NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 1 of 9
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
NULON 25W60 STREET & TRACK ENGINE OIL
SYNONYMS
PRODUCT USE
Engine oil for use as per manufacturers instructions.
SUPPLIER
Company: Nulon Products (Australia) Pty Ltd
Address:
1/4 Narabang Way
Belrose
NSW, 2085
AUS
Telephone: +61 2 9450 1791
Fax: +61 2 9450 2448
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to
the Criteria of NOHSC, and the ADG Code.
POISONS SCHEDULE
None
RISK
SAFETY
Do not breathe gas/fumes/vapour/spray.
Wear eye/face protection.
Take off immediately all contaminated clothing.
In case of contact with eyes, rinse with plenty of water and contact Doctor or
Poisons Information Centre.
If you feel unwell contact Doctor or Poisons Information Centre. (Show the label
if possible).
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
paraffinic distillate, heavy, solvent-dewaxed (severe) 64742-65-0. >60
residual oils, petroleum, solvent dewaxed 64742-62-7. 5-15
mineral oil Not avail. 1-9
zinc alkyldithiophosphate <1
molybdenum compounds <1
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 2 of 9
Section 4 - FIRST AID MEASURES
SWALLOWED
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down
position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced
awareness; i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as
casualty can comfortably drink.
- Seek medical advice.
EYE
If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from
eye and moving the eyelids by occasionally lifting the upper and lower lids.
- If pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by
skilled personnel.
SKIN
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
- If fumes or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
NOTES TO PHYSICIAN
Treat symptomatically.
- Heavy and persistent skin contamination over many years may lead to dysplastic
changes. Pre-existing skin disorders may be aggravated by exposure to this
product.
- In general, emesis induction is unnecessary with high viscosity, low
volatility products, i.e. most oils and greases.
- High pressure accidental injection through the skin should be assessed for
possible incision, irrigation and/or debridement.
NOTE: Injuries may not seem serious at first, but within a few hours tissue may
become swollen, discoloured and extremely painful with extensive subcutaneous
necrosis. Product may be forced through considerable distances along tissue
planes.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 3 of 9
Section 5 - FIRE FIGHTING MEASURES
- Water spray or fog - Large fires only.
FIRE FIGHTING
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water
course.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- Avoid spraying water onto liquid pools.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
FIRE/EXPLOSION HAZARD
- Combustible.
- Slight fire hazard when exposed to heat or flame.
- Heating may cause expansion or decomposition leading to violent rupture of
containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
- May emit acrid smoke.
- Mists containing combustible materials may be explosive.
Combustion products include, carbon dioxide (CO2), phosphorus oxides (POx),
sulfur oxides (SOx), other pyrolysis products typical of burning organic
material.
May emit poisonous fumes.
FIRE INCOMPATIBILITY
Avoid contamination with oxidising agents i.e. nitrates, oxidising acids,
chlorine bleaches, pool chlorine etc. as ignition may result.
HAZCHEM
None
Personal Protective Equipment
PERSONAL PROTECTION EQUIPMENT
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
Slippery when spilt.
- Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.
- Contain and absorb spill with sand, earth, inert material or vermiculite.
- Wipe up.
- Place in a suitable labelled container for waste disposal.
MAJOR SPILLS
Slippery when spilt.
Moderate hazard.
- Clear area of personnel and move upwind.
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 4 of 9
Section 6 - ACCIDENTAL RELEASE MEASURES
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water
course.
- No smoking, naked lights or ignition sources.
- Increase ventilation.
- Stop leak if safe to do so.
- Contain spill with sand, earth or vermiculite.
- Collect recoverable product into labelled containers for recycling.
- Absorb remaining product with sand, earth or vermiculite.
- Collect solid residues and seal in labelled drums for disposal.
- Wash area and prevent runoff into drains.
- If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.
- DO NOT enter confined spaces until atmosphere has been checked.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
- Avoid physical damage to containers.
- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately.
- Use good occupational work practice.
- Observe manufacturer's storing and handling recommendations.
- Atmosphere should be regularly checked against established exposure standards
to ensure safe working conditions.
DO NOT allow clothing wet with material to stay in contact with skin.
SUITABLE CONTAINER
- Metal can or drum
- Packaging as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.
