APPENDIX G
CHEMICAL MATERIAL SAFETY DATA SHEETS
MAXIM Power Corp. October 16, 2007
AENV Application ?Deerland Peaking Station Appendix G
Issue Date: 12-JAN-2007
Material Safety Data Sheet Supercedes: 12-JAN-2007
HYPERSPERSE MDC700
1 Identification of Product and Company
Identification of substance or preparation
HYPERSPERSE MDC700
Product Application Area
Membrane deposit control agent
Company/Undertaking Identification
GE Betz Canada, Inc.
3451 Erindale Station Road
Mississauga, Ontario L5C 2S9
T 905 279 2222
Emergency Telephone
(800) 877-1940
Prepared by Product Stewardship Group: 215 355-3300
2 Composition / Information On Ingredients
Information for specific product ingredients as required by the
WHMIS Regulations is listed. Refer to additional sections of this
MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
Product contains no hazardous ingredients reportable under WHMIS regulation
No component is considered to be a carcinogen by the U.S. National
Toxicology Program (NTP), the International Agency for Research on
Cancer (IARC), the American Conference of Governmental Industrial
Hygienists (ACGIH), or under WHMIS.
3 Hazards Identification
********************************************************************************
EMERGENCY OVERVIEW
May cause slight irritation to the skin. May cause slight
irritation to the eyes. Mists/aerosols may cause irritation to
upper respiratory tract.
Odor: Slight; Appearance: Light Yellow To Amber, Liquid
Fire fighters should wear positive pressure self-contained breathing
apparatus(full face-piece type). Proper fire-extinguishing media:
Substance or Preparation: HYPERSPERSE MDC700 Page 1
dry chemical, carbon dioxide, foam or water
********************************************************************************
POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
ACUTE EYE EFFECTS:
May cause slight irritation to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause gastrointestinal irritation.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
4 First Aid Measures
SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Get medical attention if irritation develops or persists.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes
with plenty of low-pressure water for at least 15 minutes. Get
medical attention if irritation persists after flushing.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air
and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions
5 Fire Fighting Measures
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water
HAZARDOUS DECOMPOSITION PRODUCTS:
elemental oxides
FLASH POINT:
> 213F > 101C P-M(CC)
6 Accidental Release Measures
Substance or Preparation: HYPERSPERSE MDC700 Page 2
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
The waste characteristics of the absorbed material, or any contaminated
soil, should be determined in accordance with provincial regulations.
Water contaminated with this product may be sent to a sanitary sewer
treatment facility, in accordance with any local agreement or
discharged under provincial regulations.
Incinerate or land dispose in an approved landfill.
7 Handling & Storage
HANDLING:
Normal chemical handling.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen,
thaw and mix completely prior to use.
8 Exposure Controls / Personal Protection
EXPOSURE LIMITS
Consult local authorities for acceptable provincial values.
Product contains no hazardous ingredients reportable under WHMIS regulation
ENGINEERING CONTROLS:
adequate ventilation
RESPIRATORY PROTECTION:
If air-purifying respirator use is appropriate, use a respirator
with dust/mist filters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles
9 Physical & Chemical Properties
Specific Grav.(70F,21C) 1.130 Vapor Pressure (mmHG) ~ 18.0
Freeze Point (F) 23 Vapor Density (air=1) < 1.00
Freeze Point (C) -5
Viscosity(cps 70F,21C) 22 % Solubility (water) 100.0
Odor Slight
Appearance Light Yellow To Amber
Physical State Liquid
Flash Point P-M(CC) > 213F > 100C
pH As Is (approx.) 4.7
Evaporation Rate (Ether=1) < 1.00
Percent VOC: 0.0
NA = not applicable ND = not determined
10 Stability & Reactivity
Substance or Preparation: HYPERSPERSE MDC700 Page 3
STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
elemental oxides
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"A"
11 Toxicological Information
No Data Available.
