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MSDS Material Safety Data Sheet
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625-86-5

File Name: 625-86.asp

                                                                                                               2,5-Dimethylfuran
Material Safety Data Sheet
MSDS Date: 09/1/2008

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

Product Name: Manufacturer's Name and Address:
2,5-Dimethylfuran Penn A Kem. LLC
3324 Chelsea Avenue
Synonyms: Dimethylfuran Memphis, TN 38108
Stabilized dimethylfuran Emergency Number, if inside US: (901) 320 4092
Emergency Number, if outside US: (877) 895 7366

SECTION 2: Composition/Information on Ingredients

625-86-5
CAS NO.:
210-914-3
EINECS/ELINCS:
2,5-dimethylfuran
Chemical Name:
96.
Molecular Weight:
C6H8O
Chemical Formula:
93-100.%
Percent:

This material may be stabilized with a hindered phenol antioxidant, less than 0.04 wt%.
Note:

SECTION 3: Hazards Identification


This material is HAZARDOUS by OSHA Communication definition.
Emergency Overview:
Danger.
Signal Word:
Health: 2; Flammability: 3; Reactivity: 0
NFPA Rating:
Health: 2; Flammability: 3; Reactivity: 0
NHIS Rating:
Highly flammable. Avoid oxidizing agents. Avoid prolonged or repeated breathing
Hazards:
of gases, vapors or mists.
Inhalation
Primary Route of entry:
May be irritating to eye.
Eye:
May be irritating to skin.
Skin:
May cause irritation of the digestive tract.
Ingestion:
May cause respiratory tract and mucous membrane irritation. May cause
Inhalation:
unconsciousness or respiratory arrest.
No information available.
Chronic:
No information available.
Target Organs:
Note:

SECTION 4: First Aid Measures

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get
Eyes:
medical aid.
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash
Skin:
skin thoroughly with mild soap and water. Wash clothing before reuse. Get medical aid if ill effects or irritation
develops.
Do not induce vomiting. Never give anything by mouth to an unconscious person. If conscious and alert, rinse
Ingestion:
mouth and drink water. Get medical aid.
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing
Inhalation:
is difficult, give oxygen. Get medical aid if breathing difficulty persists.

SECTION 5: Fire Fighting Measures


As in any fire, wear a self-contained breathing apparatus in pressure-
General Information:
demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
During a fire, irritating and highly toxic gases may be generated by thermal

Page 1 of 5
2,5-Dimethylfuran
Material Safety Data Sheet
MSDS Date: 09/01/2008

decomposition or combustion. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Cool containers
with flooding quantities of water.

Small fire use water spray, dry chemical, carbon dioxide. Large fire use water
Extinguishing Media:
spray, water fog dry chemical, carbon dioxide, or alcohol resistant foam.
DO NOT USE SOLID WATER STREAM.
45癋, 7癈
Flash Point:

Not Available
Auto ignition Temperature:

Not Available
Explosion limits, Lower:

Not Available
Upper:
Health: 2; Flammability: 3; Reactivity: 0
NFPA Rating:
Health: 2; Flammability: 3; Reactivity: 0
NHIS Rating:

SECTION 6: Accidental Release Measures


Eliminate all sources of ignition. Use proper personal protective equipment as
General Information:
indicated in Section 8.

Absorb spill with inert non-combustible material (e.g. vermiculite, sand or earth),
Spills/Leaks:
then place in a suitable container. Clean up spills immediately using non-sparking
tools. Provide ventilation.

SECTION 7: Handling and Storage


Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with
Handling:
adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Handle empty containers with care. Vapor/residues may be
flammable.

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry,
Storage:
well-ventilated area away from incompatible substances.

SECTION 8: Exposure Controls, Personal Protection


Facilities storing or utilizing this material should be equipped with an eyewash
Engineering Controls:
facility and a safety shower. Use adequate ventilation and exhaust to keep airborne
concentrations low.

Exposure Limits:
2,5-dimethylfuran
Chemical name:
Not reported
ACGIH:
Not Reported
OSHA




Page 2 of 5
2.5-Dimethylfuran
Material Safety Data Sheet
MSDS Date: 09/1/2008

SECTION 8: Exposure Controls, Personal Protection Cont'd


Personal Protective Equipment:
Wear appropriate protective eyeglasses or chemical safety goggles and
Eyes:
face shield as described by OSHA's eye and face protection regulations in
29 CFR 1910.133 or European Standard EN166.

