http://hazard.com/msds/f2/byv/byvfl.html 09/06/2005 05:10 PM
SIGMA CHEMICAL CO -- 42205-3, DBE DIBASIC ESTER (MIXT DIMETHYL (SUP DAT) -- 6810-
00N062703
===================== Product Identification =====================
Product ID:42205-3, DBE DIBASIC ESTER (MIXT DIMETHYL (SUP DAT)
MSDS Date:05/01/1995
FSC:6810
NIIN:00N062703
MSDS Number: BYVFL
=== Responsible Party ===
Company Name:SIGMA CHEMICAL CO
Box:14508
City:SAINT LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:800-325-3010
Emergency Phone Num:314-771-5765
CAGE:0DK69
=== Contractor Identification ===
Company Name:HATCH INC
Address:1206 MYRTLE AVE
Box:City:EL PASO
State:TX
ZIP:79901-1602
Country:US
Phone:915-542-1991
CAGE:21067
Company Name:SIGMA CHEMICAL CO SIGMA DIAGNOSTICS DIV
Address:3050 SPRUCE ST
Box:City:ST LOUIS
State:MO
ZIP:63103-2530
Country:US
Phone:314-771-5765
CAGE:0DK69
============= Composition/Information on Ingredients =============
Ingred Name:ADIPIC ACID, DIMETHYL ESTER; (DIMETHYL ADIPATE)
CAS:627-93-0
RTECS #:AV1645000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DIMETHYL GLUTARATE (MFR CAS # 1119-40-0)
CAS:119-40-0
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUCCINIC ACID, DIMETHYL ESTER; (DIMETHYL SUCCINATE)
CAS:106-65-0
RTECS #:WM7675000
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
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===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT): 8191 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHAL,
INGEST/SKIN ABSORPTION. VAP/MIST IRRIT TO EYES, MUC MEMB & UPPER
RESP TRACT. SKIN IRRIT. TOX EFTS DESCRIBED IN ANIMALS FROM EXPOS BY
INHAL INCL UPPER RESP TRACT IRRIT. SINGLE 4-HR EXPOS TO 60 PPM
CAUSED TRANSIENT CORNEAL OPACITY & TRANSIENT INCR IN DIST FROM
CORNEA TO (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: ANTERIOR SURF OF LENS OF EYE.
TOXICITY DESCRIBED IN ANIMALS FROM RPTD EXPOS BY INHAL INCL DECR WT
GAIN, ABSOLUTE & RELATIVE LIVER WT DECR, & DEGENERATION OF
OLFACTORY EPITHELIUM (NASAL TISS) . TOXICITY DESCRIBED IN ANIMALS
FROM RPTD EXPOS BY INGEST INCL WT LOSS. SINGLE APPLICATION OF 10
MICROLITERS TO EYE CAUSED CORNEAL OPACITY. ADMIN OF 10-100
MICROLITERS OF SIMILAR MIX CAUSED CORNEAL OP ACITY, TRANSIENT INCR
IN CORNEAL THICKNESS & TRANSIENT CORNEAL ANESTH. SINGLE APPLIC OF
APPROX 60 MG/KG TO SKIN CAUSED INCR IN DIST FROM CORNEA TO ANTERIOR
SURF OF LENS OF EYE. CHRONIC: TARGET ORGANS: LIVER, EYES, NOSE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. INHALATION: REMOVE TO FRESH AIR.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING
ISDIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONSCIOUS. CALL MD.
===================== Fire Fighting Measures =====================
Flash Point:212F,100C
Lower Limits:0.9%
Upper Limits:8%
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL
POWDER OR APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA,
RUBBER BOOTS AND HEAVY RUBBER GLOVES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE VAPOR. AVOID CONTACT
WITH EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
READILY ABSORBED THROUGH SKIN. IRRITANT.
Other Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL DRY PLACE.
============= Exposure Controls/Personal Protection =============
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============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:WEAR PROTECTIVE CLOTHING. EMERGENCY EYEWASH
& DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
TRADE NAME/PART #: GLUTARATE DIMETHYL SUCCINATE & DIMETHYL ADIPATE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>385F,>196C
Vapor Pres:0.2 @ 20C
Spec Gravity:1.092
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES, OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE, AND LOCAL
ENVIRONMENTAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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