Page 1/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 29.03.2006 Reviewed on 20.09.2004
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: Pi-Ku-Plast HP 36 Cleaner ?Article number: 540 0022 4
?Application of the substance / the preparation Cleaner.
?Manufacturer/Supplier:
Bredent
Wei遝nhorner Stra遝 2
D-89250 Senden
Tel.: +49 (0) 7309/872-0
Fax: +49 (0) 7309/872-24
?Further information obtainable from: R & D
?Information in case of emergency: Tel.: +49 (0) 6132-84436 (24 h)
2 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 141-78-6 ethyl acetate Xi, F; R 11-36-66-67 50-100%
EINECS: 205-500-4
CAS: 110-19-0 isobutyl acetate F; R 11-66 10-25%
EINECS: 203-745-1
?Additional information: For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
?Hazard description:
Xi Irritant
F Highly flammable
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
At long or repeated contact with skin it may cause dermatitis due to the degreasing effect of the solvent.
Has a narcotizing effect.
R 11 Highly flammable. R 36 Irritating to eyes.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
4 First aid measures
?After inhalation: Supply fresh air; consult doctor in case of complaints.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
?After swallowing: Call a doctor immediately.
GB
(Contd. on page 2)
Page 2/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 29.03.2006 Reviewed on 20.09.2004
Trade name: Pi-Ku-Plast HP 36 Cleaner
(Contd. of page 1)
5 Fire-fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Protective equipment: No special measures required.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about fire - and explosion protection: Keep ignition sources away
- Do not smoke. Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace: 141-78-6
ethyl acetate
OES Short-term value: 400 ppm
Long-term value: 200 ppm Rev
110-19-0 isobutyl acetate
OES Short-term value: 903 mg/m? 187 ppm
Long-term value: 724 mg/m? 150 ppm
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated
clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin.
?Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation.
?Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
(Contd. on page 3)
GB
Page 3/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 29.03.2006 Reviewed on 20.09.2004
Trade name: Pi-Ku-Plast HP 36 Cleaner
(Contd. of page 2)
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
?Body protection: Protective work clothing
9 Physical and chemical properties
?General Information
Fluid
Form:
Colourless
Colour:
Fruit-like
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 77癈
-1癈
?Flash point:
Product is not selfigniting.
?Self-igniting:
Product is not explosive . However, formation of explosive air/vapour
?Danger of explosion:
mixtures are possible.
?Explosion limits:
2.1 Vol %
Lower:
11.5 Vol %
Upper:
0.894 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Not miscible or difficult to mix.
water:
10Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
GB
(Contd. on page 4)
DR
Page 4/5
Material Safety Data Sheet
According to 91/155 EEC
Printing date 29.03.2006 Reviewed on 20.09.2004
Trade name: Pi-Ku-Plast HP 36 Cleaner
(Contd. of page 3)
11Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for
classification: 141-78-6 ethyl acetate
Oral LD50 5620 mg/kg (rabbit)
Inhalative LC50/4 h 1600 mg/l (rat)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
12Ecological information
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow
undiluted product or large quantities of it to reach ground water, water course or sewage system.
13Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14Transport information
?Land transport ADR/RID (cross-border)
3 Flammable liquids.
?ADR/RID class:
?Danger code (Kemler): 33
1993
?UN-Number:
II
?Packaging group:
3
?Hazard label:
?Description of goods: 1993 FLAMMABLE LIQUID, N.O.S. (ETHYL ACETATE, ISOBUTYL ACETATE),
special provision 640D
?Maritime transport IMDG:
15Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product: Xi Irritant
F Highly flammable
?Risk phrases:
11Highly flammable.
36Irritating to eyes.
66Repeated exposure may cause skin dryness or cracking.
67Vapours may cause drowsiness and dizziness.
?Safety phrases:
9 Keep container in a well-ventilated place. 16Keep
away from sources of ignition - No smoking.
23Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
60This material and its container must be disposed of as hazardous waste.
16Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
11Highly flammable.
36Irritating to eyes.
66Repeated exposure may cause skin dryness or cracking.
67Vapours may cause drowsiness and dizziness.
?Department issuing MSDS: R & D ?Contact: R & D