Wear appropriate protective gloves to prevent skin exposure. Polyvinyl
Hands:
alcohol, Teflon, or 4H and Silver Shield brand.

Wear appropriate protective clothing to prevent skin exposure.
Clothing:

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and
Respirators:
ANSI Z88.2 requirements or European Standard EN 149 must be followed
whenever workplace conditions warrant respirator use.

SECTION 9: Physical and Chemical Properties


Liquid
Physical State:
Clear, colorless to yellow to amber.
Appearance:
Ether-like odor.
Odor:
Not available
pH:
155 mm Hg @ 25 癈 (77 癋)
Vapor Pressure:
Not available.
Vapor Density:
Not available.
Evaporation Rate:
Not available.
Viscosity:
92-94 癈
Boiling Point:
Not available.
Freezing/Melting Point:
Not available.
Autoignition Temperature:
Insoluble.
Solubility: water
0.90 g/cc.
Specific Gravity/Density:
C6H8O
Molecular Formula:
96
Molecular Weight:

SECTION 10: Stability and Reactivity


Stable under normal temperatures and pressures.
Chemical Stability:

Incompatible materials, excess heat, strong oxidants.
Conditions to Avoid:

Strong oxidizing agents.
Incompatibilities with other Materials:

Carbon monoxide, irritating and toxic fumes and gases, carbon
Hazardous Decomposition Products:
dioxide.

Not reported.
Hazardous Polymerization:




SECTION 11: Toxicological Information




No information available.
LD50

Page 3 of 5
2,5-Dimethylfuran
Material Safety Data Sheet
MSDS Date: 09/01/2008

No information available.
LC50:
No information available.
Carcinogenicity:
No information available.
Epidemiology:

No information available.
Sensitization

Liquid and vapor is irritating to eyes.
Eye
No information available.
Skin


No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Genetic toxicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:

SECTION 12: Ecological Information


No information available.
Acute toxicity fish
No information available.
Invertebrates
No information available.
Aquatic plants
No information available.
Microoganisms
No information available.
Other Studies:



SECTION 13: Disposal Considerations


Contaminated products, oil or water may be a US RCRA or OSHA hazardous waste due to a potentially low
flash point. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete
and accurate classification.


SECTION 14: Transport Information


US DOT
Flammable Liquid, N.O.S. (2,5-dimethylfuran)
Shipping Name:
Flammable liquid
Hazard Class:
UN1993
UN Number:
II
Packing Group:




International
Flammable Liquid, N.O.S. (2,5-dimethylfuran)
Shipping Name:
Flammable liquid
Hazard Class:
UN1993
UN Number:
II
Packing Group:


SECTION 15: Regulatory Information




Page 4 of 5
2,5-Dimethylfuran
Material Safety Data Sheet
MSDS Date: 09/01/2008

US FEDERAL:
2,5-dimethylfuran is listed on the TSCA inventory.
TSCA (Toxic Substance Control Act):


Not listed.
TSCA Section 12b:
CERLA Hazardous Substances
and Corresponding RQs:

SARA Section 302 (Superfund Amendments and Reauthorizations Act):
Based on available information, 2,5-dimethylfuran is classified as follows:
SARA 311/312
Fire Hazard

None of the chemicals are reportable under Section 313.
313 Reportable Ingredients:



This material does not contain any Class 1 Ozone depletors, or Class 2 Ozone depletors.
Clean Air Act:

None of the chemicals in this product are listed as Hazardous Substances, Priority
Clean Water Act:
Pollutants, or Toxic Pollutants under the CWA.


STATE:

California Prop 65:
None of the chemicals in this product are listed.
California No Significant Risk Level:

European/International Regulations

European Labeling in Accordance with EC Directives:
.
Hazard Symbols:
R11?Highly Flammable.
Risk Phrases:

?br> Safety Phrases: S 24/25, Avoid contact with skin and eyes.
? S 37, Wear suitable gloves.
? S 45, In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
? S 28A, In case of skin contact, wash immediately with plenty of water.

WGK (Water Danger/Protection):
This chemical is listed on the DSL list.
Canada ?DSL/NDSL:

None.
Canadian Ingredient Disclosure List:

SECTION 16: Additional Information


09/1/2008
MSDS Creation Date:
Revision #0 Date:
The data contained herein is based on information currently available to Penn A Kem LLC, and believed to be factual and the opinions
expressed to be those of qualified experts; however, this data is not to be taken as a warranty or representation for which Penn Specialty
Chemicals, Inc. assumes legal responsibility.




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