3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
Material Safety Data Sheet
Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B
MANUFACTURER: 3M
DIVISION: Corrosion Protection Products Dept
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 02/11/2004
Supercedes Date: 01/05/2004
Document Group: 16-0702-7
Product Use:
Specific Use: Part B of 2 Part Epoxy Coating
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
P-TERT-BUTYLPHENOL 98-54-4 20 - 30
HYDROUS MAGNESIUM SILICATE 14807-96-6 20 - 30
M-XYLENE-ALPHA,ALPHA'-DIAMINE 1477-55-0 5 - 15
TRIMETHYLHEXAMETHYLENEDIAMINE 25620-58-0 5 - 15
PHENOL FORMALDEHYDE AMINE POLYMER 104242-08-2 5 - 15
4-NONYL PHENOL, branched 84852-15-3 1- 9
POLYAMIDE Unknown 1- 5
PHTHALO GREEN 1328-53-6 1- 3
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Viscous, Green, Strong Amine Odor
General Physical Form: Liquid
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause chemical skin burns.
May cause allergic skin reaction. May cause allergic respiratory reaction.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.
Vapors from heated material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or
hazy vision.
Skin Contact:
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and
tissue destruction.
Prolonged or repeated exposure may cause:
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
May be absorbed through skin and cause target organ effects.
Inhalation:
Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Prolonged or repeated exposure may cause:
Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest.
Lung Effects: Signs/symptoms may include difficulty breathing, cough, wheezing, weakness, increased heart rate, bluish
colored skin (cyanosis), sputum production and changes in lung function tests.
Vapors from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal
discharge, headache, hoarseness, and nose and throat pain.
May be absorbed following inhalation and cause target organ effects.
Ingestion:
Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain, nausea, vomiting, and diarrhea;
blood in the feces and/or vomitus may also be seen.
May be absorbed following ingestion and cause target organ effects.
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
Target Organ Effects:
Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.
Kidney Effects: Signs/symptoms may include reduced or absent urine production, increased serum creatinine, lower back
pain, increased protein in urine, and increased blood urea nitrogen (BUN).
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15 minutes.
Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person.
Get immediate medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
No Data Available
Autoignition temperature
> 200 潞F [Test Method: Pensky-Martens Closed Cup]
Flash Point
1 % volume
Flammable Limits - LEL
7 % volume
Flammable Limits - UEL
5.2 EXTINGUISHING MEDIA
Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). Use fire extinguishers
with class B extinguishing agents (e.g., dry chemical, carbon dioxide). Water or fog may cause frothing which can be violent,
especially if sprayed into containers of hot or burning liquid
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
Unusual Fire and Explosion Hazards: Non-flammable: ordinary combustible material. There is the possibility of pressure buildup
in closed containers when heated. Water spray may be used to cool these containers.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to
prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite,
vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much
of the spilled material as possible. Clean up residue with detergent and water. Place in a closed container approved for transportation
by appropriate authorities. Dispose of collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Avoid breathing of vapors created during
cure cycle. Avoid breathing of dust created by cutting, sanding, grinding or machining. Do not breathe thermal decomposition
products. Avoid skin contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and
water. Avoid skin contact with hot material. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition.
Avoid contact with oxidizing agents. Contents may be under pressure, open carefully. For industrial or professional use only. Keep
out of the reach of children.
7.2 STORAGE
Store away from areas where product may come into contact with food or pharmaceuticals. Store away from acids. Store away from
flammable and combustible materials. Store away from oxidizing agents. Keep container in well-ventilated area. Store away from
heat. Keep container tightly closed.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust when product is heated. Provide ventilated enclosure for heat curing. Curing enclosures must be
exhausted to outdoors or to a suitable emission control device. Local exhaust ventilation with a minimum capture velocity of 100
linear feet per minute should be provided for applications at or above the boiling temperature. Provide appropriate local exhaust
ventilation on open containers. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Provide appropriate
local exhaust for molten or extruded material. Provide local exhaust ventilation at transfer points. Use general dilution ventilation
and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or
spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Full Face Shield, Indirect Vented Goggles.