12 Ecological Information
AQUATIC TOXICOLOGY
Daphnia magna 48 Hour Static Screen
0% Mortality= 2500; 50% Mortality= 5000 mg/L
Fathead Minnow 96 Hour Static Bioassay with 48-Hour Renewal
0% Mortality= 5000 mg/L
Menidia beryllina (Silversides) 96 Hour Static Acute Bioassay
(pH adjusted)
LC50= 23100; No Effect Level= 6250 mg/L
Mysid Shrimp 48 Hour Static Acute Bioassay (pH adjusted)
LC50= 13800; No Effect Level= 6250 mg/L
BIODEGRADATION
BOD-28 (mg/g): 12
BOD-5 (mg/g): 9
COD (mg/g): 190
TOC (mg/g): 70
13 Disposal Considerations
Incinerate or bury in approved landfill. Please be advised that there
may be additional local or provincial requirements relating to the
disposal of waste. Consult provincial and local regulations regarding
the proper disposal of this material.
14 Transport Information
Transportation of Dangerous Goods:
DOT EMERGENCY RESPONSE GUIDE #: Not applicable
15 Regulatory Information
This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all the information required by the CPR.
CEPA:
All components of this product comply with substance notification
requirements under CEPA.
WHMIS CLASSIFICATION:
NOT REGULATED
16 Other Information
Substance or Preparation: HYPERSPERSE MDC700 Page 4
NFPA/HMIS CODE TRANSLATION
Health 1 Slight Hazard
Fire 0 Minimal Hazard
Reactivity 0 Minimal Hazard
Special NONE No special Hazard
(1) Protective Equipment B Goggles,Gloves
(1) refer to section 8 of MSDS for additional protective equipment
recommendations.
CHANGE LOG
EFFECTIVE
DATE REVISIONS TO SECTION: SUPERCEDES
--------- --------------------- ----------
MSDS status: 24-JAN-2001 ** NEW **
18-MAY-2001 12 24-JAN-2001
02-AUG-2001 12 18-MAY-2001
16-NOV-2001 12 02-AUG-2001
25-MAR-2002 15 16-NOV-2001
28-MAR-2002 12 25-MAR-2002
16-APR-2002 15 28-MAR-2002
03-JUL-2002 12 16-APR-2002
12-FEB-2003 16 03-JUL-2002
17-JAN-2006 16 12-FEB-2003
12-JAN-2007 14 17-JAN-2006
Substance or Preparation: HYPERSPERSE MDC700 Page 5
Issue Date: 18-JAN-2007
Material Safety Data Sheet Supercedes: 12-JAN-2007
KLEEN MCT103
1 Identification of Product and Company
Identification of substance or preparation
KLEEN MCT103
Product Application Area
Reverse osmosis membrane cleaner
Company/Undertaking Identification
GE Betz Canada, Inc.
3451 Erindale Station Road
Mississauga, Ontario L5C 2S9
T 905 279 2222
Emergency Telephone
(800) 877-1940
Prepared by Product Stewardship Group: 215 355-3300
2 Composition / Information On Ingredients
Information for specific product ingredients as required by the
WHMIS Regulations is listed. Refer to additional sections of this
MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
Cas# Chemical Name Range(w/w%)
* (E038)CARBOXYLIC ACID; *
Irritant (eyes and skin); may cause toxicity to the
kidneys and/or reproductive system; fetotoxic and
developmental toxin in laboratory animals
ORAL LD50-RAT: 1,950 MG/KG
DERMAL LD50: NO DATA.
INHL. LC50-RAT: 3.6 MG/L/4H (AEROSOL)
5064-31-3 NITRILOTRIACETIC ACID,TRISODIUM SALT (NTA.3NA) 0.1-1.0
Possible human carcinogen (IARC=2B; NTP=anticipated)
ORAL LD50-RAT: 1,100 MG/KG
DERMAL LD50: NO DATA.
INHL. LC50: NO DATA.
* (E055)ORGANIC CHELANT; *
Irritant (eyes)
ORAL LD50: NO DATA.
DERMAL LD50: NO DATA.
INHL. LC50: NO DATA.
