MSDS Material Safety Data Sheet

1333-86-4 1309-64-4 50-00-0 624-83-9

File Name: 1333-86-4_1309-64-4_50-00-0_624-83.asp

                                       Material Name: Fiber Glass Specialty Insulation                               Safety Data Sheet
ID: 1001

Section 1 - Product and Company Identification
Hazard Label WARNING label
Company Information
Johns Manville Telephone: 303-978-2000 8:00AM-5:00PM M-F
Insulation Systems Internet Address:
P.O. Box 5108 Emergency: 800-424-9300 (Chemtrec, In English)
Denver, CO 80127 USA

Trade Names:
Appliance Spin-Glas?(ASG); Microlite?MW; Tuf-GlasTM;
CM-24; Microlite?Standard Duct Wrap; Tuf-Skin?II;
CM-26; Microlite? Tuf-Skin?
DuraCoreTM; SG Series Spin-Glas? ValuliteTM
Exact-O-Board? Spin-Glas?Board Equipment Insulation;

Section 2 - Hazards Identification
Emergency Overview
Inhalation of excessive amounts of dust from the product may cause temporary upper respiratory irritation and/or congestion--
remove individual to fresh air.

In high temperature applications, treatment, curing, or in geographic areas of high heat and humidity, this product may release
gases irritating to the eyes, nose and throat. In confined or poorly ventilated areas, use air supplied respirators during the first
heat-up cycles.
Temporary mechanical irritation may occur upon exposure to dust or fibers released from cutting this product.

Irritation of the upper respiratory tract, coughing, and congestion may occur in extreme exposures. Severe irritation of the
mouth, nose, and throat, as well as signs of central nervous system depression (drowsiness, dizziness, headache), may occur
upon inhalation of vapors or gases.
Temporary irritation (itching) or redness may occur.
This product is not intended to be ingested (eaten). If ingested, it may cause temporary irritation to the gastrointestinal
(digestive) tract.
Temporary irritation (itching) or redness may occur.
Temporary irritation (itching) or redness may occur.
Primary Routes of Entry (Exposure)
Eyes, skin, inhalation (breathing dust and fibers) and ingestion.
Target Organs
Nose (nasal passages), throat, lungs, skin, eyes
Medical Conditions Aggravated by Exposure
Pre-existing chronic respiratory, skin, or eye diseases or conditions.
Section 3 - Composition/Information on Ingredients
CAS # Component Percent
Not Available Fiber Glass Wool 50-99
Not Available Urea extended phenol-formaldehyde binder (cured) 1-20*
Not Available Urea extended phenol-melamine formaldehyde binder(cured) 1-20*
1333-86-4 Carbon black (encapsulated) <10
Not Available Phenol-formaldehyde binder (cured) (Range Spin-Glas?binder only) 1-6
1309-64-4 Antimony trioxide <3
50-00-0 Formaldehyde <1

Page 1 of 7 Issue Date: 06/10/2009 Revision: 2.0016
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

Component Information
*Binder may be either of these.

Some products have facings of kraft paper, vinyl, or other materials.

Antimony trioxide (fire retardant) may be present in the facings and/or adhesives. Occupational exposure to airborne antimony
trioxide is not expected to occur due to product form(s) and intended use(s). Exposure limit is given for reference only.

Formaldehyde may be released by partial hydrolysis of the urea formaldehyde polymer.

General Product Description
Fibrous glass blanket or board; white, gold-to-yellow, orange, black, or black with an amber or black core; with or without non-
woven facings. No significant odor.
Section 4 - First Aid Measures
First Aid: Inhalation
If dust is inhaled in excess of exposure limits referenced in section 8 of this safety data sheet, remove individual to fresh air.
Drink water to clear throat, and blow nose to remove dust. A saline spray in the nose may help clear any fibers.
First Aid: Skin
Wash gently with soap and water to remove dust and fibers. Alternatively, fibers can be removed from the skin by use of
ordinary masking or wrapping tape. Should irritation persist, seek medical attention.
First Aid: Ingestion
Rinse mouth with water to remove dust and fibers and drink plenty of water to help reduce irritation. If irritation persists, seek
medical attention.
First Aid: Eyes
Do not rub or scratch eyes. Dust particles may cause the eye to be scratched. Flush eyes with large amounts of water until
irritation subsides. If irritation persists, seek medical attention.
First Aid: Ears
Wash exposed skin with soap and water. If irritation develops in the inner ear, seek medical attention.
First Aid: Notes to Physician
Dust from the product may cause mechanical irritation of the eyes, skin, and upper respiratory tract. Treat symptomatically.

