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2687-94-7 7732-18-5 79-14-1 6915-15-7 61788-90-7 68424-85-1 32426-11-2 64-17-5 7173-51-5 5538-94-3 625-45-6 68647-72-3

File Name: 2687-94-7_7732-18-5_79-14-1_6915-15-7_61788-90-7_68424-85.asp

 MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10




Material Safety Data Sheet
Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4,
Twist 'n Fill(tm) System)
MANUFACTURER: 3M
DIVISION: Building & Commercial Services Division

ADDRESS: 3M Center
St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 01/19/10
Supercedes Date: 02/06/09

Document Group: 06-1683-9

Product Use:
Intended Use: Disinfectant
Specific Use: Mild acid cleaner removes soap scum and scale from bathroom surfaces including
plastic, porcelain, ceramic, fiberglass, floors and fixtures.




SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
1-OCTYL-2-PYRROLIDINONE 2687-94-7 10 - 30
WATER 7732-18-5 10 - 30
HYDROXYACETIC ACID 79-14-1 10 - 30
MALIC ACID 6915-15-7 10 - 30
AMINES, COCO ALKYLDIMETHYL, N-OXIDES 61788-90-7 1- 5
BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM CHLORIDES 68424-85-1 2.00
OCTYLDECYLDIMETHYLAMMONIUM CHLORIDE 32426-11-2 1.5
ETHYL ALCOHOL 64-17-5 0.5 - 1.5
DIDECYLDIMETHYLAMMONIUM CHLORIDE 7173-51-5 0.9
DIOCTYL DIMETHYL AMMONIUM CHLORIDE 5538-94-3 0.6
METHOXYACETIC ACID 625-45-6 0.1 - 0.5
TERPENES AND TERPENOIDS, SWEET ORANGE-OIL 68647-72-3 0.1 - 0.5




SECTION 3: HAZARDS IDENTIFICATION

_________________________________________________________________________________________________
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MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10




3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Green color with floral fragrance.
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause allergic skin reaction.
May cause chemical skin burns. May cause chemical gastrointestinal burns. Contains a chemical or chemicals which can cause
cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing,
ulcerations, significantly impaired vision or complete loss of vision.



Skin Contact:
Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and
tissue destruction.

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.



Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.

May be absorbed following inhalation and cause target organ effects.



Ingestion:
Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea;
blood in the feces and/or vomitus may also be seen.

May be absorbed following ingestion and cause target organ effects.



Target Organ Effects:
Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,
slowed reaction time, slurred speech, giddiness, and unconsciousness.


Prolonged or repeated exposure may cause:
Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and
jaundice.

Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased
protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.



_________________________________________________________________________________________________
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MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10




Contains a chemical or chemicals which can cause birth defects or other reproductive harm.

Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.

NOTE: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of
ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an
expected effect during the foreseeable use of this product.

Ingredient C.A.S. No. Class Description Regulation
ETHYL ALCOHOL 64-17-5 Group 1 International Agency for Research on Cancer



3.3 POTENTIAL ENVIRONMENTAL EFFECTS

A 3M Product Environmental Data Sheet (PED) is available.
A conservative assessment indicates this product presents a low environmental risk. Components released to the environment
through use and disposal are expected to have insignificant environmental impacts.

SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water for at least 15
minutes. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious
person. Get immediate medical attention.

4.2 NOTE TO PHYSICIANS
Measures against circulatory shock, respiratory depression, and convulsion may be needed.

Probable mucosal damage may contraindicate the use of gastric lavage.



SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Not Applicable
Flash Point

_________________________________________________________________________________________________
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MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10



Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
Not Applicable
OSHA Flammability Classification:

5.2 EXTINGUISHING MEDIA
Material will not burn.


5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Nonflammable.

Unusual Fire and Explosion Hazards: Material will not burn.

SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures:
Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard.

Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. For
large spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully cover the spill with soda ash
(sodium carbonate) or sodium bicarbonate. Work from around the perimeter inward. Avoid splashing. Add enough water to ease
mixing and stir. Continue stirring and adding water and neutralizing agent until the reaction stops. Let cool before collecting. Or use a
commercially available 'Acid spill' clean-up kit. Follow the kit directions exactly, as specified. Clean up residue with a dilute solution
(approximately 1 to 5%) of soda ash (sodium carbonate) or baking soda (sodium bicarbonate) in water.


In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.



SECTION 7: HANDLING AND STORAGE

7.1 HANDLING
Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the product label.
Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Do not eat, drink or
smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not use on marble.

7.2 STORAGE
Do not store containers on their sides. Store away from areas where product may come into contact with food or pharmaceuticals.
Store away from strong bases.


SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS
Use in a well-ventilated area. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical
Dispenser, special ventilation is not required.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

_________________________________________________________________________________________________
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MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10




8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, eye contact with the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is
recommended: Indirect Vented Goggles, Full Face Shield.

