MATERIAL SAFETY DATA SHEET DATE: 02/18/05
Revision #6 Page 1 of 2
Section 1 HAZARD RATING For Chemical Emergency Only:
PACER TECHNOLOGY In the US & Canada (800) 424-9300
9420 Santa Anita Avenue 2 Int'l & Wash DC (COLLECT) (703) 527-3887
Rancho Cucamonga, CA 91730 1x1 Telephone for Information:(909) 987-0550
PRODUCT IDENTIFICATION: Future Glue Gel
Section 2 - HAZARDOUS INGREDIENTS INFORMATION:
Hazardous Components OSHA ACGIH OTHER %
(Common Names, CAS Number) PEL TLV LIMITS OPTION
Ethyl-2-Cyanoacrylate (7085-85-0) NE NE 0.2ppm TWA 60-100
Poly (Methyl Methacrylate) (9011-14-7) NE NE 10-30
Hydroquinone* (123-31-9) 2mg/m3 2mg/m3 0-1
*This ingredient is subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendments & Reauthorization Act of 1986 (SARA) and 40 CFR 372.
Section 3 - PHYSICAL/CHEMICAL CHARACTERISTICS:
Boiling Point: 365 F Specific Gravity (H2O=1): 1.05
Vapor Density (Air=1): nil-NE Melting Point: NE
Vapor Pressure (mm Hg): 1 @ 20 C Evaporation Rate (Butyl acetate=1): nil-NE
Solubility in Water: Insoluble, material reacts to hardened mass for non-hazardous waste.
Appearance & Odor: Transparent water-white to straw colored liquid with stimulative odor.
Section 4 - FIRE AND EXPLOSION HAZARD DATA:
Flash Point (Method Used): 185 F (TCC) Flammable Limits: LEL: NE UEL: NE
Extinguishing Media: Flush with large amounts of water or dry chemical extinguisher.
Special Fire Fighting Procedures: Fumes may be irritating if not burning and require air supply with
goggles while applying large amounts of water or dry chemical extinguisher.
Unusual Fire and Explosion Hazards: None. Combustible requiring the above procedures.
Section 5 - REACTIVITY DATA:
Stability: Stable XX Conditions to Avoid: Excessive heat above 176 F, moisture and alkalines. Stable
up to 122 F. Store in a cool dry place.
Incompatibility (Materials to Avoid): Polymerized by water, alcohol, amines, alkaline materials and
direct UV.
Hazardous Decomposition Products: Combustible by-products of carbon monoxide/dioxide.
Hazardous Polymerization: May Not Occur XX
Section 6 - HEALTH HAZARD DATA:
Route(s) of Entry: Inhalation: Yes Skin: NO Ingestion: LD50 = 12.2cc/kg
Health Hazards (Acute and Chronic): (mice)
Acute - Irritates eyes, mucous membranes.
Chronic - No residual effects of acute properties.
MATERIAL SAFETY DATA SHEET Future Glue Gel Revision #6 Page 2 of 2
Carcinogenicity: NTP: No IARC Monographs: No OSHA Regulated: No
First Aid Procedures:
Eye contact - Tearing from eye irritation. Remove to fresh air. Flush areas of contact with water.
Adhesive will disassociate from eye/eyelids over time, usually within several hours. Temporary
weeping of eyes/double vision may be experienced until clearance is achieved.
Skin contact - Immerse bonded areas in warm, soapy water. Peel or roll skin apart. Remove cured
adhesive with several applications of warm, soapy water. Prolonged or repeated contact at elevated
levels may cause dermatitis in sensitive individuals.
Inhalation - Irritation of mucous membranes/coughing. Remove to fresh air. Prolonged or repeated
exposure at elevated levels may produce allergic reactions with asthma-like symptoms in sensitive
individuals.
Ingestion - Lips may become stuck together: apply copious amounts of warm water & encourage
wetting/pressure from saliva inside mouth. Peel or roll (do not pull) lips apart. It is almost impossible
to swallow cyanoacrylate as adhesive solidifies upon contact with saliva & may adhere to inside of
mouth. Saliva will lift adhesive in 1-2 days, avoid swallowing adhesive after detachment.
Medical Conditions Generally Aggravated by Exposure: Pre-existing skin, eye and respiratory
disorders may be aggravated by exposure.
Section 7 - PRECAUTIONS FOR SAFE HANDLING AND USE:
Steps to Be Taken in Case Material is Released or Spilled: Polymerize with water. Solid material may
be scraped from surface.
Waste Disposal Method: Incinerate solid combustible waste or dump as chemical waste according to
local, state and federal regulations.
Precautions to Be Taken in Handling and Storing: Avoid contact with clothing as contact can cause
burn. Avoid moisture, direct UV-sunlight and do not store above 25 C. Keep containers closed tightly
when not in use. Ideal storage: 5-10 C.
Other Precautions: Avoid breathing vapor, contact with eyes/skin. Allow product to reach room
temperature before use.
Section 8 - CONTROL MEASURES:
Respiratory Protection (Specify Type): A NIOSH-approved organic vapor canister may be used to
maintain vapor concentration below TLV.
Ventilation: Local Exhaust: To maintain vapor concentration below TLV.
Mechanical (General): Large amounts used to 0.2ppm.
Protective Clothing or Equipment: Safety glasses with side shield, Vinyl (polyethylene) non-sticking
gloves, rubber apron to protect clothing.
Work/Hygienic Practices: Soap and water helps remove adhesive from skin.
NE = Not established
The data contained herein is based upon information that Pacer Technology believes to be reliable.
Users of this product have the responsibility to determine the suitability of use and to adopt all
necessary precautions to ensure the safety and protection of property and persons involved in said
use. All statements or suggestions are made without warranty, express or implied, regarding
accuracy of the information, the hazards connected with the use of the material or the results to be
obtained from the use thereof.
MATERIAL SAFETY DATA SHEET Page 1 of 2
Rev. #5 Date: 08/29/06
Section 1 For Chemical Emergency Only
Pacer Technology In the US & Canada (800) 424-9300
9420 Santa Anita Avenue Int'l & Wash DC (COLLECT) (703) 527-3887
Rancho Cucamonga, CA 91730 Telephone for Information (909) 987-0550
I. PRODUCT IDENTIFICATION: PRO LOKTM Removable Thread Lock HAZARD RATING (HMIS)
Health = 2 Equip.
Flammability = 1 safety glasses
Reactivity = 1 gloves
II. COMPOSITION
INGREDIENTS CONCENTRATION% C.A.S.# ACGIH TLV
Polyglycol Dimethacrylate 60-70 Proprietary ---
Polyglycol Oleate 20-25 Proprietary ---
Poly(Tetrafluoroethylene) 5-10 9002-84-0 ---
Modified Silicon Dioxide 3-5 112945-52-5 ---
Saccharin 0.1-1.0 81-07-2 ---
Organic Peroxide* 1-3 80-15-9 ---
Maleic Acid 0.1-1.0 110-16-7 ---
N,N,Dialkyltoluidine 0.2-0.6 99-97-8 Not est.
Titanium Dioxide 0.1-0.5 13463-67-7 ---
*SARA Section 313 Toxic Chemical
III. CHEMICAL AND PHYSICAL PROPERTIES
Vapor Pressure: >0.1mmHg @ 25C Vapor Density: Heavier than Air
Solubility in water: N/A Specific Gravity: 1.08
Boiling point: >300F Appearance: blue
Odor: mild pH: N/A
IV. FLAMMABILITY AND EXPLOSIVE PROPERTIES
Flashpoint (T.C.C.): >200F
Recommended Extinguishing Agents: Water, foam, dry chemical or CO2
Hazardous Products Formed by Fire or Thermal Decomposition: Toxic fumes of carbon oxides
may evolve upon exposure to heat or open flame.
Unusual Fire or Explosive Hazards: none
Compressed gases: none Solvents: none Pressure at 23C: N/A
V. REACTIVITY DATA
Stability: Stable Hazardous Polymerization: Will not occur
Hazardous Decomposition Products: None known
Incompatibility: Active metal ions, heat
VI. SPILL OR LEAK PROCEDURES
Dike area to prevent spreading. Absorb on vermiculite, sand or other inert absorbing material.
Dispose of as a chemical waste in accordance with current local, state, and federal regulations.
VII. STORAGE AND HANDLING PROCEDURES
Avoid exposure to light, heat, loss of dissolved air, contamination with incompatible materials
such as copper or iron dust or material.
Handling: none
MATERIAL SAFETY DATA SHEET PRO LOKTM Removable Thread Lock Rev. #5 Page 2 of 2
VIII. SHIPPING REGULATIONS
DOT and IATA Hazard Classification: Unrestricted Articles
Proper DOT Shipping Name: N/A
IX. EMERGENCY TREATMENT
Eye Irritation: Immediately flush eyes with water for at least 15 minutes. Get medical attention.
Skin Contact: Wash thoroughly with soap and water. Do not use organic solvents on skin.
Inhalation: does not apply
Ingestion: Get medical attention, low toxicity
X. PERSONAL PROTECTION
Respiratory: not normally necessary
Skin: Avoid skin contact, wear gloves and protective clothing if in direct contact with material.
Disposable polyethylene gloves with vinyl latex overgloves will give protection.
Eyes: Wear safety goggles or side shield safety glasses.
XI. HEALTH HAZARD DATA
Hazard Categories: immediate X Delayed X fire pressure reactivity
Potential Routes of Entry: skin X inhalation ingestion X
Symptoms of Overexposure: Possible skin and eye irritation on contact is likely.
Sara Listed Ingredients: Organic Peroxide
XII. PREPARATION INFORMATION
Original Issue Date: 3/26/96 Revision #4: 02/18/05
Current Revision 5: 08/2906 PREPARED BY: Mary K. Robles
NA = not applicable
The data contained herein is based upon information that Pacer Technology believes to be reliable.
Users of this product have the responsibility to determine the suitability of use and to adopt all
necessary precautions to ensure the safety and protection of property and persons involved in said
use. All statements or suggestions are made without warranty, express or implied, regarding
accuracy of the information, the hazards connected with the use of the material or the results to be
obtained from the use thereof.
Fire Reactivity
2
2 0
0
Health Special
NFPA
MATERIAL SAFETY DATA SHEET
I. PRODUCT IDENTIFICATION
Manufacturer: WD-40 Company Telephone:
Emergency only: 1-(800) 424-9300 (CHEMTREC)
Address: 1061 Cudahy Place (92110) Information: (619) 275-1400
P.O. Box 80607 Chemical Name: Organic Mixture
San Diego, California Trade Name: WD-40 Aerosol
92138-0607
II. HAZARDOUS INGREDIENTS
Exposure Limit
Chemical Name CAS Number % ACGIH/OSHA
Aliphatic Petroleum Distillates 8052-41-3 45-50 100 ppm PEL
5 mg/M3 TWA (mist)
Petroleum Base Oil 64742-65-0 15-25
1200 mg/M 3 TWA
LVP Hydrocarbon Fluid 64742-47-8 12-18
Carbon Dioxide 124-38-9 2-3 5000 ppm PEL
< 10
Non-hazardous Ingredients
III. PHYSICAL DATA
Boiling Point: 323癋 (minimum) Evaporation Rate: Not determined
Vapor Density (air=1): Greater than 1 Vapor Pressure: 110 ? PSI @ 70癋
Solubility in Water: insoluble Appearance: Light amber
Specific Gravity (H20=1): 0.817 @ 72癋 Odor: Characteristic odor
Percent Volatile (volume): 74% VOC: 412 grams/liter (49.5%)
IV. FIRE AND EXPLOSION
Flash Point: 131癋 Tag Closed Cup
Flammable Limits: (Solvent Portion) [Lel] 1.0% [Uel] 6.0%
Extinguishing Media: CO2, Dry Chemical, Foam.
Special Fire Fighting Procedures: Contents Under Pressure
Unusual Fire and Explosion Hazards: FLAMMABLE - U.F.C. level 3 AEROSOL
V. HEALTH HAZARD / ROUTE(S) OF ENTRY
Threshold Limit Value Aliphatic Petroleum Distillates (Stoddard Solvent) lowest TLV (ACGIH 100 ppm.)
Symptoms of Overexposure
Inhalation (Breathing): May cause anesthesia, headache, dizziness, nausea and upper respiratory irritation.
Skin contact: May cause drying of skin and/or irritation.
Eye contact: May cause irritation, tearing and redness.
Ingestion (Swallowed): May caused irritation, nausea, vomiting and diarrhea.
First Aid Emergency Procedures
Ingestion (Swallowed): Do not induce vomiting, seek medical attention.
Eye Contact: Immediately flush eyes with large amounts of water for 15 minutes.
Skin Contact: Wash with soap and water.
Inhalation (Breathing): Remove to fresh air. Give artificial respiration if necessary.
If breathing is difficult, give oxygen.
Pre-existing medical conditions such as eye, skin and respiratory disorders may be
aggravated by exposure.
DANGER!
Aspiration Hazard: If swallowed, can enter lungs and may cause chemical pneumonitis.
Do not induce vomiting. Call Physician immediately.
Suspected Cancer Agent The components in this mixture have been found to be noncarcinogenic by NTP,
X
Yes___ No___ IARC and OSHA
VI. REACTIVITY DATA
X
Stability: Stable ____ Unstable____
Conditions to avoid: NA
Incompatibility: Strong oxidizing agents
Hazardous decomposition products: Thermal decomposition may yield carbon monoxide and/or carbon dioxide.
X
Hazardous polymerization: May occur ____ Will not occur____
VII. SPILL OR LEAK PROCEDURES
Spill Response Procedures
Spill unlikely from aerosol cans. Leaking cans should be placed in plastic bag or open pail until pressure has dissipated.
Waste Disposal Method
Empty aerosol cans should not be punctured or incinerated; bury in land fill. Liquid should be incinerated or buried in
land fill. Dispose of in accordance with local, state and federal regulations.
VIII. SPECIAL HANDLING INFORMATION
Ventilation: Sufficient to keep solvent vapor less than TLV.
Respiratory Protection: Advised when concentrations exceed TLV.
Protective Gloves: Advised to prevent possible skin irritation.
Eye Protection: Approved eye protections to safeguard against potential eye contact, irritation or injury.
Other Protective Equipment: None required.
IX. SPECIAL PRECAUTIONS
Keep from sources of ignition. Avoid excessive inhalation of spray particles, do not take internally. Do not puncture, incinerate or
store container above 120癋. Exposure to heat may cause bursting. Keep can away from electrical current or battery terminals.
Electrical arcing can cause burn-through (puncture) which may result in flash fire, causing serious injury. Keep from children.
X.TRANSPORTATION DATA (49 CFR 172.101)
Domestic Surface
Description: Consumer Commodity
Hazard Class: ORM-D
ID No: None
Label Required: Consumer commodity (ORM-D)
XI. REGULATORY INFORMATION
All ingredients for this product are listed on the TSCA inventory.
SARA Title III chemicals: None
California Prop 65 chemicals: None
CERCLA reportable quantity: None
RCRA hazardous waste no: D001 (Ignitable)
SIGNATURE: Peter Fougner TITLE: Director of Global Quality Assurance
REVISION DATE: December, 2004 SUPERSEDES: November, 2003
< = Less than > = More than
NA: Not applicable NDA: No data available
We believe the statements, technical information and recommendations contained herein are reliable. However, the data is provided without warranty, expressed
or implied. It is the user's responsibility both to determine safe conditions for use of this product and assume loss, damage or expense, direct or consequential,
arising from its use. Before using product, read label.
