MATERIAL SAFETY DATA SHEET
SECTION I ?PRODUCT AND COMPANY IDENTIFICATION
Product Name: Washroom Cleaner HMIS Hazard Rating
Product Code: ES51 1 0 ?Insignificant
HEALTH
Product Use: Cleaner for toilets and urinals 1 ?Slight
0
FLAMMABILITY
2 ?Moderate
0
REACTIVITY
Manufacturer/Supplier: Enviro-Solutions Limited 3 ?High
B
Address: 2060 Fisher Dr., PERSONAL 4 - Extreme
PROTECTION
Peterborough, ON K9J 8N4
Telephone: (705) 745-3070
Emergency Phone: CANUTEC (613) 996-6666
SECTION II ?INFORMATION ON INGREDIENTS
Ingredients CAS# WT% ACGIH-TLV LD50 LC50
Water 7732-18-5 60-100 Not applicable 14,500 mg/kg (Oral, Rat) NA
Sodium citrate 68-04-2 3-7 Not applicable NA NA
Monoethanolamine 141-43-5 1-5 3 ppm TWA 1,720 mg/kg (Oral, Rat) NA
Alcohol ethoxylates NJ TRSN: 07613759-02 1-5 Not applicable >2,000 mg/kg (Oral, Rat) NA
Propylene glycol 57-55-6 1-5 Not applicable 18,300 mg/kg (Oral, Rat) NA
Xanthum gum 11138-66-2 0.1-1 Not applicable >5,000 mg/kg (Oral, Rat) NA
Fragrance Mixture 0.1-1 Not applicable NA NA
D&C Red #33 3567-66-6 0-0.1 Not applicable NA NA
SECTION III ?HAZARDS IDENTIFICATION SECTION IV ?FIRST AID MEASURES
Route of Entry: Eye, skin contact, inhalation, ingestion. Eye Contact: Flush with water for 15 minutes. Seek medical attention if irritation persists.
Effects of Acute Exposure: Skin Contact: Flush with water for 15 minutes. Seek medical attention if irritation develops.
Eye Contact: May cause moderate to severe irritation upon direct contact. Inhalation: Remove to fresh air and take deep, slow breaths. Seek medical attention if irritation
Skin Contact: May cause moderate to severe irritation upon direct contact . persists.
Inhalation: No hazards under normal conditions of use. Prolonged exposure may cause nose, Ingestion: Do not induce vomiting. Rinse mouth with water, then drink one glass of water. Seek
throat and respiratory tract irritation. medical attention if symptoms persist. Never give anything by mouth if victim is
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. unconscious, is rapidly losing consciousness, or is convulsing.
Effects of Chronic Exposure: See Section 11.
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Enviro-Solutions Limited ?ES51
SECTION XII ?ECOLOGICAL INFORMATION
SECTION V ?FIRE FIGHTING MEASURES
Biodegradability: Not established for this product.
Flammability: Not flammable. Flash Point: (deg C, TCC): None
Aquatic Acute Toxicity: Not established for this product.
LEL: None UEL: None
Auto-Ignition Temperature: None
SECTION XIII ?DISPOSAL CONSIDERATIONS
Hazardous Combustion Products: Ammonia, oxides of carbon and nitrogen.
Dispose of in accordance with local state/provincial and federal regulations.
Means of Extinction: Water mist (fog), dry chemical, carbon dioxide, or foam.
Special Fire Hazards: Firefighters should wear self-contained breathing apparatus. SECTION XIV - TRANSPORTATION
Explosion Data ?Sensitivity to Mechanical Impact: None. Special Shipping Information: Keep from freezing.
Explosion Data ?Sensitivity to Static Discharge: None.
