3M Canada Company
Material Safety Data Sheet
SECTION 1: PRODUCT AND COMPANY INFORMATION
3M Canada Company
Post Office Box 5757, London, Ontario N6A4T1
Medical Emergency Telephone: (519)451-2500, Ext. 2222
Prepared by: Environmental Health and Safety Services Department, 3M Canada Company.
Telephone: (519) 452-6102, Fax: (519) 452-6015.
PRIMER 94
Product ID:
70-0160-5476-2 70-0160-5477-0 70-0160-5478-8 70-0705-7964-7
70-0160-5507-4 70-0160-5506-6 70-0160-5508-2 70-0707-4298-9
70-0160-5497-8 70-0160-5499-4 70-0160-5500-9 70-0160-5501-7
70-0160-4782-4
Intended Use of Product: Adhesive primer.
Division: ENGINEERED ADHESIVES
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient Name CAS Number Percentage
_______________________________________________________________________________________
CYCLOHEXANE 110-82-7 45 - 50
XYLENE 1330-20-7 10 - 30
ETHYLALCOHOL 64-17-5 5 - 10
ETHYLBENZENE 100-41-4 5 - 10
ETHYLACETATE 141-78-6 1-5
ACRYLIC POLYMER (NJTS#04499600-5984P) Trade Secret 1-5
CHLORINATED POLYETHYLENE 68609-36-9 1-5
ISOPROPYLALCOHOL 67-63-0 0.1 - 1
NOTE: ACRYLIC POLYMER is a non-hazardous Trade Secret material according to WHMIS criteria.
SECTION 3: HAZARDS IDENTIFICATION
Critical Hazards
_______________________________________________________________________________________
Flammable liquid and vapor. Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain,
tearing, and hazy vision. Moderate Skin Irritation (after prolonged or repeated contact): signs/
symptoms can include redness, swelling, itching, and dryness.
Inhalation may cause: Central Nervous System Depression: signs/symptoms can include headache,
dizziness, drowsiness, in coordination, slowed reaction time, slurred speech, giddiness and unconscious-
ness.
Harmful or fatal if swallowed. High exposures to xylenes in some animal studies have been reported to
cause health effects on the developing embryo/fetus. These effects were often at levels toxic to the mother.
The significance of these findings to humans has not been determined. See Sections 7 and 11 for further
information.
SECTION 4: FIRST AID MEASURES
Instructions for Eye Contact: Immediately flush eyes with large amounts of water. Get immediate medical
attention.
Instructions for Skin Contact: Flush skin with large amounts of water. If irritation persists, get medical
attention.
Instructions for Inhalation: Remove person to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, get immediate medical attention.
Instructions for Ingestion: If swallowed, call a physician immediately. Only induce vomiting at the
instruction of a physician. Never give anything by mouth to anunconscious person.
SECTION 5: FIRE FIGHTING MEASURES
Flash point: Approximately -20 C OC ASTM D92
Lower Explosive Limit (%): Approximately 1 % calculated
Upper Explosive Limit (%): Approximately 6 % calculated
Autoignition temperature: Not available
Suitable Extinguishing Media: Water spray; Carbon Dioxide; Dry chemical; Foam
Exposure Hazards during Fire: Vapors may travel long distances along the ground or floor to an ignition
source and flash back.
Combustion Products from Fire: Carbon monoxide and carbon dioxide
Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure
or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face
mask, and protective covering for exposed areas of the head. Water may not effectively extinguish fire;
however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Refer to other sections of this MSDS for information regarding physical and health
hazards, respiratory protection, ventilation, and personal protective equipment.
Spill Response: Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected person-
nel from hazard area. Cover with absorbent material. Cover spill area with Light Water Brand or other ATC
foam. (For further information on ATC foam usage, contact 3M Fire Protection Systems.) Collect using
non-sparking tools. Clean up residue. Place in an approved metal container. Seal the container.
Methods for Disposal: Incinerate in a permitted hazardous waste incinerator. Combustion products will
include HCl.
SECTION 7: HANDLING AND STORAGE
Storage Requirements: Keep container closed when not in use.