7664-38-2 PHOSPHORIC ACID 10-20
Substance or Preparation: KLEEN MCT103 Page 1
Corrosive
ORAL LD50-RAT: 1,530 MG/KG
DERMAL LD50-RABBIT: 2,740 MG/KG
INHL. LC50: NO DATA.
625-45-6 METHOXYACETIC ACID 0.1-1.0
Corrosive (eyes and skin); developmental toxin;
fetotoxic and developmental toxin in laboratory
animals
ORAL LD50-RAT: 1,000 MG/KG
DERMAL LD50: NO DATA.
INHL. LC50-RAT: >3,200 PPM/7HR
*HMIRC Trade Secret Registry #:5710 Date Granted:17-AUG-2006
3 Hazards Identification
********************************************************************************
EMERGENCY OVERVIEW
Severe irritant to the skin. Severe irritant to the eyes, possibly
corrosive. Mists/aerosols cause irritation to the upper respiratory
tract.
Odor: Slight Acetic; Appearance: Colorless To Amber, Liquid
Fire fighters should wear positive pressure self-contained breathing
apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water
********************************************************************************
POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS:
Primary route of exposure; Severe irritant to the skin.
ACUTE EYE EFFECTS:
Severe irritant to the eyes, possibly corrosive.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols cause irritation to the upper respiratory tract.
INGESTION EFFECTS:
May cause gastrointestinal irritation with possible nausea,
vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS:
Prolonged or repeated exposures may cause primary irirtant
dermatitis and/or toxicity to the kidney and reproductive system.
Product or product component may increase risk of cancer.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
Causes irritation of the skin, eyes, and/or respiratory system.
4 First Aid Measures
Substance or Preparation: KLEEN MCT103 Page 2
SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Thoroughly wash clothing before reuse. Get medical attention if
irritation develops or persists.
EYE CONTACT:
URGENT! Immediately flush eyes with plenty of low-pressure water
for at least 20 minutes while removing contact lenses. Hold eyelids
apart. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air
and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician. Wash
mouth with water. Do not give water to drink.
NOTES TO PHYSICIANS:
No special instructions
5 Fire Fighting Measures
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water
HAZARDOUS DECOMPOSITION PRODUCTS:
oxides of carbon, nitrogen and phosphorus
FLASH POINT:
> 200F > 93C P-M(CC)
6 Accidental Release Measures
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
The waste characteristics of the absorbed material, or any contaminated
soil, should be determined in accordance with provincial regulations.
Water contaminated with this product may be sent to a sanitary sewer
treatment facility, in accordance with any local agreement or
discharged under provincial regulations.
Incinerate or land dispose in an approved landfill.
7 Handling & Storage
HANDLING:
Normal chemical handling.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen,
thaw and mix completely prior to use.
8 Exposure Controls / Personal Protection
EXPOSURE LIMITS
Consult local authorities for acceptable provincial values.
CHEMICAL NAME
Substance or Preparation: KLEEN MCT103 Page 3
(E038)CARBOXYLIC ACID;
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
MISC: Note- manufacturer's recommended exposure limit: 10 mg/m3.
NITRILOTRIACETIC ACID,TRISODIUM SALT (NTA.3NA)
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
(E055)ORGANIC CHELANT;
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
PHOSPHORIC ACID
PEL (OSHA): 1 MG/M3
TLV (ACGIH): 1 MG/M3
METHOXYACETIC ACID
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure
limits.