MSDS No.:WDA
MATERIAL SAFETY DATA SHEET
I. PRODUCT IDENTIFICATION
Manufacturer: WD-40 Company Telephone:
Emergency only: 1-800-424-9300 (Chemtrec)
Address: 1681 Cudahy Place (92110) Information: (619) 275-1400
P.O. Box 80607 Chemical Name: Organic Mixture
San Diego, California Trade Name: Three-In-One Multi-Purpose Oil
92138-0607
II. HAZARDOUS INGREDIENTS
Exposure Limit
Chemical Name CAS Number % ACGIH/OSHA
Severely Hydrotreated
5mg/M3 TWA (mist)
Heavy Naphthenic Oil 64742-52-5 >97
Non-hazardous Ingredients <3
III. PHYSICAL DATA
Appearance: Clear amber liquid Volatiles: Nil
Odor: Faint citronella pH: Not applicable
Boiling Point: Above 550癋 Specific Gravity: 0.866 - 0.923 @ 20癈
Freezing Point: Not applicable Vapor Pressure: Not determined
Solubility in Water: Insoluble Vapor Density (Air = 1): Not determined
IV. FIRE AND EXPLOSION
Flash Point: Above 305癋 TOC
Flame Extension: Not applicable
Extinguishing Media: C02, Dry Chemical, Foam, Water Spray
Fire Fighting Procedures: Use water to keep fire-exposed containers cool.
V. HEALTH HAZARD / ROUTE(S) OF ENTRY
Symptoms of Overexposure
Inhalation (Breathing): May cause anesthesia, headache, dizziness, nausea and upper respiratory irritation.
Skin Contact: May cause drying of skin and/or irritation.
Eye Contact: May cause irritation, tearing and redness.
Ingestion (Swallowed): May cause irritation, nausea, vomiting and diarrhea.
First Aid Procedures:
Ingestion (Swallowed): Do not induce vomiting. Seek medical attention.
Eye Contact: Immediately flush eyes with large amounts of water for 15 minutes.
Skin Contact: Wash with soap and water.
Inhalation (Breathing): Remove to fresh air. Give artificial respiration if necessary. If breathing is difficult, give oxygen.
DANGER!
Aspiration Hazard: If swallowed, can enter lungs and may cause chemical pneumonitis.
Do not induce vomiting. Call Physician immediately.
Suspected Cancer Agent
X
Yes_____ No_____ The components in this mixture have been found to be noncarcinogenic by NTP, IARC and
OSHA.
VI. REACTIVITY DATA
X
Stability: Stable____ Unstable ____
Conditions to avoid: NA
Incompatibility: Strong oxidizing materials
Hazardous decomposition products: Thermal decomposition may yield carbon monoxide and/or carbon dioxide.
X
Hazardous polymerization: May occur ____ Will not occur____
VII. SPILL OR LEAK PROCEDURES
Spill Response Procedures
Absorb small quantities with sand, earth, sawdust. Large quantities pump into tank.
Waste Disposal Method
Incinerate liquid, bury saturated absorbent in land fill. Dispose of in accordance with local, state and federal regulations.
VIII. SPECIAL HANDLING INFORMATION
Ventilation Requirements: Use local exhaust to capture vapor, mists or fumes, if necessary. Provide ventilation
sufficient to prevent exceeding recommended exposure limit or build-up of explosive
concentrations of vapor in air. No smoking, or use of lame or other ignition sources.
Respiratory Protection: Use air respiratory protection in confined or enclose spaces, if needed.
Protective Gloves: Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact.
Eye Protection: Use splash goggles or face shield when eye contact may occur.
IX. SPECIAL PRECAUTIONS
Keep from open flame. Do not take internally. Avoid excessive inhalation of vapors. Keep from children.
X. REGULATORY INFORMATION
All ingredients for this product are listed on the TSCA Inventory.
SARA Title III chemicals: None
California Prop 65 chemicals: None
CERCLA reportable quantity: None
RCRA hazardous waste no.: None
SIGNATURE: Peter Fougner TITLE: Director of Global Quality Assurance
REVISION DATE: January 2005 SUPERSEDES: June 2003
NA = Not applicable NDA = No data available < = Less than > = More than
We believe the statements, technical information and recommendations contained herein are reliable. However, the data is provided without warranty, expressed or implied.
It is the user's responsibility both to determine safe conditions for use of this product and assume loss, damage or expense, direct or consequential, arising from its use.
Before using product, read label.
MSDS No.:3N1MP
Document # 6810-005
Flammability
1
Health Reactivity
1 0
HMIS Rating
MATERIAL SAFETY DATA SHEET
GENERAL INFORMATION
PRODUCT NAME OR NUMBER (as it appears on label) CATALOG NUMBER
Noalox?Anti-Oxidant All "30" Series
MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.
IDEAL INDUSTRIES, INC. 895-5181
(815)
ADDRESS (Number, Street, City, State, Zip Code)
Becker Place, Sycamore, IL 60178
HAZARDOUS MATERIAL DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS, HAZARD CLASS NO., HAZARD ID NO. (49 CFR 172.101)
None
CHEMICAL DESCRIPTION FORMULA
Petroleum-Based Mixture Proprietary
SECTION I - INGREDIENTS
Listed as a carcinogen
in NTP, I ARC or OSHA
CAS REGISTRY NO. CHEMICAL NAME(S)*
%W
1910(z) (specify)
9003-29-6 <80 Polybutene No
7440-66-6 20 Zinc Dust No
7631-86-9 <5 Silicon Dioxide No
SECTION II - PHYSICAL DATA
BOILING POINT SPECIFIC GRAVITY (H2O=1) PERCENT VOLATILE BY VOLUME (%)
>500癋 1 04 NE
癈
SOLUBILITY IN WATER pH = PERCENT SOLID BY
Moderate 65-80 100
WEIGHT (%)
APPEARANCE AND ODOR IS MATERIAL: LIQUID SOLID GEL
GAS PASTE
Gray solid paste, mild odor
SECTION III - FIRE AND EXPLOSION HAZARD DATA
FLAMMABLE LIMITS LEL UEL
310 F C.O.C
FLASH POINT method used
N.E. N.E.
EXTINGUISHING MEDIA
Use dry chemical carbon dioxide or foam
SPECIAL FIRE FIGHTING PROCEDURES
Self-contained respiratory protection should be provided for fire fighters Keep fire exposed
containers cool with water.
UNUSUAL FIRE AND EXPLOSION HAZARDS
Water or foam may cause a frothing reaction (Water reacts with zinc dust)
* None of the chemical raw materials contained in this formulation are considered hazardous under the Federal Hazards Communication Standard 29 C. F. R 1910.1200
form #5100-048-01, rev. date 3/10/06
SECTION IV - HEALTH HAZARD INFORMATION
EFFECTS OF OVEREXPOSURE - Conditions to Avoid
None normally expected Upon prolonged contact may cause temporary eye
discomfort.
THRESHOLD LIMIT VALUE
Zinc dust or silicon dioxide as dust: 10mg/m
PRIMARY ROUTES OF ENTRY Inhalation Skin Contact Other (specify)
EMERGENCY FIRST AID PROCEDURES
Wash with soap and water for 15 minutes
SKIN CONTACT:
EYE CONTACT:
Flush with water for 15 minutes
INGESTION:
Induce vomiting and consult physician or local poison control center
SECTION V - REACTIVITY DATA
UNSTABLE CONDITIONS TO AVOID
Avoid conditions of moisture or high humidity.
STABILITY
STABLE X
INCOMPATIBILITY (materials to avoid)
Avoid strong oxidizers strong acids and water
HAZARDOUS DECOMPOSTION PRODUCTS:
Excessive heat and burning may release oxides of carbon
CONDITIONS TO AVOID
MAY OCCUR
HAZARDOUS None
POLYMERIZATION
X
WILL NOT OCCUR
SECTION VI - SPILL AND LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Wipe up shovel or vacuum spilled material Clean up spills immediately
Use absorbent media.
WASTE DISPOSAL METHOD
Comply with Federal state and local regulations for solid landfill
CERCLA (Superfund) REPORTABLE QUANTITY (in lbs)
None Required
RCRA HAZARDOUS WASTE NO. (40CFR 261.33)
None Required
VOLATILE ORGANIC COMPOUND (VOC) (as packaged, minus water)
120 g/l calculated
N/A N/A
?Theoretical lb/gal ?Analytical lb/gal
SECTION VII - PERSONAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (specify type)
If TLV exceeded use NIOSH respirator
Necessary above TLV None
LOCAL EXHAUST (Specify Rate) SPECIAL
VENTILATION
MECHANICAL (General) (Specify Rate) None
OTHER
Recommended in closed areas
PROTECTIVE GLOVES (specify type) EYE PROTECTION (specify type)
None normally needed -Neoprene if necessary Safety glasses or splash goggles
OTHER PROTECTIVE EQUIPMENT
Eye fountain in work area is recommended
SECTION VIII - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store in dry conditions at temperatures between 40 - 120 F
OTHER PRECAUTIONS
Keep away from children infants and pets
SECTION IX - ADDITIONAL INFORMATION
This product contains the following materials that are subject to the reporting requirements of
Section 313 of EPCRA:
CAS # 7440-66-6, Zinc Dust, 20%
N/A = Not Applicable, N.E. = None Established
THIS MATERIAL SAFETY DATA SHEET PREPARED BY:
James R. MacMurdo SIGNATURE
NAME
Director, Corporate Quality Assurance
TITLE
03/10/2006
DATE
Noalox?Anti-Oxidant
MSDS No: SOL210E5
Issue Date: 15 July 2005
Page: 1 of 4
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: OATEY SILVER LEAD-FREE PLUMBING SOLDER
Product Use: Solder for copper water lines
Formula: See Section 2
Synonyms: Solder
Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For
Numbers: chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the U.S. 1-703-527-3887.
Prepared By: Corporate Director ?Safety and Environmental Compliance
Preparation Date: July 15, 2005
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
% wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA:
INGREDIENTS:
Tin 60 - 100% 7440-31-5 2 mg/m3 2 mg/m3
Copper 1 - 5% 7440-50-8 0.2 mg/m3(fume) 0.1 mg/m3(fume)
1 mg/m3 (dust) 1 mg/m3 (dust)
Bismuth 1 - 5% 7440-69-9 None None
Silver 1 ?5% 7440-22-4 0.1 mg/m3 0.01 mg/m3
SECTION 3 HAZARDS IDENTIFICATION
Emergency Overview:
Silver-gray wire metal. The fumes may be hazardous during soldering operations.
Fumes can cause eye irritation and may cause headache and respiratory system
irritation. Ingestion of metal alloys may be harmful.
OSHA Hazard Classification: Not hazardous as is. In use, irritant and
organ effects.
SECTION 4 FIRST AID MEASURES
CALL 1-303-623-5716 COLLECT
Skin: If irritation arises, wash thoroughly with soap and water. Seek medical
attention if irritation persists.
Eyes: If material gets into eyes, immediately flush eyes with water while
holding eyelids open until material is removed. If irritation
persists, seek medical attention.
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. If not
breathing, give artificial respiration. Keep victim quiet and warm. Call
a poison control center or physician immediately.
Ingestion: DO NOT INDUCE VOMITING. Ingestion is not a likely route of entry. Never
give anything by mouth to a person who is unconscious or drowsy. Get
medical attention by calling a Poison Control Center, or hospital
emergency room.
MSDS No: SOL210E5
Issue Date: 15 July 2005
Page: 2 of 4
SECTION 5 FIRE FIGHTING MEASURES
Flashpoint / Method: Not applicable
Flammability: LEL = Not applicable, UEL = Not applicable
Extinguishing Not applicable
Media:
Special Fire
Fighting Not applicable
Procedure:
Unusual Fire and
Explosion None known
Hazards:
Hazardous Material will not decompose under normal conditions. If
Decomposition overheated, oxides of tin, bismuth, copper and silver
Products: may result.
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Collect solid and place in properly labeled containers.
Leak
Procedures:
SECTION 7 HANDLING AND STORAGE
Handling: Avoid inhalation of fumes and vapors. Keep away from children.
Wash thoroughly after handling before eating, drinking, or smoking.
Storage: Store in a cool, dry place away from heat or open flame.
Other: None.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Good general ventilation (equivalent to outdoors) should be adequate
for normal use. For operations where the TLV may be exceeded,
mechanical ventilation such as local exhaust may be needed to maintain
exposure levels below applicable limits.
Respiratory For operations where the TLV may be exceeded, a NIOSH approved
Protection: respirator or supplied air respirator is recommended. Equipment
selection depends on contaminant type and concentration, select in
accordance with 29 CFR 1910.134 and good industrial hygiene practice.
Skin Wear rubber gloves.
Protection:
Eye Safety glasses with sideshields or safety goggles.
Protection:
Other: Eye wash and safety shower should be available.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: Not determined
Melting Point: 415 to 455 Degrees F (213 to 235 Degrees C)
Vapor Pressure: Not determined
Vapor Density: (Air = 1) Greater than 1
Volatile Components: None
Solubility In Water: Negligible
pH: Not applicable
Specific Gravity: 9 to 11
Evaporation Rate: Not applicable
Appearance: Silver-gray wire metal
Odor: None
Will Dissolve In: Not applicable
Material Is: Solid
MSDS No: SOL210E5
Issue Date: 15 July 2005
Page: 3 of 4
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Do not heat over 480 Degrees F (250 Degrees C).
Hazardous If overheated, oxides of tin, bismuth, copper, and silver.
Decomposition
Products:
Incompatibility/ None.
Materials To Avoid:
Hazardous Will not occur.
Polymerization:
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Fumes from soldering operations may be irritating to the
respiratory system. Prolonged exposure to fumes may cause
stannosis, a mild benign pneumoconiosis. Repeated inhalation of
fumes may cause occupational asthma. Symptoms may be delayed.
Skin: Fumes may cause irritation.
Eye: Fumes may cause irritation.
Ingestion: Ingestion may cause abdominal pain, nausea, vomiting, diarrhea,
gastrointestinitis, or internal cuts.
Toxicity Data: No data available
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA.
Mutagenicity: None of the components have been found to be mutagenic.
Reproductive None of the components are known to cause adverse reproductive
Toxicity: effects.
Medical Persons with pre-existing skin, lung, kidney or liver disorders
Conditions may be at increased risk from exposure to the fumes of this
Aggravated By product.
Exposure:
SECTION 12 ECOLOGICAL INFORMATION
No data available. Keep out of waterways.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose of in accordance with federal, state, and local regulations.
It is the responsibility of the end-user to determine at the time of
disposal of the product.
RCRA Hazardous Waste Number: None
EPA Hazardous Waste ID Number: None
EPA Hazard Waste Class: None
SECTION 14 TRANSPORT INFORMATION
DOT
Proper Shipping Name: Not regulated
Hazard Class/Packing Group: None
UN/NA Number: None
Hazard Labels: None
IMDG
Proper Shipping Name: Not regulated
Hazard Class/Packing Group: None
UN Number: None
Label: None
2004 North American Emergency Response Guidebook Number: Not applicable
MSDS No: SOL210E5
Issue Date: 15 July 2005
Page: 4 of 4
SECTION 15 REGULATORY INFORMATION
Hazard Category for Section Not hazardous unless heated. If heated, acute and
311/312: chronic health hazards.
Section 302 Extremely This product does not contain chemicals regulated
Hazardous Substances (TPQ): under SARA Section 302.
Section 313 Toxic Chemicals: This product contains the following chemicals
subject to SARA Title III Section 313 Reporting
requirements:
CAS # % wt
Chemical
Copper 7440-50-8 1 - 5%
Silver 7440-22-4 1 ?5%
CERCLA 103 Reportable This product contains no chemicals subject to
Quantity: CERCLA reporting.
California Proposition 65: This product does not contain chemicals regulated
under California Proposition 65.
TSCA Inventory: All of the components of this product are listed on
the TSCA inventory.
