MATERIAL SAFETY DATA SHEET
E-Z BRITE
SECTION I 鈥? MANUFACTURER鈥橲 NAME AND CONTACT INFORMATION
Manufacturer
E-Zoil Products, Inc. Emergency 1-800-424-9300 Chemtrec
2355 Bailey Avenue Information 716-892-4632
Buffalo, NY 14215 Date prepared July 1, 2005
NFPA Code: Health 3 Fire 0 Reactivity 0
SECTION II 鈥? HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Hydrofluoric Acid Sulfuric Acid Monobutyl Ether EB
11%W CAS# 7664-93-3 8%W 764-93-9 4%W 111-76-2
SECTION III 鈥? PHYSICAL & CHEMICAL CHARACTERISTICS
Appearance and odor: Blue liquid, slight chemical order
Boiling Point: Not established Melting Point: N/A
Vapor Pressure (MM Hg/70掳F) Vapor Density (Air=1): <1
Specific Gravity: 1.02 (H2O=1) Evaporation rate and ref: <1 (Butyl Acetate=1)
Solubility in water: 100% pH: 2
SECTION IV 鈥? FIRE & EXPLOSION HAZARD DATA
Flash Point: Non-Flammable
Extinguishing Media: Use dry chemical, carbon dioxide/foam to fight surrounding fires. Water may be ineffective, may cause
exothermic reaction with cleaner
Special Fire Fighting Procedures: Wear NIOSH approved SCBA & full protective equipment. This material is not combustible
but has acids that may react under heat.
Unusual Fire and Explosion Hazards: Minimal amounts of hydrogen gas could result on contact with certain metals. Heated
product may have some reactions to organic material.
SECTION V 鈥? REACTIVITY DATA
Stability: Yes
Conditions To Avoid (Stability): Highly reactive with metals, metal oxides, & alkaline materials. Avoid contact with zinc,
magnesium & galvanized metals.
Materials To Avoid: Oxidizers, alkali鈥檚, glass, ceramics, highly polished aluminum or chrome.
SECTION VI 鈥? HEALTH HAZARD DATA
LD50-LC50 Mixture: None specified by manufacturer.
Route of Entry 鈥? Inhalation: Yes
Route of Entry 鈥? Skin: Yes
Route of Entry 鈥? Ingestion: Yes
Health Hazards: Acute and chronic: Acute: Ingestion: Severe irritation to burns of mouth, throat & stomach. Inhalation:
Vapor/mist will irritate to damage tissues of nasal & respiratory tract. Skin: Mild to severe irritation or burns. Eyes: Vapor/mists
can severely irritate or burn cornea. Signs & symptoms of exposure: Ingestion: Burns to mouth & throat, severe abdominal burn
possible, pain, nausea, vomiting, diarrhea & lethargy.
(Effects of Overexposure)
Carcinogen 鈥? NTP: No
Carcinogen 鈥? IARC: Yes
Carcinogen 鈥? OSHA: No
Explanation Carcinogen: Sulfuric Acid: IARC mono on the evaluation of carcinogenic risk of chemicals to man, Vol 54, PG 41,
1992: Group 1.
Signs/Symptoms of overexposure: Health Hazard: Inhalation: Irritation, coughing, nausea, redness & irritation. Eyes: Tearing,
redness, swelling, blurred vision & burning adverse effects on CNS, Heamtopoietic Tiss, blood, kidneys, (Sup Dat)
Medical Condition Aggravated by Exposure: Permanent disability can occur
Emergency/First Aid Procedure:
EYE CONTACT 鈥? Immediately flush with running water for at least 15 min. forcibly holding upper and lower eyelids apart to
ensure complete irrigation. In all cases get immediate medical attention.
INHALATION: Remove to fresh air, give artificial respiration if not breathing.
INGESTION 鈥? Do not induce vomiting. Drink large quantities of water/milk. Do not give anything by mouth to unconscious
person. Get immediate medical attention.
SKIN CONTACT 鈥? Immediately flush with running water for 15 min. while removing contaminated clothing; wash before reuse.
SECTION VII 鈥? PRECAUTIONS FOR SAFE HANDLING AND USE
Wear acid-resistant full protective clothing and equipment.
Small Spills: Neutralize with mild alkali such as lime or soda ash and remove to absorbent diking material. Neutralize as above
and vacuum or shovel material as appropriate into proper disposal container. Dispose of in accordance with all local, state, and
federal regulations.
Neutralizing Agent: Mild solution of caustic soda, lime or soda ash. Sodium bicarbonate
Waste Disposal Method: Dispose of in accordance with local, state, and federal regulations.
Precautions-Handling/Storing: Store in a cool dry place out of direct sunlight and away from oxidizers.
Wear Proper protective clothing, slash goggles, protective chemical suit and boots, gloves.
Use in a well ventilated area. Other Precautions: Keep containers closed when not in use. Improper reuse of container including
use as a mixing vessel can be dangerous and/or illegal. Do not use press to empty containers. Do not cut, grind/drill near
containers. Follow all product label instructions. Always loosen closure slowly when opening to relieve internal pressure.
SECTION VIII 鈥? CONTROL MEASURES
Respiratory Protection: Normally not required if adequate ventilation is maintained. If use conditions generate vapors , mist or
workplace exposure limits of product is exceeded, wear NIOSH approved respirator.
Ventilation: Provide sufficient ventilation to maintain minimum exposure to vapors or mists.
Protective Gloves: Rubber or plastic gloves.
Eye Protection: ANSI approved chemical workers goggles
Other Protective Equipment: ANSI approved emergency eyewash and deluge shower. Chemical-resistant clothing, apron.
Work Hygienic Practices: Wash with soap and water after handling. Launder contaminated clothing before reuse.
Supplier. Safety and Health Data: Effects of overexposure: & liver, association with administration of ethylene glycol monobutyl
ether (EGBE) (Extracted from DHHS (NIOSH) Publication #90-118). Spill procedure: Decontaminate spill area with neutralizing
agent as above. Transport to EPA approved disposal facility. Keep non-neutralized material out of sewers, storm drains, surface
waters and soil.
TRANSPORTATION DATA
DOT: Hazardous Material
Proper shipping information: Corrosive Liquid, acidic, organic, n.o.s., (contains Hydrofluoric acid, Sulfuric Acid), 8, UN3265, PG
II.
Disclaimer of liability. The information in this msds was obtained from sources we believe are reliable; however the information is provided without any warranty
expressed or implied regarding its correctness. The conditions or methods of handling, storage, use of, and disposal of the product may be beyond our control or
knowledge. For this reason we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected
with the handling, storage, use or disposal of this product.
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