T.D.G. Classification: Not regulated under TDG
SECTION VI ?ACCIDENTAL RELEASE MEASURES D.O.T. Classification: Not regulated under DOT
Leak and Spill Procedures: Before attempting clean up, refer to hazard data given above. Small SECTION XV ?REGULATORY INFORMATION
spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labeled
Occupational Health and Safety Regulations:
containers. Product is readily biodegradable as per OECD Test Method 301D. For large quantities,
WHMIS Class: D2B.
dispose of in accordance with local, state/provincial and federal laws. OSHA & WHMIS: MSDS prepared pursuant to the Hazard Communication Standard (CFR29
1910.1200) and Canadian WHMIS regulations (Controlled Products Regulations Under the
SECTION V II ?HANDLING AND STORAGE
Hazardous Product Act).
Storage Requirements: KEEP OUT OF REACH OF CHILDREN. Store in closed container. Store
Environmental Regulatory Lists:
in a cool, dry, well-ventilated area away from incompatible materials.
SARA ?Section 313 (Toxic Chemical Release Reporting) 40 CFR 372 ?None of these
SECTION VIII ?EXPOSURE CONTROL/PERSONAL PROTECTION ingredients are listed.
Gloves: If prolonged/repeated contact can occur, use protective gloves. CERCLA ?Section 102 (Reportable Quantity) 40 CFR 302 ?None of these ingredients are
Eye protection: Use safety glasses when direct contact may occur. listed.
Respiratory protection: Not normally required if good ventilation is maintained. RCRA 40CFR 261 (SUBPART D) ?None of these ingredients are listed.
Other protective equipment: As required by employer code. CLEAN WATER ACT ?Section 311 (Reportable Quantity) 40 CFR 116 - None of these
Engineering Controls: General ventilation normally adequate. ingredients are listed.
CLEAN AIR ACT ?Section 312 (List of Hazardous Air Pollutants) 40 CFR 63 (Subpart C) ?br>
SECTION IX ?PHYSICAL AND CHEMICAL PROPERTIES
None of these ingredients are listed.
Appearance/Odor: Red; floral. Physical State: Liquid National Pollutant Release Inventory ?None of the ingredients are listed.
Boiling Point (癈): 100 Freezing Point (癈): NE % Volatile (Wt%): >90 Toxic Substances Control Act (TSCA) ?All the ingredients are registered on the Chemical
Specific Gravity (H2O=1): 1.04 pH (as supplied): 11.70 Substance Inventory.
Evaporation Rate (Water=1): Similar Viscosity: Viscous. Canadian Domestic Substance List (DSL) ?All the ingredients are registered on the DSL.
Coefficient of Water/Oil Distribution: NE Solubility in Water: Soluble
Vapor Pressure: NA Vapor Density: NA Odor Threshold: NE SECTION XVI ?OTHER INFORMATION
Date: October 31, 2008
SECTION X ?STABILITY AND REACTIVITY
Prepared by: Technical Services Group Telephone: (705) 745-3070
Conditions for Chemical Instability: Stable.
Incompatibility Materials: May react with strong oxidizing agents and strong acids. NA: Not Available NE: Not Established
Conditions of reactivity: NE
Hazardous Decomposition Products: Ammonia, oxides of carbon and nitrogen.
Disclaimer
Information for this material safety data sheet was obtained from sources considered technically accurate and reliable. While every
SECTION XI ?TOXICOLOGICAL INFORMATION effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions
LD50 : Not established for this product. LC50 : Not established for this product. of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to
the mandatory requirements of WHMIS. No warranty, expressed or implied, is made and supplier will not be liable for any losses,
This product may cause irritation to the eyes or skin upon prolonged contact. injuries or consequential damages, which may result from the use of or reliance on any information contained in this form. If user
Conditions Aggravated by Exposure: None known. requires independent information on ingredients in this or any other material, we recommend contact with the Canadian Centre for
Occupational Health and Safety (CCOHS) in Hamilton, Ontario (905-572-4400), or CSST in Montreal, Quebec (514-873-3990).
Sensitization to Product: None known.
Carcinogenicity: No ingredients listed by IARC or NTP. Non-hazardous by WHMIS standards.
Teratogenicity, Mutagenicity, Reproductive Effects: None known.
Toxicologically Synergistic Products: None known.
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Enviro-Solutions Limited ?ES51
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