UNION CARBIDE CORPORATION
A Subsidiary of The Dow Chemical Company
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 1 of 14
Union Carbide urges each customer or recipient of this MSDS to study it carefully to become aware of and
understand the hazards associated with the product. The reader should consider consulting reference
works or individuals who are experts in ventilation, toxicology, and fire prevention, as necessary or
appropriate to use and understand the data contained in this MSDS.
To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors
and others whom it knows or believes will use this material of the information in this MSDS and any other
information regarding hazards or safety; 2) Furnish this same information to each of its customers for the
product; and 3) Request its customers to notify their employees, customers, and other users of the
product of this information.
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICAT ION
1.1 IDENTIFICATION
Product Name ETHANOL, SDA-35A 200 PROOF SPECIALLY DENATURED
ALCOHOL
Chemical Name Denatured Ethyl Alcohol
Chemical Family Alcohols
Formula Not applicable (mixture)
Ethyl Alcohol SDA 35A, 200 Proof
Synonym
1.2 COMPANY IDENTIFICATION
Union Carbide Corporation
A Subsidiary of The Dow Chemical Company
39 Old Ridgebury Road
Danbury, CT 06817-0001
1.3 EMERGENCY TELEPHONE NUMBER
24 hours a day: CHEMTREC 1-800-424-9300.
Number for non-emergency questions concerning MSDS (732) 563-5522
Additional information on this product may be obtained by calling the Union
Carbide Corporation Customer Service Center at 1-800-568-4000.
Copyright?2000, Union Carbide Chemicals & Plastics Technology Corporation.
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 2 of 14
2. COMPOSITION INFORMAT ION
Component CAS # Amount (%W/W )
Ethanol 64-17-5 95.3 %
Ethyl acetate 141-78-6 4.7 %
3. HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Transparent colorless
Appearance
Liquid
Physical
State
Fragrant
Odor
WARNING! FLAMMABLE.
Hazards of
CAUSES EYE IRRITATION.
product
3.2 POTENTIAL HEALTH EFFECTS
Effects of Single Acute Overexposure
Inhalation Low concentrations of vapor may cause irritation of the nose and throat. High
concentrations of vapor may cause central nervous system depression, with weakness, drowsiness, and
loss of consciousness.
Eye Contact May cause irritation, experienced as stinging with excess blinking and tear production.
Excess redness of the conjunctiva may occur.
Skin Contact Prolonged contact may cause defatting of the skin with possible reddening and
itchiness.
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 3 of 14
Skin Absorption No harmful effects with normal skin. However, potentially harmful amounts of
material may be absorbed across markedly damaged skin when contact is sustained, particularly with
children.
Swallowing May cause dizziness, faintness, drowsiness, decreased awareness and responsiveness,
euphoria, abdominal discomfort, nausea, vomiting, staggering gait, lack of coordination, and coma.
Chronic, Prolonged or Repeated Overexposure
Effects of Repeated Overexposure Repeated contact with skin may cause a severe
cumulative dermatitis. Long term repeated oral exposure to ethanol may result in the development of
progressive liver injury with fibrosis. Repeated skin contact may cause a cumulative dermatitis.
Other Effects of Overexposure Repeated ingestion of ethanol by pregnant mothers has been
shown to adversely affect the central nervous system of the fetus, producing a collection of effects which
together constitute the fetal alcohol syndrome. These include mental and physical retardation,
disturbances of learning, motor and language deficiencies, behavioral disorders, and small size head.
Medical Conditions Aggravated by Exposure
Skin contact may aggravate an existing dermatitis. Repeated exposure to ethanol may
aggravate liver injury produced from other causes.
3.3 POTENTIAL ENVIRONMENTAL EFFECTS
See Section 12 for Ecological Information.
4. FIRST AID PROCEDURES
4.1 INHALATION
Remove to fresh air. Give artificial respiration if not breathing. If breathing is difficult, oxygen
may be given by qualified personnel. Obtain medical attention.
4.2 EYE CONTACT
Immediately flush eyes with water and continue washing for several minutes. Remove contact
lenses, if worn. Obtain medical attention if discomfort persists.