Canadian WHMIS Classification: Not a controlled product.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16 OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 Special: None
HMIS Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 PPE: B
DISCLAIMER
The information herein has been compiled from sources believed to be reliable, up-
to-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
MATERIAL SAFETY DATA SHEET CODE: M/L 1134
This Material Safety Data Sheet complies with
the U.S. OSHA Hazard Communication
Standard 29CFR 1910.1200
PRODUCT: DUTCH BOY?PASTE FLUX
________________________________________________________________________________________________________
NFPA/HMIS HAZARD CODES: HEALTH: 1/1 FIRE: 0/0 REACTIVITY: 0/0 SPECIAL: NA
------------------------------------------------------------------------------------------------------------------------------------------------------------------------
0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
SECTION I
MANUFACTURER: Taracorp ISSUE DATE: October 2004
ADDRESS: 1690 Lowery Street
Winston-Salem, NC 27101
PHONE: (336) 777-8600
SECTION II HAZARDOUS INGREDIENTS
INGREDIENTS CAS NO. PERCENT OSHA PEL ACGIH TLV
Petrolatum 08002059 70.8 N/A N/A
Zinc Chloride 07646857 25.3 1mg/m3 1mg/m3
Moisture, as water 3.9
SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS
APPEARANCE AND ODOR: Amber colored jelly
BOILING POINT: 74?C
VAPOR PRESSURE: 10MM Hg
VAPOR DENSITY: NA
SOLUBILITY IN H2O: NO
SPECIFIC GRAVITY: 0.9
MELTING POINT: 67?C
EVAPORATION RATE: NA
SECTION IV FIRE AND EXPLOSION HAZARD DATA
FLASH POINT: 180癈
FLAMMABLE LIMITS: NA
AUTO IGNITION TEMPERATURE: NA
EXTINGUISHING MEDIUM: No Preference
SPECIAL FIRE FIGHTING PROCEDURES: None
UNUSUAL FIRE & EXPLOSIVE CONDITIONS: None
SECTION V REACTIVITY DATA
STABILITY: Stable
CONDITIONS TO AVOID: NA
INCOMPATIBILITIES: None
HAZARDOUS DECOMPOSITION: None
HAZARDOUS POLYMERIZATION: Will not occur.
Rev 002
Date: 11/24/04
M/L 1134 1
SECTION IV HEALTH HAZARD DATA
ROUTES OF ENTRY: inhalation (fume), ingestion, dermal.
SYMPTOMS & EFFECT OF OVEREXPOSURE:
Acute: Inhalation can cause irritation & damage to eyes, lungs, mucous & mucous membranes. Skin contact can cause ulceration
of the skin.
Chronic: Irritation of the eyes, skin and mucous membranes.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Skin conditions or respiratory problems.
CARCINOGENICITY: Not listed.
EMERGENCY AND FIRST AID PRCEDURES:
EYES: Flush with water for 10 minutes. Obtain immediate medical attention.
SKIN: Wash thoroughly with water; If irritation develops, obtain medical attention.
ACUTE INHALATION: Remove to fresh air. Obtain immediate medical attention.
INGESTION: Give water; Obtain immediate medical attention.
SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE THIS MATERIAL IS RELEASED OR SPILLED: Normal clean-up procedures are sufficient.
Protect skin from exposure during the
procedure.
WASTE DISPOSAL METHOD: Permitted landfill, check local ordinances.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store below melting temperature: do not expose
to heat in storage.
OTHER PRECAUTIONS: None
SECTION VIII CONTROL MEASURES
RESPIRATORY PROTECTION: NIOSH Approved Respirator
VENTILATION: Good general dilution ventilation
PROTECTIVE GLOVES: Recommended for prolonged contact/heat.
EYE PROTECTION: Safety glasses or goggles are recommended.
OTHER PROTECTIVE EQUIPMENT: Safety equipment should be worn as appropriate for the work environment; includes, apron,
safety goggles.
WORK/HYGIENIC PRACTICES: Wash hands thoroughly after use to prevent exposure to the eyes or skin.
SECTION IX UNITED STATES SARA TITLE III INFORMATION
This product/mixture contains the following toxic chemical(s) subject to the reporting of Section 313 of the Title of the U.S.
Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR part 372. Percent by weight of each toxic chemical
abstract system (CAS) number are to be found in Section II of this Material Safety Data Sheet.
CHEMICAL NAME EHS RQ (LBS) EH TPQ (LBS) SEC. 313 313 CATEGORY 311/312 CATEGORIES
*1 *2 *3 *4 *5
Zinc Chloride 1,000 1,000 yes yes H-1
*1=Reportable quantity of extremely hazardous material substance, Section 302
*2=Threshold planning quantity, extremely hazardous substance, Section 302
*3=Toxic chemical list, Section 313.
*4=Chemical category as required by Section 313 (40 CFR 372.42). Subject to annual release reporting requirements.
*5=Hazard category as required by SARA Section 311/312 reporting:
Health H-1=Immediate (ACUTE) Health Hazard Physical P-3= Fire Hazard
H-2=Delayed (CHRONIC) Health Hazard P-4= Sudden Release of Pressure Hazard
P-5= Reactive Hazard
SECTION X TRANSPORTATION AND DISPOSAL CONSIDERATIONS
D.O.T. PROPER SHIPPING NAME: Non-hazardous
WASTE DISPOSAL METHOD: Dispose of in accordance with EPA regulations
Rev 002
Date: 11/24/04
M/L 1134 2
SECTION XI OTHER INFORMATION
This Material Safety Data Sheet is offered solely for your information, consideration and investigation. Taracorp, Inc. provides no warranties, either
express or implied, and assumes no responsibilities for the accuracy or completeness of the data contained in this document. The data in this
Material Safety Data Sheet relates only to this product and does not relate to use in combination with any other material or in any process.
Rev 002
Date: 11/24/04
M/L 1134 3
MSDS No: CEM010E5
Issue Date: 20 May 2005
Page: 1 of 5
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: OATEY ALL PURPOSE CEMENT
Product Use: Cement for PVC, ABS, AND CPVC Pipe
Formula: PVC & CPVC Resin in Solvent Solution
Synonyms: None
Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For
Numbers: chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the U.S. 1-703-527-3887.
Prepared By: Corporate Director ?Safety and Environmental Compliance
Preparation Date: May 20, 2005
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS: %wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER:
Tetrahydrofuran 30 - 45% 109-99-9 50 ppm(skin) 200 ppm 25 ppm (Mfg)
100 ppm STEL
Methyl Ethyl Ketone 20 - 40% 78-93-3 200 ppm 200 ppm None
300 ppm STEL
Cyclohexanone 10 - 20% 108-94-1 20 ppm(skin) 50 ppm None
50 ppm STEL
9002-86-2 10 mg/m3 15 mg/m3 None
PVC Resin 8 - 15%
(Non-hazardous)
CPVC Resin 3 - 7% 68648-82-8 10 mg/m3 None None
(Non-hazardous) Established
Amorphous Fumed Silica 1 - 4% 112945-52-5 10 mg/m3 None None
(Non-hazardous) Established
OSHA Hazard Classification: Flammable, irritant, organ effects
SECTION 3 HAZARDS IDENTIFICATION
Emergency Overview:
Milky liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors
may cause flash fire. May cause eye and skin irritation. Inhalation of vapors or
mist may cause respiratory irritation and central nervous system effects. Swallowing
may cause irritation, nausea, vomiting, diarrhea and kidney or liver disorders.
Aspiration hazard. May be fatal if swallowed. Symptoms may be delayed.
SECTION 4 FIRST AID MEASURES
CALL 1-303-623-5716 COLLECT
Skin: Remove contaminated clothing immediately. Wash all exposed areas with
soap and water. Get medical attention if irritation develops. Remove
dried cement with Oatey Plumber's Hand Cleaner or baby oil.
Eyes: If material gets into eyes or if fumes cause irritation, immediately
flush eyes with plenty of water until chemical is removed. If
irritation persists, get medical attention immediately.
Inhalation: If symptoms of exposure develop, remove to fresh air. If breathing
becomes difficult, administer oxygen. Administer artificial respiration
if breathing has stopped. Seek immediate medical attention.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Never give anything
by mouth to a person who is unconscious or drowsy. Get immediate medical
attention by calling a Poison Control Center, or hospital emergency
person and
room. If medical advice cannot be obtained, then take the
product to the nearest medical emergency treatment center or hospital.
MSDS No: CEM010E5
Issue Date: 20 May 2005
Page: 2 of 5
SECTION 5 FIRE FIGHTING MEASURES
Flashpoint / Method: 0 - 5 Degrees F. (-18 - -15 Degrees C) / PMCC
Flammability: LEL = 1.8 % Volume, UEL = 11.8 % Volume
Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media: exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire Firefighters should wear positive pressure self-contained
Fighting breathing apparatus and full protective clothing for fires in
Procedure: areas where chemicals are used or stored
Unusual Fire and Extremely flammable liquid. Keep away from heat and all
Explosion sources of ignition including sparks, flames, lighted
Hazards: cigarettes and pilot lights. Containers may rupture or
explode in the heat of a fire. Vapors are heavier than air
and may travel to a remote ignition source and flash back.
This product contains tetrahydrofuran that may form explosive
organic peroxide when exposed to air or light or with age.
Hazardous Combustion will produce toxic and irritating vapors including
Decomposition carbon monoxide, carbon dioxide and hydrogen chloride.
Products:
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Remove all sources of ignition and ventilate area. Stop leak if it
Leak can be done without risk. Personnel cleaning up the spill should
Procedures: wear appropriate personal protective equipment, including respirators
if vapor concentrations are high. Soak up spill with an inert
absorbent such as sand, earth or other non-combusting material. Put
absorbent material in covered, labeled metal containers. Prevent
liquid from entering watercourses, sewers and natural waterways.
Report releases to authorities as required. See Section 13 for
disposal information.
SECTION 7 HANDLING AND STORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid breathing vapors
or mists. Use with adequate ventilation (equivalent to outdoors).
Wash thoroughly after handling. Do not eat, drink or smoke in the
work area. Keep product away from heat, sparks, flames and all other
sources of ignition. No smoking in storage or use areas. Keep
containers closed when not in use.
Storage: Store in a cool, dry, well-ventilated area away from incompatible
materials. Keep containers closed when not in use.
Other: "Empty" containers retain product residue and can be hazardous.
Follow all MSDS precautions in handling empty containers. Do not cut
or weld on or near empty or full containers.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Open doors & windows. Provide ventilation capable of maintaining
emissions at the point of use below recommended exposure limits. If
used in enclosed area, use exhaust fans. Exhaust fans should be
explosion-proof or set up in a way that flammable concentrations of
solvent vapors are not exposed to electrical fixtures or hot
surfaces.
Respiratory For operations where the exposure limit may be exceeded, a NIOSH
Protection: approved organic vapor respirator or supplied air respirator is
recommended. Equipment selection depends on contaminant type and
concentration, select in accordance with 29 CFR 1910.134 and good
industrial hygiene practice. For firefighting, use self-contained
breathing apparatus.
Skin Rubber gloves are suitable for normal use of the product. For long
Protection: exposures chemical resistant gloves may be required such as 4H(tm)
or Silver Shield(tm) to avoid prolonged skin contact.
MSDS No: CEM010E5
Issue Date: 20 May 2005
Page: 3 of 5
SECTION 8 (Continued)
Eye Safety glasses with side shields or safety goggles.
Protection:
Other: Eye wash and safety shower should be available.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 151 Degrees F / 66 Degrees C
Melting Point: Not applicable
Vapor Pressure: 145 mmHg @ 20 Degrees C
Vapor Density: (Air = 1) 2.5
Volatile Components: 84-88%
Solubility In Water: Negligible
pH: Not applicable
Specific Gravity: 0.93 +/- 0.02 @ 20 Degrees C
Evaporation Rate: (BUAC = 1) = 5.5 - 8.0
Appearance: Milky Liquid
Odor: Ether-Like
Will Dissolve In: Tetrahydrofuran
Material Is: Liquid
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition.
Hazardous Combustion will produce toxic and irritating vapors
Decomposition including carbon monoxide, carbon dioxide and hydrogen
Products: chloride.
Incompatibility/ Oxidizing agents, alkalis, amines, ammonia, acids, chlorine
Materials To Avoid: compounds, chlorinated inorganics (potassium, calcium and
sodium hypochlorite) and hydrogen peroxides. May attack
plastic, resins and rubber.
Hazardous Will not occur.
Polymerization:
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Vapors or mists may cause mucous membrane and respiratory
irritation, coughing, headache, dizziness, dullness, nausea,
shortness of breath and vomiting. High concentrations may cause
central nervous system depression, narcosis and unconsciousness.
May cause kidney, liver and lung damage.
Skin: May cause irritation with redness, itching and pain. Methyl
ethyl ketone and cyclohexanone may be absorbed through the skin
causing effects similar to those listed under inhalation.
Eye: Vapors may cause irritation. Direct contact may cause irritation
with redness, stinging and tearing of the eyes. May cause eye
damage.
Ingestion: Swallowing may cause abdominal pain, nausea, vomiting and
diarrhea. Aspiration during swallowing or vomiting can cause
chemical pneumonia and lung damage. May cause kidney and liver
damage.
Chronic Prolonged or repeated overexposure cause dermatitis and damage
Toxicity: to the kidney, liver, lungs and central nervous system.
Toxicity Data: Cyclohexanone: Oral rat LD50: 1,620 mg/kg
Inhalation rat LC50: 8,000 ppm/4 hours
Skin rabbit LD50: 1 mL/kg
Oral rat LD50: 1,650 mg/kg
Tetrahydrofuran:
Inhalation rat LC50: 21,000 ppm/3 hours
Methyl Ethyl Ketone: Oral rat LD50: 2,737 mg/kg
Inhalation rat LC50: 23,500 mg/m3/8 hours
Skin rabbit LD50: 6,480 mg/kg
MSDS No: CEM010E5
Issue Date: 20 May 2005
Page: 4 of 5
SECTION 11 (Continued)
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA. The National Toxicology Program
has reported that exposure of mice and rats to tetrahydrofuran
(THF) vapor levels up to 1800 ppm 6 hr/day, 5 days/week for their
lifetime caused an increased incidence of kidney tumors in male
rats and liver tumors in female mice. The significance of these
findings for human health is unclear at this time, and may be
related to "species specific" effects. Elevated incidences of
tumors in humans have not been reported for THF. ACGIH has
classified cyclohexanone (CYH) and tetrahydrofuran as "A3,"
Confirmed Animal Carcinogens with Unknown Relevance to Humans.
Mutagenicity: Cyclohexanone has been positive in bacterial and mammalian
assays. Methyl ethyl ketone and tetrahydrofuran are
generally thought not to be mutagenic.
Reproductive Methyl ethyl ketone and cyclohexanone have been shown to cause
Toxicity: embryofetal toxicity and birth defects in laboratory animals.
Tetrahydrofuran has been found to cause adverse developmental
effects only when exposure levels cause other toxic effects to the
mother.
Medical Persons with pre-existing skin, lung, kidney or liver disorders
Conditions may be at increased risk from exposure to this product.
Aggravated By
Exposure:
SECTION 12 ECOLOGICAL INFORMATION
This product is not expected to be toxic to aquatic organisms.
Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.
Tetrahydrofuran: 96 hour LC50 fathead minnow: 2160 mg/L.
Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.
VOC This product emits VOC's (volatile organic compounds) in its use.
Information: Make sure that use of this product complies with local VOC emission
regulations, where they exist.