Irritating gases may be released under conditions of high heat or humidity. At high levels, these could cause severe upper
respiratory and eye irritation. Formaldehyde gas is a skin and respiratory sensitizer. Treatment should be directed toward
removing the source of irritation with symptomatic treatment as necessary.
Section 5 - Fire Fighting Measures
Flash Point: Not applicable Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not determined Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
There is no potential for spontaneous fire or explosion. Inorganic glass fibers are naturally non-combustible and non-
Extinguishing Media
Carbon dioxide (CO2), water, water fog, dry chemical.
Fire Fighting Equipment/Instructions
No special procedures are expected to be necessary for this product. Normal fire fighting procedures should be followed to
avoid inhalation of smoke and gases.
Section 6 - Accidental Release Measures
Clean-Up Procedures
Pick up large pieces. Vacuum dusts. If sweeping is necessary, use a dust suppressant such as water. Do not dry sweep dust
accumulation. These procedures will help to minimize potential exposures.

Page 2 of 7 Issue Date: 06/10/2009 Revision: 2.0016
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

Section 7 - Handling and Storage
Handling Procedures
Use protective equipment as described in Section 8 of this safety data sheet when handling uncontained material. Handle in
accordance with good industrial hygiene and safety practices.

Storage Procedures
Warehouse storage should be in accordance with package directions, if any. Material should be kept clean, dry, and in original
Section 8 - Exposure Controls / Personal Protection
The Occupational Safety and Health Administration (OSHA) has not adopted specific occupational exposure standards for
fiber glass. Fiber glass is treated as a nuisance dust and is regulated by OSHA as a particulate not otherwise regulated (total
dust) shown in CFR 1910.1000 Table Z-3.
Respirable fraction 5 mg/m3
Total dust 15 mg/m3

JM has adopted the fiber glass industry voluntary Product Stewardship Program (PSP), formerly the NAIMA-OSHA Health and
Safety Partnership Program (HSPP). Under the PSP, JM recommends that exposures be limited to the voluntary concentration
of 1 f/cc TWA for fibers longer than 5 microns with a diameter less than 3 microns. This will help minimize potential irritation
effects. The PSP also includes the PPE recommendations described below.

Carbon black (encapsulated) (1333-86-4)
OSHA: 3.5 mg/m3 TWA
3.5 mg/m3 TWA
ACGIH: 3.5 mg/m3 TWA

Formaldehyde (50-00-0)
OSHA: 0.75 ppm TWA
0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29
CFR 1910.1048)
3 ppm TWA (unless specified in 1910.1048)
ACGIH: 0.3 ppm Ceiling

Exposure Limits for Chemicals which may be generated during processing
Methyl isocyanate (624-83-9)
ACGIH: 0.02 ppm TWA
Skin - potential significant contribution to overall exposure by the cutaneous route
OSHA: 0.02 ppm TWA; 0.05 mg/m3 TWA
Prevent or reduce skin absorption
NIOSH: 0.02 ppm TWA; 0.05 mg/m3 TWA
Potential for dermal absorption

Personal Protective Equipment: Eyes/Face
Safety glasses with side shields are recommended to keep dust out of the eyes.
Personal Protective Equipment: Ears
Use ear protection (earplugs, hood, or earmuffs) to prevent airborne dust or fibers from entering the ear, if necessary.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to protect against mechanical abrasion. See also Personal Protective Equipment:
General, below.
Personal Protective Equipment: Respiratory
A respirator should be used if ventilation is unavailable, or is inadequate for keeping dust and fiber levels below the applicable
exposure limits referenced in Section 8 of this SDS. Wear a NIOSH-certified disposable or reusable particulate respirator with
an efficiency rating of N95 or higher (per 42 CFR 84) when dust or fiber concentrations exceed the applicable exposure limits.
Operations such as sawing, blowing, tear out, and spraying may generate airborne fiber concentrations requiring a higher level
of respiratory protection. For exposures up to 50 times the established exposure limits use a full-face respirator, rated N99 or

Page 3 of 7 Issue Date: 06/10/2009 Revision: 2.0016
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

In fixed manufacturing settings, local exhaust ventilation should be provided at areas of cutting, milling or other processing to
remove airborne dust and fibers.
Personal Protective Equipment: General
Wear a cap, a loose-fitting, long-sleeved shirt and long pants to protect skin from irritation. Exposed skin areas should be
washed with soap and water after handling or working with fiber glass. Clothing should be washed separately from other
clothes, and the washer should be rinsed thoroughly (run empty for a complete wash cycle). This will reduce the chances of
fiber glass being transferred to other clothing.
Section 9 - Physical & Chemical Properties
Appearance: Odor:
White, gold-to-yellow, orange, black, or No significant odor
black with an amber or black core; fibrous
glass blanket or board.
Physical State: pH:
Solid Not applicable
Vapor Pressure: Vapor Density:
Not applicable Not applicable
Boiling Point: Melting Point:
Not applicable >704篊/1300篎
Solubility (H2O): Specific Gravity:
Nil Variable
Freezing Point: Evaporation Rate:
Not applicable Not applicable
Percent Volatile: VOC:
0 Less than or equal to 0.00661 g/L

Section 10 - Stability & Reactivity Information
These products are not reactive.
Hazardous Decomposition
May form carbon dioxide and carbon monoxide.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
A: General Product Information
If dust evolves from this product during use it may cause temporary mechanical irritation or scratchiness of the throat and/or
itching of the eyes and skin.