STORAGE INCOMPATIBILITY
CARE: Water in contact with heated material may cause foaming or a steam
explosion with possible severe burns from wide scattering of hot material.
Resultant overflow of containers may result in fire.
Avoid reaction with oxidising agents.
STORAGE REQUIREMENTS
- Store in original containers.
- Keep containers securely sealed.
- No smoking, naked lights or ignition sources.
- Store in a cool, dry, well-ventilated area.
- Store away from incompatible materials and foodstuff containers.
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 5 of 9
Section 7 - HANDLING AND STORAGE
- Protect containers against physical damage and check regularly for leaks.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
No data available: paraffinic distillate, heavy, solvent-dewaxed (severe) as (CAS: 64742-65-0)
No data available: residual oils, petroleum, solvent dewaxed as (CAS: 64742-62-7)
No data available: mineral oil as (CAS: Not avail)
Not available. Refer to individual constituents.
INGREDIENT DATA
For each of the following
PARAFFINIC DISTILLATE, HEAVY, SOLVENT-DEWAXED (SEVERE):
MINERAL OIL:
oil mist, mineral
TLV TWA: 5 mg/m鲁; STEL: 10 mg/m鲁.
NOTICE OF INTENDED CHANGE.
TLV TWA 0.2 mg/m鲁 inhalable fraction highly refined A4
NOTE: This substance has been classified by the ACGIH as A4
NOT classifiable as causing cancer in humans.
ES TWA: 5 mg/m鲁 (oil mist, refined mineral)
Human exposure to oil mist alone has not been demonstrated to cause health
effects except at levels above 5 mg/m鲁 (this applies to particulates sampled by
a method that does not collect vapour). It is not advisable to apply this
standard to oils containing unknown concentrations and types of additive.
RESIDUAL OILS, PETROLEUM, SOLVENT DEWAXED:
Not available. Refer to individual constituents.
PERSONAL PROTECTION
EYE
- Safety glasses with side shields.
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and
concentrate irritants. A written policy document, describing the wearing of lens
or restrictions on use, should be created for each workplace or task. This
should include a review of lens absorption and adsorption for the class of
chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be
readily available. In the event of chemical exposure, begin eye irrigation
immediately and remove contact lens as soon as practicable. Lens should be
removed at the first signs of eye redness or irritation - lens should be removed
in a clean environment only after workers have washed hands thoroughly. [CDC
NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
Wear chemical protective gloves, eg. PVC.
Wear safety footwear or safety gumboots, eg. Rubber.
OTHER
- Overalls.
- P.V.C. apron.
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 6 of 9
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
- Barrier cream.
- Skin cleansing cream.
- Eye wash unit.
RESPIRATOR
Selection of the Class and Type of respirator will depend upon the level of
breathing zone contaminant and the chemical nature of the contaminant.
Protection Factors (defined as the ratio of contaminant outside and inside the
mask) may also be important.
Breathing Zone Maximum Protection Half-face Full-Face
Level ppm (volume) Factor Respirator Respirator
1000 10 A-AUS P -
1000 50 - A-AUS P
5000 50 Airline * -
5000 100 - A-2 P
10000 100 - A-3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and
conditions of use determine the type of personal
protective equipment required.
For further information consult site specific
CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust
ventilation may be required in special circumstances. If risk of overexposure
exists, wear approved respirator. Supplied-air type respirator may be required
in special circumstances. Correct fit is essential to ensure adequate
protection. Provide adequate ventilation in warehouses and enclosed storage
areas.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Light brown liquid with a characteristic odour; does not mix with water.
PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.
Molecular Weight: Not Available Boiling Range (掳C): Not Available
Melting Range (掳C): Not Available Specific Gravity (water=1): 0.9 (15C)
Solubility in water (g/L): Immiscible pH (as supplied): Not Available
pH (1% solution): Not Available Vapour Pressure (kPa): Not Available
Volatile Component (%vol): Not Available Evaporation Rate: Not Available
Relative Vapour Density (air=1): Not Available Flash Point (掳C): >100
Lower Explosive Limit (%): Not Available Upper Explosive Limit (%): Not Available
Autoignition Temp (掳C): Not Available Decomposition Temp (掳C): Not Available
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 7 of 9
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
State: Liquid
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
- Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Accidental ingestion of the material may be damaging to the health of the
individual.