VOC Level: 600 g/l per SCAQMD Test Method 316A.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number: U057, U159, U213
EPA Hazardous Waste ID Number: D001, D035, F003, F005
EPA Hazard Waste Class: Ignitable Waste. Toxic Waste (Methyl Ethyl Ketone content)
SECTION 14 TRANSPORT INFORMATION
Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
DOT
Proper Shipping Name: Consumer Commodity Adhesives
Hazard Class/Packing Group: ORM-D 3, PGII
UN/NA Number: None UN1133
Hazard Labels: None Flammable Liquid
IMDG
Proper Shipping Name: Adhesives Adhesives
Hazard Class/Packing Group: 3, II 3, II
UN Number: UN1133 UN1133
Class 3 (Flammable
Label: None (Limited Quantities
are excepted Liquid)
from labeling)
2004 North American Emergency Response Guidebook Number: 127 or 128
MSDS No: CEM010E5
Issue Date: 20 May 2005
Page: 5 of 5
SECTION 15 REGULATORY INFORMATION
Hazard Category for Section Acute Health, Chronic Health, Flammable
311/312:
Section 302 Extremely This product does not contain chemicals regulated
Hazardous Substances (TPQ): under SARA Section 302.
Section 313 Toxic Chemicals: This product contains the following chemicals
subject to SARA Title III Section 313 Reporting
requirements:
Chemical CAS # % by wt.
Methyl Ethyl Ketone 78-93-3 20-40%
CERCLA 103 Reportable Spills of this product over the RQ (reportable
Quantity: quantity) must be reported to the National Response
Center. The RQ for the product, based on the RQ for
Tetrahydrofuran (45% maximum) of 1,000 lbs, is 2,222
lbs. Many states have more stringent release
reporting requirements. Report spills required under
federal, state and local regulations.
California Proposition 65: This product contains trace amounts of chemicals
known to the State of to cause cancer. Under normal
Use conditions, exposure to these chemicals at levels
above the State of California "No Significant Risk
Level" (NSRL) are unlikely. Oatey strongly
encourages the use of proper personal protective
equipment (PPE) and ventilation guidelines noted in
Section 8 to minimize exposure to these chemicals.
TSCA Inventory: All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification: Class B, Division 2; Class D, Division 2,
Subdivision B; Class D, Division 2, Subdivision A.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16 OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 2 Flammability: 3 Reactivity: 1 Special: None
HMIS Hazard Signal: Health: 2* Flammability: 3 Reactivity: 1 PPE: G
Disclaimer:
The information herein has been compiled from sources believed to be reliable, up-
to-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
MSDS No: OTH070E6
Issue Date: 19 Apr 2006
Page: 1 of 4
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: OATEY GREAT WHITE PIPE JOINT COMPOUND WITH PTFE
Product Use: Compound for sealing and lubricating threaded pipe joints.
Formula: See SECTION 2
Synonyms: Pipe dope.
Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For
Numbers: chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the U.S. 1-703-527-3887.
Prepared By: Corporate Director ?Safety and Environmental Compliance
Preparation Date: April 19, 2006
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
%wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER:
INGREDIENTS:
Calcium Carbonate 35 - 45% 1317-65-3 10 mg/M3 15 mg/M3 None
(Total dust)
Hydrocarbon oil 30 - 40% 64742-52-5 5 mg/M3 5 mg/M3 None
Titanium Dioxide 5 ?10% 13463-67-7 10 mg/M3 15 mg/M3 None
Clay 1 ?5% 68953-58-2 10 mg/M3 10 mg/M3 None
OSHA Hazard Classification: Not hazardous
SECTION 3 HAZARDS IDENTIFICATION
Emergency Overview:
White putty with a mild petroleum odor. May cause mechanical irritation of the eyes.
SECTION 4 FIRST AID MEASURES
CALL 1-303-623-5716 COLLECT
Skin: Wash all exposed areas with soap and water.
Eyes: As with most foreign materials, should eye contact occur,
flush eyes with water until foreign matter is removed. If
irritation develops, seek medical attention.
Inhalation: Not a likely route of entry.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician.
SECTION 5 FIRE FIGHTING MEASURES
Flashpoint / Method: Not applicable
Flammability: LEL = Not determined, UEL = Not determined
Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media: exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire As appropriate for surrounding fire.
Fighting
Procedure:
Unusual Fire and None
Explosion
Hazards:
Hazardous Combustion will produce toxic and irritating vapors including
Decomposition carbon monoxide and carbon dioxide.
Products:
MSDS No: OTH070E6
Issue Date: 19 Apr 2006
Page: 2 of 4
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Sweep up dried material and dispose of with ordinary trash.
Leak
Procedures:
SECTION 7 HANDLING AND STORAGE
Handling: No special handling required. Wash thoroughly after handling.
Storage: Store in a cool, dry area.
Other: None.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Use with adequate ventilation. If putty dries and becomes dusty,
Respiratory wear a dust respirator during clean-up.
Protection:
Skin Gloves are not normally required.
Protection:
Eye Safety glasses with side shields are recommended.
Protection:
Other: Eye wash should be available.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: Not applicable
Melting Point: Not applicable
Vapor Pressure: Not determined
Vapor Density: Not determined
Volatile Components: Not determined
Solubility In Water: Negligible.
pH: Not applicable
Specific Gravity: 2.0 @ 20 Degrees C
Evaporation Rate: Not determined
Appearance: White Paste
Odor: Petroleum odor
Will Dissolve In: Not determined
Material Is: Paste
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Avoid heat, flames and other sources of ignition.
Hazardous Combustion will produce toxic and irritating vapors
Decomposition including carbon monoxide and carbon dioxide.
Products:
Incompatibility/ Oxidizing agents.
Materials To Avoid:
Hazardous Will not occur.
Polymerization:
MSDS No: OTH070E6
Issue Date: 19 Apr 2006
Page: 3 of 4
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Not a likely route of entry.
Skin: May cause mild irritation. Prolonged and repeated contact
may cause dermatitis.
Eye: Contact may cause irritation.
Ingestion: Swallowing may cause a laxative effect including cramps and
diarrhea.
Chronic Prolonged or repeated overexposure cause dermatitis.
Toxicity: to the kidney, liver, lungs and central nervous system.
Toxicity Data: Not available
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA.
Mutagenicity: None of the components are known to be mutagenic.
Reproductive None of the components are known to be toxic to reproduction.
Toxicity:
Medical None known.
Conditions
Aggravated By
Exposure:
SECTION 12 ECOLOGICAL INFORMATION
No ecotoxicological information known.
VOC
Information: This product has very low VOC level.
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number: Not a hazardous waste.
EPA Hazardous Waste ID Number: Not a hazardous waste.
EPA Hazard Waste Class: Not a hazardous waste.
SECTION 14 TRANSPORT INFORMATION
Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
DOT
Proper Shipping Name: Not regulated. Not regulated.
Hazard Class/Packing Group: None None
UN/NA Number: None None
Hazard Labels: None None
IMDG
Proper Shipping Name: Not regulated
Hazard Class/Packing Group: None
UN Number: None
Label: None
2004 North American Emergency Response Guidebook Number: None
MSDS No: OTH070E6
Issue Date: 19 Apr 2006
Page: 4 of 4
SECTION 15 REGULATORY INFORMATION
Hazard Category for Section Not hazardous.
Section 302 Extremely This product does not contain chemicals regulated
Hazardous Substances (TPQ): under SARA Section 302.
Section 313 Toxic Chemicals: This product does not contain any chemicals regulated
under SARA Title III Section 313.
CERCLA 103 Reportable This product does not contain any chemicals regulated
Quantity: under CERCLA.
California Proposition 65: This product does not contain any chemicals subject
To California Proposition 65 regulation.
TSCA Inventory: All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification: Not a controlled product.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16 OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 Special: None
HMIS Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 PPE: A
Disclaimer:
The information herein has been compiled from sources believed to be reliable, up-
to-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
Material Safety Data Sheet
F
1. Chemical Product and Company Identification
DESCRIPTION: ELMER'S ULTIMATE GLUE
PRODUCT TYPE: POLYURETHANE
APPLICATION: FOR PRODUCT CODES SEE SECTION 16
Manufacturer/Supplier Information
?br>
MSDS Prepared by:
Elmer's Products, Inc. Emergency Phone Number
1000 Kingsmill Parkway Poison Control Center
Columbus, OH 43229 1-800-228-5635 ext 22
For additional health, safety or regulatory information, call 614-225-7695.
Call 1-800-848-9400 to place an order or request additional MSDSs.
2. Composition, Information on Ingredients
The ingredients listed below have been associated with one or more
immediate and/or delayed(*) health hazards. Risk of damage and effects
depends upon duration and level of exposure. BEFORE USING, HANDLING, OR
EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS.
% by weight
101-68-8 *Diphenylmethane 4,4'-Diisocyanate 10-30
9016-87-9 *Polymeric Diphenylmethane Diisocyanate 30-50
*Modified Polymeric MDI 50-70
3. Hazards Identification
3.1 Emergency Overview
Appearance Viscous dark brown liquid
Odor Slightly musty
WARNING!
Hazardous polymerization may occur.
Will burn.
Reacts with water.
Harmful if inhaled. If material is heated, sprayed or otherwise
dispersed, may cause irritation of nose, throat and lungs.
May cause allergic skin and respiratory reactions.
May be harmful if absorbed through skin.
Causes skin irritation.
Causes eye irritation.
HMIS Rating
?br>
HEALTH = 3 (serious)
FLAMMABILITY = 1 (slight)
REACTIVITY = 1 (slight)
CHRONIC = *
3.2 Potential Health Effects
Immediate Hazards
?br>
INGESTION: Not expected to be harmful under normal conditions of
use.
If accidentally swallowed, burns or irritation to
mucous membranes, esophagus or GI tract can result.
INHALATION: Harmful if inhaled. If material is heated, sprayed
or otherwise dispersed, may cause irritation of nose,
throat and lungs. Concentrations below the exposure
guidelines may cause allergic respiratory reactions
in individuals already sensitized. Symptoms may
include coughing, difficult breathing and a feeling
of tightness in the chest. Effects may be delayed.
SKIN: Skin contact may result in allergic skin reactions or
respiratory sensitization. However, it is not expected
to result in absorption of amounts sufficient to cause
other adverse effects. Causes irritation.
EYES: Causes irritation.
Delayed Hazards
?br>
Diphenylmethane 4,4'-Diisocyanate 101-68-8
Lung tumors have been observed in laboratory animals exposed to
aerosol droplets of diphenylmethane 4,4'-diisocyanate (MDI)/polymeric
MDI (6 mg/m ) for their lifetime. Tumors occurred concurrently with
respiratory irritation and lung injury. This material has not been
listed by NTP, classified by IARC, nor regulated by OSHA as a
carcinogen.
May cause allergic skin and respiratory reactions.
Can cause lung damage. Pre-existing respiratory disorders may be
aggravated by exposure.
Polymeric Diphenylmethane Diisocyanate 9016-87-9
Lung tumors have been observed in laboratory animals exposed to
aerosol droplets of diphenylmethane 4,4'-diisocyanate (MDI)/polymeric
MDI (6 mg/m ) for their lifetime. Tumors occurred concurrently with
respiratory irritation and lung injury. This material has not been
listed by NTP, classified by IARC, nor regulated by OSHA as a
carcinogen.
May cause allergic skin and respiratory reactions.
Can cause lung damage. Pre-existing respiratory disorders may be
aggravated by exposure.
Modified Polymeric MDI
May cause allergic skin and respiratory reactions.
-- See Footnote C.
Footnote C: As of the date of issuance of this document, this
material has not been listed by NTP, classified by IARC nor regulated
by OSHA as a carcinogen.
4. First Aid Measures
INGESTION: If accidentally swallowed, dilute by drinking large
quantities of water. Immediately contact poison control
center or hospital emergency room for any other
additional treatment directions.
INHALATION: If inhaled, remove to fresh air. If not breathing
give artificial respiration, preferably mouth-to-mouth.
If breathing is difficult, give oxygen. Call a
physician.
SKIN: Immediately wash with soap and plenty of water for
at least 15 minutes while removing contaminated clothing
and shoes. Call a physician if symptoms occur. Wash
clothing and shoes before reuse.
EYES: Immediately flush eyes with plenty of water for at
least 15 minutes. Eyelids should be held apart during
irrigation to insure water contact with entire surface of
eyes and lids. Call a physician.
5. Fire Fighting Measures
Flash Point >250 deg F (121 deg C)
Will burn.
In case of fire, DO NOT use water. Use dry chemical or CO2.
6. Accidental Release Measures
Soak up with absorbent material and remove to a chemical disposal
area. Prevent entry into natural bodies of water.
7. Handling and Storage
7.1 Handling
Handle in accordance with good industrial hygiene and safety
practices. These practices include avoiding unnecessary exposure and
removal of the material from eyes, skin and clothing.
Wash thoroughly after handling. Always use appropriate Personal
Protective Equipment (PPE).
INHALATION: Do not breathe vapor. Use with adequate ventilation.
SKIN: Avoid contact with skin and clothing.
EYES: Avoid contact with eyes.
7.2 Storage
Keep container closed.
Keep from freezing.
Keep in tightly sealed containers and store in a cool dry place,
avoiding exposure to heat, light, moisture and air.
Store at 60-100 F (16-38 C).
8. Exposure Controls/Personal Protection
8.1 Exposure Controls
ENGINEERING CONTROLS: The following exposure control techniques may
be used to effectively minimize employee exposure: local exhaust
ventilation, enclosed system design, process isolation and remote
control in combination with appropriate use of personal protective
equipment and prudent work practices. These techniques may not
necessarily address all issues pertaining to your operations. We,
therefore, recommend that you consult with experts of your choice to
determine whether or not your programs are adequate.
If airborne contaminants are generated when the material is heated or
handled, sufficient ventilation in volume and air flow patterns should
be provided to keep air contaminant concentration levels below
acceptable criteria.
8.2 Personal Protection
Wear synthetic apron and boots if contact is likely. Where air
contaminants can exceed acceptable criteria, use NIOSH/MSHA approved
respiratory protection equipment. Respirators should be selected
based on the form and concentration of contaminants in air in
accordance with OSHA laws and regulations or other applicable
standards or guidelines, including ANSI standards regarding
respiratory protection. Use goggles and face shield if contact is
likely. Wear impervious gloves as required to prevent skin contact.
8.3 Exposure Guidelines
Diphenylmethane 4,4'-Diisocyanate 101-68-8
ACGIH TLV: 0.005 ppm (0.051 mg/m ) TWA
OSHA PEL: 0.02 ppm (0.2 mg/m ) Ceiling
Polymeric Diphenylmethane Diisocyanate 9016-87-9
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
Modified Polymeric MDI
ACGIH TLV: NONE ESTABLISHED
OSHA PEL: NONE ESTABLISHED
9. Physical and Chemical Properties
pH @ 25 C Not applicable
Specific Gravity 1.14
Appearance Viscous dark brown liquid
Boiling Point Not applicable
Vapor Density (Air=1) 8.5 approx.
Vapor Pressure, mm Hg @ 20 C <0.0003
Evaporation Rate (Butyl Acetate=1) Not available
Flash Point >250 deg F (121 deg C)
Melting point Not available
Odor Slightly musty
Odor Threshold, ppm 0.4 (4,4'-Diphenylmethane diisocyanate)
Solubility (other) Soluble in most organic solvents
Solubility in Water Reacts with water
10. Stability and Reactivity
Normally stable, but will react with water.
Incompatibilities:
?br>
Contact with water, alcohols, amines and alkalies causes
polymerization.
Decomposition products may include:
?br>
None known to company.
Hazardous polymerization:
?br>
May occur.
Other Hazards:
?br>
None known to company.
11. Toxicological Information
See Section 3 Hazards Identification information.
Diphenylmethane 4,4'-Diisocyanate 101-68-8
LC50: rat=178 mg/m (RTECS)
LD50: orl-mus=2200 mg/kg (RTECS)
Polymeric Diphenylmethane Diisocyanate 9016-87-9
LC50: rat=490 mg/m /4H (respirable aerosol)
LD50: orl-rat>5000 mg/kg; skn-rbt>5000 mg/kg
Modified Polymeric MDI
LC50: Not available
LD50: Not available
12. Ecological Information
Not determined.