RESPIRATORY PROTECTION:
If air-purifying respirator use is appropriate, use a respirator
with HEPA cartridges.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles
9 Physical & Chemical Properties
Specific Grav.(70F,21C) 1.350 Vapor Pressure (mmHG) ~ 18.0
Freeze Point (F) -5 Vapor Density (air=1) > 1.00
Freeze Point (C) -21
Viscosity(cps 70F,21C) 50 % Solubility (water) 100.0
Odor Slight Acetic
Appearance Colorless To Amber
Physical State Liquid
Flash Point P-M(CC) > 200F > 93C
pH As Is (approx.) 3.4
Evaporation Rate (Ether=1) < 1.00
Percent VOC: 10.0
NA = not applicable ND = not determined
10 Stability & Reactivity
Substance or Preparation: KLEEN MCT103 Page 4
STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
oxides of carbon, nitrogen and phosphorus
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B"
11 Toxicological Information
Oral LD50 RAT: >2,000 mg/kg
NOTE - Estimated value
Dermal LD50 RABBIT: >2,000 mg/kg
NOTE - Estimated value
Reproductive Toxicity ANIMALS: Positive
NOTE - An ingredient has caused fetotoxicity and developmental
effects
12 Ecological Information
AQUATIC TOXICOLOGY
Daphnia magna 48 Hour Static Renewal Bioassay (pH adjusted)
LC50= 1890; No Effect Level= 1060 mg/L
Fathead Minnow 96 Hour Static Bioassay with 48-Hour Renewal (pH
adjusted)
0% Mortality= 2000 mg/L
BIODEGRADATION
BOD-28 (mg/g): 105
BOD-5 (mg/g): 70
COD (mg/g): 335
TOC (mg/g): 150
13 Disposal Considerations
Incinerate or bury in approved landfill. Please be advised that there
may be additional local or provincial requirements relating to the
disposal of waste. Consult provincial and local regulations regarding
the proper disposal of this material.
14 Transport Information
Transportation of Dangerous Goods:
DOT EMERGENCY RESPONSE GUIDE #: Not applicable
15 Regulatory Information
This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all the information required by the CPR.
CEPA:
All components of this product comply with substance notification
requirements under CEPA.
WHMIS CLASSIFICATION:
D2A D2B
Substance or Preparation: KLEEN MCT103 Page 5
16 Other Information
NFPA/HMIS CODE TRANSLATION
Health 3 Serious Hazard
Fire 1 Slight Hazard
Reactivity 0 Minimal Hazard
Special NONE No special Hazard
(1) Protective Equipment B Goggles,Gloves
(1) refer to section 8 of MSDS for additional protective equipment
recommendations.
CHANGE LOG
EFFECTIVE
DATE REVISIONS TO SECTION: SUPERCEDES
--------- --------------------- ----------
MSDS status: 23-SEP-1999 ** NEW **
04-APR-2000 12 23-SEP-1999
01-MAY-2000 2,8 04-APR-2000
17-JUL-2000 15 01-MAY-2000
11-DEC-2002 3,5,14 17-JUL-2000
25-SEP-2003 2 11-DEC-2002
16-MAY-2006 16 25-SEP-2003
03-JAN-2007 2 16-MAY-2006
12-JAN-2007 14 03-JAN-2007
18-JAN-2007 1,2,4,5,9,10,11 12-JAN-2007
Substance or Preparation: KLEEN MCT103 Page 6
Issue Date: 12-JAN-2007
Material Safety Data Sheet Supercedes: 21-JUN-2006
KLEEN MCT511
1 Identification of Product and Company
Identification of substance or preparation
KLEEN MCT511
Product Application Area
Reverse osmosis membrane cleaner
Company/Undertaking Identification
GE Betz Canada, Inc.
3451 Erindale Station Road
Mississauga, Ontario L5C 2S9
T 905 279 2222
Emergency Telephone
(800) 877-1940
Prepared by Product Stewardship Group: 215 355-3300
2 Composition / Information On Ingredients
Information for specific product ingredients as required by the
WHMIS Regulations is listed. Refer to additional sections of this
MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
Cas# Chemical Name Range(w/w%)
5064-31-3 NITRILOTRIACETIC ACID,TRISODIUM SALT (NTA.3NA) 0.1-1.0
Possible human carcinogen (IARC=2B; NTP=anticipated)
ORAL LD50-RAT: 1,100 MG/KG
DERMAL LD50: NO DATA.
INHL. LC50: NO DATA.
139-89-9 N-HYDROXYETHYLENEDIAMINE TRIACETIC ACID TRISODIUM 15-40
SALT
Irritant (eyes)
ORAL LD50: NO DATA.
DERMAL LD50: NO DATA.
INHL. LC50: NO DATA.
