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CAS

65997-17-3 1333-86-4 50-00-0 624-83-9

File Name: 65997-17-3_1333-86-4_50-00-0_624-83.asp

                                      Material Name: Fiber Glass Specialty Insulation                             Safety Data Sheet
ID: 1001

Section 1 - Product and Company Identification
Hazard Label WARNING label
Company Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Insulation Systems Internet Address: http://www.jm.com
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA

Trade Names:
Appliance Spin-Glas?(ASG); Microlite?TC; Spin-Glas?Board Equipment Insulation;
CM-24; Microlite?WH; Spin-Glas?Water Heater (SG-WH);
CM-26; Microlite?XP; Tuf-GlasTM;
Exact-O-Board? Microlite? Tuf-Skin?II;
Flex-GlasTM PC; Range Spin-Glas? Tuf-Skin?
Microlite?Duct Wrap; Spin-Glas?(SG) 22-32; ValuliteTM
Microlite?MW; Spin-Glas?All Types;


Section 2 - Composition / Information on Ingredients
CAS # Component Percent
65997-17-3 Fiber Glass Wool 50-99
Not Available Urea extended phenol-formaldehyde binder (cured) 1-20**
Not Available Urea extended phenol-melamine formaldehyde binder(cured) 1-20**
1333-86-4 Carbon black (encapsulated) 0-20*
Not Available Phenol-formaldehyde binder (cured) 1-6***
50-00-0 Formaldehyde <1

Component Related Regulatory Information
Glass filaments, Glass wool fiber, Fibrous glass.
*Carbon black is a component of some black products only and is encapsulated within binder or coatings. Note: Due to the
product form, exposures to hazardous dusts or fumes are not expected to occur. Exposure limits are given for reference only.
** For trade names other than Range Spin-Glas? binder may be any of these.
*** Range Spin-Glas?binder.
Some products have facings of kraft paper, vinyl, or other materials.

Free formaldehyde released only with high temperature and humidity. Temperatures >32癈/90癋.
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Fibrous glass blanket or board; white, gold-to-yellow, orange, black, or black with an amber or
black core; with or without non-woven facings. No significant odor.

Inhalation of excessive amounts of dust from the product may cause temporary upper respiratory irritation and/or congestion--
remove individual to fresh air.

Potential Health Effects
Summary
Breathing dust from this product may cause a scratchy throat, congestion, and slight coughing. Getting dust or fibers on the
skin, or in the eyes may cause itching, rash, or redness. Additional health and safety information is provided in Section 11 of
this material safety data sheet.
Inhalation
Irritation of the upper respiratory tract (scratchy throat), coughing, and congestion may occur in extreme exposures.
Skin
Temporary irritation (itching) or redness may occur.


____________________________________________________________
Page 1 of 7 Issue Date: 07/02/2007 Revision: 2.0012
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

Absorption
Not applicable
Ingestion
This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal
(digestive) tract.
Eyes
Temporary irritation (itching) or redness may occur.
Ears
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Inhalation (breathing dust), skin, and eye contact.
Target Organs
Nose (nasal passages), throat, lungs, skin, eyes.
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air. Drink water to clear throat, and blow nose to remove dust.
First Aid: Skin
Wash gently with soap and water to remove dust. Wash hands before eating or using the restroom.
First Aid: Ingestion
Product is not intended to be ingested or eaten. If this product is ingested, irritation of the gastrointestinal (GI) tract may occur,
and should be treated symptomatically. Rinse mouth with water to remove fibers, and drink plenty of water to help reduce the
irritation. No chronic effects are expected following ingestion.
First Aid: Eyes
Do not rub or scratch your eyes. Dust particles may cause the eye to be scratched. Flush eyes with large amounts of water for
5-15 minutes. If irritation persists, contact a medical professional.
First Aid: Ears
Wash exposed skin with soap and water. If irritation develops in the inner ear, seek medical attention.
First Aid: Notes to Physician
This product is a mechanical irritant, and is not expected to produce any chronic health effects from acute exposures.
Treatment should be directed toward removing the source of irritation with symptomatic treatment as necessary.
Section 5 - Fire Fighting Measures
Flash Point: Not applicable Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion.
Extinguishing Media
Carbon dioxide (CO2), water, water fog, dry chemical.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Clean-Up Procedures
Pick up large pieces. Vacuum dusts. If sweeping is necessary, use a dust suppressant such as water. Do not dry sweep dust
accumulation. These procedures will help to minimize potential exposures.
Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in
accordance with good industrial hygiene and safety practices.


