Material Safety Data Sheet
Product: 20312 KIWOBOND 930st
Date: 4/8/2003 Revision date: 7/10/2007
1. IDENTIFICATION OF PRODUCT AND COMPANY
Product Code: 20312
Product Name: KIWOBOND 930st
Company: KISSEL + WOLF GmbH
In den Ziegelwiesen 6
D-69168 Wiesloch
Importer: KIWO, Inc.
1929 Marvin Circle
Seabrook, TX 77586 USA
Phone: 281-474-9777
Emergency Contact: 1-800-255-3924 (Chemtel)
Supplier: Screentec Corporation
930 West Port Crescent
Mississauga, ONT
L5T 1G1, Canada
Phone: (905) 670-7042
Fax: (905) 670-7046
MSDS prepared by: Fred Widman
Recommended use: Adhesive
2. HAZARD IDENTIFICATION OF THE PREPARATION
Potential Health Effects Eyes
This product may be irritating to the eyes.
Potential Health Effects: Skin
Repeated exposure may cause skin dryness or cracking
Some absorption expected
Potential Health Effects: Ingestion
Ingestion of this product may be irritating to the digestive system.
Potential Health Effects: Inhalation
Inhalation of this product may be irritating to the respiratory system.
Vapours may cause drowsiness and dizziness
F Highly flammable
Xi Irritant
11 Highly flammable
36 Irritating to eyes
66 Repeated exposure may cause skin dryness or cracking
67 Vapors may cause drowsiness and dizziness
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of information
required by the CPR, and it is classified as a Code B2, D2B hazardous material.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Mixture of the below mentioned materials and non-hazardous substances
Hazardous components:
EINECS-No Name Hazard %content
CAS-No. R-phrases
205-500-4 Ethyl Acetate Xi, F 60.0 -100%
141-78-6 11-36-66-67
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Material Safety Data Sheet
Product: 20312 KIWOBOND 930st
Date: 4/8/2003 Revision date: 7/10/2007
200-662-2 Acetone
67-64-1 11-36-66-67 Xi, F 10.0 -30.0%
224-588-5 Trimethoxysilane
4420-74-0 Mercaptopropyl- Xn, N 0.5 -1.5%
21/22-51/53
Additional information:
For full text of risk phrases see Section 16.
4. FIRST AID MEASURES
After skin contact, clean thoroughly with soap and water.
After eye contact, (remove contact lenses) keep eyelid open, rinse under
running water for at least 10 minutes. If irritation continues seek medical advice.
After ingestion, do not induce vomiting. Seek medical advice. If unconscious, do not
administer anything orally. Place in stable side position and seek medical advice. If
breathing is irregular or has stopped, apply artificial respiration.
5. FIRE-FIGHTING MEASURES
Flammable: yes Means of extinction: foam, dry powder, carbon dioxide
Unsuitable extinguishing media: Hard water stream
Flash point: -11癈 Upper flammable limit: 13.0%
Explosion data impact: Not known Lower flammable limit: 2.1%
Explosion data static: above flashpoint yes
Hazardous combustion products: typical carbon oxygen compounds. Fire fighters
should wear SCBA for fighting fires in enclosed areas.
Autoignition temp: 460癈
6. ACCIDENTAL RELEASE MEASURES
Do not empty into drains. Keep away sources of ignition. Ensure
sufficient ventilation. Prevent unauthorized access. Collect with
liquid absorbing material and proceed according to local waste
disposal regulations.
7. HANDLING AND STORAGE
Keep container tightly closed and in a cool and well ventilated
place. Ensure adequate ventilation, especially when using a
spray-gun. Avoid contact with skin and eyes. Avoid flammable /
explosive air / vapor-mixtures and prevent concentrations exceeding
the exposure limits.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Occupational exposure limit:
CAS # Name CANADA STEL CANADA TWA
141-78-6 Ethyl Acetate 500 ppm 400 ppm
67-64-1 Acetone 1000 ppm 750 ppm
Engineering controls
General- not required
Local exhaust- recommended
Other- none
Personal Protection
Gloves- solvent impermeable recommended
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Material Safety Data Sheet
Product: 20312 KIWOBOND 930st
Date: 4/8/2003 Revision date: 7/10/2007
Respirator- yes if local or general exhaust is not used
Eye- protective goggles recommended
Protective footwear- not required
Protective clothing- not required
Other- none
9. PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Colour: Depending on coloration
Odour: Typical
Flash point: -11?C
Ignition temperature: 460癈
0.94 g/cm3
Density:
Viscosity: 900 mPas
Explosion limits: 2.1-13.0 Vol %
Boiling point: 56?C
Vapour density: >1(air=1)
Vapour pressure: 400 mm Hg @ 39.5癈
Freezing point: not known, gels below 0癈
pH: not applicable
Coefficient of water/ oil distribution: not known
10. STABILITY AND REACTIVITY
Stable under recommended storage and handling conditions
(see Section 7).