13. Disposal Considerations
Recover free liquid. Absorb residue and dispose of according to
local, state/provincial, and federal requirements.
14. Transport Information
14.1 U.S. Department of Transportation (DOT)
The data provided in this section is for information only and may not
be specific to your package size. You will need to apply the
appropriate regulations to properly classify your shipment for
transportation.
Non-Regulated.
14.2 Canadian Transportation of Dangerous Goods (TDG)
Non-Regulated.
15. Regulatory Information (Selected Regulations)
15.1 U.S. Federal Regulations
OSHA Hazard Communication Standard
?br>
29CFR1910.1200
This material is a "health hazard" and/or a "physical hazard" as
determined when reviewed according to the requirements of the
Occupational Safety and Health Administration 29 CFR Part 1910.1200
"Hazard Communication" Standard.
SARA Title III: Section 311/312
?br>
Reactivity hazard
Immediate health hazard
Delayed health hazard
SARA Title III Section 313 and 40 CFR Part 372
?br>
This product contains the following toxic chemical(s) subject to the
reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986, and Subpart C-Supplier
Notification Requirement of 40 CFR Part 372.
Methylenebis(4-phenylisocyanate) (MDI) 101-68-8 28.00%
Polymeric Diphenylmethane Diisocyanate 9016-87-9 45.00%
TSCA Section 8(b) Inventory
?br>
All reportable chemical substances are listed on the TSCA Inventory.
We rely on certifications of compliance from our suppliers for
chemical substances not manufactured by us.
15.2 Canadian Regulations
Workplace Hazardous Materials Information System
?br>
(WHMIS)
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulation (CPR) and the MSDS
contains all the information required by the CPR.
CLASS D, DIV 1A
CLASS D, DIV 2A, 2B
Canadian Environmental Protection Act (CEPA)
?br>
All reportable chemical substances are listed on the Domestic
Substances List (DSL) or otherwise comply with CEPA new substance
notification requirements.
National Pollutant Release Inventory (NPRI)
?br>
This product contains the following chemical(s) subject to the
reporting requirements of the Canadian Environmental Protection Act
(CEPA) subsection 16(1), National Pollutant Release Inventory.
Methylenebis(phenylisocyanate) 101-68-8 28.00%
Polymeric Diphenylmethane Diisocyanate 9016-87-9 45.00%
16. Other Information
MSDS covers items:
U.S.: P9410, P9411, P9412, P9413
Canada:
HL (Cautions Required): Products bearing the HL Health Label
(Cautions Required) Seal of The Art & Creative Materials Institute,
Inc. (ACMI) are certified to be properly labeled in a program of
toxicological evaluation by a medical expert. This program is
reviewed by ACMI's Toxicological Advisory Board. These products are
certified by ACMI to be labeled in accordance with the chronic hazard
labeling standard, ASTM D-4236 and Federal Law, P.L. 100-695.
User's Responsibility
?br>
The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace
Hazardous Materials Information System (WHMIS) require that the information
contained on these sheets be made available to your workers. Educate and
train your workers regarding OSHA and WHMIS precautions. Instruct your
workers to handle this product properly. Consult with appropriate experts
to guard against hazards associated with use of this product and its
ingredients.
Disclaimer
?br>
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE
MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product
shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind
shall be greater in amount than the purchase price of the quantity of
product in respect of which damages are claimed. In no event shall Seller
be liable for incidental or consequential damages, whether Buyer's claim is
based on contract, breach of warranty, negligence or otherwise.
CUR ISSUE 01-APR-03
PREVIOUS ISSUE: 01-APR-03
NEW Rapid Tap Page 1
Page 1
NFPA
Fire HMIS
1 Health 1
Health 1
1 Reactivity
MATERIAL SAFETY DATA SHEET Fire 1
Reactivity 1
Meets requirements of 29 CFR 1910.1200
(Federal Hazard Communication Standard)
SECTION I
MANUFACTURER'S NAME: PRODUCT NAME OR NUMBER:
NEW Rapid Tap?br>
RELTON CORPORATION
317 ROLYN PLACE CHEMICAL NAME & SYNONYMS:
Predominantly Chlorinated Paraffin
ARCADIA, CA 91007-2838
CHEMICAL FAMILY:
EMERGENCY RESPONSE for spill, leak, exposure, etc:
Chlorinated Paraffin
Chemtrec - (800) 424-9300
FORMULA:
For non-emergency product information:
Mixture (see Section II)
Relton Corp - (323) 681-2551 (800) 423-1505
SECTION II COMPONENTS
TLV PEL STEL C.A.S. NO. % wt.
Paraffin, chlorinated NE NE NE 61788-76-9 < 40
5 mg/m3 5 mg/m3
Mineral Oil NE 64742-58-1 < 50
5 mg/m3 10 mg/m3
Metal-Cutting-Fluid Additive NE Trade secret <8
Soybean Oil, epoxidized NE NE NE 8013-07-8 >1
5 mg/m3 5 mg/m3
Olefin Sulfide NE Trade secret <1
Cinnamon Oil Perfume NE NE NE -- -- trace
SECTION III - PHYSICAL DATA
Data is based upon testing mixture as a whole.
BOILING POINT ( X篎 ) ( C?): 450?F SPECIFIC GRAVITY ( H2O=1 ) @ 25?C: 1.02 Freezing Point: -20?F
VAPOR PRESSURE ( mm Hg ): NF PERCENT VOLATILE BY VOLUME ( % ): NA VOC: Negligible
VAPOR DENSITY ( AIR=1 ): NF EVAPORATION RATE ( WATER=1 ): Slower than water
SOLUBILITY IN WATER: < .2% pH: NA
APPEARANCE AND ODOR: light amber color; slight, sweet odor MATERIAL IS LIQUID
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Data is based upon testing mixture as a whole.
350?F COC FLAMMABLE LIMITS: LFL UFL
FLASH POINT ( method used ):
Non-Flammable ND ND
EXTINGUISHING MEDIA: Carbon Dioxide, Foam, Dry Chemical, Water, Fog
SPECIAL FIRE FIGHTING PROCEDURES:
Self-contained breathing apparatus with full facepiece in a pressure-demand mode; full-body protective clothing. Treat as oil fire
UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustion can produce acid gases (hydrogen chloride, hydrogen sulfide)
Exposing containers to intense heat could cause drums to rupture. Cool fire-exposed containers with water spray to prevent rupture
SECTION V - HEALTH HAZARD DATA
ROUTES OF ENTRY & SYMPTOMS OF OVEREXPOSURE:
Eyes and skin: may cause mild irritation. Inhalation: may cause mild upper respiratory irritation. Ingestion: possible nausea.
EMERGENCY AND FIRST AID PROCEDURES:
Eyes: flush for 15 min. with water. Skin: wash with soap and water. Inhalation: remove to fresh air.
Ingestion: do not induce vomiting; give lots of water to a conscious person. Call Doctor
NE=not established NF=not found NA=not applicable ND=not determined
NEW Rapid Tap
Page 2 Page 2
SECTION VI - REACTIVITY DATA
STABILITY UNSTABLE CONDITIONS TO AVOID:
STABLE X Elevated temperatures produce decomposition
INCOMPATIBILITY (materials to avoid): Strong oxidizing and reducing agents, strong alkalies. Iron and zinc catalyze deterioration
HAZARDOUS DECOMPOSITION PRODUCT: Combustion can produce carbon-dioxide and monoxide, hydrogen chloride,
incompletely burned hydrocarbon products, oxides of sulfur & nitrogen, aldehydes, & traces of hydrogen sulfide.
HAZARDOUS MAY OCCUR CONDITIONS TO AVOID:
POLYMERIZATION: WILL NOT OCCUR X NA
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Clean up promptly by vacuum or absorbent material. Prevent
discharge to streams or sewage systems; report if required.
WASTE DISPOSAL METHOD: Transport in DOT-approved container to EPA-approved treatment, storage, and disposal facility.
Follow local, State & Federal disposal regulations.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (specify type): Normally not needed. For oil-type mist, use NIOSH-listed respirator.
VENTILATION: LOCAL EXHAUST (Specify Rate): SPECIAL: Not required normally
Local-mechanical Adequate to avoid fumes and oil mists
MECHANICAL (General) (Specify Rate): OTHER:
PROTECTIVE GLOVES: Freshly washed cotton or rubber, nitrile EYE PROTECTION: Chemical goggles or full faceshield
OTHER PROTECTIVE EQUIPMENT: Clean clothes Apron or chemical suit where splashing may occur
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in a dry place. Vent vapors to open area if stored above 100篎.
Don't store near food or in zinc or iron containers.
OTHER PRECAUTIONS: Chlorinated Paraffin will darken at elevated temperatures. Avoid mist and vapor; use with adequate
ventilation & exhaust of work area.
ADDITIONAL INFORMATION
DOT: No hazardous substance UN or NA#: Not applicable
No hazard class Freight Classification: Chlorinated paraffin
It# 155250 Class 65 No DOT ID#
SARA: Not considered to be subject to Title III
TSCA: All components required to be listed on the inventory are listed.
IARC-NTP-OSHA: Neither the mixture nor any component is listed as a carcinogen or suspected carcinogen.
Ozone-Depleting Substance: No 1,1,1-Trichloroethane (methyl chloroform) or other ozone-depleting substance
No 5/15/93 labeling required
California Prop. 65 Material: None
Note: Although no exposure limits are established, observe ACGIH-OSHA TWA for oil mists: 5Mg/meter3.
Use with adequate local ventilation and exhaust devices.
Prepared: 2/24/93 Updated: 11/07/94
Updated: 3/04/93 Updated: 11/04/96
Updated: 7/15/93 Updated: 07/25/97
Updated: 02/29/00 Updated: 07/22/05
317 ROLYN PLACE, ARCADIA, CALIFORNIA 91007-2838
Phone: (323) 681-2551 (800) 423-1505
Emerg: Chemtrec - (800) 424-9300
by Dr. Robert E. Pratt,
consulting chemist
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 01 of 05
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: Loctite Epoxy Gel
Item number: Resin (A) Part of kit: 01-32427
Product Type: Epoxy resin
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS Number % Exposure Limits
Epoxy resin Proprietary 40-100 Not established.
Epoxy resin Proprietary 40-100 Not established.
Silica, amorphous, 112945-52-5 1-5 6 mg/m3 ACGIH TLV TWA
fumed crystalline-free 10 mg/m3 ACGIH TWA OSHA PEL
3 mg/m3 TWA respirable dust
3. HAZARDS IDENTIFICATION
****EMERGENCY OVERVIEW****
PHYSICAL STATE:Liquid. COLOR:Clear.
WARNING! MAY CAUSE ALLERGIC SKIN REACTION.
MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE EYE, SKIN, AND RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Eye:
Moderate eye irritation. Redness. Excess tearing.
Skin:
Allergic skin reaction. Itching. Rash. Moderate skin irritation.
Redness.
Ingestion:
May be harmful if swallowed.
Inhalation:
Mild respiratory tract irritation. May cause irritation to nose and throat.
Vapors may cause headaches, nausea, dizziness and respiratory tract
irritation.
Conditions Aggravated by Exposure:
Respiratory disorders. Skin disorders. Eye disorders. Skin allergies.
Chronic:
Detailed information provided in section 11.
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Loctite Epoxy Gel
Item No.: Resin (A) 01-32427
4. FIRST AID MEASURES
Eye:
Immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention.
Skin:
Immediately flush skin with plenty of water (using soap, if available)
for at least 15 minutes. Remove contaminated clothing and shoes. Wash
clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention if symptoms occur.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Get medical
attention.
Inhalation:
Remove to fresh air. If symptoms develop and persist, get medical
attention.
Note to Physician:
None.
5. FIRE FIGHTING MEASURES
Flash Point:
CLOSED CUP : Greater than 149篊 (300篎)
Extinguishing Media:
In case of fire, use water spray (fog), foam, dry chemicals, or CO2.
Flammable Limits:
Not available.
Special Fire Fighting Procedures:
Fire fighters should wear positive pressure self-contained breathing
apparatus (SCBA) and full turnout gear.
Hazardous Combustion Products:
Oxides of carbon. Aldehydes. Phenolics. Irritating organic fragments.
Unusual Fire or Explosion Hazards:
None.
6. ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak:
Soak up with inert absorbent. Store in closed container until
disposal.
7. HANDLING AND STORAGE
Handling:
Do not swallow. Avoid contact with eyes. Avoid breathing vapor or
mist. Avoid contact with skin and clothing. Wash thoroughly after
handling.
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Loctite Epoxy Gel
Item No.: Resin (A) 01-32427
Storage:
Keep container tightly closed. Keep in a cool and well-ventilated
area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls:
Use local exhaust ventilation if the potential for airborne exposure
exists.
Eye/Face Protection:
Chemical splash goggles or safety glasses with side shields.
Skin Protection:
Use chemical resistant, impermeable gloves.
Respiratory Protection:
Use NIOSH approved respirator if there is potential to exceed any
exposure limit(s).
See Section 2 COMPOSITION/INFORMATION ON INGREDIENTS for exposure limits
9. PHYSICAL AND CHEMICAL PROPERTIES
Color: Translucent clear.
Material State: Liquid.
Odor: None.
Boiling point: Greater than 149篊 (300篎)
pH: Not applicable.
Solubility in Water: slight
Specific gravity: 1.12
VOC: 0.113 g/l (value of resin and hardener together)
Vapor Pressure: Less than 5 mm Hg at 26.7篊 (80篎)
Vapor density: >1 (Air = 1)
Evaporation Rate: <1 compared to Butyl acetate.
10. STABILITY AND REACTIVITY
Stability:
Stable.
Conditions to Avoid:
Excessive heat. Storage with incompatible materials.
Incompatibility:
Strong acids. Strong Bases. Strong oxidizers. Amines. Mercaptans.
Hazardous Polymerization:
Will not occur.
Hazardous Decomposition Products:
None known
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Loctite Epoxy Gel
Item No.: Resin (A) 01-32427
11. TOXICOLOGY INFORMATION
Product Toxicology Data:
Not available.
Carcinogen
Ingredient NTP IARC OSHA
Epoxy resin No No No
Epoxy resin No No No
Silica, amorphous No No No
Key to abbreviations:
Not applicable.
Ingredient Health Effects/Target organs
Epoxy resin Allergen. Irritant.
Epoxy resin Allergen. Irritant.
Silica, amorphous Nuisance dust.
12. ECOLOGICAL INFORMATION
Ecological Information:
None known
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal:
Dispose according to EPA and local governmental regulations.
EPA Hazardous Waste Number:
Material as supplied is non-hazardous under RCRA (U.S. Federal)
regulations.
14. TRANSPORTATION INFORMATION
Domestic Transportation (D.O.T. 49 CFR)-GROUND
Shipping Description:
Not regulated.
Exceptions:
Not applicable.
International Air Transportation (ICAO/IATA)-
Shipping description:
Not regulated.
Exceptions:
Not applicable.
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Loctite Epoxy Gel
Item No.: Resin (A) 01-32427
Marine pollutant:
None known
15. REGULATORY INFORMATION
SARA Title III Section 313 Chemicals:
None.
SARA Title III Section 311/312:
Immediate health hazard.
Toxic Substances Control Act:
All components are listed on or are exempt from listing on the Toxic
Substances Control Act Inventory.
TSCA Section 12(b) annual:
None.
TSCA Section 12(b) one time:
None.
Canadian Inventory Status:
All components are listed on or are exempt from listing on the Canadian
Domestic Substances List.
California Proposition 65:
No California Proposition 65 listed chemicals are know to be present.
16. OTHER INFORMATION
HMIS Code:
Health: 2
Flammability: 1
Reactivity: 0
Protective Equipment: See Section 8.
