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MSDS Material Safety Data Sheet
CAS

627-30-5

File Name: 627-30-5.asp

                              SIGMA-ALDRICH

Material Safety Data Sheet

Date Printed: 11/OCT/2005
Date Updated: 14/MAR/2004
Version 1.1
According to 91/155/EEC

Classified as Hazardous according to the criteria of EU Annex 1 and
NOHSC.

1 - Product and Company Information

Product Name 3-CHLORO-1-PROPANOL, 98%
Product Number C46403

Company Sigma-Aldrich Pty. Ltd.
12 Anella Avenue
Castle Hill NSW 2154
Australia
Technical Phone # +61 2 9841 0555 (1800 800 097)
Fax +61 2 9841 0500 (1800 800 096)
Emergency Phone # +44 8701906777 (1800 448 465)

2 - Composition/Information on Ingredients

Product Name CAS # EC no Annex I
Index Number
3-CHLORO-1-PROPANOL 627-30-5 210-992-9 None

Formula C3H7ClO
Molecular Weight 94.54 AMU
Synonyms 3-Chlorpropan-1-ol (German) * 3-Chloropropanol *
Trimethylene chlorohydrin

3 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.


4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.

AFTER EYE CONTACT
Assure adequate flushing of the eyes by separating the eyelids
with fingers.

AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately.

5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam. Water spray.
SPECIAL RISKS
Specific Hazard(s): Combustible liquid. Emits toxic fumes under
fire conditions.

SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.

METHODS FOR CLEANING UP
Absorb on sand or vermiculite and place in closed containers for
disposal. Ventilate area and wash spill site after material
pickup is complete.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not get in eyes, on skin, on
clothing. Do not breathe vapor.

STORAGE
Conditions of Storage: Keep tightly closed. Keep away from heat
and open flame. Store in a cool dry place.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.

GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Discard contaminated shoes. Wash
contaminated clothing before reuse.

PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Government approved respirator.
Hand Protection: Rubber gloves.
Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties

Appearance Color: Colorless
Form: Clear liquid

Property Value At Temperature or Pressure

pH N/A
BP/BP Range 48.0 - 50.0 癈 0.2 mmHg
MP/MP Range N/A
Flash Point 75 癈 Method: closed cup
Flammability N/A
Autoignition Temp N/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion Limits N/A
Vapor Pressure N/A
SG/Density 1.131 g/cm3


ALDRICH - C46403 www.sigma-aldrich.com Page 2
Partition Coefficient N/A
Viscosity N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
Evaporation Rate N/A
Bulk Density N/A
Decomposition Temp. N/A
Solvent Content N/A
Water Content N/A
Surface Tension N/A
Conductivity N/A
Miscellaneous Data N/A
Solubility N/A

10 - Stability and Reactivity

STABILITY
Conditions of Instability: Moisture.
Conditions to Avoid: Moisture.
Materials to Avoid: Strong bases, Strong acids, Strong oxidizing
agents.

HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Hydrogen chloride gas.

11 - Toxicological Information

RTECS NUMBER: UA8930000

ACUTE TOXICITY

LD50
Oral
Mouse
2300 mg/kg
Remarks: Behavioral:Muscle contraction or spasticity.
Gastrointestinal:Ulceration or bleeding from stomach.
Liver:Other changes.

SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and
toxicological properties have not been thoroughly investigated.

ROUTE OF EXPOSURE
Multiple Routes: May be harmful by inhalation, ingestion, or
skin absorption. Causes eye and skin irritation. Vapor or mist
is irritating to the eyes, mucous membranes, and upper
respiratory tract.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
This combustible material may be burned in a chemical incinerator
equipped with an afterburner and scrubber. Observe all federal,
state, and local environmental regulations.

14 - Transport Information


ALDRICH - C46403 www.sigma-aldrich.com Page 3
RID/ADR
UN#: 2849
Class: 6.1
PG: III
Proper Shipping Name: 3-Chloropropanol-1

IMDG
UN#: 2849
Class: 6.1
PG: III
Proper Shipping Name: 3-Chloropropanol-1
Marine Pollutant: No
Severe Marine Pollutant: No

IATA
UN#: 2849
Class: 6.1
PG: III
Proper Shipping Name: 3-Chloropropanol-1
Inhalation Packing Group I: No

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: Xn
Harmful.
R-PHRASES: 22-36/37/38
Harmful if swallowed. Irritating to eyes, respiratory system
and skin.
S-PHRASES: 26-36
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear suitable protective
clothing.

COUNTRY SPECIFIC INFORMATION

Germany
WGK: 2 (self-classification)

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2005 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.

DISCLAIMER
For R&D use only. Not for drug, household or other uses.




ALDRICH - C46403 www.sigma-aldrich.com Page 4

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