4.3 SKIN CONTACT
Wash skin with soap and water.
4.4 SWALLOWING
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 4 of 14
If patient is fully conscious, give two glasses of water. Induce vomiting. This should be done
only by medical or experienced first-aid personnel. Obtain medical attention.
4.5 NOTES TO PHYSICIAN
Symptoms vary with the alcohol level of the blood. Mild alcohol intoxication occurs at blood
levels between 0.05%-0.15% and approximately 25% of individuals will show signs of
intoxication at these levels. Above 0.15% the person is definitely under the influence of ethanol
and 50% - 95% of individuals at this level are clinically intoxicated. Severe poisoning occurs
when the blood ethanol level is 0.3% - 0.5%. Above 0.5% the individual will be comatose and
death can occur. The unabsorbed ethanol should be removed by gastric lavage after intubating
the patient to prevent aspiration. Avoid the use of depressant drugs or the excessive
administration of fluids. In the presence of hypoglycemia, administer 5% - 10% glucose
intravenously, plus thiamine 100 mg intramuscularly. Hemodialysis is indicated if the blood
ethanol is above 5 mg/ml. Naloxone may be useful to reverse clinical alcoholic coma and 0.4-1.2
mg intravenously may arouse ethanol-intoxicated patients.
5. FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
Flash Point - Closed Cup: Tag Closed Cup ASTM D 56 11 癈 52 癋
Flash Point - Open Cup: Tag Open Cup ASTM D 1310 17 癈 62 癋
Autoignition Temperature: Not currently available.
Flammable Limits In Air:
3.3 %(V) (Ethanol)
Lower
19.0 %(V) (Ethanol)
Upper
5.2 EXTINGUISHING MEDIA
Extinguish fires with water spray or apply alcohol-type or all-purpose-type foam by
manufacturer's recommended techniques for large fires. Use carbon dioxide or dry chemical
media for small fires.
5.3 EXTINGUISHING MEDIA TO AVOID
No information currently available.
5.4 SPECIAL FIRE FIGHTING PROCEDURES
Use water spray to cool fire-exposed containers and structures.
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 5 of 14
5.5 SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Use self-contained breathing apparatus and protective clothing.
5.6 UNUSUAL FIRE AND EXPLOSION HAZARDS
Vapors form from this product and may travel or be moved by air currents and ignited by pilot
lights, other flames, smoking, sparks, heaters, electrical equipment, static discharges or other
ignition sources at locations distant from product handling point.
Vapors from this material may settle in low or confined areas or travel a long distance to an
ignition source and flash back explosively.
Static ignition hazard can result from handling and use. Electrically bond and ground all
containers, personnel and equipment before transfer or use of material. Special precautions
may be necessary to dissipate static electricity for non-conductive containers. Use proper
bonding and grounding during product transfer as described in National Fire Protection
Association Document NFPA 77.
Avoid splash filling of containers when handling this flammable liquid because static electricity
may be generated. Use proper bonding and grounding during product transfer as described in
National Fire Protection Association Document NFPA 77.
See Section 8.3 - Engineering Controls
This material may produce a floating fire hazard.
Flame may be invisible. Approach fire with caution.
5.7 HAZARDOUS COMBUSTION PRODUCTS
Burning can produce the following products: Carbon monoxide and/or carbon dioxide. Carbon
monoxide is highly toxic if inhaled. Carbon dioxide in sufficient concentrations can act as an
asphyxiant.
6. ACCIDENTAL RELEASE MEASURES
Steps to be Taken if Material is Released or Spilled:
Extinguish and do not turn on any ignition source until the area is determined to be free from fire
or explosion hazard. Small spills can be flushed with large amounts of water; larger spills should
be collected for disposal. Observe government regulations.
Personal Precautions: Wear suitable protective equipment. See Section 8.2 - Personal
Protection.
7. HANDLING AND STORAGE
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 6 of 14
7.1 HANDLING
General Handling
Keep away from heat, sparks and flame.
Avoid contact with eyes.
Keep container closed.
Use with adequate ventilation.
