11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Material Safety Data Sheet B-4 BRUSH CLEANER Page 1 of 1
Revised Date:11/04/2004 | Replaces Date: 02/20/2001
MSDS#: KIA022001-B4C
Section 1 - Identification of the Substance/Preparation and of the
Company/Undertaking
Product Name: B-4 Brush Cleaner
________________________________________
MSDS Approval
Date:
02/20/2001
Chemical
Name:
N/A MSDS Prepared by: BSQ
Family: Solvent Manufacturer: KEYSTONE INDUSTRIES
616 Hollywood Ave. Cherry Hill, NJ 08002
Product Use: Cleansing Agent Emergency Phone Numbers: ( 800 ) 535 - 5053
Product #: 1001774 Information Contacts: (856)-663-4700
Section 2 - Composition/Information on Ingredients
Chemical Identity CAS Numbers EINECS# INCI Name Exposure Limits Carcinogen %
OSHA ACGIH
TWA/STEL TWA/STEL IARC/NTP/OSHA
Ethyl Acetate 141-78-6 205-500-4 Ethyl Acetate 400 ppm 400 ppm Not Listed 55-65
n-Butyl Acetate 123-86-4 204-658-1 Butyl Acetate 150 ppm 150 ppm Not Listed 15-25
Isopropyl Alcohol 67-63-0 200-661-7 Isopropyl Alcohol 400 ppm 400 ppm 3/no/no 5-10
Methyl Ethyl Ketone 78-93-3 201-159-0 MEK 200 ppm 200 ppm Not Listed 1-5
Ethanol 64-17-5 200-578-6 Alcohol 1000ppm 1000ppm Not Listed 1-5
N/E - None Established
N/R - Not Reviewed
N/DA - No Data Available
N/A - Not Applicable
Hazard Symbols: F, Xi Risk Phrases: R11, R20, R36/37/38 Safety Phrases: S7/9, S16, S26, S33,
S36/37, S45, S61
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
? Flammable liquid and vapor!
? May cause allergic skin reaction.
? May cause eye irritation.
? May cause respiratory tract irritation.
Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry Inhalation, skin contact, eye contact
Eye Exposure causes eye irritation. Symptoms include stinging, tearing, redness and swelling.
Skin Can cause skin irritation. Prolonged or repeated contact may dry the skin.Symptoms may include
redness, burning, drying and cracking, and skin burns.
Ingestion Swallowing small amounts during normal handling is not likely to cause harmful effects;
swallowing
large amounts may be harmful.This material can get into the lungs during swallowing or vomiting.
Inhalation Vapor and mist are irritating to mucous membrane. Breathing small amounts during normal
handling
is not likely to cause harmful effects. Breathing large amounts may be harmful. Symptoms usually
occur at air concentrations higher than the recommended exposure limits.
Sub-Chronic Effects It may cause headaches,nausea,vomiting and narcotic effect if over-exposed.
NOTE: Refer to Section 11, Toxicological Information for Details
Section 4 - First Aid Measures
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
First Aid for Eye If symptoms develop, move individual away from exposure and into fresh air. Flush eyes
gently with water
while holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention.
First Aid for Skin Remove contaminated clothing. Wash exposed area with soap and water. If symptoms
persist, seek
medical attention.
First Aid for Inhalation Remove to fresh air.If breathing is difficult, administer oxygen. If symptoms
persist, seek medical
attention.
First Aid for Ingestion If individual is drowsy or unconscious. do not give anything by mouth; place
individual on the leftside
with the head down.Seek medical attention for advice about whether to induce vomiting. If possible, do
Material Safety Data Sheet B-4 BRUSH CLEANER Page 2 of 2
Revised Date:11/04/2004 | Replaces Date: 02/20/2001
MSDS#: KIA022001-B4C
not leave individual unattended.
Section 5 - Fire Fighting Measures
Flash Point (癋/癈) Flammable Limit (vol%) Auto-ignition Temperature (vol%)
TAG Closed: 68篎/20篊 400 ppm N/DA
Method:
Extinguishing Media: Foam, dry chemical, cold water spray.