102-71-6 TRIETHANOLAMINE 15-40
Irritant; potential liver and kidney toxin
ORAL LD50-RAT: 8,000 MG/KG
DERMAL LD50: NO DATA.
INHL. LC50: NO DATA.
141-43-5 MONOETHANOLAMINE (ETHANOLAMINE) 10-20
Combustible; corrosive; irritant; may cause liver
Substance or Preparation: KLEEN MCT511 Page 1
and kidney toxicity
ORAL LD50-RAT: 1,720 MG/KG
DERMAL LD50-RABBIT: 1,000 MG/KG
INHL. LC50-DOG: >2 MG/L/7HR
111-42-2 DIETHANOLAMINE (ETHANOL,2,2'-IMINODI-) 3-7
Irritant (eyes); absorbed by skin; IARC=3
(carcinogen status not classifiable); potential
blood, nervous system, liver and kidney toxin
ORAL LD50-RAT: 5,660 MG/KG
DERMAL LD50-RABBIT: 4,000 MG/KG
INHL. LC50: NO DATA.
119345-04-9 BENZENE, 1,1'-OXYBIS-,TETRAPROPYLENE DERIVATIVES, 1-5
SULFONATED, SODIUM SALTS
Severe irritant (eyes)
ORAL LD50: NO DATA.
DERMAL LD50: NO DATA.
INHL. LC50: NO DATA.
3 Hazards Identification
********************************************************************************
EMERGENCY OVERVIEW
Severe irritant to the skin. Severe irritant to the eyes, possibly
corrosive. Irritation of the upper respiratory tract. Prolonged
exposure may cause dizziness and headache.
Odor: Slight; Appearance: Colorless To Amber, Liquid
Fire fighters should wear positive pressure self-contained breathing
apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water
********************************************************************************
POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS:
Primary route of exposure; Severe irritant to the skin.
ACUTE EYE EFFECTS:
Severe irritant to the eyes, possibly corrosive.
ACUTE RESPIRATORY EFFECTS:
Primary route of exposure;Irritation of the upper respiratory
tract. Prolonged exposure may cause dizziness and headache.
INGESTION EFFECTS:
May cause gastrointestinal irritation with possible nausea,
vomiting, abdominal discomfort and diarrhea.
TARGET ORGANS:
Prolonged or repeated exposure may cuses primary irritant
dermatitis and/or toxicity to the liver, kidney, nervous system and
blood. May increase the risk of cancer based on limited animal
data.
MEDICAL CONDITIONS AGGRAVATED:
Substance or Preparation: KLEEN MCT511 Page 2
Pre-existing skin disorders and chronic respiratory disease.
SYMPTOMS OF EXPOSURE:
Causes irritation of the skin, eyes, and/or respiratory system.
4 First Aid Measures
SKIN CONTACT:
Wash thoroughly with soap and water. Remove contaminated clothing.
Thoroughly wash clothing before reuse. Get medical attention if
irritation develops or persists.
EYE CONTACT:
URGENT! Immediately flush eyes with plenty of low-pressure water
for at least 20 minutes while removing contact lenses. Hold eyelids
apart. Get immediate medical attention.
INHALATION:
If nasal, throat or lung irritation develops - remove to fresh air
and get medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions
5 Fire Fighting Measures
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water
HAZARDOUS DECOMPOSITION PRODUCTS:
elemental oxides
FLASH POINT:
> 200F > 93C P-M(CC)
6 Accidental Release Measures
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
The waste characteristics of the absorbed material, or any contaminated
soil, should be determined in accordance with provincial regulations.
Water contaminated with this product may be sent to a sanitary sewer
treatment facility, in accordance with any local agreement or
discharged under provincial regulations.
Incinerate or land dispose in an approved landfill.
7 Handling & Storage
HANDLING:
Normal chemical handling.
STORAGE:
Keep containers closed when not in use. Do not freeze. If frozen,
thaw and mix completely prior to use.
Substance or Preparation: KLEEN MCT511 Page 3
8 Exposure Controls / Personal Protection
EXPOSURE LIMITS
Consult local authorities for acceptable provincial values.