Vapor forms from this product and may travel or be moved by air currents and ignited by pilot
lights, other flames, smoking, sparks, heaters, electrical equipment, static discharges or other
ignition sources at locations distant from product handling point and may flash back explosively.
Wash thoroughly after handling.
FOR INDUSTRY USE ONLY.
Ventilation
General (mechanical) room ventilation is expected to be satisfactory where this product is stored
and handled in closed equipment. Special, local ventilation is needed at points where vapor can
be expected to escape to the workplace air.
Other Precautions
Contains ingredients which render this product wholly unfit for beverage purposes. If taken
internally, will cause serious consequences to health. Vapor may settle in low or confined areas,
or travel a long distance to an ignition source and flash back explosively.
7.2 STORAGE
Store in accordance with good industrial practices. Storage information may be obtained from
product-specific Union Carbide Storage and Handling Guides, or by calling a Union Carbide
Customer Service Representative.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 EXPOSURE LIMITS
Component Exposure Limits Skin Form
Ethanol 1000 ppm TWA8 ACGIH
1880 mg/m3 TWA8 ACGIH
1000 ppm TWA8 OSHA
1900 mg/m3 TWA8 OSHA
Ethyl acetate 1440 mg/m3 TWA8 ACGIH
400 ppm TWA8 ACGIH
1400 mg/m3 TWA8 OSHA
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 7 of 14
400 ppm TWA8 OSHA
In the Exposure Limits Chart above, if there is no specific qualifier (i.e., Aerosol) listed in the
Form Column for a particular limit, the listed limit includes all airborne forms of the substance
that can be inhaled.
A "Yes" in the Skin Column indicates a potential significant contribution to overall exposure by
the cutaneous (skin) route, including mucous membranes and the eyes, either by contact with
vapors or by direct skin contact with the substance. A "Blank" in the Skin Column indicates that
exposure by the cutaneous (skin) route is not a potential significant contributor to overall
exposure.
8.2 PERSONAL PROTECTION
Use self-contained breathing apparatus in high vapor concentrations.
Respiratory
Protection:
General (mechanical) room ventilation is expected to be satisfactory
Ventilation:
where this product is stored and handled in closed equipment.
Special, local ventilation is needed at points where vapor can be
expected to escape to the workplace air.
Safety glasses or monogoggles
Eye Protection:
Neoprene
Protective
PVC-coated
Gloves:
Eye Bath, Safety Shower
Other Protective
Equipment:
8.3 ENGINEERING CONTROLS
PROCESS HAZARD: Sudden release of hot organic chemical vapor or mists from process
equipment operating at elevated temperature and pressure, or sudden ingress of air into hot
equipment under a vacuum, may result in ignitions without the presence of obvious ignition
sources. Published "autoignition" or "ignition" temperature values cannot be treated as safe
operating temperatures in chemical processes without analysis of the actual process conditions.
Any use of this product in elevated-temperature processes should be thoroughly evaluated to
establish and maintain safe operating conditions. Further information is available in a technical
bulletin entitled "Ignition Hazards of Organic Chemical Vapor."
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 8 of 14
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid
Appearance: Transparent colorless
pH: Not currently available.
Solubility in Water (by weight): 20 癈 100 %
Odor: Fragrant
Flash Point - Closed Cup: Tag Closed Cup ASTM D 56 11 癈 52 癋
Flash Point - Open Cup: Tag Open Cup ASTM D 1310 17 癈 62 癋
Percent Volatiles: 100 Wt%
Boiling Point (760 mmHg): 78.3 癈 172.9 癋
Freezing Point: < -80 癈 < -112 癋
Specific Gravity (H2O = 1): 0.796 20 癈 / 20 癈
Vapor Pressure at 20癈: 6.03 kPa 45.2 mmHg
Vapor Density (air = 1): 1.6
Evaporation Rate (Butyl Acetate = 1): 3.4
Melting Point: Not applicable.
10. STABILITY AND REACTIVITY
10.1 STABILITY/INSTABILITY Stable
Incompatible Materials: Strong oxidizing agents. Strong inorganic acids.
