W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Serpiflex庐 Shield (White)
Product Name:
Z-01555
MSDS Number:
Z-01548
Cancelled MSDS Number:
06/26/2002
MSDS Date:
Polymer Mixture
Chemical Family Name:
Lead/Asbestos Abatement
Product Use:
Mixture-NA
Chemical Formula:
Mixture-NA
CAS # (Chemical Abstracts
Service Number):
Manufactured by:
W.R.Grace & Co.-Conn. Grace Canada, Inc.
62 Whittemore Avenue 294 Clements Road West
Cambridge, MA 02140 Ajax, Ontario L1S 3C6
In Case of Emergency Call:
In USA: (617) 876-1400 In Canada: (905) 683-8561
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS# Percent (max)
2-Propenoic acid, butyl ester, polymer with ethenyl 025067-01-0 10-25
acetate
Calcium carbonate 001317-65-3 1-10
Magnesium Aluminum Silicate 012174-11-7 <1
Ethylene Glycol 000107-21-1 1-10
Phenol, isopropylated, phosphate (3:1) 068937-41-7 1-10
Quartz 014808-60-7 <1
Titanium dioxide 013463-67-7 1-10
Zinc borate 001332-07-6 1-10
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
SECTION 3 - HAZARDS IDENTIFICATION
Emergency Overview:
Caution!
Causes eye irritation.
Causes skin irritation.
Causes respiratory tract irritation.
Causes digestive tract irritation if ingested.
May cause liver and kidney damage.
May cause teratogenic and developmental toxic effects.
HMIS Rating:
Health: 2*
Flammability: 0
Reactivity: 0
Personal Protective Equipment: G (See Section 8)
Potential Health Effects:
Inhalation:
Spray applications of this material may create aerosols which may be irritating to the upper
respiratory tract, nose, and throat.
May cause nausea and headaches.
Vapors or mist in unusually high concentrations generated from spraying, heating or use in
poorly ventilated areas can cause a burning sensation, shortness of breath, headache, nausea,
coughing and wheezing. Prolonged or repeated overexposure may result in fluid in the
lungs, chemical pneumonia and serious damage to lung tissue and respiratory tract.
Absorption through the lungs may cause symptoms similar to those identified under
ingestion.
Effects include: Nausea. Sneezing. Coughing. Burning.
Eye Contact:
Spray applications of this material may create aerosols which may be irritating to the eyes.
Prolonged eye contact can result in redness and itching.
Skin Contact:
Skin contact causes irritation.
Prolonged skin contact can result in irritation causing redness and itching.
Skin Absorption:
Not expected to be harmful if absorbed through the skin.
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
Ingestion:
Harmful if ingested.
If ingested, causes irritation to the linings of the mouth, esophagus and stomach.
Effects include: Drowsiness, nausea, fatigue, pulmonary edema (from aspiration into the
lungs), CNS depression and headache.
Diethylene & Ethylene glycol can cause liver and kidney damage. Ethylene glycol has been
shown to produce teratogenic and developmental toxic effects in laboratory animals.
SECTION 4 - FIRST AID MEASURES:
Skin Contact:
Wash with soap and water.
If discomfort or irritation persists, consult a physician.
Remove contaminated clothing and wash before reuse.
Eye Contact:
Flush eyes with water for at least 15 minutes while holding eyelids open.
If discomfort or irritation persists, consult a physician.
Ingestion:
Do not induce vomiting.
Never give anything by mouth to an unconscious person.
If discomfort or irritation persists, consult a physician.
Inhalation:
If symptoms develop, get fresh air. If symptoms persist, consult a physician.
If breathing has stopped, give artificial respiration then oxygen if needed.
SECTION 5 - FIRE AND EXPLOSION HAZARD DATA
Flash Point: Not Applicable
Flash Point Method: Not Applicable
Lower Explosion Limit: Not Available
Upper Explosion Limit: Not Available
Auto-Ignition Temperature: Not Available
NFPA Rating:
Health: 1
Flammability: 0
Reactivity: 0
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
Extinguishing Media: Foam, Alcohol Foam, C02, Dry Chemical, Water Fog.
Special Fire Fighting Procedures:
Wear self-contained breathing apparatus and complete personal protective equipment
when potential for exposure to vapors or products of combustion exist. Isolate area and
keep unnecessary people away.
Unusual Fire and Explosion Hazards:
None unless noted below.
SECTION 6 - ACCIDENTAL RELEASE MEASURES:
Spills/Leaks:
Prevent spills from entering drinking water supplies, streams, or sewers.
Collect material with an inert, noncombustible material and remove for disposal.
SECTION 7 - HANDLING AND STORAGE
Precautionary Measures:
Avoid contact with eyes, skin and clothing.