Prepared by:
Company: Regulatory Affairs
(24hr.) Phone: (440) 937-7000
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 01 of 06
1. PRODUCT AND COMPANY IDENTIFICATION
Product name: Loctite Epoxy Gel
Item number: Hardener (B) Part of kit: 01-32427
Product Type: Epoxy hardener
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS Number % Exposure Limits
Polymercaptan hardener Proprietary 60-100 None
N-(2-Aminoethyl)piperazine 140-31-8 5-10 None
Triethylaminetetramine 112-24-3 5-10 None
Phenol, 2,4,6- tris[(di-
methylamino)methyl] 90-72-2 5-10 None
Silica, amorphous, 112945-52-5 1-5 6 mg/m3 ACGIH TLV TWA
fumed crystalline-free 10 mg/m3 ACGIH TWA OSHA PEL
3 mg/m3 TWA respirable dust
Aminoethylethanolamine 111-41-1 1-5 None
Heptakis(dipropylene-
glycol)triphosphate 13474-96-9 1-5 None
Diethylaminetriamine 111-40-0 1-5 1 ppm ACGIH TWA (skin)
3. HAZARDS IDENTIFICATION
****EMERGENCY OVERVIEW****
PHYSICAL STATE:Liquid. COLOR:Opaque. ODOR: None.
DANGER! CAUSES EYE AND SKIN BURNS.
MAY BE HARMFUL IF ABSORBED THROUGH SKIN.
MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
Potential Health Effects
Eye:
Causes eye burns. Severe eye irritation. Redness. Tissue damage.
Skin:
May cause skin burns. Allergic skin reaction. Harmful if absorbed through
skin. Rash. Redness. Tissue damage.
Ingestion:
May be harmful if swallowed. May cause burns of mouth and throat if
swallowed.
Inhalation:
Allergic respiratory reaction. May cause respiratory tract irritation. May
cause irritation to nose and throat. Lung damage. Respiratory tract burns.
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 02 of 06
Product Name: Loctite Epoxy Gel
Item No.: Hardener (B) 01-32427
Conditions Aggravated by Exposure:
Respiratory disorders. Skin disorders. Eye disorders. Asthma.
Chronic:
Detailed information provided in section 11.
4. FIRST AID MEASURES
Eye:
Immediately flush eyes with plenty of water for at least 15 minutes.
Get medical attention.
Skin:
Immediately flush skin with plenty of water (using soap, if available)
for at least 15 minutes while removing contaminated clothing and shoes.
Immediately flush skin with plenty of water (using soap, if available).
Remove contaminated clothing and shoes. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention
immediately.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Get medical
attention.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Get medical attention.
Note to Physician: None.
5. FIRE FIGHTING MEASURES
Flash Point:
CLOSED CUP : Greater than 200F (93C). Tagliabue.
In case of fire, use water spray (fog), foam, dry chemicals, or CO2.
Extinguishing Media:
Flammable Limits:
Not available.
Special Fire Fighting Procedures:
Fire fighters should wear positive pressure self-contained breathing
apparatus (SCBA) and full turnout gear.
Hazardous Combustion Products:
Oxides of nitrogen. Oxides of carbon. Ammonia. Amines. Nitric acid.
Nitrosamines. Irritating organic fragments.
Unusual Fire or Explosion Hazards:
Avoid the use of a stream of water to control fires since frothing may
occur. Closed containers may rupture (due to build up of pressure)
when exposed to extreme heat. Use water spray cautiously to keep
fire-exposed containers cool.
6. ACCIDENTAL RELEASE MEASURES
In Case of Spill or Leak:
Soak up with inert absorbent. Store in closed container until
disposal.
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 03 of 06
Product Name: Loctite Epoxy Gel
Item No.: Hardener (B) 01-32427
7. HANDLING AND STORAGE
Handling:
Do not swallow. Do not get on skin. Avoid contact with eyes, skin,
and clothing. Do not breathe vapor or mist. Do not get in eyes. Keep
container closed. Use only with adequate ventilation. Wash thoroughly
after handling.
Storage:
Keep container tightly closed. Keep in a cool and well-ventilated
area.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls:
Use local exhaust ventilation if the potential for airborne exposure
exists.
Eye/Face Protection:
Chemical splash goggles or safety glasses with side shields. Full face
shield should be used if the potential exists for splashing or spraying
of product.
Skin Protection:
Use chemical resistant, impermeable clothing including gloves and
either an apron or body suit to prevent skin contact. Butyl gloves.
Neoprene gloves. Nitrile gloves.
Respiratory Protection:
Use NIOSH approved respirator if there is potential to exceed any
exposure limit(s).
See Section 2 COMPOSITION/INFORMATION ON INGREDIENTS for exposure limits
9. PHYSICAL AND CHEMICAL PROPERTIES
Color: Opaque.
Material State: Liquid.
Odor: None.
Boiling point: Greater than 300篎 (149篊)
pH: Not applicable.
Solubility in Water: Not available
Specific gravity: 1.04
VOC: 0.113 g/l (value for resin and hardener together)
Vapor Pressure: Less than 5 mm Hg at 20 篊 (68篎)
Vapor density: >1 (Air = 1)
Evaporation Rate: <1 compared to Butyl acetate.
10. STABILITY AND REACTIVITY
Stability:
Stable.
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 04 of 06
Product Name: Loctite Epoxy Gel
Item No.: Hardener (B) 01-32427
Conditions to Avoid:
None known
Incompatibility:
Oxidizing agents, Alkalis. Chlorinated rubber. Reaction with epoxy
resins and isocyanates in large amounts or under uncontrolled
conditions releases considerable heat and may release acrid fumes.
Hazardous Polymerization:
Will not occur.
Hazardous Decomposition Products:
None known
11. TOXICOLOGY INFORMATION
Product Toxicology Data:
Not available.
Carcinogen
Ingredient NTP IARC OSHA
Polymercaptan hardener No No No
N-(2-Aminoethyl)piperazine No No No
Triethylaminetetramine No No No
Phenol, 2,4,6- tris[(di-
methylamino)methyl] No No No
Silica, amorphous,
fumed crystalline-free No No No
Aminoethylethanolamine No No No
Heptakis(dipropylene-
glycol)triphosphate No No No
Diethylaminetriamine No No No
Ingredient Health Effects/Target organs
Polymercaptan hardener Not available.
N-(2-Aminoethyl)piperazine Irritant
Triethylaminetetramine Allergen, Developmental, Irritant, Mutagen
Phenol, 2,4,6- tris[(di-
methylamino)methyl] Allergen, Irritant
Silica, amorphous,
fumed crystalline-free Nuisance dust.
Aminoethylethanolamine Allergen, Irritant
Heptakis(dipropylene-
glycol)triphosphate No data
Diethylaminetriamine Allergen, Eyes, Irritant
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 06 of 06
Product Name: Loctite Epoxy Gel
Item No.: Hardener (B) 01-32427
12. ECOLOGICAL INFORMATION
Ecological Information:
None known
13. DISPOSAL CONSIDERATIONS
Recommended Method of Disposal:
Dispose according to EPA and local governmental regulations.
EPA Hazardous Waste Number:
Material as supplied is non-hazardous under RCRA (U.S. Federal)
regulations.
14. TRANSPORTATION INFORMATION
Domestic Transportation (D.O.T. 49 CFR)-GROUND
Shipping Description:
Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine /
aminoethylpiperzine) Class 8 UN 3267 PG II
Exceptions:
(Not more than one litre) Consumer Commodity ORM-D
International Air Transportation (ICAO/IATA)-
Shipping description:
Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine /
aminoethylpiperzine) Class 8 UN 3267 PG II
Water Transportation (IMO/IMDG)
Shipping description:
Corrosive liquid, basic, organic, n.o.s. (Triethylenetetramine /
aminoethylpiperzine) Class 8 UN 3267 PG II
Marine pollutant:
Nonylphenol
15. REGULATORY INFORMATION
SARA Title III Section 313 Chemicals:
None above the reporting minimus.
SARA Title III Section 311/312:
Immediate health hazard.
HENKEL CONSUMER ADHESIVES 05/15/06
AVON, OH 44011
TELEPHONE: (440) 937-7000
MATERIAL SAFETY DATA SHEET Page 05 of 05
Toxic Substances Control Act:
All components are listed on or are exempt from listing on the Toxic
Substances Control Act Inventory.
TSCA Section 12(b) annual:
None.
TSCA Section 12(b) one time:
None.
Canadian Inventory Status:
All components are listed on or are exempt from listing on the Canadian
Domestic Substances List.
WHMIS hazard class: E, D2A, D2B
California Proposition 65:
This product contains a chemical know to the State of California to cause
cancer.
16. OTHER INFORMATION
HMIS Code:
Health: 3
Flammability: 1
Reactivity: 1
Protective Equipment: See Section 8.
Prepared by:
Company: Regulatory Affairs
(24hr.) Phone: (440) 937-7000
page 1 of 3 December 21, 1999
STICK EASE SEAM ADHESIVE 209454
___________________________________________________________
MATERIAL SAFETY DATA SHEET
________________________________________________________________
Section 1
________________________________________________________________
Manufacturer's Name: Emergency Assistance:
Roman Adhesives,Inc. 1-800-488-6117
824 State Street HMIS Hazard Rating:
Calumet City, Illinois 60409
FIRE=0 Least=0
HEALTH=1 Slight=1
REACTIVITY=1 Moderate=2
Date: Mar 29, 1995 PERSONAL PROTECTION=B High=3
Revised: Sep 28, 1999 Extreme=4
_________________________________________________________________
Trade name and Synonyms:
STICK EASE SEAM ADHESIVE 209454
Chemical Name and Synonyms: Copolymer adhesive
Chemical Family: Synthetic resin emulsion
______________________________________________________________
Section 2-Hazardous Ingredients/Identity Information
_________________________________________________________________
CAS No. Chemical Name(s) OSHA PEL ACGIH TLV max %
No Hazardous Ingredients
__________________________________________________________________
Section 3-Physical/Chemical Characteristics
__________________________________________________________________
Appearance and Odor: Opaque white liquid, slight acrid odor
Specific Gravity(water=1): 1.07
Percent Solids by Weight:
by Volume:
Solubility in Water: Miscible in all proportions
Boiling Point: 212F
Vapor Density: Same as water
Vapor Pressure: Same as water
Evaporation Point: Same as water
Melting Point: n.a.
Volatile Organic Compounds (VOC, less water): max 50 g/l; 0.42
lb/gal
_______________________________________________________________
Section 4-Fire and Explosion Hazard Data
________________________________________________________________
Flash Point(methods used) n.a.
Extinguishing Methods:
Special Fire Fighting Procedures:
Self contained breathing apparatus should be worn in fighting
all fires involving general chemicals.
Unusual Fire and Explosion Hazards: None
___________________________________________________________________
Section 5-Health Hazard Data
________________________________________________________________
Carcinogenicity: NTP:no IARC:no OSHA regulated: no
page 2 of 3 December 21, 1999
STICK EASE SEAM ADHESIVE 209454
Overexposure--Under current OSHA criteria this product is
considered non-hazardous.
Emergency First Aid Procedures
Eyes- Flush with water for 15 minutes, seek medical attention
Skin- Wash from skin at first opportunity.
Inhalation- No hazardous volatiles
Ingestion- Give water to drink if conscious, seek medical
attention. Do not give anything by mouth to an unconscious person.
________________________________________________________________
Section 6-Reactivity Data
________________________________________________________________
This product is stable and compatible with all compounds that
are compatible with water and water solutions. Hazardous
polymerization does not occur.
____________________________________________________________
Section 7-Precautions for Safe Handling and Use
_______________________________________________________________
Steps to be taken in case the product is released or spilled:
Small spills of 1-2 gallons or less may be diluted 50:1 with
water and washed down the drain.
Large spills should be recovered as much as possible and
disposed of as non-hazardous liquid waste. Consult Federal, State
and Local regulations. Spilled adhesive may present a slip hazard
and personnel should be cautious during cleanup.
___________________________________________________________________
Section 8-Control Measures
_________________________________________________________________
Respiratory protection is not usually required, however any
room where this product is used should have good ventilation,i.e.,
open windows, exhaust fans, etc. A good, normal precaution is to
wear protective gloves and glasses. No other protection equipment
isnecessary.
___________________________________________________________________
Section 9- Special Precautions
_______________________________________________________________
Store at moderate temperatures (50-100 F). Protect from
freezing. Keep out of the reach of children. Keep container closed
when not in use.
_______________________________________________________________
SUPPLEMENTAL INFORMATION
_______________________________________________________________
Waste Disposal
This product can handled as a non-hazardous industrial waste.
________________________________________________________________
REGULATORY INFORMATION
_________________________________________________________________
Workplace Classifications
This product is considered non-hazardous under the OSHA
Hazard Communication Standard ( 29CFR 1910.1200 ).
This product is not a "controlled product" under the Canadian
Environmental Act.
page 3 of 3 December 21, 1999
STICK EASE SEAM ADHESIVE 209454
Workplace Hazardous Materials Information System (WHMIS).
_______________________________________________________________
Transportation Classifications
US DOT Shipping Class --- 60
US DOT Description --- Adhesive Paste NOI
_________________________________________________________
Emergency Planning and Community Right to Know ( SARA Title 3 )
Section 311/312 Categorizations ( 40CFR 370 )
This product is not a hazardous chemical under 29CFR
1910.1200, and therefore is not covered by Title III of SARA.
Section 313 Information (40CFR 372 )
This product does not contain a chemical which is listed
in Section 313 above de minimis concentrations.
______________________________________________________________
CERCLA Information ( 40CFR 302.4 )
Releases of this material to air, land or water are not
reportable to the National Response Center under the Comprehensive
Environmental Response, Compensation and Liability Act or to state
and local emergency planning committees under the Superfund
Amendments and Reauthorization Act, Title III Section 304.
_______________________________________________________________
RCRA Information
When this product becomes a waste, it is classified as a
non-hazardous waste under criteria of the Resource Conservation
and Recovery Act (40CFR 261).
__________________________________________________________________
Chemical Control Law Status
All components of this product are listed on the US-EPA
Toxic Substance Control Act (TSCA) Chemical Substance Inventory.
All components of this product are listed on the Canadian
Environmental Protection Act Domestic Substances List
(CEPA-DSL).
___________________________________________________________________
Material Safety Data Sheet
PC METAL EPOXY PUTTY MSDS No. 50505-08
Date of Preparation: 5-5-2005 Revision: 6
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: PC METAL EPOXY PUTTY
Chemical Formula: Mixture
CAS Number: Mixture
General Use: Adhesive
Manufacturer: Protective Coating Company, 221 S. Third St., Allentown, PA 18102-4922, Phone (610)432-3543, FAX
(610)432-5043 (9AM-5PM EST).
Section 2 - Composition / Information on Ingredients
Ingredient Name CAS Number %
Bisphenol A Epoxy Resin 25068-38-6 10 ?30
Tri(dimethylaminomethyl)phenol 90-72-2 0.5 ?1.5
Crystalline silica 14808-60-7 7 ?3
OSHA PEL ACGIH TLV NIOSH REL NIOSH
Ingredient TWA STEL TWA STEL TWA STEL IDLH
Bisphenol A Epoxy
resin None estab. None estab. None estab. None estab. None estab None estab. None estab.
Tri(dimethylamino
methyl)phenol None estab. none estab. None estab. none estab. None None estab. None estab.
estab.
Crystalline silica 0.10 mg/m3 none estab. none estab. 0.10 mg/m3 none estab. None estab. none estab.
Section 3 - Hazards Identification
HMIS
Emergency Overview H1
1
F
Warning! Respirable crystalline silica (quartz) is classified as a probable carcinogen. The crystalline silica present 0
R
in this product is encapsulated in the epoxy resin and could only be liberated by sanding or abrading, and then not PPEB
as pure crystalline silica. Appropriate precautions, however, should be taken, if the product is sanded or abraded Sec. 8
to preclude personnel from breathing the dust.
