Material Safety Data Sheet
WHMIS (Pictograms) WHMIS (Classification) Protective Clothing TDG (pictograms)
Not controlled
Section 1. Chemical Product and Company Identification
490-138, HDXAW22;
Product Name Code
HYDREX* AW 22, 32, 46, 68, 80, 100 490-139, HDXAW32;
490-140, HDXAW46;
490-141, HDXAW68;
490-142, HDXAW80;
490-137, HDXAW10.
Validated on 12/12/2003.
Not available
Synonym
Petro-Canada: 403-296-3000
In case of
PETRO-CANADA
Manufacturer
Emergency Canutec Transportation:
P.O. Box 2844
613-996-6666
Calgary, Alberta
Poison Control Centre: Consult
T2P 3E3
local telephone directory for
These products are designed for use as heavy duty hydraulic power
Material Uses emergency number(s).
transmission fluids and for lubrication where good anti-wear and anti-oxidation
properties are required. They would typically be used in high-pressure
hydraulic systems, machine tools, presses, compressors, pumps, gear sets,
and centralized bearing lubrication systems.
Section 2. Composition and Information on Ingredients
Exposure Limits (ACGIH)
CAS # % (V/V) TLV-TWA(8 h) STEL CEILING
Name
1) Mixture of severely hydrotreated and hydrocracked base Mixture 100 5 mg/m³ (oil mist) 10 mg/m³ (oil Not established
mist)
oil (petroleum) and other proprietary, non-hazardous
additives.
Not applicable
Manufacturer
Recommendation
Consult local, state, provincial or territory authorities for acceptable exposure limits.
Other Exposure
Limits
Section 3. Hazards Identification.
Prolonged or repeated contact may cause skin irritation, defatting, drying and dermatitis. Not expected to cause more than
Potential Health
slight skin or eye irritation. With its relatively low vapour pressure, this product is not expected be inhaled in any
Effects
appreciable quantity at ambient conditions. If heated to high temperatures or subjected to mechanical actions which
produce vapours or mists, inhalation may cause respiratory tract irritation. Ingestion may produce a laxative effect. For
more information refer to Section 11 of this MSDS.
Section 4. First Aid Measures
IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical attention.
Eye Contact
Remove contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin with running
Skin Contact
water and non-abrasive soap. Seek medical attention.
Evacuate the victim to a safe area as soon as possible. If the victim is not breathing, perform artificial respiration. Allow
Inhalation
the victim to rest in a well ventilated area. Seek medical attention.
DO NOT induce vomiting because of danger of aspirating liquid into lungs. Seek medical attention.
Ingestion
Not available
Note to Physician
Section 5. Fire-fighting Measures
May be combustible at high temperature. Not available
Flammability Flammable Limits
OPEN CUP: >207°C (404.6°F) (Cleveland) Not available
Flash Points Auto-Ignition
Temperature
Low fire hazard. This material must be heated Explosion Do not cut, weld, heat, drill or pressurize empty
Fire Hazards
before ignition will occur. container. Containers may explode in heat of
in Presence of Hazards in
fire.
Various Presence of
Substances Various
Substances
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HYDREX* AW 22, 32, 46, 68, 80, 100 Page Number: 2
Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), smoke and irritating vapours as products of
Products of
incomplete combustion.
Combustion
NAERG96, GUIDE 171, Substances (low to moderate hazard). If tank, rail car or tank truck is involved in a fire, ISOLATE
Fire Fighting
for 800 meters (0.5 mile) in all directions; also, consider initial evacuation for 800 meters (0.5 mile) in all directions. Shut
Media and
off fuel to fire if it is possible to do so without hazard. If this is impossible, withdraw from area and let fire burn out under
Instructions
controlled conditions. Withdraw immediately in case of rising sound from venting safety device or any discolouration of
tank due to fire. Cool containing vessels with water spray in order to prevent pressure build-up, autoignition or explosion.
SMALL FIRE: use DRY chemicals, foam, water spray or CO2. LARGE FIRE: use water spray, fog or foam. For small
outdoor fires, portable fire extinguishers may be used, and self contained breathing apparatus (SCBA) may not be
required. For all indoor fires and any significant outdoor fires, SCBA is required. Respiratory and eye protection are
required for fire fighting personnel.
