STEP 3
Prepare the MSDS
3
3
56 PART 3 ?Step 3: Prepare the MSDS
Step 3:
Prepare the MSDS
BASIC INFORMATION General MSDS Requirements
A Material Safety Data Sheet is a technical bulletin that MSDSs must:
provides specific hazard information, safe handling ?Contain nine categories of information
information, and emergency procedures for a controlled
?Include information items listed in CPR, Schedule I (if
product. The MSDS contains detailed health and safety
available and applicable)
information specific to each controlled product, and
?Contain no unregistered trade secrets for controlled
should be used as a key source of information for
products sold or imported
developing training programs and safe work procedures.
?Be available in English and French 3
The MSDS is also a valuable source of health and safety
information for workers, health and safety committees, ?Be no more than three years old
and emergency service personnel. To be useful, the MSDS
should be complete, legible, and understandable by
workers and employers. For more detailed information on
REQUIREMENTS IN CANADA
MSDSs, see the WHMIS Core Material manual. (To
obtain a copy of this manual, see page 217.) Information Items on an Acceptable
Canadian MSDS
WHMIS legislation lists the minimum content require-
SUPPLIER RESPONSIBILITIES
ments for an MSDS:
The supplier has the following responsibilities:
?The CPR requires that nine headings, which may
?Developing or obtaining an accurate and complete appear as subheadings under another heading, appear
MSDS for each product imported or sold in Canada. on the MSDS.
?Preparing an MSDS in both official languages ?Schedule I of the CPR requires that an MSDS have
(English and French), and transmitting it in either or specific information items, if available and applicable.
both languages, as requested.
?No section of the MSDS can be left blank. If no
?Providing the current MSDS (no more than three years information exists that the supplier is aware of, then
old) to purchaser on or before the day of purchase. N/AV "not available" or N/AP "not applicable" must
be used.
?Ensuring that information required on the MSDS is
not disclaimed or contradicted by other information ?Canada accepts the International Labour Organization
that is not required but is also disclosed on the MSDS. (ILO), International Standards Organization (ISO), or
If abbreviations are used, they should be explained in European Union (EU) 16-section MSDSs, as long as all
the text. of items of CPR, Schedule I are addressed. Informa-
tion on The 16-section MSDS is given in this guide on
?Updating each MSDS three years from its date of
page 101.
preparation or as soon as new information becomes
available. ?OSHA MSDSs do not meet CPR requirements.
?Providing confidential business information to
medical personnel in case of emergency.
PART 3 ?Step 3: Prepare the MSDS 57
No standard format exists for an MSDS. However, the section headings and information items. See the back of
following format is recommended for presenting the nine this guide for a blank sample 9-section MSDS.
MATERIAL SAFETY DATA SHEET -- 9 Sections Acetone
SECTION 1 -- PRODUCT INFORMATION
Product Identifier WHMIS Classification (optional)
Acetone B2, D2B X X X X
Product Use
Solvent, general-purpose cleaning of adhesives, contact cements, printing inks, gums, waxes, resins, greases, and oils Irritation; possible effects on central nervous system (CNS); at air concentrations above
Manufacturer's Name Supplier's Name
Happy Chemical Company Big Chemical Company 8,000 ppm may cause drowsiness, incoordination, loss of reflexes, unconsciousness, and respiratory failure
Street Address Street Address
5556 Helium Lane 123 Nitro Avenue
City Province City Province
Gaseous Bay BC Vapour Town BC Dermatitis. No significant harmful effects from oral or inhalation exposures.
Postal Code Emergency Telephone Postal Code Emergency Telephone
X0X 0X0 (604) 234-5678 X5X 5X5 (604) 345-6789
SECTION 2 -- HAZARDOUS INGREDIENTS
Hazardous Ingredients (specific) % CAS Number LD50 of Ingredient LC50 of Ingredient
(specify species and route) (specify species)
250 ppm, 8-hour TWA limit (WorkSafeBC) X
250 ppm, 8-hour TWA limit (WCB) Severe eye irritant, skin and respiratory irritant
Acetone 99-100 67-64-1 5,800 mg/kg (oral, rat) 30,000 ppm (inhal.,4 hrs.)
X X
X X
X X Chlorinated solvents, ethyl alcohol
Sample MSDS
X X X
SECTION 3 -- PHYSICAL DATA
Butyl rubber gloves. NIOSH-approved respirator with organic vapour cartridge for air concentrations
Clear, colourless liquid with mildly
Physical State Odour and Appearance Odour Threshold (ppm)
Liquid pungent, sweet and fruity odour 62 (average) up to 2,500 ppm. Splash-proof chemical safety goggles or face shield.
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
0.791 at 20?C 2.0 24-24.7 1 kPa 5.6 (n-butyl acetate=1)
Use mechanical ventilation to reduce exposure. Use non-sparking and
Boiling Point (癈) Freezing Point (癈) pH Coefficient of Water/Oil Distribution
56.2 -94.6 n/ap 0.58 grounded ventilation system.
SECTION 4 -- FIRE AND EXPLOSION DATA
Eliminate all ignition sources. Wear adequate protective equipment. Contain spill with absorbent
Flammability If yes, under which conditions?
X Yes No
Flammable liquid
material and place in a suitable covered and labelled container for disposal.
Carbon dioxide, dry chemical powder, "alcohol" foam, polymer foam. Water may be ineffective because
Means of Extinction
it will not cool acetone below its flashpoint. Check with federal, provincial, and local government requirements for disposal.
