MSDS Name: DEVCON?Flexane?Brushable
Manufacturer Name: ITW Devcon
Stock No.: 15350
Components:
FLEXANE BRUSHABLE CURING AGENT
FLEXANE BRUSHABLE RESIN
ITW Performance Polymers (Finished Goods) Product Code : 15350
View Section :
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: FLEXANE BRUSHABLE CURING AGENT
HMIS
Manufacturer Name: ITW Devcon
Address: 30 Endicott Street
Danvers, MA 01923
Health Hazard 2*
MSDS Revision Date: 10/10/2006
Fire Hazard 2
Emergency telephone number (800) 424-9300
REACTIVITY 0
Personal
x
Protection
DISTRIBUTED BY FREEMAN MFG & SUPPLY CO.
* Chronic Health
800-321-8511 www.freemansupply.com
Effects:
In the US, call CHEMTREC: (800) 424-9300
To Top of page
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS#
1-methoxy-2-propanol acetate 108-65-6 60 - 100 by Weight
Epoxidized soybean oil 8013-07-8 1 - 5 by Weight
Diethyltoluenediamine 68479-98-1 10 - 30 by Weight
Carbon black 1333-86-4 1 - 5 by Weight
To Top of page
SECTION 3: HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Flammable. Harmful. Potential Sensitizer. Irritant.
Primary Routes of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye Contact: Can cause severe eye irritation and burns. Eye contact may cause permanent
damage or blindness.
Skin Contact: Causes severe skin irritation. May cause permanent skin damage. Allergic
reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on
reexposure to this material.
Inhalation: Vapor or mist may cause severe respiratory system irritation. May cause
respiratory sensitization with asthma-like symptoms in susceptible individuals.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal
tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening,
swelling, and possible tissue destruction
Signs/Symptoms: Overexposure may cause eye watering or discomfort, redness and swelling.
Target Organs: Eyes. Skin. Respiratory system. Digestive system.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
To Top of page
SECTION 4: FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure
adequate flushing of the eyes by separating the eyelids with fingers. Get
immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while
removing contaminated clothing and shoes. Get medical attention if irritation
develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.
Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested.
Provide a glass of water to dilute the material in the stomach. If vomiting occurs
naturally, have the person lean forward to reduce the risk of aspiration.
To Top of page
SECTION 5: FIRE FIGHTING MEASURES
Auto Ignition Temp : Not determined.
Flash Point: 114癋 (45.5癈) (PGMEA)
Flash Point Method: Setaflash
Lower Explosive Limit (LEL) Not determined.
Upper Explosive Limit (UEL) Not determined.
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire space
without full protective gear. If possible, contain fire run-off water.
Unsuitable Media: Water or foam may cause frothing.
To Top of page
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering
the spill area.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical
waste container. Provide ventilation. Collect spill with a non-sparking tool. Place
into a suitable container for disposal. Clean up spills immediately observing
precautions in the protective equipment section. After removal, flush spill area
with soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture with
air. Vapors can flow along surfaces to distant ignition sources and flash back.
Ventilate area. Use proper personal protective equipment as listed in section 8.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Other Precautions: Pump or shovel to storage/salvage vessels.
To Top of page
SECTION 7: HANDLING AND STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Material
will accumulate static charges which may cause an electrical spark (ignition
source). Use proper grounding procedures. Do not reuse containers without
proper cleaning or reconditioning.
Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible
materials, direct sunlight, and incompatible substances. Keep container tightly
closed when not in use. Do not store in reactive metal containers. Keep away
from acids, oxidizers.
Hygiene Practices: Wash thoroughly after handling.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to protect
against dust during sanding/grinding of cured product. Hazardous liquid or vapor
residue may remain in emptied container. Do not reuse, heat, burn, pressurize,
cut, weld, braze, solder, drill, grind, expose to sparks, flame, or ignition sources
of empty containers without proper commercial cleaning or reconditioning.
To Top of page
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA or
other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin
contact. Consult manufacturer's data for permeability data.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash
and a deluge shower safety station.
Carbon black:
Guideline ACGIH : ACGIH TLV-TWA 3.5 mg/m3
Notes : Only established PEL and TLV values for the ingredients are listed below.
To Top of page
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State/Appearance: Liquid.