Section 6. Accidental Release Measures
Consult current National Emergency Response Guide Book (NAERG) for appropriate spill measures if necessary.
Material Release
Extinguish all ignition sources. Stop leak if safe to do so. Dike spilled material. Use appropriate inert absorbent material
or Spill
to absorb spilled product. Collect used absorbent for later disposal. Avoid contact with spilled material. Avoid
contaminating sewers, streams, rivers and other water courses with spilled material. Notify appropriate authorities
immediately.
Section 7. Handling and Storage
Avoid contact with any sources of ignition, flames, heat, and sparks. Avoid eye contact. Avoid skin contact. Avoid
Handling
inhalation of product vapours or mists. Empty containers may contain product residue. Do not pressurize, cut, heat, or
weld empty containers. Do not reuse containers without commercial cleaning and/or reconditioning. Personnel who
handle this material should practice good personal hygiene during and after handling to help prevent accidental ingestion
of this product. Properly dispose of contaminated leather articles including shoes that cannot be decontaminated.
Store away from incompatible and reactive materials (See section 5 and 10). Keep container tightly closed. Store in dry,
Storage
cool, well-ventilated area.
Section 8. Exposure Controls/Personal Protection
Engineering Controls For normal application, special ventilation is not necessary. If user's operations generate vapours or mist, use ventilation to
keep exposure to airborne contaminants below the exposure limit. Make-up air should always be supplied to balance air
removed by exhaust ventilation. Ensure that eyewash station and safety shower are close to work-station.
Personal Protection - The selection of personal protective equipment varies, depending upon conditions of use.
Eyes Eye protection (i.e., safety glasses, safety goggles and/or face shield) should be determined based on conditions of use. If
product is used in an application where splashing may occur, the use of safety goggles and/or a face shield should be
considered.
Body Wear appropriate clothing to prevent skin contact. As a minimum long sleeves and trousers should be worn.
Respiratory Where concentrations in air may exceed the occupational exposure limits given in Section 2 (and those applicable to your
area) and where engineering, work practices or other means of exposure reduction are not adequate, NIOSH approved
respirators may be necessary to prevent overexposure by inhalation.
Hands Wear appropriate chemically protective gloves. When handling hot product ensure gloves are heat resistant and
insulated.
Feet Wear appropriate footwear to prevent product from coming in contact with feet and skin.
Section 9. Physical and Chemical Properties
Viscous liquid. 22: 21.59 cSt @ 40ºC, 4.26 cSt @ 100ºC,
Physical State and Viscosity
VI=101
Appearance
32: 34.5 cSt @ 40ºC, 5.68 cSt @ 100ºC,
VI=103
46: 46.6 cSt @ 40ºC, 6.94 cSt @ 100ºC,
VI=105
68: 65.7 cSt @ 40ºC, 8.51 cSt @ 100ºC, VI=99
80: 80.0 cSt @ 40ºC, 9.71 cSt @ 100ºC, VI=99
100: 100 cSt @ 40ºC, 11.32 cSt @ 100ºC,
VI=99
Pale, straw-yellow. 22: -45ºC (-49ºF)
Colour Pour Point
32: -39ºC (-38ºF)
46: -33ºC (-27ºF)
68: -33ºC (-27ºF)
80: -24ºC (-11ºF)
100: -30ºC (-22ºF)
Mild petroleum oil like. Not applicable.
Odour Softening Point
Not available Not applicable.
Odour Threshold Dropping Point
Not available Not applicable.
Boiling Point Penetration
0.8587 - 0.8728 kg/L @ 15ºC (59ºF). Not available
Density Oil / Water Dist.
Coefficient
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HYDREX* AW 22, 32, 46, 68, 80, 100 Page Number: 3
Not available Not available
Vapour Density Ionicity (in water)
Negligible at ambient temperature and Dispersion Properties Not available
Vapour Pressure
pressure.
Non-volatile. Insoluble in water.
Volatility Solubility
Section 10. Stability and Reactivity
Copper corrosion, 3h, 100°C (ASTM D0130): 1a
Corrosivity
The product is stable under normal handling Hazardous Will not occur under normal working conditions.