Flashpoint (癈) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
-18癈 (cc) 12.8% at 25癈 2.5% at 25癈
Autoignition Temperature (癈) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
465癈 No Yes
Use in a well-ventilated area, away from heat and all ignition sources (including sparks, open
Hazardous Combustion Products
Carbon monoxide and carbon dioxide
flames, and hot surfaces). Do not use with incompatible substances. Use grounded and non-sparking equipment.
Store in cool, well-ventilated area out of direct sunlight, away from heat and ignition sources. Storage
SECTION 5 -- REACTIVITY DATA
facilities should be made from fire-resistant materials.
Chemical Stability If no, under which conditions?
No
X Yes
TDG shipping name: Acetone, Classification 3, Flammable liquid, Packing Group II 1090
Incompatibility with Other Substances If yes, which ones?
No
X Yes Acids (for example, nitric acid);
Strong oxidizing agents (for example, hydrogen peroxide);
Remove source of contamination or move victim to fresh air.
Bases (for example, sodium hydroxide)
If conscious, have victim rinse mouth thoroughly with water; do not induce vomiting; have victim drink
240-300 mL of water. Obtain medical attention immediately.
Flush with water for 15 minutes.
Reactivity, and under what conditions?
Attacks many forms of plastics and rubber, including rayon Immediately flush contaminated eye(s) with lukewarm, gently flowing water for 20 minutes, while holding
eyelids(s) open. Obtain medical attention immediately.
Hazardous Decomposition Products
Carbon monoxide from prolonged exposure to sunlight
Sally Safemeister (604) 123-2222 January 4, 2005
57M2 (R6/99) SAMPLE FORMAT PROVIDED BY THE WORKERS' COMPENSATION BOARD OF BRITISH COLUMBIA
Please continue on reverse side
9-SECTION MSDS
Section 1: Product Information
This section identifies the product, the manufacturer, and manufacturer and supplier for information and/or in
the supplier, and describes the intended product use. case of emergency.
Section 1 also provides the contact details of the
MATERIAL SAFETY DATA SHEET -- 9 SECTIONS
SECTION 1 -- Product Information
Product Identifier WHMIS Classification (optional)
[1]
Product Use
[2]
Manufacturer's Name Supplier's Name
[3] [4]
Street Address Street Address
City Province City Province
Postal Code Emergency Telephone Postal Code Emergency Telephone
58 PART 3 ?Step 3: Prepare the MSDS
[1] Product Identifier -- Give the name of the product as [3] Manufacturer's Information -- Identify the manufac-
it appears on the product label. The product turer's name, address, and emergency phone
identifier is often the chemical name of the product, number, which must be listed if one is available.
but can also be the trade name, common name, code
[4] Supplier's Information -- Give the supplier's (seller
name, or code number.
or distributor) name, address, and emergency phone
[2] Product Use -- Identify the product use intended by number. Include supplier information if the supplier
the manufacturer or supplier. Any other use, is different from the manufacturer.
intended or unintended, can be dangerous.
Section 2: Hazardous Ingredients
This section lists the specific chemical names, percentages, and acute toxicity data for the individual components.
SECTION 2 -- Hazardous Ingredients
3
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
[8]
[5] [6] [7] [9]
(specific) (specify species and route) (specify species)
?Identify complex, naturally occurring mixtures by the
[5] Specific Hazardous Ingredients -- List each
hazardous ingredient by specific chemical name. commonly known generic name corresponding to the
CAS number (e.g., solvent naphtha [petroleum], light
DO: aromatic; or gasoline). Listing every component may
be confusing.
?Identify the specific chemical name of each hazardous
ingredient if it is present at or above the cut-off ?Include the trade secret exemption statement for any
concentration (as defined by CPR 4): secret ingredient that is not listed. If the supplier has
applied for or received a Trade Secret exemption, this
? 1% (chronic effects, e.g., kidney or liver damage)
item may state:
? 0.1% (carcinogens, respiratory sensitizers,
?HMIRC filing #1938, filed on April 20, 2005
reproductive toxins, teratogens, mutagens,
(while a CBI claim is being processed)
embryotoxins)
?CBI #1938, granted on December 5, 2005 (after
?Include each ingredient the supplier has reason to
a CBI claim has been granted)
believe may be harmful.
DO NOT:
?Include each ingredient for which the health hazards
are not known. ?List overly generic names (e.g., hydrocarbon mixture)
?Include each ingredient present on the Ingredient ?List a generic name for a single ingredient, for example:
Disclosure List (IDL) at greater than or equal to the
?Alkanolamine instead of ethanolamine
minimum concentration requiring disclosure.
?Ensure the specific name disclosed for the hazardous ?Aliphatic hydrocarbon instead of n-hexane
ingredient matches the CAS number given.
PART 3 ?Step 3: Prepare the MSDS 59
For each listed hazardous ingredient include: Acceptable Concentration Ranges as per CPR 11
[6] % -- Percentages -- Give either the percentage or 0.1?% 10?0%
range of percentages for each hazardous ingredient
0.5?.5% 15?0%
(weight/weight; volume/volume; or weight/volume):
1?% 30?0%
?Identify percentage (%) concentration if the exact 3?% 40?0%
concentration can be specified.
5?0% 60?00%
?Identify percentage (%) range if the concentration 7?3%
varies in normal production. The concentration
range used must lie within both limits of a range
listed in the CPR (see below).