8.2.2 Skin Protection
Avoid skin contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin
contact with the concentrate is not expected to occur.


If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective
clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl
Rubber, Nitrile.

8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, respiratory protection is not required.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH
approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Fullface air-
purifying respirator with organic vapor/acid gas cartridges. Consult the current 3M Respiratory Selection Guide for additional
information or call 1-800-243-4630 for 3M technical assistance.

8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
ETHYL ALCOHOL ACGIH STEL 1000 ppm Table A3
ETHYL ALCOHOL ACGIH TWA 1000 ppm Table A4
ETHYL ALCOHOL OSHA TWA 1000 ppm Table Z-1
HYDROXYACETIC ACID CMRG TWA 10 mg/m3


SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)



SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Green color with floral fragrance.
Odor, Color, Grade:
Liquid
General Physical Form:

Not Applicable
Flash Point
Not Applicable
Flammable Limits - LEL
Not Applicable
Flammable Limits - UEL
> 95 篎
Boiling point


_________________________________________________________________________________________________
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MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10




15 psia - 40 psia [@ 131 篎]
Vapor Pressure

Approximately 1.12 [Ref Std: WATER=1]
Specific Gravity
Approximately 0.9 - 1.5
pH


Complete
Solubility in Water
No Data Available
Hazardous Air Pollutants
1 % - 5 % [Test Method: calculated per CARB title 2]
Volatile Organic Compounds
No Data Available
Percent volatile
12.58 g/l - 62.88 g/l [Test Method: calculated per CARB title 2]
VOC Less H2O & Exempt Solvents
Approximately 100 centipoise
Viscosity


SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.

Materials and Conditions to Avoid:
10.1 Conditions to avoid
None known
10.2 Materials to avoid
Strong bases

Additional Information: DO NOT USE ON MARBLE OR MARBLE PRODUCTS.

Hazardous Polymerization: Hazardous polymerization will not occur.




Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous
decomposition products may occur as a result of oxidation, heating, or reaction with another material.



SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.



SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.


CHEMICAL FATE INFORMATION

_________________________________________________________________________________________________
Page 6 of 9
MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10




A 3M Product Environmental Data Sheet (PED) is available.




SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility.


EPA Hazardous Waste Number (RCRA): D002 (Corrosive)

Since regulations vary, consult applicable regulations or authorities before disposal.


SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
70-0705-2685-3 00-48011-19154-1 70-0705-2686-1 00-48011-19155-8
70-0705-4315-5 00-48011-19204-3 70-0705-4316-3 00-48011-19205-0
70-0705-4904-6 00-48011-19308-8 70-0705-8964-6 00-48011-19967-7
70-0707-1409-5 00-48011-20797-6 70-0708-3905-8 00-48011-23903-8
70-0708-3992-6 00-48011-19204-3 70-0709-9000-0 00-48011-29615-4
70-0710-0961-0 00-48011-23903-8 70-0711-6337-5 00-48011-34887-7
70-0711-9216-8 00-48011-19204-3




Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.


SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes




STATE REGULATIONS



CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.

All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.

_________________________________________________________________________________________________
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MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10




The components of this material are in compliance with the new chemical notification requirements for the Korean Existing
Chemicals Inventory.

The components of this product are listed on the Australian Inventory of Chemical Substances.

All the components of this product are listed on China's Inventory of Chemical Substances.

The components of this product are listed on the Canadian Domestic Substances List.




INTERNATIONAL REGULATIONS


This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.


SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 3 Flammability: 0 Reactivity: 0 Special Hazards: None
Acid/Base: Acid Corrosive: Yes

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.

HMIS Hazard Classification
Health: 3 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.

Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and
Coatings Association (NPCA).


Revision Changes:
Copyright was modified.
Section 2: Ingredient table was modified.
Section 8: Exposure guidelines ingredient information was modified.
Section 5: Flammable limits (UE) information was added.
Section 5: Flammable limits (LEL) information was added.
Section 9: Flammable limits (LEL) information was added.
Section 9: Flammable limits (UEL) information was added.
Section 10.1 Conditions to avoid was added.
Section 10.2 Materials to avoid was added.
Section 6: Release measures information was added.
Section 6: Release measures information was added.
Section 10: Materials to avoid physical property was added.
Section 10: Conditions to avoid physical property was added.

_________________________________________________________________________________________________
Page 8 of 9
MATERIAL SAFETY DATA SHEET 3M(TM) BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist
'n Fill(tm) System) 01/19/10



Section 6: Release measures information was deleted.
Section 10: Materials and conditions to avoid physical property was deleted.


DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.


3M MSDSs are available at www.3M.com




_________________________________________________________________________________________________
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