____________________________________________________________
Page 2 of 7 Issue Date: 07/02/2007 Revision: 2.0012
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and in original
packaging.
Section 8 - Exposure Controls / Personal Protection
The Occupational Safety and Health Administration (OSHA) has not adopted specific occupational exposure standards for
fiber glass. Fiber glass is treated as a nuisance dust and is regulated by OSHA as a particulate not otherwise regulated (total
dust) shown in CFR 1910.1000 Table Z-3.
Respirable fraction 5 mg/m3
Total dust 15 mg/m3

Carbon black (encapsulated) (1333-86-4)
ACGIH: 3.5 mg/m3 TWA
OSHA: 3.5 mg/m3 TWA

Formaldehyde (50-00-0)
ACGIH: 0.3 ppm Ceiling
OSHA: 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29
CFR 1910.1048)

Exposure Limits for Chemicals which may be generated during processing
Methyl isocyanate (624-83-9)
ACGIH: 0.02 ppm TWA
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 0.02 ppm TWA; 0.05 mg/m3 TWA
Prevent or reduce skin absorption
NIOSH: 0.02 ppm TWA; 0.05 mg/m3 TWA
Potential for dermal absorption

PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Safety glasses with side shields are recommended to keep dust out of the eyes.
Personal Protective Equipment: Ears
Use ear protection (earplugs, hood, or earmuffs) to prevent airborne dust or fibers from entering the ear, if necessary.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to prevent skin contact and irritation. Barrier creams may also be used to reduce skin
contact and irritation caused by fiber glass.
Personal Protective Equipment: Respiratory
A respirator should be used if ventilation is unavailable, or is inadequate for keeping dust and fiber levels below the applicable
exposure limits. In those cases, use a NIOSH-certified disposable or reusable particulate respirator with an efficiency rating of
N95 or higher (under 42 CFR 84) when working with this product. For exposures up to five times the established exposure
limits use a quarter-mask respirator, rated N95 or higher; and for exposures up to ten times the established exposure limits
use a half-mask respirator (e.g., MSA's DM-11, Racal's Delta N95, 3M's 8210), rated N95 or higher. Operations such as
sawing, blowing, tear out, and spraying may generate airborne fiber concentrations requiring a higher level of respiratory
protection. For exposures up to 50 times the established exposure limits use a full-face respirator, rated N99 or higher.
Ventilation
In fixed manufacturing settings, local exhaust ventilation should be provided at areas of cutting to remove airborne dust and
fibers. General dilution ventilation should be provided as necessary to keep airborne dust and fibers below the applicable
exposure limits and guidelines. The need for ventilation systems should be evaluated by a professional industrial hygienist,
while the design of specific ventilation systems should be conducted by a professional engineer.
Personal Protective Equipment: General
Wear a cap, a loose-fitting, long-sleeved shirt and long pants to protect skin from irritation. Exposed skin areas should be
washed with soap and warm water after handling or working with fiber glass. Clothing should be washed separately from other
clothes, and the washer should be rinsed thoroughly (run empty for a complete wash cycle). This will reduce the chances of
fiber glass being transferred to other clothing.