For example:
Acceptable Ranges Unacceptable Ranges
2?% 1?%
(lies within 1?%) (does not lie within any of the above listed range)
> 60% < 10%
(represents 60?00%, which is within a listed range) (represents 0?0%, which is not within a listed range)
[7] CAS Number -- State the unique registry number The LD50 can be determined for many routes of
assigned to each hazardous ingredient by the entry: oral (given by mouth), dermal (applied to
Chemical Abstracts Services, a Division of the skin), intramuscular (within muscle), subcutaneous
American Chemical Society. Information on the (under the skin), or intraperitoneal (within the
chemical name can be obtained from the CAS peritoneal cavity). Oral and dermal LD50s are used
number. To date, over 27 million CAS numbers have for WHMIS classification.
been assigned to organic and inorganic substances.
When more than one LD50 value is given for the
When completing this item, remember that:
same route of exposure for a chemical, use the
?Each ingredient listed must have a correspond- lowest value for disclosure or classification.
ing CAS number.
The route and species tested must be specified.
?Each individual CAS number contains three For example:
groupings of numbers separated with hyphens.
?Methanol has an LD50 of 5628 mg/kg (oral, rat)
For example:
and 15,800 mg/kg (skin, rabbit)
Xylene = 1330-20-7
?Toluene has an LD50 of 2600--7500 mg/kg (oral,
Butanolamine = 13552-21-1 rat) and 12,210 mg/kg (skin, rabbit)
[8] LD50 of Each Ingredient -- State the LD50, a measure [9] LC50 of Each Ingredient -- Give the LC50, another
of the immediate poisoning potential of a hazardous measure of the immediate poisoning potential of a
ingredient. LD50 is the single dose at which 50% of a hazardous ingredient. LC50 is the lethal concentra-
specified test group of animals die as a result of tion at which 50% of a specified test population die,
exposure to this substance under controlled but relates to inhalation exposure to dust, fume,
conditions based on OECD (Organization for vapour, or gas. The route is always inhalation. For
Economic Co-operation and Development) Test WHMIS classification, the dose time is four hours;
Guidelines or other accepted standards. (See other dose times must be specified. The species
Guidelines for Testing a Pure Substance or Mixture tested must be specified as well. For example:
on page 246.)
60 PART 3 ?Step 3: Prepare the MSDS
?Hydrogen cyanide has an LC50 of 71 ppm Conversions
(4 hours, rat)
24.45 x mg/m3
ppm =
?Sulphuric acid has an LC50 of 255 mg/m3
gram molecular weight of substance
(4 hours, rat)
3
mg/m = ppm x gram molecular weight of substance
LD50 and LC50 measure only immediate toxicity. 24.45
Lower LD50 and LC50 values indicate higher
immediate toxicity.
Section 3: Physical Data
This section contains general information on the product's physical and chemical properties, such as the specific gravity,
boiling point, and evaporation rate.
SECTION 3 -- Physical Data 3
Physical State Odour and Appearance Odour Threshold (ppm)
[10] [11] [12]
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
[13] [14] [15] [16]
Boiling Point (?C) Freezing Point (癈) pH Coefficient of Water/Oil Distribution
[17] [18] [19] [20]
[10] Physical State -- Describe the physical state of the [12] Odour Threshold (ppm) -- State the lowest airborne
product at room temperature. For example: concentration of the chemical that can be detected
by the sense of smell. Odour threshold is always a
?Gas, liquid, solid, paste, powder, or gel component that is noticeable to the human nose.
Because the sense of smell varies from person to
[11] Odour and Appearance -- Give details that help to
person, a listed odour threshold is only a guide.
identify materials.
If the odour threshold of a mixture has not been
Odour describes the quality of the odour and its
determined, include the odour threshold of either the
intensity rather than odour acceptability (pleasant,
major component or a very smelly minor component.
unpleasant). For example:
?For example, a lacquer thinner containing a
?Quality: almond-like, fruity, sharp, sweet, bitter
small percentage of isobutyl acetate should
identify the odour threshold of this component
?Intensity: weak, strong, mild, faint
since this substance has a much lower odour
Appearance refers to colour (including colourless) threshold than any of the other components.
and surface texture, and includes particle size for
Odour threshold gives an indication of the warning
solids. Liquids can be described by their viscosity.
properties of a chemical. For example, would a
For example:
worker be able to smell the airborne chemical before
?Surface texture: greasy, waxy, soft hazardous exposure occurred?
?Particle size: finely divided particulate,
Warning Properties Odour Threshold Limit
flakes, granules
1
Good /10 of Exposure Limit
?Viscosity: gelatinous, viscous, thick, thin
1
Fair /10 to 3X Exposure Limit
Poor 3X Exposure Limit
PART 3 ?Step 3: Prepare the MSDS 61
The relationship of odour threshold to the Thresh- important and may determine the type of respirator
old Limit Value (TLV) or other exposure limit is that should be used.
Odour Exposure Warning Respirator
Compound Threshold Limit Properties (3M Respirator Guide)
Toluene 6.7 ppm 100 ppm Good OV-Cartridge
Methanol 6000 ppm 200 ppm Poor Air-supplied
Note: Respirator selection is dependent on the workplace conditions. These are only suggestions for respiratory
protection under "normal conditions of use." (OV-Cartridge = organic vapour cartridge).