Color: Black, Viscous
Odor: pungent
Boiling Point: >300癋 (148.8癈)
Melting / Freezing Point : Not determined.
Solubility: appreciable
Specific Gravity: 1.06
pH: Approximately 7 @ 5 Percent Solution
Vapor Density: > 1 (air = 1)
Vapor Pressure: 4.9 mbar
Molecular Formula: Mixture
Molecular Weight: Mixture
Percent Volatile: Not determined.
VOC Data : 679
Percent Solids by Weight 36
To Top of page
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions.
Incompatibilities with Other Oxidizers, acids, and chlorinated organic compounds. Reactive metals (e.g.
Materials: sodium, calcium, zinc). Sodium/calcium hypochlorite. Nitrous acid/ oxide,
nitrites. Peroxides. Materials reactive with hydroxyl compounds.
Hazardous Polymerization: Not reported.
To Top of page
SECTION 11: TOXICOLOGICAL INFORMATION
1-methoxy-2-propanol acetate:
Skin Effects: Skin - Rat LD50: >5 gm/kg - [Details of toxic effects not reported other than
lethal dose value ](RTECS)
Ingestion Effects: Oral - Rat LD50: 8532 mg/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
Epoxidized soybean oil:
Skin Effects: Skin - Rat Open irritation test -: 500 mg - [mild](RTECS)
Skin - Rat LD50: >20 mL/kg - [Details of toxic effects not reported other than
lethal dose value](RTECS)
Ingestion Effects: Oral - Rat LD50: 22500 uL/kg - [Details of toxic effects not reported other than
lethal dose value] (RTECS)
Diethyltoluenediamine:
Ingestion Effects: Oral - Rat LD50: 472 mg/kg - [Sense Organs and Special Senses (Eye) -
lacrimation oral - somnolence (general depressed activity) Musculoskeletal -
other changes] (RTECS)
Carbon black:
Skin Effects: Skin - Rat LD50: >3 gm/kg - [Details of toxic effects not reported other than
lethal dose value ](RTECS)
Inhalation Effects: Inhalation - Rat TCLo - Lowest published toxic concentration: 7 mg/m3 - [Lungs,
Thorax, or Respiration - other changes Biochemical - Metabolism (Intermediary)
- effect on inflammation or mediation of inflammation ] (RTECS)
Ingestion Effects: Oral - Rat LD50: >15400 mg/kg - [oral - somnolence (general depressed
activity) ] (RTECS)
Carcinogenicity: IARC: Group 2B: Possibly carcinogenic to humans
To Top of page
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
To Top of page
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number : D001
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal con
To Top of page
SECTION 14: TRANSPORT INFORMATION
DOT Shipping Name: Coating solution
DOT UN Number: 1139
DOT Hazard Class: 3
DOT Packing Group: III
DOT Exemption ORM-D Small quantity exemption
To Top of page
SECTION 15: REGULATORY INFORMATION
1-methoxy-2-propanol acetate:
TSCA Inventory Status Listed
EC Num : 607-195-00-7
Carbon black:
TSCA Inventory Status Listed
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
Canadian Regulations. WHMIS Hazard Class(es): D2B;B3;D2A
All components of this product are on the Canadian Domestic Substances List.
To Top of page
SECTION 16: ADDITIONAL INFORMATION
HMIS Health Hazard: 2*
HMIS Fire Hazard: 2
HMIS Reactivity: 0
HMIS Personal Protection: x
MSDS Revision Date: 10/10/2006
Disclaimer: "This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. The information given in the
Data Sheet is designed only as a guidance for safe handling, storage and the use
of the substance. It is not a specification nor does it guarantee any specific
properties. All chemicals should be handled only by competent personnel, within
a controlled environment."
Copyright?1996-2007 Actio Software Corporation. All Rights Reserved.
