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5989-27-5 1119-40-0 627-93-0 106-65-0 5324-84-5 127087-87-0 111-42-2

File Name: 5989-27-5_1119-40-0_627-93-0_106-65-0_5324-84-5_127087-87-0.asp

                                                      MATERIAL SAFETY DATA SHEET
CLEANER as used in ORANGE PEELS Page 1 of 4
Revised 2/05/02
Replaces 11/21/00
MSDS ID: MC2375 Printed 3/04/02

1. PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME : HAND CLEANER MSDS ID : MC2375
CHEMICAL NAME SYNONYMS : L0000382A CAS NUMBER : MIXTURE
CHEMICAL FAMILY : Cleaner FORMULA : Proprietary Information

MANUFACTURED BY: EMERGENCY RESPONSE NUMBERS:
Hydrite Chemical Co. 24 Hour Emergency # - (414) 277-1311
300 N. Patrick Blvd. CHEMTREC Emergency # - (800) 424-9300
Brookfield, WI 53008-0948
(262) 792-1450 DISTRIBUTED BY: BRO-TEX INC. Phone (800) 328-2282

2. COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENT CAS NUMBER OSHA HAZARD % BY WT.
d-Limonene 5989-27-5 Yes 3?%
Dimethyl Glutarate 1119-40-0 Yes 1?%
Dimethyl Adipate 627-93-0 Yes 0 ?3%
Dimethyl Succinate 106-65-0 Yes 0?%
Sodium Octanesulfonate 5324-84-5 Yes 0?%
Poly (oxy-1, 2-ethanediyl), 127087-87-0 Yes 0?%
alpha ?(4-nonylphenyl) ?br> omega-hydroxy-, branched
Diethanolamine 111-42-2 Yes < 1.0 %
3. HAZARDS IDENTIFICATION
PHYSICAL STATE : Liquid. COLOR : Light yellow. Opaque. ODOR : Fruity orange.

***EMERGENCY OVERVIEW***: WARNING!; Causes eye irritation. Prolonged or repeated contact may dry skin and cause irritation.
Harmful if swallowed.
POTENTIAL HEALTH EFFECTS

ROUTES OF EXPOSURE: Eyes. Ingestion. Inhalation. Skin. TARGET ORGANS: No data.
EYE CONTACT: May cause moderate to severe irritation. SKIN CONTACT: May cause mild irritation.
Prolonged and repeated contact with skin can cause defatting and drying of the skin which may result in skin irritation and dermatitis.
Contact may cause: sensitization.

SKIN ABSORPTION: No absorption hazard expected under normal use.
INHALATION: Vapors or mists may irritate: nose, throat, respiratory tract. Excessive exposure may case: headache.
INGESTION: Do not swallow. Harmful if swallowed. Aspiration into the lungs may occur during ingestion or vomiting,
resulting in lung injury.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE TO PRODUCT: Eye disorders. Skin disorders. Upper respiratory disorders.
OTHER: None known. POTENTIAL ENVIRONMENTAL EFFECTS: See Section 12.
CANCER INFORMATION: This product does not contain greater than 0.1% of the known or potential carcinogens listed in NTP, IARC, or
OSHA.
4. FIRST AID MEASURES

EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes while holding eyelids open. Tilt head to avoid
contaminating unaffected eye. Get immediate medical attention.
SKIN CONTACT: Flush skin with plenty of water while removing contaminated clothing and shoes. Do not reuse clothing or shoes until
cleaned. If irritation develops or persists, get medical attention.
INHALATION: Remove to fresh air. Get medical attention if breathing becomes difficult or respiratory irritation occurs.
INGESTION: If swallowed, call a physician immediately. DO NOT induce vomiting unless directed to do so by a physician. Never
give anything by mouth to an unconscious person. If vomiting occurs spontaneously, keep head below hips to prevent
aspiration of liquid into the lungs.
MATERIAL SAFETY DATA SHEET
CLEANER as used in ORANGE PEELS Page 2 of 4
Revised 2/05/02
Replaces 11/21/00
MSDS ID: MC2375 Printed 3/04/02