CHEMICAL NAME
NITRILOTRIACETIC ACID,TRISODIUM SALT (NTA.3NA)
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
N-HYDROXYETHYLENEDIAMINE TRIACETIC ACID TRISODIUM SALT
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
TRIETHANOLAMINE
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): 5 MG/M3
MONOETHANOLAMINE (ETHANOLAMINE)
PEL (OSHA): 3 PPM(6PPM-STEL)
TLV (ACGIH): 3 PPM(6PPM-STEL)
DIETHANOLAMINE (ETHANOL,2,2'-IMINODI-)
PEL (OSHA): 3 PPM
TLV (ACGIH): 2 MG/M3-(SKIN)
BENZENE, 1,1'-OXYBIS-,TETRAPROPYLENE DERIVATIVES, SULFONATED, SODIUM SALTS
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure
limits.
RESPIRATORY PROTECTION:
If air-purifying respirator use is appropriate, use a respirator
with organic vapor cartridges and dust/mist prefilters.
SKIN PROTECTION:
neoprene gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles
9 Physical & Chemical Properties
Specific Grav.(70F,21C) 1.197 Vapor Pressure (mmHG) ~ 18.0
Freeze Point (F) 23 Vapor Density (air=1) ~ 5.00
Freeze Point (C) -5
Viscosity(cps 70F,21C) 99 % Solubility (water) 100.0
Odor Slight
Appearance Colorless To Amber
Physical State Liquid
Flash Point P-M(CC) > 200F > 93C
pH As Is (approx.) 10.9
Evaporation Rate (Ether=1) < 1.00
Percent VOC: 36.0
NA = not applicable ND = not determined
Substance or Preparation: KLEEN MCT511 Page 4
10 Stability & Reactivity
STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
elemental oxides
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B"
11 Toxicological Information
Oral LD50 RAT: >2,000 mg/kg
NOTE - Estimated value
Dermal LD50 RABBIT: >2,000 mg/kg
NOTE - Estimated value
12 Ecological Information
AQUATIC TOXICOLOGY
Daphnia magna 48 Hour Static Renewal Bioassay (pH adjusted)
LC50= 342; No Effect Level= 250 mg/L
Fathead Minnow 96 Hour Static Renewal Bioassay (pH adjusted)
LC50= 61.6; No Effect Level= 25 mg/L
BIODEGRADATION
BOD-28 (mg/g): 142
BOD-5 (mg/g): 130
COD (mg/g): 805
TOC (mg/g): 242
13 Disposal Considerations
Incinerate or bury in approved landfill. Please be advised that there
may be additional local or provincial requirements relating to the
disposal of waste. Consult provincial and local regulations regarding
the proper disposal of this material.
14 Transport Information
Transportation of Dangerous Goods:
DOT EMERGENCY RESPONSE GUIDE #: Not applicable
15 Regulatory Information
This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all the information required by the CPR.
CEPA:
All components of this product comply with substance notification
requirements under CEPA.
WHMIS CLASSIFICATION:
D2A D2B E
16 Other Information
Substance or Preparation: KLEEN MCT511 Page 5
NFPA/HMIS CODE TRANSLATION
Health 3 Serious Hazard
Fire 1 Slight Hazard
Reactivity 0 Minimal Hazard
Special NONE No special Hazard
(1) Protective Equipment B Goggles,Gloves
(1) refer to section 8 of MSDS for additional protective equipment
recommendations.
CHANGE LOG
EFFECTIVE
DATE REVISIONS TO SECTION: SUPERCEDES
--------- --------------------- ----------
MSDS status: 23-SEP-1999 ** NEW **
06-JUL-2000 12 23-SEP-1999
03-JAN-2001 2,3,8 06-JUL-2000
21-MAY-2003 14 03-JAN-2001
28-APR-2006 16 21-MAY-2003
21-JUN-2006 14 28-APR-2006
12-JAN-2007 14 21-JUN-2006
Substance or Preparation: KLEEN MCT511 Page 6
Material Safety Data Sheet - BETZDEARBORN DCL30
Company logo
GE Betz Canada, Inc. Material Safety Data Sheet
3451 Erindale Station Road
Mississauga, ON L5C 2S9 Issue Date: 09-JUL-2002
Business telephone: (905) 279-2222
EMERGENCY TELEPHONE (Health/Accident): (800) 877-1940
1 PRODUCT IDENTIFICATION
PRODUCT NAME:
BETZDEARBORN DCL30
PRODUCT APPLICATION AREA:
DECHLORINATING AGENT
2 COMPOSITION / INFORMATION ON INGREDIENTS
Information for specific product ingredients as required by the
WHMIS Regulations is listed. Refer to additional sections of this
MSDS for our assessment of the potential hazards of this formulation.