View Section :
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
Product Name: FLEXANE BRUSHABLE RESIN
HMIS
Manufacturer Name: ITW Devcon
Address: 30 Endicott Street
Danvers, MA 01923
Health Hazard 3*
MSDS Revision Date: 10/10/2006
Fire Hazard 3
Emergency telephone number (800) 424-9300
REACTIVITY 1
Personal
x
Protection
* Chronic Health
Effects:
In the US, call CHEMTREC: (800) 424-9300
To Top of page
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS#
Proprietary N/A 60 - 100 by Weight
Ethyl acetate 141-78-6 10 - 30 by Weight
Isophorone diisocyanate 4098-71-9 1 - 5 by Weight
2,6-Di-tertiary-butyl-para-cresol 128-37-0 1 - 5 by Weight
4,4'-Diphenylmethane diisocyanate 101-68-8 1 - 5 by Weight
Cyclohexanone 108-94-1 1 - 5 by Weight
Dicyclohexylmethane-4,4'-diisocyanate 5124-30-1 1 - 5 by Weight
To Top of page
SECTION 3: HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Flammable. Potential Sensitizer. Irritant.
Primary Routes of Exposure: Eyes. Skin. Inhalation. Ingestion.
Potential Health Effects:
Eye Contact: Can cause moderate irritation, burning sensation, tearing, redness, and swelling.
Overexposure may cause lacrimation, conjunctivitis, corneal damage and
permanent injury..
Skin Contact: Can cause skin irritation; itching, redness, rashes, hives, burning, and swelling.
Allergic reactions are possible.
May cause skin sensitization, an allergic reaction, which becomes evident on
reexposure to this material.
Inhalation: Respiratory tract irritant. High concentration may cause dizziness, headache, and
anesthetic effects. May cause respiratory sensitization with asthma-like
symptoms in susceptible individuals.
Ingestion: Causes irritation, a burning sensation of the mouth, throat and gastrointestinal
tract and abdominal pain.
Chronic Health Effects: Prolonged skin contact may lead to burning associated with severe reddening,
swelling, and possible tissue destruction
Signs/Symptoms: Overexposure can cause headaches, dizziness, nausea, and vomiting.
Target Organs: Eyes. Skin. Respiratory system. Digestive system. Kidney. Liver. Central nervous
system.
Aggravation of Pre-Existing Individuals with pre-existing skin disorders, asthma, allergies or known
Conditions: sensitization may be more susceptible to the effects of this product.
Isocyanate exposure levels must be monitored. Medical supervision of all
employees who handle or come in contact with isocyanates is recommended (i.e.
FEV, FVC). This should include pre-employment and periodic medical
examinations.
Persons with asthmatic-type conditions, chronic bronchitis, other chronic
respiratory diseases, recurrent skin eczema or sensitization should be excluded
from working with this product. Once sensitized no further exposure can be
permitted.
To Top of page
SECTION 4: FIRST AID MEASURES
Eye Contact: Immediately flush eyes with plenty of water for at least 15 to 20 minutes. Ensure
adequate flushing of the eyes by separating the eyelids with fingers. Get
immediate medical attention.
Skin Contact: Immediately wash skin with plenty of soap and water for 15 to 20 minutes, while
removing contaminated clothing and shoes. Get medical attention if irritation
develops or persists.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration or give
oxygen by trained personnel. Seek immediate medical attention.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.
Other First Aid: Due to possible aspiration into the lungs, DO NOT induce vomiting if ingested.
Provide a glass of water to dilute the material in the stomach. If vomiting occurs
naturally, have the person lean forward to reduce the risk of aspiration.
Note to Physicians: Asthmatic type symptoms may develop, which may be immediate or delayed for
several hours.
To Top of page
SECTION 5: FIRE FIGHTING MEASURES
Flammable Properties : Flammable.
Flammable liquid Class I B.
Auto Ignition Temp : Not determined.
Flash Point: 24癋 (-4.4癈)
Flash Point Method: Tag Closed Cup (TCC)
Lower Explosive Limit (LEL) 2%
Upper Explosive Limit (UEL) 11%
Extinguishing Media: Use carbon dioxide (CO2) or dry chemical when fighting fires involving this
material.
Protective Equipment: As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHA/NIOSH (approved or equivalent) and full protective gear.
Fire Fighting Instructions: Evacuate area of unprotected personnel. Use cold water spray to cool fire
exposed containers to minimize risk of rupture. Do not enter confined fire space
without full protective gear. If possible, contain fire run-off water.
Unsuitable Media: Water may cause frothing.
To Top of page
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions: Evacuate area and keep unnecessary and unprotected personnel from entering
the spill area.