Store as a flammable liquid
INCOMPATABILITY: Strong oxidizers
11. TOXICOLOGICAL INFORMATION
Effects of acute exposure:
COMPONENT CAS# LD50 LC50
Ethyl Acetate 141-78-6 5620 mg/kg oral, rat 1600 ppm inhalation 8 hour, rat
50, 100 mg/m3 inhalation, rat
Acetone 67-64-1 5800 mg/kg, oral, rat
Trimethoxysilane 4420-74-0 730祃/kg, oral, rat Unknown
Mercaptopropyl- 2140祃/kg, skin, rabbit
General information:
Effects of acute exposure:
Repeated or prolonged contact causes local irritation of skin and
mucous membranes, particularly the eyes. Inhalation of high
concentrations may cause nausea, dizziness, narcotic effect.
Irritancy of product- yes
Skin sensitization- no
Respiratory sensitization- none known
Carcinogenicity- no
IARC- no
ACGIA- no
Reproductive toxicity-none known
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Material Safety Data Sheet
Product: 20312 KIWOBOND 930st
Date: 4/8/2003 Revision date: 7/10/2007
Teratogenicity- None known
Embryotoxicity- none known
Mutagenicity- None known
Name of synergistic products/effects- none known
12. ECOLOGICAL INFORMATION
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Do not empty into drains or release into open water.
Do not store at public waste disposal sites.
13. WASTE DISPOSAL INFORMATION
Dispose of as a flammable hazardous waste
Empty container: scrap metal recycling or re-conditioning
Soiled container: (treatment like product itself)
14. TRANSPORT INFORMATION
ADR/RID/DOT: Class: 3
UN: 1133
Adhesives, containing flammable liquid
(not viscous)
(vapor pressure 110kPa maximum @ 50癈)
Packaging group: III
IMDG: Class: 3
EMS: F-E, S-D
UN: 1133
Adhesives, containing flammable liquid
Marine pollutant: No
Packaging group: III
15. REGULATORY INFORMATION
All ingredients are listed on the TSCA registry.
Labeling
F Flammable liquid
R-phrases:
11 Highly flammable
36 Irritating to eyes
66 Repeated exposure may cause skin dryness or cracking
67 Vapors may cause drowsiness and dizziness
S-phrases:
7/9 Keep container tightly closed and in a well-ventilated place
16 Keep away from sources of ignition ?No smoking
24 Avoid contact with skin
26 In case of contact with eyes, rinse immediately with plenty of water
and seek medical attention
Special labeling:
n.a
National Regulation for Germany:
Water pollution class: 2
4
Material Safety Data Sheet
Product: 20312 KIWOBOND 930st
Date: 4/8/2003 Revision date: 7/10/2007
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of information
required by the CPR, and it is classified as a Code B2, D2B hazardous material.
--Canada--
Ingredient TSCA EC DSL NDSL
Ethyl Acetate (141-78-6) Yes Yes Yes No
Acetone (67-64-1) Yes Yes Yes No
Trimethoxysilane, Mercaptopropanol- Yes Yes Yes No
-SARA 302- SARA 313 -RCRA- CERCLA - TSCA
Ingredient RQ TPQ List RQ 261.33 8(d)
Ethyl Acetate No No No U112 5,000 No
Acetone No No No U002 5,000 No
Trimethoxysilane
Mercaptopropyl, No No No No No No
VOC'S = 647 GRAMS / LITER, 5.40 LBS / GALLON
16. OTHER INFORMATION
HMIS: Health 2, Flammability 2, Reactivity 0
Text of risk phrases mentioned in Section 2:
11 Highly flammable
36 Irritating to eyes
66 Repeated exposure may cause skin dryness or cracking
67 Vapors may cause drowsiness and dizziness
21/22 Harmful in contact with skin and if swallowed
51/53 Toxic to aquatic organisms, may cause long term adverse effects in the
aquatic environment
For further information please refer to our technical information
sheet. Data in this MSDS correspond with our current level of
knowledge, but do not represent any assurance of product proper-
ties. The user personally is responsible for compliance with all
legal requirements.
DISCLAIMER OF RESPONSIBILITY:
This document is generated for the purpose of distributing health, safety and environmental
data. It is not a specification sheet nor should any displayed data be construed as a
specification. The information on this MSDS was obtained from sources which we believe
are reliable. However, the information is provided without any warranty, expressed or
implied, regarding its correctness. Some information presented and conclusions drawn
herein are from sources other than direct test data on the substance itself. The conditions
or methods of handling, storage, use and disposal of the product are beyond our control and
may be beyond our knowledge. For this and other reasons, we do not assume responsibility
and expressly disclaim liability for loss, damage or expense arising out of or in any way
connected with handling, storage, use or disposal of this product.
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