EYE
There is some evidence to suggest that this material can cause eye irritation
and damage in some persons.
SKIN
There is some evidence to suggest that this material can cause inflammation of
the skin on contact in some persons.
Entry into the blood-stream, through, for example, cuts, abrasions or lesions,
may produce systemic injury with harmful effects. Examine the skin prior to the
use of the material and ensure that any external damage is suitably protected.
INHALED
The material is not thought to produce either adverse health effects or
irritation of the respiratory tract following inhalation (as classified by EC
Directives using animal models). Nevertheless, adverse systemic effects have
been produced following exposure of animals by at least one other route and good
hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
Not normally a hazard due to non-volatile nature of product.
CHRONIC HEALTH EFFECTS
Substance accumulation, in the human body, may occur and may cause some concern
following repeated or long-term occupational exposure. There has been some
concern that this material can cause cancer or mutations but there is not enough
data to make an assessment. High boiling residues of petroleum process can
produce both benign and malignant skin tumours, according to animal testing.
They may contain significant concentrations of polynuclear aromatic hydrocarbons
(PAHs). Oil may contact the skin or be inhaled. Extended exposure can lead to
eczema, inflammation of hair follicles, pigmentation of the face and warts on
the soles of the feet. Exposure to oil mists can cause asthma, pneumonia and
scarring of the lungs. Oils have been linked to cancer of the skin and scrotum.
Compounds that are less viscous and with smaller molecular weights are more
dangerous. There may be liver damage and the lymph nodes may be affected; heart
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 8 of 9
Section 11 - TOXICOLOGICAL INFORMATION
inflammation can also occur at high doses.
TOXICITY AND IRRITATION
Not available. Refer to individual constituents.
unless otherwise specified data extracted from RTECS - Register of Toxic Effects
of Chemical Substances
PARAFFINIC DISTILLATE, HEAVY, SOLVENT-DEWAXED (SEVERE):
No data of toxicological significance identified in literature search.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
RESIDUAL OILS, PETROLEUM, SOLVENT DEWAXED:
Not available. Refer to individual constituents.
MINERAL OIL:
Toxicity and Irritation data is related to chemical components and
varies as does the composition and source of the original crude.
A small but definite risk of occupational skin cancer occurs in workers
exposed to persistent skin contamination by oils over a period of years.
This risk has been attributed to the presence of certain polycyclic
aromatic hydrocarbons (PAH) (typified by benz[a]pyrene).
Petroleum oils which are solvent refined/extracted or severely hydrotreated,
contain very low concentrations of both.
Section 12 - ECOLOGICAL INFORMATION
DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
- Consult manufacturer for recycling options and recycle where possible .
- Consult State Land Waste Management Authority for disposal.
- Incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Dangerous Goods Class: None
Subrisk: None
UN/NA Number: None
Packing Group: None
Labels Required:
Additional Shipping Information:
International Transport Regulations:
IMO Dangerous Goods class: None
IMO Packing group: None
IATA Dangerous goods class: None
Cargo Instructions:
Cargo Max:
Passenger Instructions:
Passenger Max:
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NULON 25W60 STREET & TRACK ENGINE OIL
Chemwatch Material Safety Data Sheet CHEMWATCH 5133-06
Issue Date: Thu 6-Oct-2005 CD 2005/3 Page 9 of 9
Section 14 - TRANSPORTATION INFORMATION
Special Provisions: None, None
HAZCHEM
None
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
paraffinic distillate, heavy, solvent-dewaxed (severe) (CAS: 64742-65-0) is
found on the following regulatory lists
Australian Inventory of Chemical Substances (AICS)
Australia High Volume Industrial Chemical List (HVICL)
Chinese Synonyms
residual oils, petroleum, solvent dewaxed (CAS: 64742-62-7) is found on the
following regulatory lists
Australian Inventory of Chemical Substances (AICS)
No data available for mineral oil as CAS: Not avail.
Section 16 - OTHER INFORMATION
This document is copyright. Apart from any fair dealing for the purposes of
private study, research, review or criticism, as permitted under the Copyright
Act, no part may be reproduced by any process without written permission from
CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: Thu 6-Oct-2005
Print Date: Wed 12-Oct-2005
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