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 9 of 14
10.2 HAZARDOUS POLYMERIZATION Will Not Occur.
10.3 INHIBITORS/STABILIZERS Not applicable.
11. TOXICOLOGICAL INFORM ATION
SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMANS
The International Agency for Research on Cancer (IARC) has determined that the consumption
of alcoholic beverages is causally related to the occurrence of malignant tumors of the oral
cavity, pharynx, larynx, esophagus and liver in humans. The carcinogenic response attributed to
drinking alcoholic beverages has not been verified in studies with laboratory animals.
Established uses of denatured ethanol and non-beverage uses of pure ethanol are not
considered to pose any significant cancer hazard. Ethanol has been shown to have a weak skin
sensitizing potential in a very small percentage of the population.
12. ECOLOGICAL INFORMATION
12.1 ENVIRONMENTAL FATE
Information may be available, call Union Carbide.
12.2 ECOTOXICITY
Information may be available, call Union Carbide.
12.3 FURTHER INFORMATION
None.
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 10 of 14
13. DISPOSAL CONSIDERATIONS
13.1 WASTE DISPOSAL METHOD
Incinerate in a furnace where permitted under Federal, State, and local regulations. Dispose in
accordance with all applicable Federal, State, and local environmental regulations. Empty
containers should be recycled or disposed of through an approved waste management facility.
13.2 DISPOSAL CONSIDERATIONS
See Section 13.1
Disposal methods identified are for the product as sold. For proper disposal of used material, an
assessment must be completed to determine the proper and permissible waste management
options permissible under applicable rules, regulations and/or laws governing your location.
14. TRANSPORT INFORMATION
14.1 U.S. D.O.T.
NON-BULK
Proper Shipping Name : ETHANOL SOLUTION
Technical Name : DENATURED ETHANOL
ID Number : UN1170
Hazard Class : 3
Packing Group : PG II
BULK
Proper Shipping Name : ETHANOL SOLUTION
Technical Name : DENATURED ETHANOL
ID Number : UN1170
Hazard Class : 3
Packing Group : PG II
This information is not intended to convey all specific regulatory or operational
requirements/information relating to this product. Additional transportation system information
can be obtained through an authorized sales or customer service representative. It is the
responsibility of the transporting organization to follow all applicable laws, regulations and rules
relating to the transportation of the material.
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 11 of 14
15. REGULATORY INFORMATION
15.1 FEDERAL/NATIONAL
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT OF 1980 SECTION 103
(CERCLA)
The following components of this product are specifically listed as hazardous substances in 40
CFR 302.4 (unlisted hazardous substances are not identified) and are present at levels which
could require reporting:
Component CAS # Amount
Ethyl acetate 141-78-6 <= 4.7000%
Methanol 67-56-1 <= 0.0060%
Acetaldehyde 75-07-0 <= 0.0010%
Acetone 67-64-1 <= 0.0002%
Acetic acid 64-19-7 <= 0.0002%
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EPCRA) SECTIONS 302 AND 304
The following components of this product are listed as extremely hazardous substances in 40
CFR Part 355 and are present at levels which could require reporting and emergency planning:
None.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EPCRA) SECTION 313
The following components of this product are listed as toxic chemicals in 40 CFR 372.65 and are
present at levels which could require reporting and customer notification under Section 313 and
40 CFR Part 372:
This product does not contain toxic chemicals at levels which require reporting under the
statute.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 TITLE III (EPCRA) SECTIONS 311 AND 312
Delayed Hazard : Yes
Fire Hazard : Yes
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 12 of 14
Immediate Health Hazard : Yes
Reactive Hazard : No
Sudden Release of Pressure Hazard : No
TOXIC SUBSTANCES CONTROL ACT (TSCA)
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements.
