SAFETY DATA SHEET
in accordance with 2001/58/EC Revision Date: 28.05.2003
Trade name: MIXOL No. 1 Schwarz (Black) Page 1
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND COMPANY
TRADE NAME:
MIXOL No. 1 Schwarz (Black)
USE OF THE SUBSTANCE / PREPARATION:
Industry sector: Industrial Performance Chemicals
Paints, lacquers and varnishes industry
Polymers industry
Printing Inks Industry
Type of use: Colourant preparation
IDENTIFICATION OF THE COMPANY:
MIXOL-PRODUKTE
DIEBOLD GMBH
Postfach 1119
73219 KIRCHHEIM/TECK
Germany
Phone: 07021 / 950090
Fax: 07021 / 56030
2. COMPOSITION / INFORMATION ON INGREDIENTS
CHEMICAL CHARACTERIZATION:
C.I. Pigment Black 7 in aqueous dispersion containing diethylene glycol
HAZARDOUS INGREDIENTS:
Amines, soya-alkyl-
Concentration: 0,8 - 1,6 %
CAS number: 61790-18-9
EINECS number: 263-112-0
Hazard symbols: C N
R phrases: 22 35 50
Ethoxylated oleyl alcohol
Concentration: 12,4 - 14,6 %
CAS number: 9004-98-2
Hazard symbols: Xn
R phrases: 22 41
Diethylene glycol
Concentration: 10 - 11,2 %
CAS number: 111-46-6
EINECS number: 203-872-2
Hazard symbols: Xn
R phrases: 22
3. HAZARDS IDENTIFICATION
According to the present state of knowledge provided this product is handled correctly,
there is no danger to humans or the environment.
4. FIRST AID MEASURES
GENERAL INFORMATION:
Seek medical assistence if discomfort continues.
AFTER CONTACT WITH SKIN:
In case of contact with skin, clean with soap and water. Consult a physician if any symptoms
develop.
Safety data sheet in accordance with 2001/58/EC Revision Date: 28.05.2003
Trade name: MIXOL No. 1 Schwarz (Black) Page 2
AFTER CONTACT WITH EYES:
Immediately rinse eyes with running water and seek medical advice.
AFTER INGESTION:
If swallowed, do not induce vomiting, seek medical advice immediately and show safety data sheet.
5. FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA:
water spray jet
dry powder
carbon dioxide
alcohol-resistant foam
EXTINGUISHING MEDIA THAT MUST NOT BE USED FOR SAFETY REASONS:
Full water jet
SPECIAL HAZARDS FROM THE SUBSTANCE ITSELF ITS COMBUSTION PRODUCTS OR FROM ITS VAPOURS:
In case of fires, hazardous combustion gases are formed:
Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTING:
Use self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
METHODS FOR CLEANING UP / TAKING UP:
Take up with absorbent material (eg. sand, kieselguhr, universal binder).
When picked up, treat material as prescribed under point 13 鈥淒isposal considerations鈥?.
ENVIRONMENTAL PRECAUTIONS:
Do not discharge into the drains/surface waters/groundwater.
7. HANDLING AND STORAGE
ADVICE ON SAFE HANDLING:
When used and handled appropriately no special measures are needed.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
Observe the general rules of industrial fire protection.
FURTHER INFORMATION ON STORAGE CONDITIONS:
Keep only in the original container at temparature not exceeding 50掳 C. In case of the
product becoming opaque, thickening or being frozen due to the effects of cold, allow to
thaw slowly at room temperature. Stir briefly before use.
STORAGE STABILITY:
Shelf-life: at least 36 months
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
GENERAL PROTECTIVE MEASURES:
Observe the usual precautions for handling chemicals.
HYGIENE MEASURES:
Wash hands before breaks and after work.
Use barrier skin cream.
Remove soiled or soaked clothing immediately and clean thoroughly before using again.
Keep away from foods and drinks.
Safety data sheet in accordance with 2001/58/EC Revision Date: 28.05.2003
Trade name: MIXOL No. 1 Schwarz (Black) Page 3
HAND PROTECTION: rubber gloves
EYE PROTECTION: safety glasses
BODY PROTECTION: protective clothing
9. PHYSICAL AND CHEMICAL PROPERTIES
FORM: liquid
COLOUR: black
ODOUR: odourless
BOILING POINT: > 80 掳C
FLASH POINT: No flash point 鈥? Measure made up to the boiling point
DENSITY: approx. 1,23 g/cm鲁 (20掳 C)
SOLUBILITY IN WATER: miscible (20掳 C)
pH-VALUE: approx. 7,3 (20掳 C) aqueous suspension
FURTHER INFORMATION:
No incompatible substance known.
10. STABILITY AND REACTIVITY
THERMAL DECOMPOSITION: > 100掳 C with dehydration
HAZARDOUS REACTIONS:
When handled and stored appropriately no dangerous reactions are known.
HAZARDOUS DECOMPOSITION PRODUCTS:
When handled and stored appropriately no dangerous decomposition products are known.
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL TOXICITY: LD50 > 5.000 mg/kg (rat)
Method: 88/379/EC
IRRITANT EFFECT ON SKIN: non-irritant
Method: FDA-guideline
IRRITANT EFFECT ON EYES: non-irritant
Method: OECD 405
12. ECOLOGICAL INFORMATION
BIODEGRADABILITY: This property is substance specific and cannot be given for the
preparations.
FISH TOXICITY: not determined
DAPHNIA TOXICITY: not determined
ALGAE TOXICITY: not determined
BACTERIA TOXICITY: not determined
REMARKS:
Do not allow to enter soil, waterways or waste water.
Classification according to the calculation procedure of the Dangerous Preparations Directive
(1999/45/EC)
Safety data sheet in accordance with 2001/58/EC Revision Date: 28.05.2003
Trade name: MIXOL No. 1 Schwarz (Black) Page 4
13. DISPOSAL CONSIDERATIONS
PRODUCT:
Product should be taken to a suitable and authorized waste disposal site in accordance
with relevant regulations and if necessary after consultation with the waste disposal
operator and/or the competent authorities.
UNCLEANED PACKAGING:
Packaging that cannot be cleaned should be disposed of as product waste.
14. TRANSPORTATION INFORMATION
ADR: not restricted
RID: not restricted
ADNR: not restricted
IMDG: not restricted
IATA: not restricted
15. REGULATORY INFORMATION
LABELLING IN ACCORDANCE WITH EC-DIRECTIVES:
Hazard warning labelling not compulsory.
NATIONAL RULES:
The product is not subject of the regulation of inflammable liquids.
16. OTHER INFORMATION
TEXT OF THE R-PHRASES WHICH ARE ALLOCATED TO THE INGREDIENTS/COMPONENTS MENTIONED IN SECTION 2
OF THIS SAFETY DATA SHEET:
22 Harmful if swallowed.
35 Causes severe burns.
41 Risk of serious damage to eyes.
50 Very toxic to aquatic organisms.
These product informations are based on our present state of our knowledge, information and experience.
No responsibility or liability can be assumed for factors lying outside our knowledge and control.
Statements in catalogues and any other written information handed over to customers are in no way to be
understood as guarantees as to characteristics and neither as an agreement on the characteristics. The
possible purpose of use of the object of delivery is by no means part of the agreed characteristics. All users
are responsible for checking that all products used comply with the specific requirements of their intended
application.
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