Note: If the value is unknown, state whether the
[13] Specific Gravity -- Give the ratio of the weight of a
product is heavier or lighter than air.
substance to the weight of water. The specific gravity
indicates whether the substance is heavier or lighter
[15] Vapour Pressure (mmHg) -- State the vapour
than water.
pressure of a liquid, one measure of its tendency to
form vapours. The higher the vapour pressure
Specific gravity > 1 means an immiscible material
number, the more quickly the liquid evaporates.
will sink in water
Vapour pressure is measured at 20癈 unless another
?Specific gravity of lead is 11.3 temperature is specified. For example:
Specific gravity < 1 means an immiscible material ?Vapour pressure of Stoddart solvent is 2 mmHg
will float in water. (i.e., 2 millimetres of mercury)
?Specific gravity of mineral spirits is 0.78 ?Vapour pressure of methylene chloride is
46.5 kPa (i.e., 349 mmHg)
Note: If the value is unknown, state whether the
product is heavier or lighter than water. Pressure Conversions:
[14] Vapour Density (air = 1) -- Give the ratio of the
1 atmosphere = 101.3 kPa = 760 mmHg = 14.7 psi
molecular weight of a gas or vapour to the equivalent
weight of air. The vapour density indicates whether a
material is lighter or heavier than air. All gases and
[16] Evaporation Rate -- Give the evaporation rate,
vapours will eventually mix with the air in a room,
describing how fast a substance evaporates relative
the rate depending on air currents and temperature.
to a given known reference standard (usually n-butyl
Those gases several times heavier than air, however,
acetate or ether). Where n-butyl acetate = 1:
will have an initial tendency to sink to ground level.
Vapour density is calculated by dividing the molecu- Evaporation rate > 3.0 is a fast rate.
lar weight of the substance by 29.
?Evaporation of methanol is 5.9
Vapour density > 1 means a product is heavier than
Evaporation rate 0.8?.0 is a medium rate.
air. For example:
?Evaporation of perchloroethylene is 1.5
?Vapour density of perchlorethylene is 5.72
Evaporation rate < 0.8 is a slow rate.
Vapour density < 1 means a product is lighter than
air. For example:
?Evaporation of xylene is 0.7
?Vapour density of helium is 0.138
62 PART 3 ?Step 3: Prepare the MSDS
[17] Boiling Point -- State the temperature at which the pH can be used as a guide to the irritant or corro-
vapour pressure of a liquid equals the external sive nature of a product.
pressure (usually normal atmospheric pressure), and
Any product with a pH of 2.0 or lower, or 11.5 or
the liquid changes freely to a gas or vapour.
greater, can be assumed to be corrosive unless
Boiling point is an important consideration when testing has been done that proves otherwise (Refer
chemicals are stored. Volumes can change significantly to OECD Test Guidelines 404 (skin) and 405 (eyes).
inside a container as the contents approach boiling See Guidelines for Testing a Pure Substance or
point. For example: Mixture on page 246.)
?Outdoor storage of a chemical such as methylene
pH Scale
chloride is dangerous, as it boils at 40?C. Even at
25癈 , a significant pressure builds up in the Battery acid Ammonia, Lye
container, which may rupture or explode.
0 to 2 -- Corrosive 11.5 to 14 -- Corrosive
[18] Freezing Point (melting point) -- State the tempera-
3
0 2 7 -- Neutral 11.5 14
ture, at normal room pressure, at which a liquid
Low High
changes to a solid or a solid to a liquid (melting point).
Milk, Sea water
Freezing point is also important to consider when
storing chemicals. Containers or tanks may
[20] Coefficient of Water/Oil Distribution -- Give the
rupture when contents freeze, causing leaks or
coefficient of water/oil distribution, a number that
spills. For example:
indicates how easily the product is absorbed into
?Glacial acetic acid freezes at 16癈. The bottle the body.
may crack due to expansion of the contents;
Coefficient of water/oil distribution > 1 indicates
when the temperature rises again, a serious spill
that a material is water-soluble. It can enter the body
may result.
through the mucous membranes of the eye, nose,
Temperature Conversions: and lungs.
?CPR (12) requires disclosure of units of measure- ?Coefficient of water/oil distribution for methanol
ment. In this case, units should be given in is 1.9
Celsius or Fahrenheit.
Coefficient of water/oil distribution < 1 indicates
?The units for temperatures should be consistent the material dissolves better in oils and greases
within an MSDS. than water. Fatty tissue below the skin may absorb
the substance and allow entry through the skin into
the body.
Fahrenheit to Celsius = (?F - 32) x 0.556
?Coefficient of water/oil distribution for hexane
Celsius to Fahrenheit = (1.8 x ?C) + 32
is 0.0013
[19] pH -- Give a pH value (between 0 to 14), which This information is useful for selection of proper
indicates the acidity or alkalinity of a product in skin protective equipment and first aid treatment.
aqueous solution. Low pH values are considered
acidic, and high pH values are considered alkaline.
The value or measurement has no relevance in non-
aqueous solvents.
PART 3 ?Step 3: Prepare the MSDS 63
Section 4: Fire and Explosion Data
This section lists the conditions under which the product may catch fire or explode. Section 4 also gives information for
developing strategies and procedures to deal with fire and explosion hazards.
SECTION 4 -- Fire and Explosion Data
Flammability If yes, under which conditions?
