Page: 1 MATERIAL SAFETY DATA SHEET Printed : 02/15/99
For Coatings, Resins and Related Materials
Revised : 02/15/99
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SECTION I - PRODUCT IDENTIFICATION
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Manufacturer: SIA ADHESIVES, INC. Information Phone: (330) 374-2786
123 WEST BARTGES ST. Emergency Phone: (330) 374-2900
DEPARTMENT 1932/1904 CHEMTREC Phone: (800)424-9300
AKRON OH 44311 -----------------------------------
! Hazard Ratings: Health - 2
Product Class: SOLVENT BASED PRIMER ! none -> extreme Fire - 3
Trade Name : A-1104-B ! 0 ---> 4 Reactivity - 0
Product Code : 2766290 !
C.A.S. Number: NA !
Prepared By : MICHAEL T. EBERHART
Title : MANAGER ENVIRONMENTAL AFFAIRS
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SECTION II - HAZARDOUS INGREDIENTS
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Weight --- Exposure Limits ---- VP
Ingredients CAS # % ACGIH/TLV OSHA/PEL mm HG
___________ ________________________________________________
METHYL ETHYL KETONE 78-93-3 20. 200 ppm 200 ppm 70.6
STEL = 300 ppm 300 ppm
TOLUENE (SKIN) 108-88-3 35. 50 ppm 100 ppm 22.1
STEL = 150 ppm
BUTYL ALCOHOL (SKIN) 71-36-3 < 5. 50 ppm 100 ppm 8.8
METHYL METHACRYLATE 80-62-6 < 1. 100 ppm 100 ppm 0
ACRYLIC COPOLYMER PROPRIETARY 15. N.E. N.E. 0
ETHYL ACETATE 141-78-6 < 5. 400 ppm 400 ppm 86
ETHANOL 67-17-5 20. 1000ppm 1000 ppm 40
ISOPROPYL ALCOHOL 67-63-0 < 5. 400 ppm 400 ppm 33
STEL = 500 ppm 500 ppm
FORMALDEHYDE 50-00-0 < 0.1 0.3 ppm 0.75 ppm 0
STEL = 0.3 ppm 2 ppm
LISTED BY IARC AS PROBABLY CARCINOGENIC TO HUMANS
LISTED BY NTP AS REASONABLY ANTICIPATED TO BE CARCINOGENIC
LISTED BY OSHA AS A CARCINOGEN
PHENOLIC RESIN 9039-25-2 < 5. 0
*** ALL Ingredients in this product are listed in the T.S.C.A. Inventory.
N.E. = Not Established
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SECTION III - PHYSICAL DATA
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Boiling Range: 171 - 231 Deg. F Vapor Density: Heavier than Air.
Evap. Rate: 3.2 x n-Butyl Acetate Liquid Density: Lighter than Water.
Volatiles vol % 87 Wgt% 81 Wgt per gallon: 7.34 Pounds.
Spec. Gravity: 0.88115
Appearance: CL.TO LHT.BLU.WATER-THN LIQ.W/AR.OR
V.O.C.: 725 G/L
Page: 2 SIA ADHESIVES, INC.
Material Safety Data Sheet for: A-1104-B(2766290)
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SECTION IV - FIRE AND EXPLOSION HAZARD DATA
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Flammability Class: 1B Flash Point: 10 F TCC LEL: 1.40% UEL: 19.00%
-EXTINGUISHING MEDIA:
WATER FOG, CARBON DIOXIDE, FOAM, DRY CHEMICAL.
-SPECIAL FIREFIGHTING PROCEDURES:
DO NOT ENTER CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE
EQUIPMENT INCLUDING NIOSH APPROVED SELF CONTAINED BREATHING
APPARATUS.
-UNUSUAL FIRE & EXPLOSION HAZARDS:
VAPORS MAY BUILD UP IN POORLY VENTILATED AREAS AND BE IGNITED,
CAUSING FLASH FIRES OR EXPLOSIONS. VAPORS ARE HEAVIER THAN AIR
AND MAY TRAVEL ALONG GROUND OR FLOOR TO SOURCE OF IGNITION,
CAUSING FLASH FIRES OR EXPLOSIONS.
