MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name Ink JP-R65
Name of company Hitachi Industrial Equipment Systems Co., Ltd.
Address 1-1,Higashitaga-cho 1-chome, Hitachi-shi, Ibaraki-ken, Japan
Tel 0294-36-8682 Fax 0294-36-8975
2. COMPOSITION , INFORMATION ON INGREDIENTS
Substance/Mixture Mixture
Chemical name CAS No Composition (%)
Methyl Ethyl Ketone 78-93-3 30-40
Methanol 67-56-1 10-20
Chrome-Complex Dye TSCA Registered 1-5
2-Hydroxypropylacrylate TSCA Registered 1-5
3. HAZARDS IDENTIFICATION
Class name of hazardous chemicals for SDS in Japan
Flammable Liquids.
Physical and chemical hazardous Highly flammable liquids.
Adverse human health hazardous Irritating to eyes, respiratory system and skins.
4. FIRST AID MEASURES
Eye contact
Gently rinse the affected eyes with clean water for at least 15 minutes. Remove contact
lenses if easily possible. and refer for medical attention.
Skin contact
Remove all contaminated clothing, shoes and socks from the affected areas as quickly as
possible. Wash the affected area under running water using a mild soap. If irritation
persists, arrange for transport to the nearest medical facility for examination and treatment
by a physician as son as possible.
Inhalation
Remove the victim from the contamination immediately to fresh air. Keep the victim warm
and quiet and arrange for transport to the neatest medial facility for examination and
treatment by a physician as soon as possible.
Ingestion
Never give anything by mouth to someone who is unconscious or convulsing. If the victim
is responsive, give him one or two glasses of water. And refer for medial attention.
5. FIRE AID MEAFURES
Specific Hazards with regard to fire-fighting measure
fight fire from maximum distance.
Shut off fuel to fire if possible to do so without hazards.
Extinguishing media
Dry chemical powder, foam or dioxide.
6. ACCIDENTIAL RELEASE MEARURES
Shut off all sources of ignition; No smoking or flames in area. Absorb spill with inert material
(e.g., dry sand or earth), then place in closed containers using non-sparking tools. Flush
residual spill (area) with copious amounts of water.
7.HANDLING AND STORAGE
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Handling
Use only in the well-ventilated areas.
Make available in the work area emergency shower and eyes wash.
Avoid contact with skin or eyes.
Storage
Close up the container and keep it in dark cool(0~20 ) place.
Keep away from combustible materials and sources of ignition.
8.EXPOSURE CONTROL , PERSONAL PROTECTION
Exposure guidelines
Methyl Ethyl Ketone ACGIH TLV TWA 200ppm
STEL 300ppm
OSHA PEL TWA 200ppm
Methanol ACGIH TLV TWA 200ppm
STEL 250ppm
OSHA PEL TWA 200ppm
STEL 250ppm
2-Hydroxypropylacrylate ACGIH TLV TWA 0.5ppm
Engineering measure
Use exhaust ventilation to keep airborne concentration below exposure limit.
Personal protective equipment
Respiratory protection Mask for organic solvent.
Eye protection Protective glasses. Protective goggles.
Hand protection Solvent proof gloves.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Red liquid
Odor Irritant odor
Density 0.942-0.954(20 )
Boiling point Upper than 64.1
Melting point No measurement
Vapor pressure Lower than 12.8kPa
Flash point -1.1 (Closed cup)
Autoignition temperature 404
Flammable limits Lower 1.8% Upper 37%
10. STABILITY AND REACTIVITY
Stability The product is stable.
Conditions and materials to avoid Not available
Hazardous decomposition products These products are carbon oxides
11. TOXICOLOGICAL INFORMATION
Methyl Ethyl Ketone
Acute Toxicity
Eye contact (human) 350ppm Irritant properties
Skin contact (rabbit) 500mg/24h Moderate irritant properties
Inhalation TCL0 (human) 100ppm/5min
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Inhalation LCL0 (rat) 2000ppm/4h
Oral LD50 (rat) 4050mg/kg
Sub-chronic Toxicity
Rats exposed to 2150ppm for 6 weeks showed no adverse effects to nervous system
disturbances.
Chronic Toxicity
Rats exposed to 1125ppm for 5 months showed no adverse effects to peripheral nervous
system disturbances.
Mutagenic Effects
Sex chromosome loss and nondisjunction S.cerevisiae, 33,800ppm
Methanol
Acute Toxicity
Oral LDL0 (human) 340mg/kg
LDL0 (mouse) 420mg/kg
LDL0 (dog) 6300mg/kg
LDL0 (monkey) 7000mg/kg
LDL0 (rabbit) 4750mg/kg
TDL0 (human) 100mg/kg
Inhalation LC50 (monkey) 1000ppm
TCL0 (human) 300ppm
Chrome-Complex Dye
Acute Toxicity
Oral LD50 (rat) 3000mg/kg
2-Hydroxypropyl acrylate
Acute Toxicity
Oral LD50 (mouse) 1056mg/kg
LD50 (rat) 250mg/kg
12. ECOLOGICAL INFORMATION
No applicable information was found.
13. DISPOSAL CONSIDERATION
Scrap materials may be disposed by licensed contractor or burn in an approved incinerator.
Do not dump into sewer , on the ground or into any body of water.
Follow national and local regulations.
14. TRANSPORT INFORMATION
UN Class 3(Flammable liquids)
UN Number 1210
Follow all regulations in your country.
15. REGULATION INFORMATION
Follow all regulations in your country.
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Content of RoHS Directive material Cd<100ppm Pb, Hg, Hexavalent Cr, PBB, PBDE<1000ppm
16. OTHER INFORMATION
Date of issue Aug.31, 2005
Prepared by Yoshiharu Takizawa
Version 1.40
To the best of our knowledge, the information contained here in is accurate. However,
neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final
determination of suitability of any material is the sole responsibility of the user. All materials
may present unknown hazards and should be used with caution. Although certain hazards
are described herein, we cannot guarantee that these are the only hazards that exist.
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