Stability
and storage conditions. Polymerization
Reactive with oxidizing agents and acids. May release COx, SOx, H2S, POx, CaOx, ZnOx,
Incompatible Decomposition
methacrylate monomers, aldehydes, alkyl
Substances / Products
mercaptans, smoke and irritating vapours when
Conditions to Avoid
heated to decomposition.
Section 11. Toxicological Information
Skin contact, eye contact, inhalation and ingestion.
Routes of Entry
Acute toxicity information is not available for the product as a whole, therefore, data for some of the ingredients
Acute Lethality
is provided below:
Acute Oral toxicity (LD50): >5000 mg/kg (rat)
Acute Dermal toxicity (LD50): >2000 mg/kg (rabbit)
Acute Inhalation toxicity (LC50): >2500 mg/m³/4h (rat)
Chronic or Other Toxic Effects
Dermal Route: Prolonged or repeated contact may defat and dry skin, and cause dermatitis. Short-term exposure is expected
to cause only slight irritation, if any.
Inhalation Route: With its relatively low vapour pressure, this product is not expected be inhaled in any appreciable quantity at
ambient conditions. If heated to high temperatures or subjected to mechanical actions which produce vapours
or mists, inhalation may cause respiratory tract irritation.
Oral Route: Ingestion of this product may lead to aspiration of the liquid, especially if vomiting occurs. This may result in
chemical pneumonitis (inflammation of the lungs) and/or pulmonary edema (an accumulation of fluid in the
lungs). May produce a laxative effect.
Eye Irritation/Inflammation: Short-term exposure is expected to cause only slight irritation, if any.
Immunotoxicity: Not available
Skin Sensitization: Contact with this product is not expected to cause skin sensitization, based upon the available data and the
known hazards of the components.
Respiratory Tract Sensitization: Contact with this product is not expected to cause respiratory tract sensitization, based upon the available data
and the known hazards of the components.
Mutagenic: This product is not known to contain any components at >= 0.1% that have been shown to cause
mutagenicity. Therefore, based upon the available data and the known hazards of the components, this
product is not expected to be a mutagen.
Reproductive Toxicity: This product is not known to contain any components at >= 0.1% that have been shown to cause reproductive
toxicity. Therefore, based upon the available data and the known hazards of the components, this product is
not expected to be a reproductive toxin.
Teratogenicity/Embryotoxicity: This product is not known to contain any components at >= 0.1% that have been shown to cause
teratogenicity and/or embryotoxicity. Therefore, based upon the available data and the known hazards of the
components, this product is not expected to be a teratogen/embryotoxin.
Carcinogenicity (ACGIH): This product is not known to contain any chemicals at reportable quantities that are listed as Group A1 or A2
carcinogens by ACGIH.
Carcinogenicity (IARC): This product is not known to contain any chemicals at reportable quantities that are listed as Group 1, 2A, or
2B carcinogens by IARC.
Carcinogenicity (NTP): This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by
NTP.
Carcinogenicity (IRIS): This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by
IRIS.
Carcinogenicity (OSHA): This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by
OSHA.
No additional remark.
Other Considerations
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HYDREX* AW 22, 32, 46, 68, 80, 100 Page Number: 4
Section 12. Ecological Information
Persistance/
Not available Not available
Environmental
Bioaccumulation
Fate
Potential
Not available Not available
BOD5 and COD Products of
Biodegradation
No additional remark.
Additional Remarks
Section 13. Disposal Considerations
Spent/ used/ waste product may meet the requirements of a hazardous waste. Consult your local or regional authorities.
Waste Disposal
Ensure that waste management processes are in compliance with government requirements and local disposal
regulations.
Section 14. Transport Information
Not a hazardous material for transport Special Provisions Not applicable.
TDG Classification
according to the TDG Regulations. (Canada) for Transport
Section 15. Regulatory Information
This product is acceptable for use under the provisions of WHMIS-CPR. All components of this formulation are listed on
Other
the CEPA-DSL (Domestic Substances List).
Regulations
All components of this formulation are listed on the US EPA-TSCA Inventory.
All components of this formulation are listed on EINECS or are exempt.
32, 46, 68: German Water Hazard Classification (Verwaltungsvorschrift wassergefährdende Stoffe - VwVwS) WGK=1
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and
the MSDS contains all of the information required by the CPR.
Please contact Product Safety for more information.