Fire Fighting
Instructions:
Wear self-contained breathing apparatus and protective clothing. USE WATER WITH
CAUTION. Use water spray to keep fire-exposed containers cool. Water may be ineffective
in fighting the fire. Fight fire from a safe distance and protected location.
Unusual Hazards: Flammable. When exposed to heat and flame, material is a fire explosion hazard. It may
produce
toxic products CO, Carbon dioxide and oxides of nitrogen. Vapors may cause a flash fire or
ignite explosively. Vapors may travel considerable distance to a source of ignition and flash
back. Prevent buildup of vapors or gases to explosive concentrations.
Section 6 - Accidental Release Measures
Spill or Release
Procedures
Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it, wash spill material
into
retaining containers. Place containers in a well ventilated area. Consult an expert on disposal of recovered
material and ensure conformity to local disposal regulations. Keep unnecessary and unprotected personnel
from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect
liquid
in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in
a
chemical waste container. Do not use combustible materials, such as sawdust. Do not flush to sewer! US
Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable
quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802. EU
Regulations require the consultation of Directive 98/24/EC. If a leak or spill has not ignited, use water
spray to
disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures.
Section 7 - Handling and Storage
Handling Keep containers cool and dry. Keep away from heat, light and ignition sources. Avoid breathing
high vapor
concentrations. Avoid prolonged or repeated contact with skin. Use only with adequate ventilation.
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Wash thoroughly after handling.
Storage Store in well ventilated area. Store @ 70篎+/- 15篎 (21篊+/-8篊), allow some air space above
liquid level.
Keep containers closed while not in use.
Explosion Hazard Vapors are heavier than air and may travel along the ground or may be move by
ventilation and ignited by pilot
lights, other flames,sparks,heaters,smoking or other ignition sources at locations distant from material
handling
point.Never use welding or cutting torch on or near drum (even empty) because product ( even just residue)
can
ignite explosively.
Section 8 - Exposure Controls / Personal Protective Equipment
Engineering
Controls
Facilities storing or ultilizing this material should be equipped with an eye facility and safety shower. Use
process enclosures local exhaust ventilation, or other engineering controls to control airborne levels
below recommended exposure limits. Use explosion-proof ventilation equipment.
Personal Protective Equipment
General To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that
a
hazard assessment in accordance with the OSHA PPE Standard (29CFR1910.132), or European
Standard EN166 be conducted before using this product . Provide eye wash stations and safety
showers. Wear impervious clothing to prevent ANY contact with this product, such as gloves, apron,
boots, or whole body suit. Nitrile rubber is better than PVC.
Eye/ Face Protection Use impermeable clothing to prevent ANY contact with this product, such as gloves,
apron, boots, or whole
body suit. Nitrile rubber is better than PVC.
Skin Protection Wear resistant gloves.To prevent repeated or prolonged skin contact, wear impervious
clothing and boots.
Respiratory
Protection
A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible
under
certain limited circumstances where airborne concentrations are expected to exceed exsposure limits. Protection
provided
b i if i i i li i d W NIOSH/MSHA E S d d EN 149 d f llf i
Material Safety Data Sheet B-4 BRUSH CLEANER Page 3 of 3
Revised Date:11/04/2004 | Replaces Date: 02/20/2001
MSDS#: KIA022001-B4C
by air purifying respirators is limited. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepeice
airline respirator in the positive pressure mode with emergency escape provisions. Follow OSHA repsirator regulations
found in 29 CFR 1910.134 or Eurpean Standard EN 149.
Section 9 - Physical and Chemical Properties
Appearance Odor & Odor Threshold PH Specific Gravity Viscosity % Volatile
Clear mobile liquid Fruity, pungent, mix odor NA (H2O=1):0.98 N/DA W/W %: 99+
Boiling Point/
Decomposition
Octanol/Water
Vapor
Vapor
Evaporation
Ignition
Solubility
Freezing Point
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Temperature Partitioning
Coefficient
Log Po/w
Pressure: Density Rate In Water
(20癈)
170篎(77篊) N/DA N/DA N/A (Air=1): 1 N/A N/A Insoluble
Flash Point (癋/癈) Flammable Limit (vol%) Auto-ignition Temperature (vol%)
TAG Closed: 68篎/20篊 400 ppm N/DA
Section 10 - Stability and Reactivity
Stability: Incompatibility (Materials to Avoid):
Stable Avoid oxidizing agents,acids & bases (heat)
Hazardous Decomposition Products: Hazardous Polymerization:
Heated material produce NO2 , CO2 , CO Will not occur
Conditions to Avoid:
Heat, flame, ignition sources.