[21] Yes No
Means of Extinction
[22]
Flashpoint (癈) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
[23] [24] [25]
Autoignition Temperature (癈) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
[26] [28] [29]
Hazardous Combustion Products
[27]
FP 93.3癈 (> 200癋): any substance with a
[21] Flammability -- State if a product is classified as
flammable or combustible under WHMIS. Provide flashpoint greater than or equal to 93.3癈 may burn,
information on a product's ability to catch fire or but is not classified as flammable or combustible.
explode, and indicate any specific conditions under
[24] Upper Flammable Limit (% by volume) and
which the product may burn.
[25] Lower Flammable Limit (% by volume) -- Indicate
[22] Means of Extinction -- List types and classes of fire
flammable limits, a concentration range in which the
extinguisher(s) and extinguishing materials suitable
gas or vapour is flammable. Flammable limits are the
for use on the burning product or fire, and any
highest (UFL) and lowest (LFL) concentrations of a
special firefighting procedures. For example:
gas or vapour in air (expressed as a percentage) at
?Water, fogs, foam, carbon dioxide which the product will catch fire or explode if near
an ignition source (e.g., heat, spark, or open flame).
[23] Flashpoint and Method -- Give the product's For example:
flashpoint (FP), the lowest temperature at which a
?LFL for butane is 1.6%
liquid gives off enough vapour to catch fire or
explode in the presence of an ignition source (e.g.,
?UFL for butane is 8.4%
heat, spark, or open flame).
These concentrations, and all concentrations in
A flashpoint is determined either by a "cc" (closed-cup)
between, form the flammable range. If the vapour
or "oc" (open-cup) method (see CPR Schedule IV).
concentration is leaner (below the LFL) or richer
FP < 37.8癈 (< 100癋): a product with a flashpoint (above the UFL) than this range, the flammable
of less than 37.8癈 is classified as flammable material will not burn.
(Class B2). For example,
UFL and LFL are also called UEL (upper explosive
?Flashpoint of toluene is 4.4 degrees Celsius, limit) and LEL (lower explosive limit).
closed-cup (very flammable)
[26] Autoignition Temperature -- State the temperature
FP 37.8癈 but < 93.3癈 ( 100癋 but < 200癋): above which the substance (usually a vapour) will
spontaneously ignite without an external ignition
any substance with a flashpoint greater than or
equal to 37.8?C but less than 93.3?C is classified source (e.g., heat, spark, or flame). Autoignition
as combustible. temperatures are available only for flammable
liquids and gases.
?Autoignition temperature for gasoline is 250?C
64 PART 3 ?Step 3: Prepare the MSDS
[27] Hazardous Combustion Products -- List the hazard- [28] Explosion Data -- Sensitivity to Mechanical Impact --
ous products produced when the substance burns or Indicate if the material is likely to explode due to
is exposed to extreme heat. These products may physical impact. For example:
include carbon monoxide, carbon dioxide, phosgene,
?Being dropped, bumped, knocked over, or jarred
or hydrogen cyanide.
during transport
In other countries, these products are included in a
[29] Explosion Data -- Sensitivity to Static Discharge --
section headed Hazardous Decomposition Products.
Indicate if the product is likely to explode or catch
In Canada, a distinction is made between the
fire from a nearby spark from static electricity.
concepts of combustion product and decomposition
product. (See information item [33] Hazardous
Static electricity can build up in a solution or on the
Decomposition Products on page 66). walls of a container as the result of pouring or even
by convection currents in the solution.
Combustion products are formed when a chemical
is burned, and is an oxidation reaction. For example:
Grounding and bonding of containers is required.
3
?When diethylether is burned, the hazardous
combustion products are carbon dioxide and
carbon monoxide
Section 5: Reactivity Data
This section lists conditions and other substances that should be avoided to prevent dangerous reactions.
SECTION 5 -- Reactivity Data
Chemical Stability If no, under which conditions?
[30] Yes No
Incompatibility with Other Substances If yes, which ones?
[31] Yes No
Reactivity, and Under What Conditions?
[32]
Hazardous Decomposition Products
[33]
[30] Chemical Stability -- Indicate if the product is Contact may result in explosive conditions or
chemically stable when used as intended or placed production of toxic gases. For example:
in extended storage. State if the material is unstable,
?The salt sodium cyanide reacts with mildly acidic
and describe under what conditions the material will
solutions to produce hydrogen cyanide gas
likely change. For example:
?Sodium hydroxide reacts with metals such as
?Vigorously polymerize, decompose, condense,
aluminum to produce hydrogen gas
become self-reactive
Simply list general categories of chemicals that react
Conditions could include impact, vibration, pressure,
with the product, rather than describing individual
and temperature changes. For example:
reactions. For example:
?Peroxides may form
?Acids and caustics
[31] Incompatibility with Other Substances -- List any
?Organic materials and strong oxidizers
other substances (e.g., water, other chemicals, or
chemical groups) that could cause dangerous ?Glacial acetic acid and concentrated nitric acid
reactions when the two products come in contact.
PART 3 ?Step 3: Prepare the MSDS 65
[32] Conditions of Reactivity -- Specify any special condi- react with oxygen in air to form explosive peroxides.
tions under which hazardous reactions may occur. For example:
?Diethyl ether decomposes on contact with
The potential for vigorous polymerization should be
included in this location. For example: oxygen in air to form explosive peroxides
?Methyl methacrylate The product may react with moisture in air to form
very toxic gases. For example:
?Butadiene
?Stannous chloride decomposes with moisture in
[33] Hazardous Decomposition Products -- List danger- air to form hydrogen chloride vapour
ous products released by the material upon aging
or reaction with airborne oxygen or moisture. Note This information item does not include the results of
burning or excess heating (please refer to informa-
that most products do not decompose. The typical
entry here will be "None." However, a product may tion item [27] Hazardous Combustion Products,
page 65).