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Page 3 of 7 Issue Date: 07/02/2007 Revision: 2.0012
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

Section 9 - Physical & Chemical Properties
Appearance: Odor:
White, gold-to-yellow, orange, No significant odor
black, or black with an amber or
black core; fibrous glass blanket or
board.
Physical State: pH:
Solid Not applicable
Vapor Pressure: Vapor Density:
Not applicable Not applicable
Boiling Point: Melting Point:
Not applicable >704篊/1300篎
Solubility (H2O): Specific Gravity:
Nil Variable
Freezing Point: Evaporation Rate:
Not applicable Not applicable
Percent Volatile: VOC:
0 Less than or equal to 0.00661 g/L

Section 10 - Stability & Reactivity Information
Stability
This is a stable material. This product is not reactive.
Hazardous Decomposition
The decomposition products from this material are those that would be expected from any organic (carbon-containing)
material, and are mainly derived from pyrolysis, or burning, of the resin. These decomposition products may include carbon
monoxide, carbon dioxide, carbon particles, and traces of hydrogen cyanide. Methyl Isocyanate may be generated in hot end-
use applications.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
Dust from this product is a mechanical irritant, which means that it may cause temporary irritation or scratchiness of the throat,
and/or itching of the eyes and skin.
B: Component Analysis - LD50/LC50
Carbon black (encapsulated) (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit: >3 g/kg

Formaldehyde (50-00-0)
Inhalation LC50 Rat: 0.578 mg/L/4H; Inhalation LC50 Rat: 250 ppm/4H; Oral LD50 Rat: 100 mg/kg; Dermal LD50 Rabbit: 270
mg/kg

Component Carcinogenicity
Fiber Glass Wool (65997-17-3)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
NTP: Reasonably Anticipated To Be A Carcinogen (respirable size)
IARC: Group 3 - Not Classifiable (IARC Monograph 81 [2002] (listed under Man-made mineral fibres),
Monograph 43 [1988])

Carbon black (encapsulated) (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 posted, Monograph 65
[1996])

Formaldehyde (50-00-0)
ACGIH: A2 - Suspected Human Carcinogen
OSHA: 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29
CFR 1910.1048)
NTP: Reasonably Anticipated To Be A Carcinogen (Possible Select Carcinogen)
IARC: Group 1 - Known Human Carcinogen (IARC Monograph 88 [2006], Monograph 62 [1995],
Supplement 7 [1987])


____________________________________________________________
Page 4 of 7 Issue Date: 07/02/2007 Revision: 2.0012
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

Chronic Toxicity
Fiber Glass Wool: In October 2001, IARC classified fiber glass wool as Group 3, "not classifiable as to its carcinogenicity to
humans." The 2001 decision was based on current human and animal research that shows no association between inhalation
exposure to dust from fiber glass wool and the development of respiratory disease. This is a reversal of the IARC finding in
1987 of a Group 2B designation (possibly carcinogenic to humans) based on earlier studies in which animals were injected
with large quantities of fiber glass. NTP and ACGIH have not yet reviewed the IARC reclassification or the most current fiber
glass health research; at this time, both agencies continue to classify glass wool based on the earlier animal injection studies.
Section 12 - Ecological Information
Ecotoxicity
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Carbon black (encapsulated) (1333-86-4)
24 Hr EC50 Daphnia magna: >5600 mg/L

Formaldehyde (50-00-0)
96 Hr LC50 Pimephales promelas: 24.1 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 0.10 mg/L [flow-through]; 96
Hr LC50 Brachydanio rerio: 41 mg/L [static]
5 min EC50 Photobacterium phosphoreum: 9.0 mg/L; 15 min EC50 Photobacterium phosphoreum: 7.26 mg/L; 25 min EC50
Photobacterium phosphoreum: 6.81 mg/L; 30 min EC50 Photobacterium phosphoreum: 16.5 mg/L; 1 Hr EC50 Vibrio harveyi:
1.2 mg/L; 5 Hr EC50 Vibrio harveyi: 3.7 mg/L; 72 Hr EC50 Colpoda aspera: 5.39 mg/L
96 Hr EC50 water flea: 20 mg/L; 48 Hr EC50 Daphnia magna: 2 mg/L

Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
General Product Information
This product, as supplied, is not regulated as a hazardous waste by the U.S. Environmental Protection Agency (EPA) under
Resource Conservation and Recovery Act (RCRA) regulations. Comply with state and local regulations for disposal. If you are
unsure of the regulations, contact your local Public Health Department, or the local office of the EPA.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.
Section 14 - Transportation Information
International Transportation Regulations
These products are not classified as dangerous goods according to international transport regulations.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Delayed (chronic) health hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Formaldehyde (50-00-0)
SARA 302: 500 lb TPQ
SARA 313: 0.1 % de minimis concentration
CERCLA: 100 lb final RQ; 45.4 kg final RQ

State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.




