Material Safety Data Sheet
(MSDS-DET)
PRODUCT IDENTIFICATION
Detonators, Class 1.4 Explosive
Product Name
Non-electric detonators, electric detonators, detonating fuzes, EFI detonators, EBW
Trade Names and Synonyms
detonators
Various
Manufacturer/Distributor
Transportation Emergency 800-255-3924 (24 hrs -- CHEM 鈥? TEL)
PREVENTION OF ACCIDENTS IN THE USE OF EXPLOSIVES
The prevention of accidents in the use of explosives is a result of careful planning and observance of the
best known practices. The explosives user must remember that he is dealing with a powerful force and
that various devices and methods have been developed to assist him in directing this force. He should
realize that this force, if misdirected, may either kill or injure both him and his fellow workers.
WARNING
All explosives are dangerous and must be carefully handled and used following approved
safety procedures either by or under the direction of competent, experienced persons in accordance
with all applicable federal, state, and local laws, regulations, or ordinances. If you have any questions or
doubts as to how to use any explosive product, DO NOT USE IT before consulting with your
supervisor, or the manufacturer, if you do not have a supervisor. If your supervisor has any questions or
doubts, he should consult the manufacturer before use.
MSDS-DET PAGE 1 Issued 03/15/93
Revised 2/22/06
HAZARDOUS COMPONENTS
Material or Component CAS No. TLV PEL
N/A NE NE
Black Powder
00078-11-5 NE NE
PETN
(Pentaerythritol Tetranitrate)
1.5 mg/m3 1.5 mg/m3
00121-82-4
RDX
(Cyclotrimethylenetrinitramine)
026914-41-0 NE NE
HMX
(Cyclotetramethylenetetranitramine)
20062-22-0 NE NE
HNS
(Hexanitrostilbene)
38082-89-2 NE NE
PYX
(Picrylaminodinitropyridine)
25243-36-1 NE NE
TACOT
(Tetranitrodibento-tetra-azapentalene)
50 碌g/m3
0.15 mg/m3
13424-46-9
Lead azide
(TLV & PEL given for lead)
50 碌g/m3
0.15 mg/m3
15245-44-0
Lead Styphnate
(TLV & PEL given for lead)
5 mg/m3 10 mg/m3
07429-90-5
Aluminum
N/A NE NE
Corrosion resistant steel
5 mg/m3 10 mg/m3
07439-89-6
Iron
1 mg/m3 1 mg/m3
07440-50-8
Copper
Detonators may contain and/or be constructed of one or more of the items listed above
N/A = Not assigned NE = Not established
PHYSICAL DATA
Metal shells containing explosives, with or without insulated metal leg wires.
HAZARDOUS REACTIVITY
Detonates with friction, impact, heat, low level electrical current, electrostatic or RF
Instability
energy
Acids and alkalis
Incompatibility
Detonation produces hazardous fragments. Gases produced may contain iron, lead,
Hazardous decomposition
carbon and nitrogen oxides
Polymerization will not occur
Polymerization
FIRE AND EXPLOSION DATA
Not applicable
Flashpoint
None
Extinguishing media
Special fire fighting procedures
ALL EXPLOSIVES: DO NOT FIGHT EXPLOSIVES FIRES. Try to keep
fire from reaching explosives. Isolate area. Guard against intruders.
Division 1.4 Explosives: Evacuate the area for 1500 feet (1/3 mile). Consult the 2000
Emergency Response Guidebook, Guide 114 for further details.
May detonate with impact or on heating
Unusual fire and explosion hazards
MSDS-DET PAGE 2 Issued 03/15/93
Revised 2/22/06
HEALTH HAZARDS
Detonators do not present health hazards in normal handling and use; however, the
General
products are Division 1.4 explosives, and detonation may cause severe physical injury,
including death. All explosives are dangerous and must be handled carefully and used
following approved safety procedures under the direction of competent, experienced
persons in accordance with all applicable federal, state, and local laws, regulations, and
ordinances.
Inhalation of explosives powders may cause nervous system irregularities including
headaches and dizziness.