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SECTION V - HEALTH HAZARD DATA
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-PERMISSIBLE EXPOSURE LEVEL:
SEE SECTION II
-EFFECTS OF OVEREXPOSURE:
INHALATION: NOSE AND THROAT IRRITATION HEADACHE, NAUSEA, LOSS
OF COORDINATION, DIZZINESS, UNCONSCIOUSNESS,AND
EVEN ASPHYXIATION.
SKIN CONTACT: MAY CAUSE DEFATTING OR DERMATITIS.
EYE CONTACT: MAY CAUSE IRRITATION, OR CORNEAL CLOUDING.
INGESTION: ASPIRATION INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS
CHRONIC EFFECTS:MAY INCLUDE KIDNEY AND LIVER DAMAGE AND
DERMATITIS.
NOTICE:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPA-
TIONAL OVER-EXPOSURE TO SOLVENTS WITH PERMANENT BRAIN
AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS
MAY BE HARMFUL OR FATAL.
EMBRYO/FETOTOXIC EFFECTS HAVE BEEN OBSERVED IN LABORATORY RATS
EXPOSED TO OVER 1000 PPM METHYL ETHYL KETONE FOR MOST OF
GESTATION PERIOD.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN.
-FIRST AID:
INHALATION: REMOVE TO FRESH AIR, IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO MOUTH,
IF BREATHING DIFFICULT GIVE OXYGEN, CALL A
PHYSICIAN AT ONCE.
SKIN CONTACT:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE
REUSE. WASH AFFECTED AREA WITH PLENTY OF SOAP AND
WATER.
EYE CONTACT:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN (HOLD
EYE LIDS OPEN) LONGER IF THERE IS INDICATION OF
RESIDUAL MATERIAL IN EYE.
INGESTION: CALL A PHYSICIAN IMMEDIATELY.INDUCE VOMITING ONLY AT
Page: 3 SIA ADHESIVES, INC.
Material Safety Data Sheet for: A-1104-B(2766290)
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SECTION V - HEALTH HAZARD DATA (cont.)
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-FIRST AID: (cont.)
THE INSTRUCTIONS OF A PHYSICIAN.NEVER GIVE ANY THING
BY MOUTH TO AN UNCONSCIOUS PERSON.
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SECTION VI - REACTIVITY DATA
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STABLITY: [ ] Unstable [x] Stable
HAZARDOUS POLYMERIZATION: [ ] May occur [x] Will not occur
-INCOMPATABILITY:
STRONG OXIDIZING AGENTS.
-CONDITIONS TO AVOID:
SEE ABOVE.
-HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE, CARBON MONOXIDE, SMOKE, ALIPHATICS,AND OTHERS.
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SECTION VII - SPILL OR LEAK PROCEDURES
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-STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
ELIMINATE ALL IGNITION SOURCES, PROVIDE ADEQUATE VENTILATION,
AVOID BREATHING VAPORS, AVOID EYE AND SKIN CONTACT. WIPE UP
WITH RAGS,PAPER OR OTHER ABSORBENT.PLACE IN SUITABLE CLOSED
CONTAINERS FOR DISPOSAL.
-WASTE DISPOSAL METHOD:
THIS MATERIAL IF DISCARDED, IS HAZARDOUS AND MUST BE PROPERLY
STORED,TRANSPORTED,AND DISPOSED OF IN ACCORDANCE WITH APPLICABLE
LOCAL, STATE, AND FEDERAL REGULATIONS.
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SECTION VIII - SPECIAL PROTECTION INFORMATION:
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-RESPIRATORY PROTECTION:
FOR AIR CONTAMINANTS ABOVE TLV OR PERMISSIBLE LIMITS USE NIOSH
APPROVED RESPIRATOR FOR ORGANIC VAPORS.
-VENTILATION:
LOCAL EXHAUST TO KEEP VAPORS BELOW TLV OR PERMISSIBLE LIMITS.
-PROTECTIVE GLOVES:
IMPERVIOUS.