Potential Health Effects
Acute Effects
Inhalation: None.
Eye: Possible irritant and sensitizer.
Skin: Possible irritant and sensitizer.
Ingestion: Irritation of intestinal tract.
Section 4 - First Aid Measures
Inhalation: Remove to fresh air.
Eye Contact: Flush with water, consult a physician.
Skin Contact: Wash with soap and water.
Ingestion: Seek medical advice
Section 5 - Fire-Fighting Measures
NFPA
Flash Point: N/A.
Flammability Classification: IIIB
1
Extinguishing Media: Water spray, foam, CO2, dry chemicals.
0
1
Hazardous Combustion Products: CO, Aldehydes, acids, oxides of sulfur and nitrogen may be formed.
--
Fire-Fighting: Fire fighters and others who may be exposed to the products of combustion should be
equipped with NIOSH- approved positive pressure self contained breathing apparatus (SCBA)
and full protective clothing.
MSDS No. 50505-08 PC METAL EPOXY PUTTY Revision: 6
Section 6 - Accidental Release Measures
Spill /Leak Procedures: Dispose of in normal manner.
Disposal: Incinerate in furnace of bury in landfill according to applicable regulations; not a hazardous waste.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions: None.
Storage Requirements: Storage temperature: <90癋(32癈). Store in a cool, dry, well ventilated area.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 8 - Exposure Controls / Personal Protection
Ventilation: Provide general or local exhaust ventilation systems if product is sanded or ground.
Respiratory Protection: Follow OSHA respirator regulations (29 CFR 1910.134) and, if necessary, wear a MSHA/NIOSH-
approved respirator.
Protective Clothing/Equipment: Wear chemically protective gloves to prevent skin contact. Wear protective eyeglasses or
chemical safety goggles.
Section 9 - Physical and Chemical Properties
Form: Putty. % Volatile: < 1%
Specific Gravity (H2O=1, at 4 癈): 2.18
Appearance: Aluminum stick.
Odor: Mercaptan. VOC: <1%
Solubility (in water): insoluble in water. pH: >8
Section 10 - Stability and Reactivity
Stability: PC METAL EPOXY PUTTY is stable.
Polymerization: Hazardous polymerization cannot occur.
Section 11- Toxicological Information
Toxicity Data:
Lethal Dose Information(mg/kg) Oral Skin Inhale LC50
Bisphenol A Epoxy Resin 11400.00 rat 20000 rabbit No data No data
1350.00 rabbit
Tri(dimethylaminomethyl)phenol 1635.00 rat No data No data
estimated
Crystalline silica No data No data No data No data
Section 12 - Ecological Information
Ecotoxicity: No data.
Environmental Fate: No data.
Environmental Degradation: No data.
Section 13 - Disposal Considerations
Disposal: Incinerate in furnace of bury in landfill according to applicable regulations; not a hazardous waste.
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Not regulated. Packing Group: Not determined.
Shipping Symbols: Not Label: Not required.
applicable. Special Provisions (172.102):
Hazard Class: Non hazardous. None.
ID No.: Not applicable.
Page 2 of 3
Revision: 6 PC METAL EPOXY PUTTY MSDS No. 50505-08
Section 15 - Regulatory Information
EPA Regulations:
RCRA Hazardous Waste Number: Not listed (40 CFR 261.33)
RCRA Hazardous Waste Classification (40 CFR 261.??): Not classified
CERCLA Hazardous Substance (40 CFR 302.4) unlisted specific per RCRA, Sec. 3001; CWA, Sec. 311 (b)(4); CWA, Sec.
307(a), CAA, Sec. 112
CERCLA Reportable Quantity (RQ), Not listed.
SARA 311/312 Codes: None.
SARA Toxic Chemical (40 CFR 372.65): Not listed.
SARA EHS (Extremely Hazardous Substance) (40 CFR 355): Not listed.
OSHA Regulations:
Air Contaminant (29 CFR 1910.1000, Table Z-1, Z-1-A): Not listed
OSHA Specifically Regulated Substance, none
Right-to-know: The non-hazardous ingredients in this product subject to the Pennsylvania, New Jersey, and/or Massachusetts
right-to-know laws are:
CAS NAME
144807-96-6 Magnesium Silicate Hydrate
Trade Secret Polyether Polymercaptan
65997-17-3 Soda Lime Borosilicate Glass
7439-89-6 Iron/silicon/titanium/aluminum alloy
Section 16 - Other Information
Storage Requirements: Storage temperature: <90癋(32癈). Store in a cool, dry, well ventilated area.
Personal Hygiene: Wash thoroughly after handling, especially before eating, drinking, smoking, and using restroom facilities.
Wash contaminated goggles, faceshield, and gloves.
Prepared By: Charles Moloney
Revision Notes:
Disclaimer: The above information is given in good faith. No warranty expressed or implied is made.
Page 3 of 3
|-------------------------------------------------------|
| MATERIAL SAFETY DATA SHEET |
|-------------------------------------------------------|
|-------------------------------------------------------------------------|
| SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION |
|-------------------------------------------------------------------------|
THIS MSDS IS OFFERED IN CANADIAN-FRENCH UPON REQUEST.
ON PEUT DEMADER CETTE MSDS A LA ALNGUE FRANCAISE-CANADIENNE.
PRODUCT NAME : 3.2.1 SPACKLE WITH DRYDEX
UPC NUMBER : 7079812326, 7079812328, 7079812330, 7079871160,
7079871164
PRODUCT USE/CLASS : Latex Spackling
MANUFACTURER:
DAP INC. DAP CANADA CORP.
2400 BOSTON STREET 475 FINCHDENE SQUARE UNIT 5
BALTIMORE, MD 21224 SCARBOROUGH, ONTARIO M1X 1B7
24 HOUR EMERGENCY:
TRANSPORTATION: 1-800-535-5053 (352-323-3500)
MEDICAL : 1-800-327-3874 (513-558-5111)
PREPARE DATE : 06/17/1999 GENERAL INFORMATION:
REVISION NO. : 1 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477)
REVISION DATE: 05/15/2000
|-------------------------------------------------------------------------|
| SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS |
|-------------------------------------------------------------------------|
WT/WT %
ITEM ------------ CHEMICAL NAME ------------- CAS NUMBER RANGE
---------------------------------------------------------------------------
01 Calcium Carbonate 1317-65-3 65.0-70.0 %
02 Crystalline silica 14808-60-7 0.1-1.0 %
03 Polygorskite (Attapulgite) 12174-11-7 1.0-5.0 %
---------------------- EXPOSURE LIMITS --------------------
ACGIH OSHA COMPANY
ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN
---------------------------------------------------------------------------
01 10 mg/m3 N.E. 15 mg/m3 N.E. N.E. NO
02 .05 mg/m3 N.E. 0.1 mg/m3 N.E. N.E. NO
03 N.E. N.E. N.E. N.E. N.E. NO
(See Section 16 for abbreviation legend)
Remaining ingredients are not considered hazardous per the OSHA Hazard
Communication Standard.
Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor
OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states.
(Continued on Page 2)
---------------------------------------------------------------------------
Product Name: 3.2.1 SPACKLE WITH DRYDEX
Revision Date: 05/15/2000 Page 2
|-------------------------------------------------------------------------|
| SECTION 3 - HAZARDS IDENTIFICATION |
|-------------------------------------------------------------------------|
EMERGENCY OVERVIEW: CAUTION! Removal of this product after use will result
in the generation of dust. If dry-sanded, exposure to dust may result in
build-up of material in eyes, ears, nose, and mouth which may cause
irritation.
POTENTIAL HEALTH EFFECTS:
EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May dry skin.
EFFECTS OF OVEREXPOSURE - INHALATION: Vapor may irritate nose and upper
respiratory tract.
EFFECTS OF OVEREXPOSURE - INGESTION: None known.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Inhalation of dust may
result in pulmonary and respiratory damages. Prolonged or repeated
inhalation of dust may cause lung damage. Crystalline silica dust and
Polygorskite fibers are considered a suspect human carcinogen by the IARC.
Risk to one's health depends on level and duration of exposure.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: Asthma and
asthma-like conditions may worsen from prolonged and repeated exposure.
PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION
|-------------------------------------------------------------------------|
| SECTION 4 - FIRST AID MEASURES |
|-------------------------------------------------------------------------|
EYE CONTACT: Flush with large quantities of water until irritation
subsides.
SKIN CONTACT: Wash with soap and water.
INHALATION: Remove to fresh air.
INGESTION: DO NOT INDUCE VOMITING.
COMMENTS: Call 1-800-327-3874 if irritation persists or complications
arise from any of the above exposure.
|-------------------------------------------------------------------------|
| SECTION 5 - FIRE FIGHTING MEASURES |
|-------------------------------------------------------------------------|
FLASH POINT: >200 F LOWER EXPLOSIVE LIMIT: N.A.
(SETAFLASH CLOSED CUP) UPPER EXPLOSIVE LIMIT: N.A.
(Continued on Page 3)
---------------------------------------------------------------------------
Product Name: 3.2.1 SPACKLE WITH DRYDEX
Revision Date: 05/15/2000 Page 3
|-------------------------------------------------------------------------|
| SECTION 5 - FIRE FIGHTING MEASURES |
|-------------------------------------------------------------------------|
AUTOIGNITION TEMPERATURE:
EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.
SPECIAL FIREFIGHTING PROCEDURES: Use water spray to cool exposed surfaces.
|-------------------------------------------------------------------------|
| SECTION 6 - ACCIDENTAL RELEASE MEASURES |
|-------------------------------------------------------------------------|
SPILL OR LEAK PROCEDURES: Scrape up dried material and place into
containers.
|-------------------------------------------------------------------------|
| SECTION 7 - HANDLING AND STORAGE |
|-------------------------------------------------------------------------|
HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Keep containers away
from excessive heating and freezing. Avoid skin and eye contact. Do not
inhale dusts of this product.
STORAGE INFORMATION: Store away from caustics and oxidizers. Keep
containers tightly closed when not in use. Keep containers from excessive
heat and freezing. Do not store at temperatures above 120 degrees F(49 C).
OTHER PRECAUTIONS: None.
|-------------------------------------------------------------------------|
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
|-------------------------------------------------------------------------|
ENGINEERING CONTROLS: If dry-sanding, provide sufficient mechanical
ventilation to maintain exposure below PEL and TLV.
RESPIRATORY PROTECTION: If 8 hour exposure limit or value is exceeded for
any component, use an approved NIOSH/OSHA respirator. Consult your safety
equipment supplier and the OSHA regulation, 29 CFR 1910.134 for respirator
requirements. A respiratory protection program that meets OSHA 1910.134 and
ANSI Z88.2 requirements must be followed whenever workplace conditions
warrant a respirator's use. Use an approved NIOSH/OSHA respirator if dry
sanded.
EYE PROTECTION: Safety glasses with side shields recommended.
SKIN PROTECTION: Gloves recommended for repeated or prolonged contact with
skin.
(Continued on Page 4)
---------------------------------------------------------------------------
Product Name: 3.2.1 SPACKLE WITH DRYDEX
Revision Date: 05/15/2000 Page 4
|-------------------------------------------------------------------------|
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION |
|-------------------------------------------------------------------------|
OTHER PROTECTIVE EQUIPMENT: None.
HYGIENIC PRACTICES: Remove contaminated clothing and wash before reuse.
|-------------------------------------------------------------------------|
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES |
|-------------------------------------------------------------------------|
BOILING RANGE : 210-220 F (99?04 C) VAPOR DENSITY: Is lighter than air
ODOR : Mild Odor
APPEARANCE : Opaque paste EVAPORATION RATE: Is slower than Butyl
SOLUBILITY IN H2O : Soluble Acetate
SPECIFIC GRAVITY : 1.8690
VAPOR PRESSURE : 17.5 mm Hg @68F (20 C)
PHYSICAL STATE : Paste
(See Section 16 for abbreviation legend)
|-------------------------------------------------------------------------|
| SECTION 10 - STABILITY AND REACTIVITY |
|-------------------------------------------------------------------------|
CONDITIONS TO AVOID: Excessive heat and freezing.
INCOMPATIBILITY: Strong oxidizers and caustics.
HAZARDOUS DECOMPOSITION PRODUCTS: Normal decomposition products, i.e. COx,
NOx
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
|-------------------------------------------------------------------------|
| SECTION 11 - TOXICOLOGICAL PROPERTIES |
|-------------------------------------------------------------------------|
No product or component toxicological information is available.
|-------------------------------------------------------------------------|
| SECTION 12 - ECOLOGICAL INFORMATION |
|-------------------------------------------------------------------------|
No Information.
(Continued on Page 5)
---------------------------------------------------------------------------
Product Name: 3.2.1 SPACKLE WITH DRYDEX
Revision Date: 05/15/2000 Page 5
|-------------------------------------------------------------------------|
| SECTION 13 - DISPOSAL CONSIDERATIONS |
|-------------------------------------------------------------------------|
WASTE MANAGEMENT/DISPOSAL: This product does not meet the definition of a
hazardous waste according to U.S. EPA Hazardous Waste Management
Regulations, 40 CFR Section 261. State and Local regulations/restrictions
are complex and may differ from Federal regulations. Responsibility for
proper waste disposal is with the owner of the waste.
EPA WASTE CODE - If discarded (40 CFR 261): None.
|-------------------------------------------------------------------------|
| SECTION 14 - TRANSPORTATION INFORMATION |
|-------------------------------------------------------------------------|
DOT PROPER SHIPPING NAME: Not Regulated by D.O.T.
DOT HAZARD CLASS: NONE
DOT UN/NA NUMBER: NONE PACKING GROUP: NONE
Note: The shipping information provided is applicable for domestic ground
transport only. Different categorization may apply if shipped via other
modes of transportation and/or to non-domestic destinations.
|-------------------------------------------------------------------------|
| SECTION 15 - REGULATORY INFORMATION |
|-------------------------------------------------------------------------|
U.S. FEDERAL REGULATIONS: AS FOLLOWS -
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR
1910.1200)
SARA SECTION 313:
This product contains the following substances subject to the reporting
requirements of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
----------- CHEMICAL NAME ----------- CAS NUMBER WT/WT % RANGE
No SARA Section 313 components exist in this product.
TOXIC SUBSTANCES CONTROL ACT:
This product contains the following chemical substances subject to the
reporting requirements of TSCA 12(B) if exported from the United States:
----------- CHEMICAL NAME ----------- CAS NUMBER
No information is available.
(Continued on Page 6)
---------------------------------------------------------------------------
Product Name: 3.2.1 SPACKLE WITH DRYDEX
Revision Date: 05/15/2000 Page 6
|-------------------------------------------------------------------------|
| SECTION 15 - REGULATORY INFORMATION |
|-------------------------------------------------------------------------|
NEW JERSEY RIGHT-TO-KNOW:
The following materials are non-hazardous, but are among the top five
components in this product:
----------- CHEMICAL NAME ----------- CAS NUMBER
Water 7732-18-5
Vinyl Acetate Polymer TSRN-618608-5057P
PENNSYLVANIA RIGHT-TO-KNOW:
The following non-hazardous ingredients are present in the product at
greater than 3%:
----------- CHEMICAL NAME ----------- CAS NUMBER
Water 7732-18-5
Vinyl Acetate Polymer proprietary
CALIFORNIA PROPOSITION 65:
WARNING: The chemical(s) noted below and contained in this product, are
known to the state of California to cause cancer:
----------- CHEMICAL NAME ----------- CAS NUMBER
Crystalline Silica 14808-60-7
Polygorskite 12174-11-7
INTERNATIONAL REGULATIONS: AS FOLLOWS -
CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled
Product Regulations except for use of the 16 headings.
CANADIAN WHMIS CLASS: Not regulated.