Not classified under the Dangerous Does not meet the definitions of a health or
DSD/DPD (Europe) HCS (U.S.A.)
Substances or Dangerous Preparations physical hazard according to the OSHA - Hazard
Directives. Communication Standard. (United States)
ADR (Europe) DOT (U.S.A)
(Pictograms) (Pictograms)
Rating
Health Hazard 1 0 Insignificant
HMIS (U.S.A.) NFPA (U.S.A.) 1 Fire Hazard
1 Slight
Fire Hazard 1 Health 1 0 Reactivity 2 Moderate
Reactivity 0 3 High
Specific hazard
Personal Protection B 4 Extreme
Section 16. Other Information
Available upon request.
References
* Marque de commerce de Petro-Canada - Trademark
Glossary
ACGIH - American Conference of Governmental Industrial Hygienists IRIS - Integrated Risk Information System
ADR - Agreement on Dangerous goods by Road (Europe) LD50/LC50 - Lethal Dose/Concentration kill 50%
ASTM - American Society for Testing and Materials ( LDLo/LCLo - Lowest Published Lethal Dose/Concentration
BOD5 - Biological Oxygen Demand in 5 days NAERG'96 - North American Emergency Response Guide Book (1996)
CAN/CGA B149.2 Propane Installation Code NFPA - National Fire Prevention Association
CAS - Chemical Abstract Services NIOSH - National Institute for Occupational Safety & Health
CEPA - Canadian Environmental Protection Act NPRI - National Pollutant Release Inventory
CERCLA - Comprehensive Environmental Response, Compensation and Liability NSNR - New Substances Notification Regulations (Canada)
Act NTP - National Toxicology Program
CFR - Code of Federal Regulations OSHA - Occupational Safety & Health Administration
CHIP - Chemicals Hazard Information and Packaging Approved Supply List PEL - Permissible Exposure Limit
COD5 - Chemical Oxygen Demand in 5 days RCRA - Resource Conservation and Recovery Act
CPR - Controlled Products Regulations SARA - Superfund Amendments and Reorganization Act
DOT - Department of Transport SD - Single Dose
DSCL - Dangerous Substances Classification and Labeling (Europe) STEL - Short Term Exposure Limit (15 minutes)
DSD/DPD - Dangerous Substances or Dangerous Preparations Directives TDG - Transportation Dangerous Goods (Canada)
(Europe) TDLo/TCLo - Lowest Published Toxic Dose/Concentration
DSL - Domestic Substance List TLm - Median Tolerance Limit
EEC/EU - European Economic Community/European Union TLV-TWA - Threshold Limit Value-Time Weighted Average
EINECS - European Inventory of Existing Commercial Chemical Substances TSCA - Toxic Substances Control Act
EPCRA - Emergency Planning and Community Right to Know Act USEPA - United States Environmental Protection Agency
FDA - Food and Drug Administration USP - United States Pharmacopoeia
FIFRA - Federal Insecticide, Fungicide and Rodenticide Act WHMIS - Workplace Hazardous Material Information System
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HYDREX* AW 22, 32, 46, 68, 80, 100 Page Number: 5
HCS - Hazardous Communication System
HMIS - Hazardous Material Information System
IARC - International Agency for Research on Cancer
Prepared by Product Safety - JDW on 12/12/2003.
For Copy of MSDS
The Canadian Controlled Products Regulations (CPR) (Under the Hazardous Products Act, Data entry by Product Safety - JDW.
part of the WHMIS legislation) only apply to WHMIS Controlled (i.e., hazardous) products.
Therefore, the CPR and the 3-year update rule specified therein do not apply to WHMIS
Non-Controlled products. Although this is true, customarily Petro-Canada reviews and
updates Non-Controlled product MSDS if a customer requests such an update. These
Non-Controlled product updates are given a lower priority than Controlled products but
are handled as soon as practicable. If you would like to verify if the MSDS you have is the
most current, or you require any further information, please contact:
Internet: www.petro-canada.ca/msds
Lubricants:
Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564
Ontario & Central Canada, telephone: 1-800-268-5850 and (905) 822-4222; fax:
1-800-201-6285
Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 800-201-6285
For Product Safety Information: (905) 804-4752
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of
its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards
that exist.
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