HAZARDOUS INGREDIENTS:
Cas# Chemical Name Range(w/w%)
7631-90-5 SODIUM BISULFITE 30-60
May be corrosive in aqueous solutions; irritant;
sensitizer (skin and respiratory); may generate SO2
ORAL LD50-RAT: 1,000 MG/KG
DERMAL LD50: NO DATA.
INHL. LC50: NO DATA.
No component is considered to be a carcinogen by the U.S. National
Toxicology Program (NTP), the International Agency for Research on Cancer
(IARC) or under WHMIS.
3 HAZARDS IDENTIFICATION
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EMERGENCY OVERVIEW
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Material Safety Data Sheet - BETZDEARBORN DCL30
May cause slight irritation to the skin. Skin sensitizer. Severe
irritant to the eyes. May cause irritation to mucous membranes.
Repeated exposure may result in respiratory sensitization.
Odor: Strong; Appearance: Colorless To Light Yellow, Liquid
Fire fighters should wear positive pressure self-contained breathing
apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide, foam or water
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POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS:
Primary route of exposure; May cause slight irritation to the skin.
Skin sensitizer.
ACUTE EYE EFFECTS:
Severe irritant to the eyes.
ACUTE RESPIRATORY EFFECTS:
May cause irritation to mucous membranes. Repeated exposure may
result in respiratory sensitization.
INGESTION EFFECTS:
May cause gastrointestinal irritation. Very large doses may cause
diarrhea, depression, colic and death. May also cause severe
allergic reactions in sensitive individuals.
TARGET ORGANS:
Prolonged or repeated exposures may cause primary irritant
dermatitis, skin sensitization, and/or allergic respiratory
reactions.
MEDICAL CONDITIONS AGGRAVATED:
Asthma.
SYMPTOMS OF EXPOSURE:
May cause local irritation or a sensitization reaction upon direct
contact with skin or respiratory tract.
4 FIRST AID MEASURES
SKIN CONTACT:
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Material Safety Data Sheet - BETZDEARBORN DCL30
Wash thoroughly with soap and water. Remove contaminated clothing.
Thoroughly wash clothing before reuse. Get medical attention if
irritation develops or persists.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes
with plenty of low-pressure water for at least 15 minutes. Get
immediate medical attention.
INHALATION:
Remove to fresh air. If breathing is difficult, give oxygen. If
breathing has stopped, give artificial respiration. Get immediate
medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
NOTES TO PHYSICIANS:
No special instructions
5 FIRE FIGHTING MEASURES
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 200F > 93C SETA(CC)
6 ACCIDENTAL RELEASE MEASURES
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Flush area with water. Wet area may be slippery. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
The waste characteristics of the absorbed material, or any contaminated
soil, should be determined in accordance with provincial regulations.
Water contaminated with this product may be sent to a sanitary sewer
treatment facility, in accordance with any local agreement or
discharged under provincial regulations.
Incinerate or land dispose in an approved landfill.
7 HANDLING & STORAGE
HANDLING:
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Material Safety Data Sheet - BETZDEARBORN DCL30
Vent carefully before opening. Sulfur dioxide can be formed during
the normal use and handling of this product.
STORAGE:
Keep containers closed when not in use. Reasonable and safe
chemical storage. Protect from freezing.
8 EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Consult local authorities for acceptable provincial values.
CHEMICAL NAME
SODIUM BISULFITE
PEL (OSHA): 5 MG/M3
TLV (ACGIH): 5 MG/M3
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure
limits.