Spill Cleanup Measures: Absorb spill with inert material (e,g., dry sand or earth), then place in a chemical
waste container. Provide ventilation. Collect spill with a non-sparking tool. Place
into a suitable container for disposal. Clean up spills immediately observing
precautions in the protective equipment section. Neutralize residue with
appropriate neutralizer. Do not attempt to neutralize large quantities of material
unless measures to control reactivity and heat generation have been taken.
Absorb spill with inert material (e.g.., dry sand or earth), then place in a
chemical waste container. Provide ventilation. After removal, flush spill area with
soap and water to remove trace residue.
Flammable, eliminate ignition sources. Vapors can form an ignitable mixture with
air. Vapors can flow along surfaces to distant ignition sources and flash back.
Ventilate area. Use proper personal protective equipment as listed in section 8.
A blanket of protein foam may be placed over spill for temporary control of
isocyanate vapor.
Environmental Precautions: Avoid runoff into storm sewers, ditches, and waterways.
Other Precautions: Pump large quantities into closed but not sealed metal containers. Isocyanates
will react with water and generate carbon dioxide, this could result in the rupture
of any closed containers.
Neutralize using 10 parts neutralizer to 1 part isocyanate solution. Mix and allow
to stand for 48 hrs in containers, letting evolved carbon dioxide to vent.
Neutralizer consist of 90% water, 3-8% concentrated ammonia (or sodium
carbonate), 2% detergent.
To Top of page
SECTION 7: HANDLING AND STORAGE
Handling: Use with adequate ventilation. Avoid breathing vapor, aerosol or mist. Material
will accumulate static charges which may cause an electrical spark (ignition
source). Use proper grounding procedures. Do not reuse containers without
proper cleaning or reconditioning.
Storage: Store in a cool, dry, well ventilated area away from sources of heat, combustible
materials, direct sunlight, and incompatible substances. Keep container tightly
closed when not in use. Do not reseal container If moisture or water
contamination is suspected. Water contaminated material in a sealed container
may rupture due to pressure buildup.
Hygiene Practices: Wash thoroughly after handling.
Special Handling Procedures: Provide appropriate ventilation/respiratory protection against decomposition
products (see Section 10) during welding/flame cutting operations and to protect
against dust during sanding/grinding of cured product. Hazardous liquid or vapor
residue may remain in emptied container. Do not reuse, heat, burn, pressurize,
cut, weld, braze, solder, drill, grind, expose to sparks, flame, or ignition sources
of empty containers without proper commercial cleaning or reconditioning.
To Top of page
SECTION 8: EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls: Use appropriate engineering control such as process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below
recommended exposure limits. Good general ventilation should be sufficient to
control airborne levels. Where such systems are not effective wear suitable
personal protective equipment, which performs satisfactorily and meets OSHA or
other recognized standards. Consult with local procedures for selection, training,
inspection and maintenance of the personal protective equipment.
Skin Protection Description: Wear appropriate protective gloves and other protective apparel to prevent skin
contact. Consult manufacturer's data for permeability data.
Eye/Face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR
1910.133, OSHA eye and face protection regulation, or the European standard
EN 166.
Respiratory Protection: A NIOSH approved air-purifying respirator with an organic vapor cartridge or
canister may be permissible under certain circumstances where airborne
concentrations are expected to exceed exposure limits. Protection provided by
air purifying respirators is limited. Use a positive pressure air supplied respirator
if there is any potential for an uncontrolled release, exposure levels are not
known, or any other circumstances where air purifying respirators may not
provide adequate protection.
Other Protective: Facilities storing or utilizing this material should be equipped with an eyewash
and a deluge shower safety station.
Ethyl acetate:
Guideline ACGIH : ACGIH TLV-TWA 400 ppm
Guideline OSHA : OSHA PEL-TWA 400 ppm
Isophorone diisocyanate:
Guideline ACGIH : ACGIH TLV-TWA 0.005 ppm
2,6-Di-tertiary-butyl-para-cresol:
Guideline ACGIH : ACGIH TLV-TWA 2 mg/m3
4,4'-Diphenylmethane diisocyanate:
Guideline ACGIH : ACGIH TLV-TWA 0.005 ppm
Guideline OSHA : OSHA PEL-STEL 0.02 ppm Ceiling/Peak
Cyclohexanone:
Guideline ACGIH : ACGIH TLV-STEL 50 ppm
Guideline OSHA : OSHA PEL-TWA 50 ppm
Dicyclohexylmethane-4,4'-diisocyanate:
Guideline ACGIH : ACGIH TLV-TWA 0.005 ppm
Notes : Only established PEL and TLV values for the ingredients are listed below.