Incompatible Materials: Store away from heat. Sparks and/or Flames
Fire Prevention: No smoking while handling this material.
Explosion Prevention: Flammable liquid and vapor. Keep away from heat, sparks, open flame, and other
sources of ignition.
Static Prevention: Avoid static discharge.
Use Instructions: Keep container tightly closed. For industrial or professional use only.
SECTION 8: EXPOSURE CONTROL/PERSONAL PROTECTION
Personal Protection
_______________________________________________________________________________________
Eye Protection: Avoid eye contact with vapor, spray, or mist. Wear safety glasses with side shields.
Hand Protection: Wear appropriate gloves when handling this material. A pair of gloves made from the
following material(s) are recommended: fluoroelastomer (Viton);
Skin Protection: Avoid skin contact.
Respiratory Protection: Avoid prolonged breathing of vapors. Select one of the following NIOSH approved
respirators based on airborne concentration of contaminants: half-mask organic vapor respirator; full-face
organic vapor respirator;
Ingestion (Prevention): DO NOT INGEST.
Recommended Ventilation: Local exhaust is required for operations using large amounts of material. Use
in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure
limits. If exhaust ventilation is not adequate, use appropriate respiratory protection.
Ingredient Exposure Data
_______________________________________________________________________________________
CYCLOHEXANE (110-82-7) ETHYLBENZENE (100-41-4)
LD50 (rat, oral): 12,705 mg/kg LD50 (rat, oral): 3500 mg/kg
PIN (Product Identification Number): 1145 LC50 (rat, inhalation/4 hours): 4000 ppm
Ontario TWAEV: 300 ppm 1030 mg/m3 PIN (Product Identification Number): UN 1175
ACGIH TLV-TWA: 300 ppm 1030 mg/m3 Ontario TWAEV: 100 ppm 434 mg/m3
Ontario STEV: 125 ppm 540 mg/m3
XYLENE (1330-20-7) ACGIH TLV-TWA: 100 ppm 434 mg/m3
LD50 (rat, oral): 3523 mg/kg (rat, male) ACGIH TLV-STEL: 125 ppm 543 mg/m3
LC50 (rat, inhalation/4 hours): 5000 ppm
PIN (Product Identification Number): 1307 ETHYLACETATE (141-78-6)
Ontario TWAEV: 100 ppm 435 mg/m3 LD50 (rat, oral): 5600 mg/kg
Ontario STEV: 150 ppm 650 mg/m3 LC50 (rat, inhalation/4 hours): 19600 ppm
ACGIH TLV-TWA: 100 ppm 434 mg/m3 PIN (Product Identification Number): 1173
ACGIH TLV-STEL: 150 ppm 651 mg/m3 Ontario TWAEV: 400 ppm 1440 mg/m3
Specific Ingredient Data: LD50 (rabbit, dermal): ACGIH TLV-TWA: 400 ppm 1440 mg/m3
> 5 ml/kg Specific Ingredient Data: LD50 (rabbit, dermal):
> 18 g/kg
ETHYLALCOHOL(64-17-5)
LD50 (rat, oral): 7060 mg/kg CHLORINATED POLYETHYLENE (68609-36-9)
LC50 (rat, inhalation): 20000 ppm / 10 hours. Specific Ingredient Data: No data available.
PIN (Product Identification Number): UN 1170
Ontario TWAEV: 1000 ppm 1900 mg/m3 ISOPROPYLALCOHOL(67-63-0)
ACGIH TLV-TWA: 1000 ppm 1880 mg/m3 LD50 (rat, oral): 4710 mg/kg
LC50 (rat, inhalation/4 hours): 17000 ppm
PIN (Product Identification Number): 1219
Ontario TWAEV: 400 ppm 980 mg/m3
Ontario STEV: 500 ppm 1225 mg/m3
ACGIH TLV-TWA: 400 ppm 985 mg/m3
ACGIH TLV-STEL: 500 ppm 1230 mg/m3
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical form,Color,Odor: Liquid; amber; solvent Partition coefficient (K o/w): No data available.
odor;
Specific gravity: Approximately 0.82 g/ml
Odor Threshold: No data available.