Do not take internally.
Practice good personal hygiene to avoid ingestion.
Use only with adequate ventilation.
Wash clothing before reuse.
FOR PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH.
Keep away from heat, sparks and flame.
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTIVE
EQUIPMENT
EXPOSURE GUIDELINES (US)
Ingredient ACGIH TLV OSHA PEL Other
TWA STEL Ceiling TWA STEL Ceiling
2-Propenoic acid, butyl ester, - - - - - - -
polymer with ethenyl acetate
Calcium carbonate 10 mg/m3 TWA - - total dust: 15 - - -
(The value is for mg/m3 TWA;
particulate matter respirable
containing no fraction: 5
asbestos and mg/m3 TWA
Ethylene Glycol - - C 100 mg/m3 - - - -
(aerosol)
Phenol, isopropylated, phosphate - - - - - - -
(3:1)
Quartz 0.05 mg/m3 TWA - - respirable - - -
(respirable fraction) dust: 0.1
mg/m3 TWA
Titanium dioxide 10 mg/m3 TWA - - total dust: 10 - - -
mg/m3 TWA
Triphenyl phosphate 3 mg/m3 TWA - - 3 mg/m3 - - -
TWA
Zinc borate - - - - - - -
EXPOSURE GUIDELINES (CANADA)
Employers should consult local Provincial regulatory limits for exposure guidelines which may
vary locally.
Not generally required.
Engineering Controls:
Personal Protective Equipment:
Respiratory Protection: Respiratory protection is required during spray application. A
dust/mist respirator such as a 3M Type P-95 or 3M Type 3-95 with organic vapor
protection (or equivalent) is adequate. Specific working conditions, which must be
assessed periodically, may require an increased level of respiratory protection. A
respirator equipped with organic vapor cartridges may be required indoors and in other
poorly ventilated areas. Respirators may not be required during non-spray applications
and other specific situations. In all cases, maintain exposures below governmental limits
specified in Section 2. (See Work/Hygenic Practices for additional information.)
Skin Protection: Impervious (PVC, latex or nitrile) gloves should be worn anytime
direct contact is possible.
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
Eye Protection: Wear goggles to prevent exposure to high vapor or mist concentrations.
Wear goggles or safety glasses with side shields and a full-face shield to prevent contact
due to splashing.
Work/Hygienic Practices: Work clothing with long sleeves/long pants and work boots
must be worn. Clothing must be laundered before reuse. Disposable tyvek suits may be
used during spray applications.
This product contains compounds subject to exposure guidelines and/or identified as
carcinogens. (See Sections 8 and 11). However, due to the physical nature of this
product, these compounds are unlikely to reach exposure limits unless airborne dust or
spray mist is created.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Physical State:
White Liquid Mild Latex odor
Appearance/Odor:
Not Determined
Odor Threshold: (ppm)
Not Available
pH:
Unknown
Vapor Pressure: (Mm Hg)
<1.0
Vapor Density: (Air = 1)
Appreciable
Solubility In Water:
Not Available
Specific Gravity: (Water = 1)
<1.0
Evaporation Rate: (Butyl Acetate = 1)
>212掳F/100掳C
Boiling Point:
Unknown
Viscosity:
Not Applicable
Bulk Density: (Pounds/Cubic
Foot)(Pcf)
~ 60%
% Volatiles: (70掳F) (21掳C)
SECTION 10 - STABILITY AND REACTIVITY
Stable
Chemical Stability:
Strong oxidizers, Strong acids, Ammonium salts,
Conditions To Avoid:
flourine, maganese trioxide, oxygen diflouride and
chlorine trifluoride.
Will not polymerize.
Hazardous Polymerization:
Carbon dioxide, Carbon monoxide, magnesium
Hazardous Decomposition
carbonate and lime.
Products:
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
SECTION 11 - TOXICOLOGICAL INFORMATION
Ingredient(No data unless listed.) CAS Number LD50 and LC50
Ethylene Glycol 000107-21-1 Inhalation LC50 Rat : 10876 mg/kg;
Oral LD50 Rat : 4700 mg/kg;
Oral LD50 Mouse
Carcinogenicity:
IARC IARC IARC NTP NTP OSHA
Ingredient Group 1 Group 2A Group 2B Known Suspect
No No No No No No
2-Propenoic acid, butyl ester, polymer with
ethenyl acetate
No No No No No No
Calcium carbonate
No No No No No No
Ethylene Glycol
No No Yes No No No
Magnesium Aluminum Silicate
No No No No No No
Phenol, isopropylated, phosphate (3:1)
Yes No No Yes Yes Yes
Quartz
No No No No No No
Titanium dioxide
No No No No No No
Zinc borate
Product contains less than 1% Quartz. Prolonged and repeated exposure to respirable Quartz
(Crystalline silica) can decrease lung function and create risk of lung disease (i.e. silicosis and/or
lung cancer). However, Quartz is not expected to be bio-available during routine use and
application.