Exposure to formaldehyde may cause eye and upper respiratory irritation, and possible respiratory or skin sensitization
(allergy). If sensitization occurs, subsequent exposures to formaldehyde may worsen asthma or other respiratory problems,
and cause allergic-type reactions.
B: Component Analysis - LD50/LC50
Carbon black (encapsulated) (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit:>3 g/kg

Antimony trioxide (1309-64-4)
Oral LD50 Rat: >34600 mg/kg

Formaldehyde (50-00-0)
Inhalation LC50 Rat: 0.578 mg/L/4H; Oral LD50 Rat:500 mg/kg

A: General Product Information
Exposure to formaldehyde has been associated with the development of nasopharyngeal cancer in laboratory animals and
humans. Formaldehyde has been classified as a known human carcinogen, Group 1, by the International Agency for Research
on Cancer (IARC). The US Occupational Safety and Health Administration (OSHA) and the US National Toxicology Program
(NTP) consider formaldehyde to have carcinogenic potential. OSHA specifically regulates formaldehyde under 29 CFR

Page 4 of 7 Issue Date: 06/10/2009 Revision: 2.0016
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

B: Component Carcinogenicity
Fiber Glass Wool
ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (listed under Synthetic
Vitreous Fibers)
NTP: Reasonably Anticipated To Be A Human Carcinogen (respirable size)
IARC: Group 3 - Not Classifiable (IARC Monograph 81 [2002] (listed under Man-made mineral fibres),
Monograph 43 [1988])

Carbon black (encapsulated) (1333-86-4)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 93 [in preparation], Monograph
65 [1996])

Antimony trioxide (1309-64-4)
ACGIH: A2 - Suspected Human Carcinogen (production)
IARC: Group 2B - Possibly Carcinogenic to Humans (IARC Monograph 47 [1989])

Formaldehyde (50-00-0)
ACGIH: A2 - Suspected Human Carcinogen
OSHA: 0.5 ppm Action Level; 0.75 ppm TWA; 2 ppm STEL (Irritant and potential cancer hazard - see 29
CFR 1910.1048)
NTP: Reasonably Anticipated To Be A Human Carcinogen (Possible Select Carcinogen)
IARC: Group 1 - Known Human Carcinogen

Chronic Toxicity
The U.S. Department of Health and Human Services, National Toxicology Program (NTP 1998, 2000, 2002) classified glass
wool (respirable size) as reasonably anticipated to be a human carcinogen, based on sufficient evidence of carcinogenicity in
animals. This assessment was originally prepared in 1993-1994 for the 7th Report on Carcinogens (NTP 1994), but has not
been updated since then in the 8th, 9th, or 10th Reports on Carcinogens (NTP 1998, 2000, 2002).
Section 12 - Ecological Information
A: General Product Information
No data available for this product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Carbon black (encapsulated) (1333-86-4)
24 Hr EC50 Daphnia magna: >5600 mg/L

Antimony trioxide (1309-64-4)
96 Hr LC50 Pimephales promelas: >80 mg/L [static]; 96 Hr LC50 Brachydanio rerio:>1000 mg/L [static]
72 Hr EC50 Selenastrum capricornutum: 67 mg/L
48 Hr EC50 Daphnia magna: >1000 mg/L

Formaldehyde (50-00-0)
96 Hr LC50 Pimephales promelas: 22.6-25.7 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus:1510 礸/L [static]; 96 Hr
LC50 Brachydanio rerio:41 mg/L [static]; 96 Hr LC50 Oncorhynchus mykiss:0.032-0.226 ml/L [flow-through]; 96 Hr LC50
Oncorhynchus mykiss:100-136 mg/L [static]; 96 Hr LC50 Pimephales promelas:23.2-29.7 mg/L [static]
96 Hr EC50 water flea: 20 mg/L; 48 Hr EC50 Daphnia magna: 2 mg/L

Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
A: General Product Information
This product is not expected to be a hazardous waste when it is disposed of according to the U.S. Environmental Protection
Agency (EPA) under Resource Conservation and Recovery Act (RCRA) regulations. Product characterization after use is
recommended to ensure proper disposal under federal and/or state requirements.
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations.