-EYE PROTECTION:
CHEMICAL GOGGLES.
-OTHER PROTECTIVE EQUIPMENT:
EYE WASH AND SAFETY SHOWER NEAR BY.
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SECTION IX - SPECIAL PRECAUTIONS
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-PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
USE ONLY IN A WELL VENTILATED AREA. ELIMINATE ALL SOURCES OF
IGNITION SUCH AS SPARKS,FLAMES ,AND NON-EXPLOSION PROOF DEVICES.
AVOID PROLONGED OR REPEATED SKIN CONTACT OR BREATHING OF VAPORS.
FOR INDUSTRIAL USE ONLY,KEEP OUT OF THE REACH OF CHILDREN.
STORE IN TIGHTLY CLOSED CONTAINERS, IN A COOL DRY PLACE,AWAY
Page: 4 SIA ADHESIVES, INC.
Material Safety Data Sheet for: A-1104-B(2766290)
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SECTION IX - SPECIAL PRECAUTIONS (cont.)
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-OTHER PRECAUTIONS:
FROM ALL SOURCES OF IGNITION AND HEAT. LARGE CONTAINERS SHOULD
BE GROUNDED AND INTERCONNECTED TO PREVENT STATIC BUILD UP DURING
TRANSFER OPERATIONS. EMPTY CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS SINCE THEY MAY CONTAIN RESIDUAL LIQUID,VAPORS OR DUST.
IN ADDITION TO ANY LISTED PRECAUTIONS,YOU SHOULD CONSULT YOUR
OCCUPATIONAL SAFETY AND HEALTH SPECIALIST TO INSURE THAT THE
HANDLING PROCEDURES WILL BE ADEQUATE AND IN COMPLIANCE WITH
APPLICABLE LAWS AND REGULATIONS.
DISCLIAMER OF LIABILITY: THE INFORMATION CONTAINED HEREIN IS
BASED ON DATA TAKEN FROM SOURCES BELIEVED TO BE BOTH CURRENT AND
RELIABLE AT THE TIME OF PUBLICATION. SOVEREIGN ENGINEERED
ADHESIVES,L.L.C., HOWEVER MAKES NO WARRANTIES EXPRESS OR IMPLIED
AS TO ITS ACCURACY AND ASSUMES NO LIABILITY ARISING FROM ITS
USE BY OTHERS. COMPLIANCE WITH ALL APPLICABLE FEDERAL, STATE AND
LOCAL LAWS AND REGULATIONS REMAINS THE RESPONSIBILITY OF THE
USERS.
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SECTION X - ADDITIONAL REGULATORY INFORMATION
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-SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of section 313 of the Emergency Planning
and Community Right To Know Act of 1986 and of 40 CFR 372:
Percent by
CAS# Chemical Name Weight
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78-93-3 METHYL ETHYL KETONE < 50.
108-88-3 TOLUENE (SKIN) < 50.
71-36-3 BUTYL ALCOHOL (SKIN) < 5.
80-62-6 METHYL METHACRYLATE < 1.
50-00-0 FORMALDEHYDE < 1.
-PROP 65 (CARCINOGEN):
WARNING: This product contains a chemical known to the state
of California to cause cancer.
CAS# Chemical Name
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50-00-0 FORMALDEHYDE
PRODUCT MAY CONTAIN TRACE AMOUNTS OF CALIFORNIA PROPOSITION
65 LISTED CHEMICALS
Page: 5 SIA ADHESIVES, INC.
Material Safety Data Sheet for: A-1104-B(2766290)
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SECTION X - ADDITIONAL REGULATORY INFORMATION (cont.)
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-PROP 65 (TERATOGEN):
WARNING: This product contains a chemical known to the state
of California to cause birth defects or other reproductive harm.
CAS# Chemical Name
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108-88-3 TOLUENE (SKIN)
-PROP 65 (BOTH CARCINOGEN AND TERATOGEN):
WARNING: This product may contain a chemical known to the state of
California to cause cancer or birth defects or other reproductive harm
CAS# Chemical Name
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None
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