Vapor density: Approximately .0043 g/cc
pH: Approximately 5.5 calculated @ 100 C
Boiling point/boiling range: 76.6 - 137.7 C Volatile organic compounds: Approximately 750
Estimated, based on composition gms/liter SCAQMD Calculated
Melting point/melting range: Not applicable Evaporation rate: Approximately 6.4 xylene=1
calculated
Vapor pressure: Approximately 68 mmHg
calculated @ 25 C Viscosity: 30 - 40 centipoise
Water Solubility: Approximately 10 %
SECTION 10: STABILITY AND REACTIVITY
Conditions to Avoid: None known.
Materials to Avoid: Heat; Sparks and/or Flames;
Hazardous Decomposition: Carbon monoxide and carbon dioxide;
Stability and Reactivity: Stable. Hazardous polymerization will not occur.
SECTION 11: TOXICOLOGICAL INFORMATION
Effects from Eye Contact: Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain,
tearing, and hazy vision.
Effects from Skin Contact: Moderate Skin Irritation (after prolonged or repeated contact): signs/symptoms
can include redness, swelling, itching, and dryness.
Effects from Inhalation: Central Nervous System Depression: signs/symptoms can include headache,
dizziness, drowsiness, in coordination, slowed reaction time, slurred speech, giddiness and unconscious-
ness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing
and sneezing.
Effects from Ingestion: Harmful or fatal if swallowed. Gastrointestinal Effects: signs/symptoms generally
will include abdominal pain. Central
Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular
weakness, in coordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors
and convulsions. Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing,
wheezing, coughing up blood and pneumonia, which can be fatal.
Sensitization Information: No data available.
Carcinogenicity: No data available.
Mutagenicity: No data available.
Reproductive Effects: High exposures to xylenes in some animal studies have been reported to cause
health effects on the developing embryo/fetus. These effects were often at levels toxic to the mother.
The significance of these findings to humans has not been determined.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity Data: No data available.
Other Effects and Information: Not determined. Since regulations vary, consult applicable regulations or
authorities before disposal.
SECTION 13: DISPOSAL INFORMATION
Product as Sold: No data available.
Product Packaging: No data available.
Special Instructions: Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14: TRANSPORTATION INFORMATION
TDG Classification: 70-0160-5476-2: Regulated Material
70-0160-5477-0 & 70-0160-5478-8: Consumer Commodity
Proper Shipping Name: RESIN SOLUTION
Class/Division: 3.0
UN Number: UN 1866
Packing Group: II
International Dangerous Goods Classification
IMO Class: No data available.
ICAO Class: No data available.
SECTION 15: REGULATORY INFORMATION
WHMIS Classification: B2, D2A, D2B
NOTE: This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the information required by the CPR.
Product Certifications: The product on this MSDS, or all its components, is included on the following
countries' chemical inventories, as noted:
DSL - Domestic Substances List (Canada)
TSCA - Toxic Substances Control Act (USA)
EINECS - European Inventory of Existing Commercial Chemical Substances
AICS - Australian Inventory of Chemical Substances
SECTION 16: OTHER INFORMATION
Reason for Reissue: The following Sections and topics have been updated or revised: Section 12 -
Ecological Information - Other Effects and Information; WHMIS Classification change
Copyright, 1997, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or
downloading of this information for the purpose of properly utilizing 3M products is allowed provided
that:
1) the information is copied in full with no changes unless prior written agreement is obtained
from 3M, and
2) neither the copy nor the original is resold or otherwise distributed with the intention of earning
a profit thereon.
The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued.
3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, STATUTORY OR OTHERWISE,
INCLUDING, BUT NOT LIMITED TO, ANYIMPLIED WARRANTY OR CONDITION OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product
is fit for a particular purpose and suitable for user's method of use or application. Given the variety of
factors that can affect the use and application of a 3M product, some of which are uniquely within the
user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether
it is fit for a particular purpose and suitable for user's method of use or application.
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