MATERIAL SAFETY DATA SHEET Complies with OSHA's Hazard Communication Standard (29 CFR 1910.1200)
REFERENCE: RDY35-1 ITEM NO.: HIL0019106
Emergency Telephone Number: (800) 424-9300 (Only in the event of chemical
emergency involving a spill, leak, fire, exposure or accident involving chemicals)
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PRODUCT NAME
HIL-PHENE Germicidal Detergent (EPA Reg. No. 211-36-1658)
DESCRIPTION: A concentrated germicidal detergent formulated with synthetic phenols, anionic surfactants and alcohol.
Distributor Information: April 24, 2002
DATE PREPARED: SIGNATURES (Optional)
Hillyard Industries, Inc. PREPARED By:
Gary W. Helton, Environmental Health Specialist
302 N. Fourth St. REVIEWED By:
St. Joseph, MO 64502 Gary Brandt, Technical Director
Concentrate
HMIS RATING HEALTH 2 REACTIVITY 0 FLAMMABILITY 2 PERSONAL B
Diluted 1:128 (1 oz./gal.)
HMIS RATING HEALTH 1 REACTIVITY 0 FLAMMABILITY 0 PERSONAL B
HAZARD RATINGS: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Extreme A = Safety Glasses B = Safety Glasses & Gloves
SECTION 2 - COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Components (Specific Chemical Identity) CAS # OSHA PEL ACGIH TLV Other Limits % (Optional)
* Isopropyl alcohol 67-63-0 400 ppm 400 ppm 400 ppm 5 to 10 %
鈥? o-benzyl-p-chlorophenol 120-32-1 N/E N/E N/E 1 to 5 %
*鈥? 2-Phenylphenol 90-43-7 N/E N/E N/E 1 to 5 %
鈥? para-tertiary-amylphenol 80-46-6 N/E N/E N/E 1 to 5 %
* Ingredients subject to reporting requirements of Section 313 of SARA Title III 鈥? Ingredients listed as germicidal actives
N/A = Not Applicable N/E = Not Established N/D = Not Determined N/L Not Listed
SECTION 3 - HAZARDS IDENTIFICATION (Potential Health Effects)
POSSIBLE ROUTES OF ENTRY INTO THE BODY: Eyes 鈥? Skin 鈥? Ingestion 鈥? Inhalation
HEALTH HAZARDS: Will cause eye irritation and skin irritation with prolonged exposure. Can be harmful if swallowed or if spray mist is inhaled. Corrosive to lungs.
SIGNS AND SYMPTOMS OF EXPOSURE: If in eyes: Burning sensation, watering, or redness. If on skin: Redness, irritation, or burning sensation with prolonged exposure.
If spray mist is inhaled: Possible lung damage, irritation and/or burning sensation. If swallowed: Drowsiness, irregular pulse, loss of consciousness. Possible gastrointestinal irritation or
disturbance such as cramps and stomach pains. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: None known.
CARCINOGENICITY: NO ingredients listed as carcinogens by the NTP (National Toxicology Program) or the IARC (International Agency for Research on Cancer) or regulated by OSHA.
SECTION 4 - FIRST AID MEASURES
If in eyes: Flush with water for 15 minutes. If on skin: Wash liberally with soap and water. If on clothes: Wash before reuse. If spray mist is inhaled: Remove to fresh air.
If swallowed: If patient is conscious and alert, dilute by drinking milk, egg whites or large quantities of water. Do not induce vomiting without medical advice.
Always get medical attention when product is swallowed or when symptoms are significant or persist.
SECTION 5 - FIRE FIGHTING MEASURES
FLASH POINT: 1150F (METHOD USED): SETA Flammable Limits: N/D LEL: N/D UEL: N/D
EXTINGUISHING MEDIA: Methods suitable for the surrounding fire such as Carbon dioxide, Water, Dry Chemical
SPECIAL FIRE FIGHTING PROCEDURES: Apply water spray to cool closed containers.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Burning may release combustion products such as Phenolics, carbon monoxide, carbon dioxide, and chlorine
SECTION 6 - ACCIDENTAL RELEASE MEASURES
SMALL SPILLS: Small spills (less than 1 gallon) may be washed down a drain with lots of water or cleaned up and disposed of into a sanitary sewer system.
LARGE SPILLS: Large spills (more than 1 gallon) should be contained and collected (by absorption [sand, clay, or other absorbent material] or vacuuming) then disposed of properly.
SECTION 7 - HANDLING & STORAGE
HANDLING: Do not contaminate water, food, or feed. Do not reuse empty containers. Keep containers clean and closed. STORAGE: KEEP OUT OF REACH OF CHILDREN.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Mechanical (General): Normally Sufficient Local Exhaust: Not Normally Needed
RESPIRATORY PROTECTION: General ventilation is normally adequate. Use appropriate respiratory protection if application method produces a fine spray or mists.
SKIN PROTECTION: Gloves are required for exposure to the concentrate when diluting or for long exposures to end-use dilutions. Persons sensitive to cleaning chemicals should always wear
gloves. EYE PROTECTION: USE Safety Glasses when diluting concentrates or when splashing or spraying of diluted product into the eyes is likely.
WORK/HYGIENE PRACTICES: Wash hands after using. Do not get into eyes, on skin, or clothing. May be harmful if swallowed. Protect food and drink from contamination by product.
SECTION 9 - PHYSICAL / CHEMICAL PROPERTIES
Appearance and Odor: A clear light amber liquid with a slight sassafras odor. Product will darken with age.
Boiling Point: 1.024 to 1.044 pH (Concentrate):
2120 F Specific Gravity: @250C 11.50 to 12.50
Vapor Pressure: Solubility In Water: Complete pH (Diluted): 1:128
N.E. 9.50 to 10.50
Vapor Density: Melting Point: N/A Evaporation Rate:
N.E. N.E.
SECTION 10 - STABILITY & REACTIVITY
STABILITY: Stable INCOMPATIBILITY (Materials or Conditions to Avoid): Extreme high temperatures, sparks, open flames, and strong oxidizing agents.
HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION OR BYPRODUCTS: None known
SECTION 11 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: This product is not considered a RCRA Hazardous Waste as identified in Federal Regulations 40 CFR 261. Dispose of product by using in accordance with
label directions or in compliance with local, state, and federal laws and regulations (contact local or state environmental agency for specific rules).
SECTION 12 - TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: 1 Gallon = ORM-D Consumer Commodity 5 gal. & 55 gal. = Flammable Liquid, Corrosive N.O.S. (Isopropanol, Sodium Hydroxide)
DOT LABELING: ORM-D or Flammable Liquid 3 and Corrosive (subsidiary w/o #8), UN2924
DOT HAZARD CLASS: Class 3 (Flammable), Packing Group III, UN2924
NOTE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty,
expressed or implied is given. It is the responsibility of the user to comply with all Federal, State and Local laws and regulations.
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