15.2 STATE/LOCAL
PENNSYLVANIA (WORKER AND COMMUNITY RIGHT-TO-KNOW ACT)
This product is subject to the Worker and Community Right-to-Know Act. The following
components of this product are at levels which could require identification in the MSDS:
Component CAS # Amount
Ethanol 64-17-5 <= 95.3000%
Ethyl acetate 141-78-6 <= 4.7000%
MASSACHUSETTS (HAZARDOUS SUBSTANCES DISCLOSURE BY EMPLOYERS )
The following components of this product appear on the Massachusetts Substance List and are
present at levels which could require identification in the MSDS:
Component CAS # Amount
Ethanol 64-17-5 <= 95.3000%
Ethyl acetate 141-78-6 <= 4.7000%
Acetaldehyde 75-07-0 <= 0.0010%
NEW YORK (HAZARDOUS SUBSTANCES BULK STORAGE ACT)
New York State Bulk Storage Regulations (6 NYCRR Parts 595-599) This product is covered by
6 NYCRR for bulk storage and rlease reporting and response. Technical guidance and
recommended practices are as follows: MATERIALS OF CONSTRUCTION - Suitable materials
of construction are: Steel, stainless steel, baked phenolic lined steel, galvanized steel, copper,
and copper alloy. Materials not to be used: Aluminum. Plastics are not recommended for
flammable liquids. STORAGE SYSTEM DESIGN - Design should comply with applicable
industry, Federal, and local codes for a Class IB Flammable liquid with regards to mechanical,
electrical, safety and health components. Should also comply with the current versions of the
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 13 of 14
applicable reference documents cited in NYS/DEC Chemical Bulk Storage Regulations Sections
598.1(j), 598.2, 598.3, and 598.5 (for existing tanks) or Sections 599.1 and 599.10 (for new or
substantially modified tanks). CONDITIONS FOR STORAGE - Store at normal ambient
temperatures. INSPECTION AND MAINTENANCE - A testing/inspection program which ensures
structural integrity and proper system operation should be established. Inspection and
maintenance procedures and testing of equipment should comply with NYS/DEC Regulations
Sections 598.6 to 598.10. TRANSFER AND UNLOADING - These operations should comply
with NYS/DEC Regulations, Section 598.4. See also other sections of this MSDS.
CALIFORNIA PROPOSITION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986)
This product contains the following chemical(s) known to the State of California to cause
cancer:
Component CAS # Amount
Acetaldehyde 75-07-0 <= 0.0010%
CALIFORNIA SCAQMD RULE 443.1 (SOUTH COAST AIR QUALITY MANAGEMENT DISTRICT RULE 443.1,
LABELING OF MATERIALS CONTAINING ORGANIC SOLVENTS)
VOC: Vapor pressure 45.2 mmHg @ 20癈
795 g/l
This section provides selected regulatory information on this product including its components.
This is not intended to include all regulations. It is the responsibility of the user to know and
comply with all applicable rules, regulations and laws relating to the product being used.
16. OTHER INFORMATION
16.1 AVAILABLE LITERATURE AND BROCHURES
ADDITIONAL INFORMATION: There may be additional product safety information on this
product, which may be obtained by calling your Union Carbide Corporation Sales or Customer
Service Contact.
MATERIAL SAFETY DATA SHEET
Product Name: ETHANOL, SDA-35A 200 PROOF Effective Date: 07/26/2000
SPECIALLY DENATURED ALCOHOL
MSDS#: 1000 Page 14 of 14
16.2 SPECIFIC HAZARD RATING SYSTEM
Additional information on this product may be obtained by calling the Union Carbide Corporation
Customer Service Center at 1-800-568-4000.
16.3 RECOMMENDED USES AND RESTRICTIONS
FOR INDUSTRY USE ONLY
16.4 REVISION
Version: 2.
Revision: 07/26/2000
Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this
document.
16.5 LEGEND
A Asphyxiant
Bacterial/NA Non Acclimated Bacteria
F Fire
H Health
HMIS Hazardous Materials Information System
N/A Not available
NFPA National Fire Protection Association
O Oxidizer
P Peroxide Former
R Reactivity
TS Trade Secret
VOL/VOL Volume/Volume
W Water Reactive
W/W Weight/Weight
The opinions expressed herein are those of qualified experts within Union Carbide. We believe
that the information contained herein is current as of the date of this Material Safety Data Sheet.
Since the use of this information and the conditions of the use of the product are not under the
control of Union Carbide, it is the user's obligation to determine conditions of safe use of the
product.
|