Section 6: Toxicological Properties
This section identifies how the substance enters the body and the possible health effects from single or repeated
exposures. Section 6 also identifies known long-term health effects such as liver or kidney damage, sensitization, cancer,
or reproductive effects.
SECTION 6 -- Toxicological Properties
Routes of Entry
[34] Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
[35]
Effects of Chronic Exposure to Product
[36]
Exposure Limits (value, source, date) Irritancy (if yes, explain)
[37] [38]
Yes No
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)
[39] [40]
Yes No Yes No
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
[41] [42]
Yes No Yes No
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
[43] [44]
Yes No Yes No
?Short-term exposure to relatively high concentra-
[34] Routes of Entry -- Describe how the product enters
the body during normal use. tion of an organic solvent may cause any of the
typical symptoms ranging from drowsiness to
Five routes of entry are standard: skin contact, skin stupor to coma to death.
absorption, eye contact, inhalation, and/or inges-
?Exposure to high concentrations of
tion. The MSDS must identify all route(s) applicable
to the product. perchlorethylene in a tanker car may cause
narcosis or death.
[35] Effects of Acute Exposure to Product -- List the
adverse health effects resulting from short-term [36] Effects of Chronic Exposure to Product -- List the
exposure to the substance, either as a single adverse health effects resulting from repeated
exposure or as multiple exposures occurring within exposure over a relatively long period of time,
a short time, usually 24 hours or less. For example: anywhere from several days to years, where symp-
toms do not appear until much later. For example:
66 PART 3 ?Step 3: Prepare the MSDS
?Multiple skin exposure over weeks or months [37] Exposure Limits (value, source, date) -- State the
leading to dermatitis maximum allowable airborne concentration to which
nearly all workers may be repeatedly exposed day
?Exposure to silica may cause silicosis in the lungs after day without adverse effect.
?Exposure to an organic solvent may cause Several types of exposure limits are in common use:
damage to the liver or kidneys
8-hour TWA Limit Short-Term Exposure Limit Ceiling Exposure Limit
(STEL) (C)
The time-weighted average The short-term exposure limit, The ceiling concentration of an
concentration for a normal 8-hour i.e., the maximum concentration to airborne substance that must not be
work day, or 40-hour work week, to which workers can be periodically exceeded at any time. This limit is
which nearly all workers can be exposed for up to 15 minutes without applied to substances that are
repeatedly exposed without suffering from irritation, chronic or predominately irritant or fast-acting
3
adverse effect. irreversible tissue change, or and for which the TWA is
narcosis of sufficient degree to inappropriate.
increase accident proneness, or
impair ability for self rescue.
The source and date of values should be referenced. The Aggravation of a pre-existing condition or the development
recommended exposure limits are published by the of an occupational disease may affect a smaller percentage
American conference of Governmental Industrial Hygien- more seriously.
ists (ACGIH), the National Institute for Occupational
The legal exposure limits for a particular province or
Safety and Health (NIOSH), or other regulatory agencies.
territory may be different from the ones listed on the MSDS.
Because of individual susceptibility, some workers may For example, the following is an excerpt from the
BC Occupational Health and Safety Guidelines 296/05:
experience discomfort at or below the exposure limit.
TABLE 5.4: Exposure Limits for Chemical and Biological Substances (excerpt)
Substance [CAS No.] TWA STEL Notations
ABATE (SEE TEMEPHOS)
ACETALDEHYDE [75-07-0] C 25 ppm 2B
ACETAMIDE [60-35-5] 2B
ACETIC ACID [64-19-7] 10 ppm 15 ppm
ACETIC ANHYDRIDE [108-24-7] 5 ppm
ACETONE [67-64-1] 250 ppm 500 ppm
K designation = possible, suspected, or confirmed human carcinogen
?Irritancy is often described as mild, moderate,
[38] Irritancy of Product -- Describe the ability of the
product to irritate the skin, eyes, nose, throat, respira- or severe.
tory system, or any other part of the body upon
?Most substances will produce some irritation. To
contact. Irritancy is the ability to produce tearing,
be classified as an irritant under WHMIS, the
reddening, swelling, itching, and/or pain. Such an
irritation must meet criteria as listed in CPR 60.
irritation is, by definition, temporary and reversible.
Moderate to severe irritation meets this criteria.
The following points should be kept in mind:
PART 3 ?Step 3: Prepare the MSDS 67
?If no test data exists for either skin or eye [41] Reproductive Toxicity -- Indicate if the product can
irritation, the supplier must report irritancy on cause reproductive problems such as infertility or
the basis of personal experience and knowledge sterility in males or females. For example:
(CPR 60)
?Ethylene glycol monomethyl ether
?No product can be both an irritant (D2B) and a
?Ethylene glycol monoethyl ether
corrosive (E). Because corrosion is more severe
than irritation, classify such products as corrosive.
[42] Teratogenicity -- Indicate if the product may cause
birth defects to an unborn at exposures that do not
?This item refers to chemical irritation rather than
cause damage or injury to the mother. For example:
mechanical abrasion. For example, ordinary sand
is not considered to be an irritant under WHMIS.