Section 11 - Toxicological Information
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation - skin Irritation - Eye
No information available No information available No information available No information available No information available
Further hazardous properties cannot be excluded. The product should be handled with care when dealing with
chemicals.
S ensitization Mutagenicity Sub-chronic Toxicity
No information available No information available No information available
Section 12 - Ecological Information
Ecotoxicological Information
Acute Toxicity
To Fish
Acute Toxicity
to Invertebrates
Acute Toxicity
to Algae
Bioconcentration Toxicity to Sewage
Bacteria
No information available No information available No information available No information available No information available
Chemical Fate Information
Biodegradability No information available
Chemical Oxygen Demand No information available
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated.
Do not allow to enter drinking water supplies, wastewater, or soil.
Section 13 - Disposable Considerations
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual vapors
may explode on
ignition; do not cut, drill, or weld on or near the container. Mix with compatible chemical which is less flammable and
incinerate.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA
approved waste facility.
Processing, use or contamination of this product may change the waste management options. State and local disposal
regulations may differ
from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local
requirements. For EU
Member States, please refer to any relevant Community provisions relating to waste. In their absence, it is useful to
remind the user that national
or regional provisions may be in force.
Section 14 - Transport Information
DOT (49 CFR 172)
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl acetate, n-butyl acetate), 3, UN1993, PGII
Identification Number: UN1993
Marine Pollutant: No
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Special Provisions: T8, T31
Material Safety Data Sheet B-4 BRUSH CLEANER Page 4 of 4
Revised Date:11/04/2004 | Replaces Date: 02/20/2001
MSDS#: KIA022001-B4C
Emergency Response Guidebook (ERG) #: 128
IATA (DGR):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl acetate, n-butyl acetate), 3, UN1993, PGII
Class or Division: 3
UN or ID Number: UN1993
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl acetate, n-butyl acetate), 3, UN1993, PGII
Class or Division: 3.2
UN or ID Number: UN1993
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information: Flash point = 20篊
Section 15 - Regulatory Information
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following hazardous air pollutants (HAPs):
?Methyl Ethyl Ketone, CAS# 78-93-3
There are no ODS's (ozone depleting substances) as defined by the U. S. Clean Air Act.
Clean Water Act: Priority Pollutant This product contains the following chemicals listed under the U. S.
Clean Water Act
Priority Pollutant and Hazardous Substance List:
?Butyl Acetate, CAS# 123-86-4
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and /
or
other applications as an indirect food additive.
Occupational Safety and Health Act This product is considered to be hazardous under the OSHA Hazard
Communication
Standard. Its hazards are:
?Immediate (acute) health hazard
?Fire hazard
RCRA This product contains chemicals considered to be hazardous waste under RCRA (40 CFR
261):
?Ethyl Acetate CAS# 141-78-6, RCRA Code U112
?Methyl Ethyl Ketone, CAS# 78-93-3, RCRA Codes D035, U159
?May contain Characteristic of Ignitablility: RCRA Code: D001
SARA Title III: Section 302 (RQ) This product contains no chemicals regulated under Section 302 as
extremely hazardous
substances.
SARA Title III: Section 302 (TPQ) This product contains chemicals regulated under Section 302 as
extremely hazardous
chemicals for emergency release notification ("CERCLA" List):
?Ethyl Acetate, CAS# 141-78-6, RQ (Lbs): 5000
?Butyl Acetate, CAS# 123-86-4, RQ (Lbs): 5000
?Methyl Ethyl Ketone, CAS# 78-93-3, RQ (Lbs): 5000
SARA Title III: Section 311-312: This product is considered to be hazardous under the OSHA Hazard
Communication
Standard and is regulated under Section 311-312 (40 CFR 370 ). Its hazards are:
?Immediate (acute) health hazard
?Fire hazard
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
SARA Title III: Section 313: This product contains the following chemicals which are subject to the
reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
?Isopropyl Alcohol, CAS# 67-63-0
?Methyl Ethyl Ketone, CAS# 78-93-3
TSCA Section 8(b): Inventory:
TSCA Significant New Use Rule:
This product contains chemicals listed on the TSCA inventory or otherwise complies
with TSCA premanufacture notification requirements.