RESPIRATORY PROTECTION:
If air-purifying respirator use is appropriate, use a respirator
with acid gas cartridges and dust/mist prefilters.
SKIN PROTECTION:
gauntlet-type neoprene gloves, chemical resistant apron-- Wash off
after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles, face shield
9 PHYSICAL & CHEMICAL PROPERTIES
Specific Grav.(70F,21C) 1.268 Vapor Pressure (mmHG) ~ 18.0
Freeze Point (F) 18 Vapor Density (air=1) < 1.00
Freeze Point (C) -8
Viscosity(cps 70F,21C) 6 % Solubility (water) 100.0
Odor Strong
Appearance Colorless To Light Yellow
Physical State Liquid
Flash Point SETA(CC) > 200F > 93C
pH As Is (approx.) 4.5
Evaporation Rate (Ether=1) < 1.00
NA = not applicable ND = not determined
10 STABILITY & REACTIVITY
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Material Safety Data Sheet - BETZDEARBORN DCL30
STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B"
11 TOXICOLOGICAL INFORMATION
Oral LD50 RAT: >2,000 mg/kg
NOTE - Estimated value
Dermal LD50 RABBIT: >2,000 mg/kg
NOTE - Estimated value
Skin Irritation Score RABBIT: 0
NOTE - NO ERYTHEMA OR EDEMA WAS OBSERVED IN TEST OF SIMILAR PRODUCT
12 ECOLOGICAL INFORMATION
AQUATIC TOXICOLOGY
Daphnia magna 48 Hour Static Renewal Bioassay
LC50= 225; No Effect Level= 160 mg/L
Fathead Minnow 96 Hour Static Renewal Bioassay
LC50= 225; No Effect Level= 160 mg/L
Menidia beryllina (Silversides) 96 Hour Static Acute Bioassay
(pH adjusted)
LC50= 930; No Effect Level= 156 mg/L
Mysid Shrimp 48 Hour Static Acute Bioassay (pH adjusted)
LC50= 370; No Effect Level= 156 mg/L
Rainbow Trout 48 Hour Static Screen
100% Mortality= 500; 0% Mortality= 100 mg/L
BIODEGRADATION
Product contains only inorganics that are not subject to typical
biological degradation. Assimilation by microbes may occur in
waste treatment or the environment.
COD (mg/g): 49
13 DISPOSAL CONSIDERATIONS
Incinerate or bury in approved landfill. Please be advised that there
may be additional local or provincial requirements relating to the
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Material Safety Data Sheet - BETZDEARBORN DCL30
disposal of waste. Consult provincial and local regulations regarding
the proper disposal of this material.
14 TRANSPORT INFORMATION
Transportation of Dangerous Goods:
Proper Shipping Name: Enviromentally Hazardous Substances liquid
n.o.s.
(Sodium Bisulphite)
PIN:UN3082; Classification: 9.2;Packing Group III
15 REGULATORY INFORMATION
This product has been classified in accordance with the hazard criteria
of the CPR and the MSDS contains all the information required by the CPR.
CEPA:
All components of this product comply with substance notification
requirements under CEPA.
WHMIS CLASSIFICATION:
D2A D2B
FOOD AND DRUG ADMINISTRATION:
The ingredients in this product are Generally Recognized As Safe
by FDA, for use in either human or animal food.
16 OTHER INFORMATION
NFPA/HMIS CODE TRANSLATION
Health 2 Moderate Hazard
Fire 0 Minimal Hazard
Reactivity 0 Minimal Hazard
Special NONE No special Hazard
(1) Protective Equipment D Goggles,Face Shield,Gloves,Apron
(1) refer to section 8 of MSDS for additional protective equipment
recommendations.
CHANGE LOG
EFFECTIVE
DATE REVISIONS TO SECTION: SUPERCEDES
--------- --------------------- ----------
MSDS status: 29-SEP-1999 ** NEW **
13-JAN-2000 4 29-SEP-1999
09-JUL-2002 12 13-JAN-2000
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