No information available.
Mutagenicity:
Ethylene glycol contained in this product has been shown
Teratogenicity:
to produce teratogenic effects in laboratory animals.
Ethylene glycol contained in this product has been shown
Reproductive Toxicity:
to produce developmental toxic effects in laboratory
animals.
SECTION 12 - ECOLOGICAL INFORMATION
No data available for product.
Environmental Fate:
No data available for product.
Ecotoxicity:
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
SECTION 13 - DISPOSAL CONSIDERATIONS
Consult all regulations (federal, state, provincial,
Waste Disposal Procedures:
local) or a qualified waste disposal firm when
characterizing waste for disposal. According to
EPA (40 CFR 搂 261), waste of this product is not
defined as hazardous. Dispose of waste in
accordance with all applicable regulations.
SECTION 14 - TRANSPORTATION INFORMATION
Not Applicable
Proper Shipping Name:
Not Applicable
UN/NA Number:
Nonhazardous
Domestic Hazard Class:
Consumer Commodity ORM-D
Surface Freight Classification:
Not Applicable
Label/Placard Required:
SECTION 15 - REGULATORY INFORMATION
REGULATORY CHEMICAL LISTS:
CERCLA (Comprehensive Response Compensation and Liability Act):
(None present unless listed below)
Chemical Name CAS # Wt % CERCLA RQ
Acetaldehyde 000075-07-0 0.01 final RQ = 1000 pounds (454 kg)
Ethylene Glycol 000107-21-1 4.85 final RQ = 5000 pounds (2270 kg)
Glycol ethers RR-00067-9 4.85 (Includes mono- and di- ethers of
ethylene glycol; diethylene glycol and
Vinyl acetate 000108-05-4 0.02 final RQ = 5000 pounds (2270 kg)
Zinc borate 001332-07-6 2.03 final RQ = 1000 pounds (454 kg)
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
SARA Title III (Superfund Amendments and Reauthorization Act)
SARA Section 312/Tier I & II Hazard Categories:
Health Immediate (acute) Yes
Health Delayed (chronic) Yes
Flammable No
Reactive No
Pressure No
302 Reportable Ingredients (Identification Threshold 1%.):
Chemical Name CAS # Wt % SARA 302 TPQ
Vinyl acetate 000108-05-4 .02437 TPQ = 1000 pounds;
RQ = 5000 pounds
313 Reportable Ingredients (Chemicals present below reporting threshold are exempt):
Chemical Name CAS # Wt %
Ethylene Glycol 000107-21-1 4.85
Chlorothalonil 001897-45-6 .03232
Vinyl acetate 000108-05-4 .02437
Acetaldehyde 000075-07-0 .009748
Glycol ethers RR-00067-9 .0058
Zinc Compounds RR-00578-7 2.03
National Volatile Organic Compound Emission Standards For Architectural Coatings:
Volatile Organic Content: (gr/L) 70.16 g/l (as applied)
D2 B
WHMIS Classification(s):
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations (CPR). This MSDS contains all the information required by the CPR.
State Regulatory Information:
WARNING! This product contains substances
California Proposition 65:
known to the state of California to cause
cancer, birth defects or other reproductive
harm.
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W. R. GRACE
MATERIAL SAFETY DATA SHEET
Product Name: Serpiflex庐 Shield (White)
MSDS ID Number: Z-01555 MSDS Date: 07/03/2002
Massachusetts Hazardous Substance List(Identification threshold 0.001%(1ppm)):
Chemical Name CAS # Wt %
Ethylene Glycol 000107-21-1 4.85
Zinc borate 001332-07-6 2.03
Vinyl acetate 000108-05-4 .02437
Acetaldehyde 000075-07-0 .009748
Glycol ethers RR-00067-9 .0058
New Jersey Hazardous Substance List(Identification threshold (0.1%)):
Chemical Name CAS # Wt %
Pennsylvania Hazardous Substance List(Identification threshold 0.01%):
Chemical Name CAS # Wt %
SECTION 16 - OTHER INFORMATION
Non-Hazardous Ingredient Disclosure:
Chemical Name CAS Number
Water 007732-18-5
EH&S Department
Prepared by:
EH&S Department
Approved by:
06/26/2002
Approved Date:
Disclaimer:
"The data included herein are presented in accordance with various environment, health and
safety regulations. It is the responsibility of a recipient of the data to remain currently informed
on chemical hazard information, to design and update its own program and to comply with all
national, federal, state and local laws and regulations applicable to safety, occupational health,
right-to-know and environmental protection."
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