None of the chemicals in this material have a SNUR under TSCA.
State Regulations
CA Right-to-Know Law:
California No Significant Risk
Level:
Ethyl Acetate CAS #141-78-6, Isopropyl Alcohol CAS #67-63-0, Butyl Acetate CAS #123-86-4, Methyl
Ethyl Ketone CAS 78-93-3
NONE
Material Safety Data Sheet B-4 BRUSH CLEANER Page 5 of 5
Revised Date:11/04/2004 | Replaces Date: 02/20/2001
MSDS#: KIA022001-B4C
MA Right-to-Know Law: Ethyl Acetate CAS #141-78-6, Isopropyl Alcohol CAS #67-63-0, Butyl Acetate CAS #123-
86-4, Methyl
Ethyl Ketone CAS 78-93-3
NJ Right-to-Know Law: Ethyl Acetate CAS #141-78-6, Isopropyl Alcohol CAS #67-63-0, Butyl Acetate CAS #123-
86-4, Methyl
Ethyl Ketone CAS 78-93-3
PA Right-to-Know Law: Ethyl Acetate CAS #141-78-6, Isopropyl Alcohol CAS #67-63-0, Butyl Acetate CAS #123-
86-4, Methyl
Ethyl Ketone CAS 78-93-3
FL Right-to-Know Law: Ethyl Acetate CAS #141-78-6, Isopropyl Alcohol CAS #67-63-0, Butyl Acetate CAS #123-
86-4, Methyl
Ethyl Ketone CAS 78-93-3
MN Right-to-Know Law: Ethyl Acetate CAS #141-78-6, Isopropyl Alcohol CAS #67-63-0, Butyl Acetate CAS #123-
86-4, Methyl
Ethyl Ketone CAS 78-93-3
International Regulations
CDSL: Canadian Inventory
(on Canadian Transitional List)
Ethyl Acetate CAS #141-78-6 is on the DSL list. WHMIS = B2, D2B
Isopropyl Alcohol CAS #67-63-0 is on the DSL list. WHMIS = B2, D2B
Butyl Acetate CAS #123-86-4 is on the DSL list. WHMIS = B2, D1B, D2B
Methyl Ethyl Ketone CAS 78-93-3 is on the DSL list. WHMIS = B2, D2A
EINECS: European Inventory: B-4 Brush Cleaner:
?HAZARD SYMBOLS: Xn, F: Harmful, Highly Flammable
?RISK PHRASES: R11, highly flammable, R20: Harmful by inhalation, R36/37/38:
Irritating to eyes, respiratory system and skin
?SAFETY PHRASES: S7/9: keep container tightly closed and in a well ventilated place,
S16: keep away from sources of ignition- no smoking, S24/25: In case of contact with
eyes, rinse immediately with plenty of water and seek medical advise, S33: take
precautionary measures against static discharges, S37/39: wear suitable protective
clothing & gloves, S45: In case of accident or if you feel unwell, seek medical advise
immediately (show the label where possible), S61: Avoid release to the environment.
Refer to special instruction/Safety data sheets
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11652 Monarch Street
Garden Grove CA 92841
562-598-3966 Fax 598-8096.
Section 16 - Other Information
Hazard Rating System (Pictograms)
NFPA: HMIS:
231
Revised Sections since Last Version: Overall format and content change to all sections
The information presented herein was obtained from sources considered to be reliable. However, this
information is provided without
any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use
and/or application. For this and
other reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense
arising out of any way
connected with the handling, storage, use or disposal of the product. This MSDS was prepared expressly
for this product. Use the
materials only as directed. If the product is used as a component of another product, the information
contained within the MSDS may
not be applicable. If one could have any concerns with or problems understanding this MSDS form, please
direct all questions to
INFOTRAC, Chemical Emergency Resources System at 1(800) 535-5053.
3
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Flammability
Reactivity Health
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