To Top of page
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Physical State/Appearance: Liquid.
Color: Clear.
Odor: Strong solvent.
Boiling Point: 172癋 (77.7癈) solvent boils
Melting / Freezing Point : Not determined.
Solubility: Negligible reacts.
Specific Gravity: 0.902
pH: 7 @ 5 Percent Solution
Vapor Density: 3 (air = 1)
Vapor Pressure: 86 mmHg @68癋
Molecular Formula: Mixture
Molecular Weight: Mixture
Percent Volatile: 21
VOC Data : 190 g/L
Percent Solids by Weight 79
To Top of page
SECTION 10: STABILITY AND REACTIVITY
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Extreme heat, sparks, and open flame. Incompatible materials, oxidizers and
oxidizing conditions. Moisture and extended exposure over 85 F.
Incompatibilities with Other Alcohols, amines, strong bases (alkali, ammonia), acids, metal compounds,
Materials: moisture or water. Resin reacts with water to give off carbon dioxide.
Hazardous Polymerization: Polymerization may occur under certain conditions.
To Top of page
SECTION 11: TOXICOLOGICAL INFORMATION
Ethyl acetate:
Eye Effect: Eye - Human Standard Draize Test : 400 ppm(RTECS)
Skin Effects: Skin - Rat LD50: >20 mL/kg - [Details of toxic effects not reported other than
lethal dose value ](RTECS)
Inhalation Effects: Inhalation - Rat LC50: 200 gm/m3 - [Behavioral - somnolence (general
depressed activity) Lungs, Thorax, or Respiration - acute pulmonary edema
Gastrointestinal - changes in structure or function of salivary glands ] (RTECS)
Inhalation - Mouse LC50: 45 gm/m3/2H - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Ingestion Effects: Oral - Rat LD50: 5620 mg/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
Oral - Mouse LD50: 4100 mg/kg - [oral - somnolence (general depressed
activity) oral - changes in motor activity (specific assay) oral - coma ] (RTECS)
Isophorone diisocyanate:
Skin Effects: Skin - Rat LDLo: 1 mL/kg - [Details of toxic effects not reported other than lethal
dose value ](RTECS)
Inhalation Effects: Inhalation - Rat LC50: 123 mg/m3/4H - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Ingestion Effects: Oral - Rat LD50: 4825 mg/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
2,6-Di-tertiary-butyl-para-cresol:
Eye Effect: Eye - Rabbit Standard Draize Test : 100 mg/24H - [Moderate](RTECS)
Skin Effects: Skin - Rat Standard Draize Test : 500 mg/48H - [Moderate](RTECS)
Ingestion Effects: Oral - Rat LD50: 890 mg/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
Oral - Mouse LD50: 650 mg/kg - [oral - tremor Lungs, Thorax, or rat - chronic
pulmonary edema ] (RTECS)
Oral - Mouse LD50: 1040 mg/kg - [Details of toxic effects not reported other
than lethal dose value ] (RTECS)
Oral - Mouse LD50: 650 mg/kg - [oral - tremor oral - ataxia Lungs, Thorax, or
rat - other changes ] (RTECS)
4,4'-Diphenylmethane diisocyanate:
Eye Effect: Eye - Rabbit Standard Draize Test : 100 mg - [Moderate ](RTECS)
Skin Effects: Skin - Rat Standard Draize Test : 500 mg/24H(RTECS)
Inhalation Effects: Inhalation - Rat LC50: 178 mg/m3 - [Details of toxic effects not reported other
than lethal dose value] (RTECS)
Ingestion Effects: Oral - Rat LD50: 9200 mg/kg - [oral - somnolence (general depressed activity)
oral - ataxia Nutritional and Gross Metabolic - body rat decrease ] (RTECS)
Oral - Mouse LD50: 2200 mg/kg - [Details of toxic effects not reported other
than lethal dose value ] (RTECS)
Cyclohexanone:
Eye Effect: Eye - Human Standard Draize Test : 75 ppm(RTECS)
Skin Effects: Skin - Rat Open irritation test: 500 mg - [mild ](RTECS)
Skin - Rat LD50: 1 mL/kg - [Details of toxic effects not reported other than lethal
dose value ](RTECS)
Inhalation Effects: Inhalation - Rat LC50: 19000 mg/m3 - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Inhalation - Mouse LC50: 2375 mg/m3 - [Details of toxic effects not reported