5. FIRE FIGHTING MEASURES
FLASH POINT: > 200 Deg. F. (Estimated).
FLAMMABILITY LIMITS: LEL: ~0.7% UEL: ~8.0%
AUTOIGNITION TEMPERATURE: No Data
EXTINGUISHING MEDIA: Dry chemical. Foam. Carbon dioxide.
FIRE FIGHTING METHODS: Evacuate area of unprotected personnel. Wear protective clothing including NIOSH-approved self-
contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition
products. Use water spray to cool fire-exposed containers.
FIRE AND EXPLOSION HAZARDS: Material will burn in fire, releasing toxic vapors. This material may produce a floating fire hazard.
HAZARDOUS COMBUSTION PRODUCTS: Carbon dioxide. Carbon monoxide.
6. ACCIDENTAL RELEASE MEASURES
SPILL CLEAN-UP PROCEDURES: Eliminate all sources of ignition. Evacuate unprotected personnel from area. Maintain adequate
ventilation. Follow personal protective equipment recommendations found in Section 8. Never exceed any occupational exposure
limit. Contain spill, place into drums for proper disposal. Soak up residue with inert absorbent material. Place in non-leaking
containers for immediate disposal. Flush remaining area with water to remove trace residue and dispose of properly. Avoid direct
discharge to sewers and surface waters. Notify authorities if entry occurs. CAUTION: Spilled material may be slippery.

7. HANDLING AND STORAGE
STORAGE: Store in a cool, well ventilated area, out of direct sunlight. Store in a dry location away from heat. Keep away from
incompatible materials. Keep containers tightly closed. Do not store in unlabeled or mislabeled containers. Do not freeze.
HANDLING: Avoid eye contact. Do not swallow. Avoid prolonged contact with skin. Use with adequate ventilation. Do not eat, drink, or
smoke in work area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: Maintain adequate ventilation. Do not use in closed or confined spaces.
RESPIRATORY PROTECTION: None required under normal use.
EYE/FACE PROTECTION: None required under normal use.
SKIN PROTECTION: Not required for normal use.
OTHER PROTECTIVE EQUIPMENT: Eye-wash station. Safety shower.
GENERAL HYGIENE CONSIDERATIONS: Good manufacturing practices require gross amounts of any chemical be removed from skin
as soon as practical, especially before eating or smoking.
EXPOSURE GUIDELINES: ---------OSHA--------- ---------ACGIH---------
COMPONENT PEL STEL/C TWA STEL/C
d-Limonene Not Estab. Not Estab. Not Estab. Not Estab.
Dimethyl Glutarate Not Estab. Not Estab. Not Estab. Not Estab.
Dimethyl Adipate Not Estab. Not Estab. Not Estab. Not Estab.
Dimethyl Succinate Not Estab. Not Estab. Not Estab. Not Estab.
Sodium Octanesulfonate Not Estab. Not Estab. Not Estab. Not Estab.
Poly (oxy-1, 2-ethanediyl), Not Estab. Not Estab. Not Estab. Not Estab.
alpha ?(4-nonylphenyl) ?br> omega-hydroxy-, branched
Diethanolamine 3 ppm+ Not Estab. 2mg/m3-S Not Estab.
NOTE: + Vacated 1989 OSHA PEL (s). S = Skin notation. * DuPont's Acceptable Exposure Limit (AEL) is 1.5 ppm, 10 mg/m3, 8 hour
TWA. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall
take precedence.
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT (DEG. F) : N.D. SPECIFIC GRAVITY : 1.0004 @ 25C
FREEZING POINT (DEG. F) : N.D. % VOLATILE (WT%) : N.D.
MELTING POINT (DEG. F) : N.D. EVAPORATION RATE : N.D.
VAPOR PRESSURE (MM HG) : N.D. (nBuAc=1)
VAPOR DENSITY (AIR=1) : N.D. VOC (WT%) : N.D.
SOLUBILITY IN WATER : Soluble VOC (LBS/GAL) : N.D.
pH : 6.2
MATERIAL SAFETY DATA SHEET
CLEANER as used in ORANGE PEELS Page 3 of 4
Revised 2/05/02
Replaces 11/21/00
MSDS ID: MC2375 Printed 3/04/02

10. STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions.
CONDITIONS TO AVOID: Avoid elevated temperatures. WARNING: Do not mix this product with nitrites or other nitrosating agents
because a nitrosamine may be formed. Nitrosamines may cause cancer.
INCOMPATIBILITY: Strong oxidizing agents. Peroxides. Halogens or halogen compounds. Acidic agents. Acidic clays. Iodine
pentafluoride. Vinyl chloride. Acids. Alkalies.
HAZARDOUS DECOMPOSITION PRODUCTS: Sulfur oxides. Carbon dioxide. Unidentifiable organic materials.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

11. TOXICOLOGICAL INFORMATION
LD50 ORAL : No Data
LD50 SKIN : No Data
LC50 INHALATION : No Data

12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: No data available.
CHEMICAL FATE INFORMATION: No data available.