?Lead
[39] Sensitization -- Indicate if the substance is likely to ?Mercury
cause an allergic skin and/or lung reaction.
Note: Embryotoxicity -- Indicate if a product may
A sensitizer may cause severe allergic reactions with
cause toxic effects to an unborn child but not the
subsequent exposure. Sensitized persons become pregnant mother. For example:
progressively more reactive to smaller amounts of
the allergen. For example: ?Xylene (mixed isomers)
?Products containing isocyanates, formaldehyde, [43] Mutagenicity -- Indicate if the product can cause
or methyl methacrylate changes to the genetic material (DNA) of living cells
in the body.
Note: To be considered a sensitizer, a substance has
to cause sensitization in the workplace to non-atopic ?Ethylene oxide
persons. (Atopic refers to a hereditary tendency to
[44] Synergistic Products -- Identify other products that,
experience immediate allergic reactions such as
when combined with the controlled product, can
asthma or dermatitis because of the presence of an
cause adverse health effects that are worse than the
antibody in the skin and sometimes the bloodstream.)
effects of either material alone. For instance:
[40] Carcinogenicity -- State if the product, or one or
Each acting alone, product A increases the chance of
more of the ingredients in a mixture, is classified as
developing cancer by two times, and product B
a possible human carcinogen by the International
increases the chance by two times as well. When
Agency for Research on Cancer (IARC Groups 1, 2A,
product A and B are used together, however, the
or 2B), or by the ACGIH (ACGIH Groups A1, A2, or
chances for developing cancer can be increased by
A3). For example:
as much as 50 times. For example:
?Methylene chloride
?Asbestos plus tobacco smoke and their effect on
?Crystalline silica the lungs
ACGIH classification for carcinogens changed to ?Carbon tetrachloride and ethanol and their effect
include Group A3 in 1993 but the CPR requirement on the liver
in section 54 has not yet been amended to reflect
this change.
68 PART 3 ?Step 3: Prepare the MSDS
Section 7: Preventive Measures
This section includes information on required protective equipment, and describes how to safely clean up spills and
safely use, handle, store, dispose of, and transport the product.
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
[45]
If checked, specify type
Engineering Controls (specify, such as ventilation, enclosed process)
[46]
Leak and Spill Procedure
[47]
Waste Disposal
3
[48]
Handling Procedures and Equipment
[49]
Storage Requirements
[50]
Special Shipping Information PIN
[51]
The intent of this section is to provide concise, a) Gloves -- if the product is toxic by skin contact
simple information to the user of the product. or absorption, or is corrosive or an irritant,
Section 7 should neither discuss in detail the specify the type of glove that will provide a
selection of an item of personal protective equip- good level of protection.
ment (PPE), nor outline an exhaustive work
No material is totally impervious or solvent-
procedure that is potentially applicable to every
resistant. The supplier is not expected to be
routine or emergency situation.
responsible for variations in the glove-manufac-
[45] Personal Protective Equipment -- List specific PPE turing processes; if
and types of equipment required by workers to the supplier is
prevent exposure to the product. This list includes concerned about
gloves, respirators, eye protection, footwear, clothing, potential legal
and any other protective equipment required. liability, the
information can be
This section should not include a general disclaimer, provided in an
for example, that PPE is "not required under normal advisory manner.
use conditions." Such statements provide no useful For example:
information to the user, who may work under
?Wear chemical-resistant gloves, such as
different "normal use" conditions such as a confined
or enclosed space. neoprene or nitrile rubber.
If the supplier feels that a disclaimer is necessary, it The product manufacturer is expected to know
must be accompanied by the specific information best the correct glove material for the product
suggested in the following sections: when used as intended. The manufacturer will
have already researched the degradation/
permeability of glove materials when the proper
protection for employees in the manufacturing
plant was determined.
PART 3 ?Step 3: Prepare the MSDS 69
b) Respirator -- The supplier is not expected to d) Footwear -- Identify any requirements apart from
discuss every level of respirator marketed. normal work footwear. For example:
Instead, the supplier should identify the minimum
?Rubber overshoes are required because the
level of respiratory protection that provides an
substance (e.g., ethylene oxide, acids, or
effective barrier against the product. For example:
hydrazine) will rapidly penetrate or degrade
?Specifying that only air-supplied respirators normal leather footwear.
can be used for work with methanol.
e) Clothing -- Identify any special clothing needs
The user (employer) is responsible for determin- apart from normal work clothes. For example:
ing the possible exposure levels that employees
?PVC apron, full-body, protective suit
will face and confirming (usually with the
supplier of the [46] Engineering Controls -- List the specific engineering
respirator) if the controls recommended for reducing the hazards of
minimum protec-
the product. Engineering controls are preferred over
tion will be the use of PPE. For example:
sufficient.
?Local exhaust ventilation, general ventilation,
The supplier is
process equipment design
expected to
reaffirm that a Do not try to determine the detailed ventilation
specific standard is needs of any individual workplace, but do identify
met. For example: the need for carefully engineered, local exhaust
ventilation rather than general ventilation.
?The statement "Use at least a NIOSH-
approved, full-face, organic vapour cartridge If appropriate, advise if the product should be used
respirator" provides the user with all the only in an approved, mechanically ventilated
information necessary without the confusion enclosure, such as a spray booth.
of unnecessary qualifying information.