Overexposure to lead may cause adverse effects to the blood forming, nervous, urinary,
reproductive systems, including weakness, weight loss, insomnia, constipation, anemia,
motor weakness, and encephalopathy. Lead may penetrate the placental barrier and
has caused congenital abnormalities in animals. Several animal studies have indicated
that high doses of lead may be carcinogenic.
Nitrogen oxides generated during use are skin, eye, and respiratory tract irritants.
None of the components of detonators are listed as a carcinogen by NTP, IARC, or
Carcinogenicity
OSHA.
FIRST AID
Not a likely route of exposure. If inhaled, remove to fresh air. If not breathing, give
Inhalation
artificial respiration, preferably by mouth-to-mouth. If breathing is difficult, give oxygen.
Seek prompt medical attention.
Not a likely route of exposure.
Eye and skin contact
Not a likely route of exposure.
Ingestion
Seek prompt medical attention.
Injury from detonation
SPILL OR LEAK PROCEDURES
Use appropriate personal protective equipment. Isolate area and remove sources of
Spill/leak response
friction, impact, heat, low level electrical current, electrostatic or RF energy. Only
competent, experienced persons should be involved in cleanup procedures. Sweep up
with non-sparking tools and remove.
Dispose of in compliance with federal regulations under the authority of the Resource
Waste disposal
Conservation and Recovery Act (40 CFR Parts 260-271).
SPECIAL PROTECTION INFORMATION
Use only with adequate ventilation.
Ventilation
NIOSH approved particle masks for dust and mist.
Respiratory
Safety glasses or goggles.
Eye
Impervious rubber gloves.
Gloves
Cotton overalls, undergarments, and socks. Conductive soled shoes.
Other
SPECIAL PRECAUTIONS
Keep away from friction, impact, and heat. Do not consume food, drink, or tobacco in areas where they may become
contaminated with these materials.
STORAGE CONDITIONS
Store in accordance with the requirements of Subpart K, ATF: Explosives Law and Regulations (27 CFR 55.201-55.219).
MSDS-DET PAGE 3 Issued 03/15/93
Revised 2/22/06
SHIPPING INFORMATION
Detonators, electric
Proper shipping name
Detonators, non-electric
Fuzes, detonating
1.4S (UN0456, UN0455, and UN0367) or 1.4D (UN0410)
Hazard class
Detonators, electric UN0456
UN Number
Detonators, non- UN0455
electric
Fuzes, detonating UN0367 and UN0410
DOT Label
DOT Label & Placard
UN0367, UN0455, UN0456 UN0410
(1.4S products) (1.4D products)
DOT Placard
UN0367, UN0455, UN0456 UN0410 < OR >
(1.4S products) (1.4D products) (1.4D & 1.4S products)
The information contained in this Material Safety Data Sheet is based upon available data and believed to be correct;
however, as such has been obtained from various sources, including the manufacturer and independent laboratories, it is
given without warranty or representation that it is complete, accurate, and can be relied upon. OWEN COMPLIANCE SERVICES,
INC. has not attempted to conceal in any manner the deleterious aspects of the product listed herein, but makes no
warranty as to such. Further, OWEN COMPLIANCE SERVICES, INC. cannot anticipate nor control the many situations in which
the product or this information may be used; there is no guarantee that the health and safety precautions suggested will be
proper under all conditions. It is the sole responsibility of each user of the product to determine and comply with the
requirements of all applicable laws and regulations regarding its use. This information is given solely for the purposes of
safety to persons and property. Any other use of this information is expressly prohibited.
David W. Boston, President
For further information contact:
OWEN COMPLIANCE SERVICES, INC.
12001 County Road 1000
P.O. Box 765
Godley, TX 76044
Telephone number: 817-551-0660
FAX number: 817-396-4584
David W. Boston
MSDS prepared by:
Original publication date: 03/15/93
Revision date: 2/22/06
12/03/03
MSDS-DET PAGE 4 Issued 03/15/93
Revised 2/22/06
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