(Continued on Page 7)
---------------------------------------------------------------------------
Product Name: 3.2.1 SPACKLE WITH DRYDEX
Revision Date: 05/15/2000 Page 7
|-------------------------------------------------------------------------|
| SECTION 16 - OTHER INFORMATION |
|-------------------------------------------------------------------------|
HMIS RATINGS - HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 0
PREVIOUS MSDS REVISION DATE: 06/17/1999
VOC less water, less exempt solvent: 30-40 g/L
VOC material : 10-20 g/L
LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
PEL - PERMISSIBLE EXPOSURE LIMIT
NTP - NATIONAL TOXICOLOGY PROGRAM
SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986
STEL - SHORT TERM EXPOSURE LIMIT
TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA)
VOC - VOLATILE ORGANIC COMPOUND
NJRTK - NEW JERSEY RIGHT TO KNOW LAW
N.D. - NOT DETERMINED
MSDS# 10420
---------------------------------------------------------------------------
This data is offered in good faith as typical values and not as a product
specification. No warranty either expressed or implied, is hereby made.
The recommended industrial hygiene and safe handling procedures are
believed to be generally applicable. However, each user should review the
recommendations in specific context of the intended use and determine if
they are appropriate.
---------------------------------------------------------------------------
< End OF MSDS >
The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification
Product ID: 011.0002400
Product Name: GOOF OFF
Product Use: Paint product.
Print date 17/Nov/2006
Revision Date 31/Aug/2005
Company Identification
The Valspar Corporation - Architectural Coatings Division
1191 Wheeling Road
Wheeling, IL 60090
Manufacturer's Phone: 1-847-520-8580
24-Hour Medical Emergency 1-888-345-5732
Phone:
2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name Approx. Chemical name
CAS-No. Weight %
XYLENE 75 - 80 Xylenes (o-, m-, p- isomers)
1330-20-7
ETHYLBENZENE 15 - 20 Ethyl benzene
100-41-4
DIETHYLENE GLYCOL 1-5 Diethylene glycol monomethyl ether
MONOMETHYL ETHER
111-77-3
TOLUENE 1-5 Toluene
108-88-3
If this section is blank there are no hazardous components per OSHA guidelines.
3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or
respiratory irritation.
Eye Contact:
Corneal Injury/eye damage.
Product ID: 011.0002400
Page 1 / 7
Skin Contact:
May cause moderate skin irritation.
Acute Ingestion:
None known
Other Effects:
May cause central nervous system depression. May cause liver damage. May cause kidney damage.
This product contains ingredients that may contribute to the following potential chronic health effects:
Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful
or fatal. Possible birth defects hazard. Contains ingredients which may cause birth defects based on animal data. May
cause kidney damage. May cause liver damage.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.
4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never give
anything by mouth to an unconscious person. Get medical attention immediately. If swallowed, get medical attention
immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit): 80?F ( 27?C) TCC/PM
Lower explosive limit: 1%
Upper explosive limit: 7%
Autoignition temperature: Not available. ?F ( ?C)
Sensitivity to impact: No.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
Hazardous combustion products: See Section 10.
Unusual fire and explosion hazards:
None known.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.
Product ID: 011.0002400
Page 2 / 7
6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual
Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with
inert absorbent and non sparking tools. Avoid contact with eyes.
7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F.
(49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA
regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed
until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint,
an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of
liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly
bonded and grounded at all times.
8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Appropriate chemical resistant gloves should be worn.To prevent skin contact wear protective clothing covering all
exposed areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air
purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to
ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof. Eliminate
ignition sources.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name Approx. TWA (final) Ceilings limits (final) Skin designations
CAS-No. Weight %
XYLENE 75 - 80 435 mg/m?100 ppm
1330-20-7
ETHYLBENZENE 15 - 20 435 mg/m?100 ppm
100-41-4
TOLUENE 1-5 200 ppm 300 ppm
108-88-3
ACGIH Threshold Limit Value (TLV's)
Common Name Approx. TWA STEL Ceiling limits Skin designations
CAS-No. Weight %
Product ID: 011.0002400
Page 3 / 7
XYLENE 75 - 80 100 ppm 150 ppm
1330-20-7
ETHYLBENZENE 15 - 20 100 ppm 125 ppm
100-41-4
TOLUENE 1-5 50 ppm Can be absorbed
108-88-3 through the skin.
If this section is blank, no information is available.
9. PHYSICAL PROPERTIES
Odor: Normal for this product type.
Physical State: Liquid
pH: Not determined.
Vapor pressure: 28 mmHG @ 68?F ( 20?C)
Vapor density (air = 1.0): 4.1
Boiling point: 230?F ( 110?C)
Solubility in water: Insoluble.
Coefficient of water/oil distribution: Not determined.
Density (lbs per US gallon): 7.29
Specific Gravity .87
Evaporation rate (butyl acetate = 1.0): 2
10. STABILITY AND REACTIVITY
Stability Stable
Conditions to Avoid: None known.
Incompatibility: Strong oxidizers.
Hazardous Polymerization: None anticipated.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide.
Sensitivity to static discharge: Subject to static discharge hazards. Please see bonding and
grounding information in Section 7.
11. TOXICOLOGICAL INFORMATION
Mutagens:
Common Name Approx. California Prop 65 - Developmental California Prop 65 - Reproductive
CAS-No. Weight % Toxicity (Male)
TOLUENE 1-5 Listed: January 1, 1991
108-88-3 Developmental toxin.
Teratogens:
Carcinogens:
Contains ethylbenzene, which has been determined by NTP to be an animal carcinogen with no known relevance to
humans. IARC has classified ethylbenzene as possibly carcinogenic to humans (2b) on the basis of sufficient evidence of
carcinogenicity in laboratory animals but inadequate evidence of cancer in humans.
Common Name Approx. IARC Group 1 - Human IARC Group 2A - Limited IARC Group 2B -
CAS-No. Weight % Evidence Human Data Sufficient Animal Data
ETHYLBENZENE 15 - 20 Monograph 77, 2000
100-41-4
Product ID: 011.0002400
Page 4 / 7
Common Name Approx. NTP Known NTP Suspect NTP Evidence of
CAS-No. Weight % Carcinogens Carcinogens Carcinogenicity
ETHYLBENZENE 15 - 20 male rat-clear evidence;
100-41-4 female rat-some
evidence; male mice-
some evidence; female
mice-some evidence
Common Name Approx. OSHA Select OSHA Possible Select ACGIH Carcinogens
CAS-No. Weight % Carcinogens Carcinogens
ETHYLBENZENE 15 - 20 Group A3 Confirmed
100-41-4 animal carcinogen with
unknown relevance to
humans.
If this section is blank, no information is available.
12. ECOLOGICAL DATA
Not available at this time.
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name: PAINT RELATED MATERIAL
Hazard Class: 3
UN ID Number: UN1263
Packing Group: III
49 CFR Hazardous Material Regulations Parts 100-180
The supplier will apply the combustible liquid exception in 49 CFR 173.150(f), limited quantity or "does not sustain
combustion" exceptions and consumer commodity rules, when authorized. Please check 49 CFR Parts 100-180 to
determine if the use of these exceptions applies to your shipments when re-shipping our products.
International Air Transport Association:
Proper Shipping Name: PAINT RELATED MATERIAL
Hazard Class: 3
UN ID Number: UN1263
Packing Group: III
International Maritime Organization:
Proper Shipping Name: PAINT RELATED MATERIAL
Hazard Class: 3
Non-Bulk UN ID Number: UN1263
Packing Group: III
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
Product ID: 011.0002400
Page 5 / 7
15. REGULATORY INFORMATION
Common Name Approx. SARA 302 SARA 313 CERCLA RQ in lbs.
CAS-No. Weight %
XYLENE 75 - 80 form R reporting required 100
1330-20-7 for 1.0% de minimis
concentration
ETHYLBENZENE 15 - 20 form R reporting required 1000
100-41-4 for 1.0% de minimis
concentration
DIETHYLENE GLYCOL 1-5 YES
MONOMETHYL ETHER
111-77-3
TOLUENE 1-5 form R reporting required 1000
108-88-3 for 1.0% de minimis
concentration
SARA 311/312 Hazard Class:
Acute: Yes
Chronic: Yes
Flammability: Yes
Reactivity: No
Sudden Pressure: No
U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
ETHYLBENZENE 100-41-4
TOLUENE 108-88-3
DIETHYLENE GLYCOL MONOMETHYL ETHER 111-77-3
XYLENE 1330-20-7
California Proposition 65:
WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other
reproductive harm.
Rule 66 status of product Photochemically reactive.
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory: All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.
Canada Domestic Substances List: All components of this product are listed on the Domestic
Substances List.
16. OTHER INFORMATION
HMIS Codes
Health: 2
Flammability: 3
Reactivity: 1
PPE: X - See Section 8 for Personal Protective Equipment (PPE).
Product ID: 011.0002400
Page 6 / 7
Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH -
National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference
of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic
Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT -
Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ -
Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,
MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed
cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term
exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance, this
information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.
UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE
LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this
product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.
Product ID: 011.0002400
Page 7 / 7
MSDS No: OTH050E5
Issue Date: 10 June 2005
Page: 1 of 4
MATERIAL SAFETY DATA SHEET
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
Trade Name: OATEY PLUMBER'S PUTTY
Product Use: Stainless fixture setting compound.
Formula: See SECTION 2
Synonyms: Putty.
Firm Name & OATEY CO. 4700 West 160th Street P.O. Box 35906 Cleveland,
Mailing Address: Ohio 44135, U.S.A. http://www.oatey.com
Oatey Phone Number: (216) 267-7100 or (800) 321-9532
Emergency Phone For Emergency First Aid call 1-303-623-5716 COLLECT. For
Numbers: chemical transportation emergencies ONLY, call Chemtrec at
1-800-424-9300. Outside the US: 1-703-527-3887.
Prepared By: Corporate Director ?Safety and Environmental Compliance
Preparation Date: June 10, 2005
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
%wt/wt: CAS NUMBER: ACGIH TLV TWA: OSHA PEL TWA: OTHER:
INGREDIENTS:
Limestone 60 - 90% 1317-65-3 10 mg/M3 15 mg/M3 None
(Total dust)
Hydrocarbon oil 10 - 30% 64742-52-5 5 mg/M3 5 mg/M3 None
Talc 1 - 5% 14807-96-6 2 mg/M3 2 mg/M3 None
Clay 1 ?5% 68953-58-2 10 mg/M3 10 mg/M3 None
OSHA Hazard Classification: Not hazardous
SECTION 3 HAZARDS IDENTIFICATION
Emergency Overview:
White putty with a mild petroleum odor. May cause mechanical irritation of the eyes.
SECTION 4 FIRST AID MEASURES
CALL 1-303-623-5716 COLLECT
Skin: Wash all exposed areas with soap and water.
Eyes: As with most foreign materials, should eye contact occur, flush eyes
with water until foreign matter is removed. If irritation develops,
seek medical attention.
Inhalation: Not a likely route of entry.
Ingestion: DO NOT INDUCE VOMITING. Rinse mouth with water. Call a physician.
SECTION 5 FIRE FIGHTING MEASURES
Flashpoint / Method: Not applicable
Flammability: LEL = Not determined, UEL = Not determined
Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media: exposed container with water. Water may be ineffective as an
extinguishing agent.
Special Fire As appropriate for surrounding fire.
Fighting
Procedure:
Unusual Fire and None
Explosion
Hazards:
Hazardous Combustion will produce toxic and irritating vapors including
Decomposition carbon monoxide and carbon dioxide.
Products:
MSDS No: OTH050E5
Issue Date: 10 June 2005
Page: 2 of 4
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spill or Sweep up dried material and dispose of with ordinary trash.
Leak
Procedures:
SECTION 7 HANDLING AND STORAGE
Handling: No special handling required. Wash thoroughly after handling.
Use good hygiene practices.
Storage: Store in a cool, dry area.
Other: None.
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Use with adequate ventilation.
Respiratory If putty dries and becomes dusty, wear a dust respirator
Protection: during clean-up.
Skin Gloves are not normally required.
Protection:
Eye Safety glasses with side shields are recommended.
Protection:
Other: Eye wash should be available.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: Not applicable
Melting Point: Not applicable
Vapor Pressure: Not determined
Vapor Density: Not determined
Volatile Components: Not determined
Solubility In Water: Negligible.
pH: Not applicable
Specific Gravity: 2.0 @ 20 Degrees C
Evaporation Rate: Not applicable
Appearance: White Putty
Odor: Petroleum odor
Will Dissolve In: Not determined
Material Is: Putty
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Avoid heat, flames and other sources of ignition.
Hazardous Combustion will produce toxic and irritating vapors
Decomposition including carbon monoxide and carbon dioxide.
Products:
Incompatibility/ Strong oxidizing agents.
Materials To Avoid:
Hazardous Will not occur.
Polymerization:
MSDS No: OTH050E5
Issue Date: 10 June 2005
Page: 3 of 4
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Not a likely route of entry.
Skin: May cause mild irritation. Prolonged and repeated contact
may cause dermatitis.
Eye: Contact may cause irritation.
Ingestion: Swallowing may cause a laxative effect including cramps and
diarrhea.
Chronic Prolonged or repeated overexposure cause dermatitis.
Toxicity:
Toxicity Data: Not available
Sensitization: None of the components are known to cause sensitization.
Carcinogenicity: None of the components are listed as a carcinogen or suspect
carcinogen by NTP, IARC or OSHA.
Mutagenicity: None of the components are known to be mutagenic.
Reproductive None of the components are known to be toxic to reproduction.
Toxicity:
Medical None known.
Conditions
Aggravated By
Exposure:
SECTION 12 ECOLOGICAL INFORMATION
No ecotoxicological information known.
VOC This product has very low VOC level.
Information:
SECTION 13 DISPOSAL CONSIDERATIONS
Waste Disposal: Dispose in accordance with current local, state and federal
regulations.
RCRA Hazardous Waste Number: Not a hazardous waste.
EPA Hazardous Waste ID Number: Not a hazardous waste.
EPA Hazard Waste Class: Not a hazardous waste.
SECTION 14 TRANSPORT INFORMATION
Less than 1 Liter (0.3 gal) Greater than 1 Liter (0.3 gal)
DOT
Proper Shipping Name: Not regulated. Not regulated.
Hazard Class/Packing Group: None None
UN/NA Number: None None
Hazard Labels: None None
IMDG
Proper Shipping Name: Not regulated
Hazard Class/Packing Group: None
UN Number: None
Label: None
2004 North American Emergency Response Guidebook Number: None
MSDS No: OTH050E5
Issue Date: 10 June 2005
Page: 4 of 4
SECTION 15 REGULATORY INFORMATION
Hazard Category for Section Not hazardous.
Section 302 Extremely This product does not contain chemicals regulated
Hazardous Substances (TPQ): under SARA Section 302.
Section 313 Toxic Chemicals: This product does not contain any chemicals regulated
under SARA Title III Section 313.
CERCLA 103 Reportable This product does not contain any chemicals regulated
Quantity: under CERCLA.
California Proposition 65: This product does not contain any chemicals subject
To California Proposition 65 regulation.
TSCA Inventory: All of the components of this product are listed on
the TSCA inventory.
Canadian WHIMS Classification: Not a controlled product.
This product has been classified in accordance with
the hazard criteria of the Controlled Products
Regulations (CPR) and the MSDS contains all the
information required by the CPR.
SECTION 16 OTHER INFORMATION
NFPA and HMIS:
NFPA Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 Special: None
HMIS Hazard Signal: Health: 0 Flammability: 0 Reactivity: 0 PPE: A
Disclaimer:
The information herein has been compiled from sources believed to be reliable, up-
to-date, and is accurate to the best of our knowledge. However, Oatey cannot give
any guarantees regarding information from other sources, and expressly does not make
warranties, nor assumes any liability for its use.
|