HENKEL CONSUMER ADHESIVES 02/05/02
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 01 of 05
00-20273
00-20273
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MSDS No.: 00-20273
Product Type: Bondfast Rubber Cement
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Hydrotreated heavy naphtha 64742-48-9 60-80
CYCLOHEXANE* 110-82-7 10-20
n-HEXANE* 110-54-3 5-10
Natural Rubber Proprietary 5-10
Hydrocarbon Resin Proprietary 1-5
Antioxidant 6683-19-8 0.1-1.0
METHYL ETHYL KETONE* 78-93-3 <0.001
ETHYL ACETATE 141-78-6 <0.001
* This component is listed as a SARA Section 313 Toxic Chemical.
All components of this product are included on the USEPA TSCA
inventory and the Canadian DSL
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Hydrotreated heavy naphtha None None 300 ppm
CYCLOHEXANE 300 ppm TWA 300 ppm TWA None
1030mg/M3 1050mg/M3
n-HEXANE 50 ppmTWA(skin) 500 ppm TWA None
1800 mg/M3
METHYL ETHYL KETONE 200 ppm TWA 200 ppm TWA None
590 mg/m3 590 mg/m3
ETHYL ACETATE 400 ppm TWA 400 ppm TWA None
1440 mg/M3 1400 mg/M3
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
METHYL ETHYL KETONE 300 ppm 300 ppm
885 mg/m3 885 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity: Brain and nervous system damage. Drying or
cracking skin.
Primary Routes of Entry: Inhalation, ingestion, eye and skin contact.
HENKEL CONSUMER ADHESIVES 02/05/02
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 02 of 05
MSDS No.: 00-20273
3. HAZARDS IDENTIFICATION (continued)
Signs and Symptoms
of Exposure: Headache, dizziness, fatigue,drowsiness, irregular
heartbeat, skin and eye irritation.
Existing Conditions
Aggravated by Exposure: Liver, skin, respiratory,and central
nervous system diseases, and alcoholism.
Heart, kidney, and lung disorders.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Hydrotreated heavy naphtha NTO NO NO NO
CYCLOHEXANE CNS IRR NO NO NO
n-HEXANE DEV IRR LUN NER REP NO NO NO
Natural Rubber No Data NO NO NO
Hydrocarbon Resin No Data NO NO NO
Antioxidant NTO NO NO NO
METHYL ETHYL KETONE CNS IRR NO N/A NO
ETHYL ACETATE BLO CNS IRR NO NO NO
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Abbreviations
N/A Not Applicable BLO Blood
CNS Central nervous system DEV Developmental
IRR Irritant LUN Lung
NER Nervous System NTO No Target Organs
REP Reproductive
Other possible target organs: Cardiovascular system, kidney, skin,
liver, lung, respiratory system, and central and peripheral nervous
systems.
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention. Administer oxygen or artificial
respiration if necessary.
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
HENKEL CONSUMER ADHESIVES 02/05/02
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 03 of 05
MSDS No.: 00-20273
5. FIRE FIGHTING MEASURES
Flash Point: Less than <0癋 <-18癈 Method: PMCC
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical.
Self contained breathing apparatus with a full face piece operated in
pressure demand or other positive pressure mode should be used when
confronted with large fires.
Special Firefighting
Procedures: Not available
Hazardous Products formed
by Fire or Thermal Decomp Oxides of carbon.
Unusual Fire or
Explosion Hazards: This material is flammable and may be ignited by
heat, sparks, flame or static electricity.
Explosive Limits:
(% by volume in air)Lower 1.0%
(% by volume in air)Upper 10.0%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Remove sources of ignition. Maintain adequate
ventilation. Soak up with an inert absorbent.
Store in a closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 120癋 in closed container.
(Contact Loctite Customer Service 1-800-243-4874 for shelf life information)
Handling: Keep away from eyes. Avoid prolonged breathing of
vapors or prolonged skin contact. Keep away from
sparks, flames, or high heat sources.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Chemical splash goggles.
Skin: Impervious rubber or plastic gloves recommended.
Impervious clothing or boots as needed.
Ventilation: Sufficient to maintain vapor concentration below
TLV.
Respiratory NIOSH/MSHA approved organic vapor cartridge
respirator if indicated.
See Section 2 for Exposure Limits.
HENKEL CONSUMER ADHESIVES 02/05/02
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 04 of 05
MSDS No.: 00-20273
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Translucent, viscous liquid
Odor: Moderate
Boiling Point: 171癋, 77癈
pH: Does not apply
Solubility in Water: Insoluble
Specific Gravity 0.70
Volatile Organic Compound
(EPA Method 24) 89%; 5.2 pounds/gallon.
Vapor Pressure: Not available
Vapor Density: 3
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong acids, bases, oxidizing agents, selected
amines with alkali metals and halogens.
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): Oxides of carbon, formic acid, dimethylamine,
peroxides.
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number D001/D035 - Hazardous waste per 40CFR 261.21 and
a TCLP waste per 261.24/Methyl Ethyl Ketone.
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity (Not more than one liter);
Adhesives, Class 3, UN 1133, PKG Grp II >1 Liter
Hazard Class or
Division: ORM-D (Not more than one liter);
Class 3, Packing Group II (More than one liter)
HENKEL CONSUMER ADHESIVES 02/05/02
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 05 of 05
MSDS No.: 00-20273
14. TRANSPORTATION INFORMATION (continued)
Identification Number: None (Not more than one liter);
UN 1133 (More than one liter)
Marine Pollutant: None
IATA
Proper Shipping Name: Consumer Commodity (Not more than one liter);
Adhesives, Class 3, UN 1133, PKG Grp II >1 Liter
Class or Division: Class 3, Packing Group II
UN or ID Number: UN 1133
15. REGULATORY INFORMATION
CA Proposition 65:
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 3
Reactivity Hazard: 0
Specific Hazard: None
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 3
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
(24hr.) Phone: (440) 937-7000
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