious person.

Comments: Treat according to person's condition and specifics of exposure.

5. FIRE FIGHTING MEASURES

Flash Point: Not applicable.

Autoignition Not determined.
Temperature:

Flammability Limits in Air: Not determined.

Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.

Fire Fighting Measures: Self-contained breathing apparatus and protective clothing should be worn in fighting
large fires involving chemicals. Use water spray to keep fire exposed containers cool.
Determine the need to evacuate or isolate the area according to your local emergency
plan.

Unusual Fire Hazards: Vapors are heavier than air and may travel to a source of ignition and flash back.

Hazardous Decomposition Products

Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous
decomposition products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide.
Formaldehyde.

6. ACCIDENTAL RELEASE MEASURES
Commercial Food Equipment Service Association P_0000017371 D_0000337517




DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 3 of 7
DOW CORNING(R) 316 SILICONE RELEASE SPRAY

Containment/Clean up: Remove possible ignition sources. Determine whether to evacuate or isolate the area
according to your local emergency plan. Observe all personal protection equipment
recommendations described in Sections 5 and 8. Local, state and federal laws and
regulations may apply to releases and disposal of this material, as well as those
materials and items employed in the cleanup of releases. You will need to determine
which federal, state and local laws and regulations are applicable. Sections 13 and 15
of this MSDS provide information regarding certain federal and state requirements.

Note: See section 8 for Personal Protective Equipment for Spills. Call Dow Corning Corporation, (989) 496-5900,
if additional information is required.
7. HANDLING AND STORAGE

Use with adequate ventilation. Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or
fumes. Keep container closed. Do not take internally.

Contents under pressure. Do not store above 120F/49C or in direct sunlight.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Component Exposure Limits

CAS Number Component Name Exposure Limits

64742-48-9 Hydrotreated heavy petroleum naphtha Observe petroleum distillates limits. OSHA PEL (final
rule): TWA 400 ppm.

68476-85-7 Liquified petroleum gas (LPG) OSHA PEL and ACGIH TLV: TWA 1000 ppm.

Engineering Controls

Local Ventilation: Recommended.
General Ventilation: Recommended.

Personal Protective Equipment for Routine Handling

Eyes: Use proper protection - safety glasses as a minimum.

Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be
removed as soon as practical and thoroughly cleaned before reuse. Chemical
protective gloves are recommended.

Suitable Gloves: Nitrile Rubber. Silver Shield(R). 4H(R). Polyvinylalcohol. Viton(R).

Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or air
sampling data show exposures are within recommended exposure guidelines.
Industrial Hygiene Personnel can assist in judging the adequacy of existing engineering
controls.

Suitable Respirator: Organic Vapor/Dust/Mist/Fume Type.

Personal Protective Equipment for Spills
Commercial Food Equipment Service Association P_0000017371 D_0000337517




DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 4 of 7
DOW CORNING(R) 316 SILICONE RELEASE SPRAY

Eyes: Use full face respirator.

Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be
removed as soon as practical and thoroughly cleaned before reuse. Chemical
protective gloves are recommended.

Inhalation/Suitable Use respiratory protection unless adequate local exhaust ventilation is provided or air
Respirator: sampling data show exposures are within recommended exposure guidelines.
Industrial Hygiene Personnel can assist in judging the adequacy of existing engineering
controls.

Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes.
Keep container closed. Do not take internally. Use reasonable care.

Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol/spray applications may
require added precautions.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical Form: Aerosol
Color: Colorless
Odor: Solvent odor.
Specific Gravity @ 25掳C: 1.1
Viscosity: Not determined.
Freezing/Melting Point: Not determined.
Boiling Point: Not determined.
Vapor Pressure @ 25掳C: Not determined.
Vapor Density: Not determined.
Solubility in Water: Not determined.
pH: Not determined.
Volatile Content: Not determined.

Note: The above information is not intended for use in preparing product specifications. Contact Dow Corning before writing
specifications.

10. STABILITY AND REACTIVITY

Chemical Stability: Stable.

Hazardous Hazardous polymerization will not occur.
Polymerization:
Conditions to Avoid: None.

Materials to Avoid: Oxidizing material can cause a reaction.