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Page 5 of 7 Issue Date: 07/02/2007 Revision: 2.0012
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Fiber Glass Wool (箁elated to Mineral wool fiber) 65997-17-3 Yes? No Yes? Yes Yes? Yes?br> (瞨elated to Fibrous glass)
Carbon black (encapsulated) 1333-86-4 Yes No Yes Yes Yes Yes
Formaldehyde 50-00-0 Yes No Yes Yes Yes Yes

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Fiber Glass Wool (箁elated to Mineral wool fiber) (瞨elated to Fibrous glass) 65997-17-3
Formaldehyde 50-00-0

A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.

None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
International Regulations
A: General Product Information
These products are considered articles under both U.S. and international product regulations and as such, these products and
their ingredients do not require registration or notification on the various country-specific inventories.
B: Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Fiber Glass Wool 65997-17-3 1 % (related to Fibrous glass)
Carbon black (encapsulated) 1333-86-4 1%
Formaldehyde 50-00-0 0.1 %

WHMIS Classification
Controlled Product Classification: D2A based on the IARC classification of formaldehyde (Group 1).
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. This SDS
contains all the information required by the Controlled Products Regulations.

Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Insulation Systems
P. O. Box 5108
Denver, CO USA 80217-5108

Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005

The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.

Date MSDS # Reason
08/01/00 1001-1.0000 New MSDS authoring system.
01/08/01 1001-1.010 Minor regulatory update (per LOLI)
1/9/02 1001-2.0000 Update Sections 3, 11, 15 for IARC 2001 re-classification of fiber
glass wool to Group 3, not classifiable as to carcinogenicity to
humans.
____________________________________________________________
Page 6 of 7 Issue Date: 07/02/2007 Revision: 2.0012
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

06/05/02 1001-2.0001 Sect. 2, added acrylic resin for Formaldehyde-free product. Sect. 3
APPEARANCE, inserted "white" for Formaldehyde-free product.
02/27/03 1001-2.0002 Sect. 11 corrected for IARC 2002.
04/30/03 1001-2.0003 Sect. 1: Add "Range-Glas?XG" and "Microlite?XG" new trade
names.
06/02/03 1001-2.0004 Sect. 1: Changed manufacturer to Performance Materials Div.
Moved XG products to separate MSDS 1201. Updated for carbon
black Prop. 65: Sect. 2 and 11.
01/07/04 1001-2.0005 Sect. 1 Changed OEM to Specialty, Sect. 11 Deleted carcinogen
statement.
04/30/04 1001-2.0006 Minor regulatory update (LOLI)
06/21/04 1001-2.0007 Sect 3 removed 'green' and replaced it with 'amber or black core'.
Updated hazard label from 'FBG-003' to 'FGW-01'.
08/02/05 1001-2.0008 Section 2 addition of trade name Tuf-GlasTM. Minor edits
throughout.
10/06/05 1001-2.0009 Section 1, removed Microlite AWP from trade names. Obsolete
product.
01/16/07 1001-2.0011 Added Methyl Isocyanate to sections 8 and 10 based on analysis.
Section 9 added VOC content for products based on analysis.
Added article statement in Section 15.
07/02/07 1001-2.0112 Added Microlite Duct Wrap to trade names. Addition of WHMIS
classification.



This is the end of MSDS # 1001




____________________________________________________________
Page 7 of 7 Issue Date: 07/02/2007 Revision: 2.0012

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