Page 5 of 7 Issue Date: 06/10/2009 Revision: 2.0016
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

Section 14 - Transport Information
International Transport Regulations
These products are not classified as dangerous goods according to international transport regulations.
Section 15 - Regulatory Information
US Federal Regulations
A: General Product Information
SARA 311 Status. The following SARA 311 designations apply to this product: Delayed (chronic) health hazard.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Antimony trioxide (1309-64-4)
CERCLA: 1000 lb final RQ; 454 kg final RQ

Formaldehyde (50-00-0)
SARA 302: 500 lb TPQ
SARA 313: 0.1 % de minimis concentration
CERCLA: 100 lb final RQ; 45.4 kg final RQ

State Regulations
A: General Product Information
The glass fibers in this product are not known to be regulated.

Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS # CA FL MA MN NJ PA
Carbon black (encapsulated) 1333-86-4 Yes No Yes Yes Yes Yes
Antimony trioxide 1309-64-4 Yes No Yes Yes Yes Yes
Formaldehyde 50-00-0 Yes No Yes Yes Yes Yes

The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Component CAS #
Fiber Glass Wool (箁elated to Glass wool fiber) (瞨elated to Fibrous glass) Not Available
Antimony trioxide 1309-64-4
Formaldehyde 50-00-0

TSCA Status
This product and its components are listed on the TSCA 8(b) inventory.

None of the components listed in this product are listed on the TSCA Export Notification 12(b) list.
International Regulations
A: General Product Information
These products are considered articles under both U.S. and international product regulations and as such, these products do
not require registration or notification on the various country-specific inventories.
B: Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Fiber Glass Wool Not Available 1 % (related to Fibrous glass)
Carbon black (encapsulated) 1333-86-4 1%
Antimony trioxide 1309-64-4 1%
Formaldehyde 50-00-0 0.1 %

WHMIS Classification
Controlled Product Classification: D2A

Page 6 of 7 Issue Date: 06/10/2009 Revision: 2.0016
Material Name: Fiber Glass Specialty Insulation Safety Data Sheet
ID: 1001

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations. This SDS
contains all the information required by the Controlled Products Regulations.

Section 16 - Other Information
Other Information
Prepared for:
Johns Manville
Insulation Systems
P. O. Box 5108
Denver, CO USA 80217-5108

Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005

The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no
warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or
provincial, and local laws.

Date MSDS # Reason
08/01/00 1001-1.0000 New MSDS authoring system.
01/08/01 1001-1.010 Minor regulatory update (per LOLI)
1/9/02 1001-2.0000 Update Sections 3, 11, 15 for IARC 2001 re-classification of fiber
glass wool to Group 3, not classifiable as to carcinogenicity to
06/05/02 1001-2.0001 Sect. 2, added acrylic resin for Formaldehyde-free product. Sect. 3
APPEARANCE, inserted "white" for Formaldehyde-free product.
02/27/03 1001-2.0002 Sect. 11 corrected for IARC 2002.
04/30/03 1001-2.0003 Sect. 1: Add "Range-Glas?XG" and "Microlite?XG" new trade
06/02/03 1001-2.0004 Sect. 1: Changed manufacturer to Performance Materials Div.
Moved XG products to separate MSDS 1201. Updated for carbon
black Prop. 65: Sect. 2 and 11.
01/07/04 1001-2.0005 Sect. 1 Changed OEM to Specialty, Sect. 11 Deleted carcinogen
04/30/04 1001-2.0006 Minor regulatory update (LOLI)
06/21/04 1001-2.0007 Sect 3 removed 'green' and replaced it with 'amber or black core'.
Updated hazard label from 'FBG-003' to 'FGW-01'.
08/02/05 1001-2.0008 Section 2 addition of trade name Tuf-GlasTM. Minor edits
10/06/05 1001-2.0009 Section 1, removed Microlite AWP from trade names. Obsolete
01/16/07 1001-2.0011 Added Methyl Isocyanate to sections 8 and 10 based on analysis.
Section 9 added VOC content for products based on analysis.
Added article statement in Section 15.
07/02/07 1001-2.0112 Added Microlite Duct Wrap to trade names. Addition of WHMIS
05/01/08 1001-2.0113 Updated SDS to GHS format.
12/19/08 1001-2.0114 Addition of new product, DuraCore.
06/10/09 1001-2.0115 Removed the following trade names: Flex Glas PC, Microlite Duct
Wrap, Microlite TC, Microlite WH, Range Spin-Glas, Spin-Glas
(SG) 22-32, Spin-Glas All Types, Spin Glas WH, and Microlite XP.
Added Microlite?Standard Duct Wrap and SG Series Spin-Glas to
trade names.

End of Sheet 1001
Page 7 of 7 Issue Date: 06/10/2009 Revision: 2.0016

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