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
8.2.2 Skin Protection
Avoid skin contact with hot material. Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns.
Avoid skin contact.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Butyl Rubber.
8.2.3 Respiratory Protection
Avoid breathing of vapors created during cure cycle. Avoid breathing of dust created by cutting, sanding, grinding or machining.
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Fullface air-purifying respirator with organic vapor cartridges and P100 particulate prefilters, Fullface supplied-
air respirator. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical
assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
COPPER COMPOUNDS ACGIH TWA - 1 mg/m3 as Cu dust or mist
specific form
COPPER COMPOUNDS OSHA TWA - 1 mg/m3 as dust or mist; Table Z-1A
specific form
M-XYLENE-ALPHA,ALPHA'-DIAMINE ACGIH CEIL 0.1 mg/m3 Skin Notation*
M-XYLENE-ALPHA,ALPHA'-DIAMINE OSHA CEIL 0.1 mg/m3 Table Z-1A
HYDROUS MAGNESIUM SILICATE ACGIH TWA - 2 mg/m3 Table A4
respirable
HYDROUS MAGNESIUM SILICATE CMRG TWA - 0.5 mg/m3 as respirable dust
specific form
HYDROUS MAGNESIUM SILICATE OSHA TWA - 2 mg/m3 Table Z-1A
respirable
* Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous
membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter
skin absorption.
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Viscous, Green, Strong Amine Odor
Odor, Color, Grade:
Liquid
General Physical Form:
No Data Available
Autoignition temperature
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
> 200 潞F [Test Method: Pensky-Martens Closed Cup]
Flash Point
1 % volume
Flammable Limits - LEL
7 % volume
Flammable Limits - UEL
No Data Available
Boiling point
No Data Available
Density
> 1 [Ref Std: AIR=1]
Vapor Density
No Data Available
Vapor Pressure
1.2 [Ref Std: WATER=1]
Specific Gravity
Not Applicable
pH
No Data Available
Melting point
Not Applicable
Solubility In Water
Slight (less than 10%)
Solubility in Water
< 1 [Ref Std: BUOAC=1]
Evaporation rate
12 g/l [Details: For coating mixture of Parts A and B]
Volatile Organic Compounds
1.28 % volume
Percent volatile
Not Applicable
VOC Less H2O & Exempt Solvents
13,000 - 20,000 centipoise [@ 72 潞F] [Test Method: Brookfield]
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents; Reducing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Ammonia Heat
Oxides of Nitrogen During Combustion
Hazardous Decomposition: Thermal decomposition may liberate acrylic monomers and ammonia.
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
Not determined.
CHEMICAL FATE INFORMATION
Not determined.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal
alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
80-6300-0060-4, 80-6300-0062-0
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
This material contains a chemical which requires export notification under TSCA Section 12[b]:
Ingredient (Category if applicable) C.A.S. No Regulation Status
4-NONYL PHENOL, branched 84852-15-3 Toxic Substances Control Act (TSCA) 4 Test Applicable
Rule Chemicals
STATE REGULATIONS
Contact 3M for more information.
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.
INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 3 Flammability: 2 Reactivity: 0 Special Hazards: None
Corrosive: Yes
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 3 Flammability: 2 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).
Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of
the product have not changed. We encourage you to reread the MSDS and review the information.
Revision Changes:
Section 3: Potential effects from skin contact information was modified.
Section 3: Potential effects from inhalation information was modified.
Section 3: Potential effects from ingestion information was modified.
Section 5: Fire fighting procedures information was modified.
Section 4: First aid for ingestion (swallowing) - decontamination - was modified.
Section 4: First aid for ingestion (swallowing) - medical assistance - was modified.
Section 2: Ingredient table was modified.
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3M MATERIAL SAFETY DATA SHEET SCOTCHKOTE 323 Patch, Brush, and Spray Grades, Part B 02/11/2004
Section 3: Other potential health effects heading was added.
Section 3: Immediate inhalation hazard(s) was added.
Section 15: TSCA section 12[b] text was added.
Section 3: Other health effects information was added.
Section 15: TSCA section 12[b] information was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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