13. DISPOSAL CONSIDERATIONS
HAZARDOUS WATE NUMBER: N.A.
DISPOSAL METHOD: Dispose of in accordance with all local, state and federal regulations. Since emptied containers retain product
residue, follow label warnings even after container is emptied. DO NOT pressurize, cut, weld, solder, drill,
grind or expose empty containers to heat, flame, sparks or other sources of ignition.

14. TRANSPORT INFORMATION (Not meant to be all inclusive)
DOT (Department of Transportation):
Proper Shipping Name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (CONTAINS DIETHANOLAMINE)
Hazard Class :9
Identification Number : UN3082
Packing Group : PGIII
Label Required : Class 9
Note: This material is not DOT regulated in shipments of less than 32,258#.
MATERIAL SAFETY DATA SHEET
CLEANER as used in ORANGE PEELS Page 4 of 4
Revised 2/05/02
Replaces 11/21/00
MSDS ID: MC2375 Printed 3/04/02

15. REGULATORY INFORMATION
FEDERAL REGULATIONS:
TSCA INVENTORY STATUS:
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements.
SARA TITLE III SECTION 311/312 CATEGORY:
IMMEDIATE (ACUTE) HEALTH HAZARD : YES
DELAYED (CHRONIC) HEALTH HAZARD : YES
FIRE HAZARD : NO
SUDDEN RELEASE OF PRESSURE HAZARD : NO
REACTIVE HAZARD : NO
SARA SECTION 302/304/313/HAP:
COMPONENT RQ (LBS) RQ (LBS) TPQ (LBS) SEC 313 HAP
(*1) (*2) (*3) (*4)
(*5)
------------------------------------- ------------------ ------------------ ------------------- ----------------
---------------
d-Limonene N.A. N.A. N.A. NO
NO
Dimethyl Glutarate N.A. N.A. N.A. NO
NO
Dimethyl Adipate N.A. N.A. N.A. NO
NO
Dimethyl Succinate N.A. N.A. N.A. NO
NO
Sodium Octanesulfonate N.A. N.A. N.A. NO
NO
Poly (oxy-1, 2-ethanediyl), N.A. N.A. N.A. NO
NO
alpha ?(4-nonylphenyl) ?br> omega-hydroxy-, branched
Diethanolamine 100 N.A. N.A. YES YES
---------------------------------------------------------------FOOTNOTES----------------------------------------------------------
*1 = CERCLA Reportable Quantity *3 = SARA EHS Threshold Planning Quantity
*2 = SARA Reportable Quantity *4 = SARA 313 Toxic Chemical/Category
*5 = U.S. EPA Hazardous Air Pollutant
--------------------------------------------------------------------------------------------------------------------------------------------
STATE REGULATIONS:
CALIFORNIA ?The following components are listed under Prop 65:
This product may contain a detectable level of chemical (s) subject to California's Proposition 65.
WISCONSIN ?The following components are listed as a Wisconsin HAP: None.

16. OTHER INFORMATION
HMIS RATING SYSTEM NFPA RATING SYSTEM
Health : 2* Health :1
Flammability :0 Flammability :0
Reactivity :0 Reactivity :0
* = Chronic Health Hazard Special Hazard : None
MSDS ABBREVIATIONS: N.A. = Not Applicable
N.D. = Not Determined
HAP = Hazardous Air Pollutant
VOC = Volatile Organic Compound
C = Ceiling Limit
N.E./Not Estab. = Not Established
MSDS PREPARED BY: KJV
REASON FOR REVISION: Changes made in Sections 2, 8, & 15.
*****************************************************************************************************************
*******
The data in this Material Safety Data Sheet relates only to the specific material designated and does not relate to its use in combination with
any other material or process. The data contained is believed to be correct. However, since conditions of use are outside our control it
should not be taken as a warranty or representation for which HYDRITE CHEMICAL CO. assumes legal responsibility. This information is
provided solely for your consideration, investigation, and verification.
*****************************************************************************************************************
*******

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