11. TOXICOLOGICAL INFORMATION

Special Hazard Information on Components

No known applicable information.

12. ECOLOGICAL INFORMATION
Commercial Food Equipment Service Association P_0000017371 D_0000337517




DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 5 of 7
DOW CORNING(R) 316 SILICONE RELEASE SPRAY

Environmental Fate and Distribution

Complete information is not yet available.

Environmental Effects

Complete information is not yet available.

Fate and Effects in Waste Water Treatment Plants

Complete information is not yet available.

Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50) High Medium Low
Acute Aquatic Toxicity (mg/L) <=1 >1 and <=100 >100
Acute Terrestrial Toxicity <=100 >100 and <= 2000 >2000
This table is adapted from "Environmental Toxicology and Risk Assessment", ASTM STP 1179, p.34, 1993.

This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information
presented in the section concerning the overall ecological safety of this material.


13. DISPOSAL CONSIDERATIONS

RCRA Hazard Class (40 CFR 261)

When a decision is made to discard this material, as received, is it classified as a hazardous waste? Yes

Characteristic Waste:
Ignitable: D001

State or local laws may impose additional regulatory requirements regarding disposal.

Call Dow Corning Corporate Environmental Management, (989) 496-6315, if additional information is required.

14. TRANSPORT INFORMATION

DOT Road Shipment Information (49 CFR 172.101)

Proper Shipping Name: CONSUMER COMMODITY

Hazard Class: ORM-D

Packing Group: Not Applicable

Hazard Label(s): ORM-D LABEL

Not subject to DOT.

Ocean Shipment (IMDG)

Proper Shipping Name: AEROSOLS
Commercial Food Equipment Service Association P_0000017371 D_0000337517




DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 6 of 7
DOW CORNING(R) 316 SILICONE RELEASE SPRAY

Hazard Class: 2 LTD. QTY.

UN Number: 1950

Packing Group: Not Applicable

Marine Pollutant: Not Applicable

Air Shipment (IATA)

Proper Shipping Name: AEROSOLS, FLAMMABLE

Hazard Class: 2.1 LTD. QTY.

UN Number: 1950

Packing Group: Not Applicable

Hazard Label(s): FLAMMABLE GAS

Call Dow Corning Transportation, (989) 496-8577, if additional information is required.
15. REGULATORY INFORMATION

Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.

TSCA Status: All chemical substances in this material are included on or exempted from listing on the
TSCA Inventory of Chemical Substances.

EPA SARA Title III Chemical Listings

Section 302 Extremely Hazardous Substances:

None.

Section 304 CERCLA Hazardous Substances:

None.

Section 312 Hazard Class:
Acute: Yes
Chronic: Yes
Fire: Yes
Pressure: Yes
Reactive: No

Section 313 Toxic Chemicals:

None present or none present in regulated quantities.

Supplemental State Compliance Information

California
Commercial Food Equipment Service Association P_0000017371 D_0000337517




DOW CORNING CORPORATION
Material Safety Data Sheet
Page: 7 of 7
DOW CORNING(R) 316 SILICONE RELEASE SPRAY

Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking
Water and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or
other reproductive harm.


None known.

Massachusetts

CAS Number Wt % Component Name

68476-85-7 30.0 - 60.0 Liquified petroleum gas (LPG)


New Jersey

CAS Number Wt % Component Name

64742-48-9 40.0 - 70.0 Hydrotreated heavy petroleum naphtha

68476-85-7 30.0 - 60.0 Liquified petroleum gas (LPG)

63148-62-9 10.0 - 30.0 Polydimethylsiloxane


Pennsylvania

CAS Number Wt % Component Name

64742-48-9 40.0 - 70.0 Hydrotreated heavy petroleum naphtha

68476-85-7 30.0 - 60.0 Liquified petroleum gas (LPG)

63148-62-9 10.0 - 30.0 Polydimethylsiloxane



16. OTHER INFORMATION

Prepared by: Dow Corning Corporation

These data are offered in good faith as typical values and not as product specifications. No warranty, either
expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review these recommendations in the specific
context of the intended use and determine whether they are appropriate.

(R) indicates Registered Trademark

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