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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 18.03.2009 Revision: 18.03.2009
* 1 Identification of substance:
?Product details:
?Trade name: Azorubin
?Synonyma C.I. 14720; C.I. Acid Red 14; Chromotrop FB; E 122
?Article number: 14410
?Application of the substance / the preparation Laboratory chemicals
?Manufacturer/Supplier:
SERVA Electrophoresis GmbH
Carl-Benz-Str. 7
D-69115 Heidelberg
Tel.: +49 6221 13840-0
FAX: +49 6221 13840-10
msds.info@serva.de
?Information department: Product Safety department Tel.: +49 6221 13840-35
?Emergency information: +49 6131 19240 (university hospital Mainz)
* 2 Hazards identification
?Hazard description: not applicable
?Information pertaining to particular dangers for man and environment
Only for trade users / technical specialists
?Classification system
The classification was made according to the latest editions of the EU-lists, and expanded upon fom company
and literature data.
?GHS label elements Void
* 3 Composition/information on ingredients
?Chemical characterization:
?CAS No. Description:
3567-69-9 Disodium 4-hydroxy-3-[(4-sulphonatonaphthyl)
azo]naphthalenesulphonate
?Identification number(s):
?EINECS Number: 222-657-4
?Chemical characterization
?Description:
?Empirical formula: C H N O S Na
?MW: 502,4
* 4 First aid measures
?General information No special measures required.
?After inhalation Supply fresh air and to be sure call for a doctor.
?After skin contact Immediately wash with water and soap and rinse thoroughly.
?After eye contact Rinse opened eye for several minutes under running water.
?After swallowing Drink copious amounts of water and provide fresh air. Call for doctor immediately.
* 5 Fire fighting measures
?Suitable extinguishing agents
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
(Contd. on page 2)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 18.03.2009 Revision: 18.03.2009
Trade name: Azorubin
(Contd. of page 1)
?For safety reasons unsuitable extinguishing agents Water with full jet.
?Special hazards caused by the material, its products of combustion or resulting gases:
In case of fire, the following can be released:
Nitrogen oxides (NOx)
Sulphur dioxide (SO2)
Carbon monoxide and carbon dioxide
?Protective equipment: Wear self-contained respiatory protective device.
* 6 Accidental release measures
?Person-related safety precautions: Wear protective clothing.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting: Pick up mechanically.
?Additional information: No dangerous substances are released.
* 7 Handling and storage
?Handling
?Information for safe handling:
Prevent formation of dust.
Any deposit of dust which cannot be avoided must be regularly removed.
?Information about protection against explosions and fires: No special measures required.
?Storage
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Store in dry conditions.
Keep receptacle tightly sealed.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace: Not required.
?Additional information: The lists that were valid during the creation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
The usual precautionary measures should be adhered to when handling chemicals.
?Breathing equipment:
Short term filter device:
Filter P2.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 18.03.2009 Revision: 18.03.2009
Trade name: Azorubin
(Contd. of page 2)
?For the permanent contact of a maximum of 15 minutes gloves made of the following materials are
suitable:
Neoprene gloves
Nitrile rubber, NBR
?Eye protection: Safety glasses
?Body protection: Protective work clothing.
* 9 Physical and chemical properties:
?General Information
Powder
Form:
Red-brown
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: undetermined
Boiling point/Boiling range: undetermined
> 100癈
?Flash point:
?Flammability (solid, gaseous) Product is not flammable.
Product does not present an explosion hazard.
?Danger of explosion:
Not determined
?Density:
?Solubility in / Miscibility with
Soluble
Water:
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known
?Dangerous products of decomposition: No dangerous decomposition products known
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
Oral LD50 > 10 000 mg/kg (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: No irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
When used and handled according to specifications, the product does not have any harmful effects according
to our experience and the information provided to us.
The substance is not subject to classification according to the latest version of the EU lists.
* 12 Ecological information:
?General notes:
Water hazard class 2 (German Regulation) (Assessment by list): hazardous for water.
Do not allow product to reach ground water, water course or sewage system.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 18.03.2009 Revision: 18.03.2009
Trade name: Azorubin
(Contd. of page 3)
Danger to drinking water if even small quantities leak into the ground.
* 13 Disposal considerations
?Product:
?Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
?Recommended cleansing agent: Water, if necessary with cleansing agents.
* 14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: -
?Maritime transport IMDG:
-
?IMDG Class:
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: -
?UN "Model Regulation": -
?Transport/Additional information: Not dangerous according to the above specifications.
* 15 Regulations
?Markings according to EU guidelines:
Observe the general safety regulations when handling chemicals
The substance is not subject to classification according to EU lists and other sources of literature known to
us.
The product is not subject to identification regulations under EU Directives and the Ordinance on Hazardous
Materials (GefStoffV).
?Special labeling of certain preparations:
Only for trade users / technical specialists
?National regulations
?Water hazard class: Water hazard class 2 (Assessment by list): hazardous for water.
* 16 Other information:
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Department issuing MSDS: Product safety department
?Contact: +49 6221 13840-35
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 18.03.2009 Revision: 18.03.2009
Trade name: Azorubin
(Contd. of page 4)
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
?* Data compared to the previous version altered.
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