other than lethal dose value] (RTECS)
Ingestion Effects: Oral - Rat LD50: 1800 mg/kg - [Details of toxic effects not reported other than
lethal dose value ] (RTECS)
Oral - Mouse LD50: 1400 mg/kg - [Details of toxic effects not reported other
than lethal dose value ] (RTECS)
Dicyclohexylmethane-4,4'-diisocyanate:
Eye Effect: Eye - Rabbit Standard Draize Test : 100 uL/24H - [severe ](RTECS)
Skin Effects: Skin - Rat Standard Draize Test : 500 uL/24H - [Moderate](RTECS)
Skin - Rat LD - Lethal dose: >10 gm/kg - [Behavioral - somnolence (general
depressed activity) Behavioral - food intake (animal) Behavioral - muscle
weakness ](RTECS)
Inhalation Effects: Inhalation - Guinea pig LC50: 51 mg/m3/1H - [Behavioral - somnolence (general
depressed activity) Lungs, Thorax, or Respiration - cyanosis Lungs, Thorax, or
Respiration - other changes ] (RTECS)
Ingestion Effects: Oral - Rat LD50: 9900 mg/kg - [oral - food intake (animal) Gastrointestinal -
hypermotility, diarrhea Liver - other changes ] (RTECS)
To Top of page
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity: No ecotoxicity data was found for the product.
Environmental Fate: No environmental information found for this product.
To Top of page
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal: Consult with the US EPA Guidelines listed in 40 CFR Part 261.3 for the
classifications of hazardous waste prior to disposal. Furthermore, consult with
your state and local waste requirements or guidelines, if applicable, to ensure
compliance. Arrange disposal in accordance to the EPA and/or state and local
guidelines.
RCRA Number : D001
Important Disposal Information: DANGER! Rags, steel wool and waste soaked with this product may
spontaneously catch fire if improperly discarded or stored. To avoid a
spontaneous combustion fire, immediately after use, place rags, steel wool or
waste in a sealed, water-filled, metal con
To Top of page
SECTION 14: TRANSPORT INFORMATION
DOT Shipping Name: Coating solution
DOT UN Number: 1139
DOT Hazard Class: 3
DOT Packing Group: II
DOT Exemption ORM-D Small quantity exemption
To Top of page
SECTION 15: REGULATORY INFORMATION
Ethyl acetate:
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 607-022-00-5
Isophorone diisocyanate:
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 615-008-00-5
2,6-Di-tertiary-butyl-para-cresol:
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
4,4'-Diphenylmethane diisocyanate:
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 615-005-00-9
Cyclohexanone:
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 606-010-00-7
Dicyclohexylmethane-4,4'-diisocyanate:
State: Listed in the State of Massachusetts Hazardous Substance List.
Listed in the New Jersey State Right to Know List.
Listed in the Pennsylvania State Hazardous Substances List.
EC Num : 615-009-00-0
Canadian Regulations. WHMIS Hazard Class(es): B2; D2B; D2A
All components of this product are on the Canadian Domestic Substances List.
To Top of page
SECTION 16: ADDITIONAL INFORMATION
HMIS Health Hazard: 3*
HMIS Fire Hazard: 3
HMIS Reactivity: 1
HMIS Personal Protection: x
MSDS Revision Date: 10/10/2006
Disclaimer: "This Health and Safety Information is correct to the best of our knowledge and
belief at the date of its publication but we cannot accept liability for any loss,
injury or damage which may result from its use. The information given in the
Data Sheet is designed only as a guidance for safe handling, storage and the use
of the substance. It is not a specification nor does it guarantee any specific
properties. All chemicals should be handled only by competent personnel, within
a controlled environment."
Copyright?1996-2007 Actio Software Corporation. All Rights Reserved.
|