[47] Leak and Spill Procedure -- List safe work proce-
c) Eye -- Almost every controlled product is harmful dures for handling spills, leaks, and other accidental
to the eyes, and eye protection will be required. releases of the product. For this item, include the
following points where needed:
Chemical goggles and/or a full face-shield is the
norm. Safety glasses may not be recognized by ?Include any required PPE, neutralizing agent,
Eye Protection standards as acceptable protec- absorbing agent, equipment (e.g., special
tion in some vacuum) needed for clean-up.
situations, even
Briefly identify any additional precautions needed --
when fitted with
over and above any recommendations given previously.
side-shields.
Give general advice to remind the employer to plan
Where a variety of
for certain problems, such as:
eye protection is
possible, the MSDS
?Controlling all sources of ignition (vapours can
may refer to an
travel a lot further than the visible extent of a
applicable standard (e.g., CSA Z94.3 - 92) to
liquid spill may indicate)
help the user determine the most appropriate
level of protection.
70 PART 3 ?Step 3: Prepare the MSDS
?Using greater levels of PPE, such as self- [50] Storage Requirements -- Provide specific, safe-storage
contained breathing apparatus (SCBA) rather information such as storage temperature, control of
than a dual-cartridge respirator ignition sources, separation from other incompatible
materials, shelf life, testing for peroxide formation,
Advise if the product can harm fish or disrupt the and sensitivity to light, temperature, or moisture.
processes at a sewage treatment plant:
This item is intended to give brief advice to the user.
?Keep away from all watercourses and For example:
?Do not flush down the storm sewer or ?Store in a cool, dry place.
sanitary sewer.
?Keep away from any sources of ignition (heat,
Be specific about the absorbent material needed for sparks, and flames).
diking a large spill. Sand and sawdust are unlikely to
be acceptable for spills of organic solvent, as they do Also use this location to warn against unusual
not control vapour, but: properties, the significance of which may not be
3
immediately apparent to the reader. For example:
?Sand or soil may be useful in preventing the
?The Physical Properties section may have
spread of an acid or caustic spill.
specified the Freezing/Melting Point as 8癈.
[48] Waste Disposal -- Provide information such as Since aqueous products expand when they
proper waste container design, safe procedures for freeze, the product must be stored in a heated
handling waste, and agencies to contact regarding storage area when temperatures drop below 8?C.
disposal requirements. For example: Otherwise, damaged containers may start leaking
their contents once they start to thaw.
?Dispose of in accordance with local, provincial
(state), and federal regulations. [51] Special Shipping Information -- Include safe-shipping
information, such as sensitivity to temperature or
[49] Handling Procedures and Equipment -- Identify
shock. As a quick reference for those transporting
particular procedures and equipment required to
the product, the TDG manifest and placard require-
handle the product safely. For example:
ments may be included. For example:
?Avoid contact with skin and eyes by wearing
?Four-digit Product Identification Number (PIN)
nitrile gloves and goggles.
used for shipping, also known as United Nations
(UN) number or North America (NA) number.
?Use in a well-ventilated area or wear
PIN refers to the product, not the ingredients.
NIOSH-approved respirator with organic
vapour cartridges.
?Packing group as determined by TDG legislation.
?Keep container closed when not in use.
?Classification as determined by TDG legislation.
?Keep away from heat, sparks, and open flame.
?Proper shipping name.
?Ground and bond containers and equipment to
avoid accumulation of static charge.
?Do not pressurize, cut, heat, or weld empty
containers.
PART 3 ?Step 3: Prepare the MSDS 71
Section 8: First Aid Measures
This section contains specific instructions for the immediate treatment of a worker who has inhaled or swallowed the
product, or who has had skin or eye contact with the product.
SECTION 8 -- First Aid Measures [52]
Inhalation
Ingestion
Skin Contact
Eye Contact
[52] Specific First Aid Measures -- Provide specific, step- contain antidotes, which are essential for crucial first
by-step procedures for immediate first aid. response. For example:
?Use of calcium gluconate paste or zephiran
Separate, specific procedures are needed for the
management of each route of entry (eye, skin chloride for treatment of hydrofluoric acid burns
contact or absorption, ingestion and inhalation).
Note: See General Guidelines for First Aid
Indicate any specific antidotes or any other treat- Statements, for each route of entry, on page 149 in
ment. Note: First aid kits at the workplace should the "Supplier Label" chapter.
Section 9: Preparation Information
This section contains the date the MSDS was prepared and the name of the person who prepared it.
SECTION 9 -- Preparation Information
Prepared by (group, department, etc.) Telephone Number Preparation Date
[54] [53]
[53] Preparation Date -- Give the date of original [54] Prepared by (group, department, etc.) -- List the
preparation (one of the most important items on the name and telephone number of the person or group
MSDS) or the date of the last review. The MSDS who prepared the MSDS.
must be updated when significant new information
The phone number may be the main switchboard for
arises, or at minimum of every three years.
the supplier's company, but should be a direct line
Even if no significant new information appears to to the person who prepared the MSDS.
have been discovered about the product or its
ingredients, all of the information on the MSDS
must be reviewed once the MSDS is three years old
to determine if current scientific research has
revealed any new properties or hazards.
The date the copy was printed to send to the
customer is not an acceptable substitute for
these dates.
72 PART 3 ?Step 3: Prepare the MSDS
REVIEWING A 9-SECTION MSDS
Suppliers can use the MSDS Checklist (9-Section) to
To prepare a compliant MSDS, suppliers should start
identify missing or incorrect information. See below for a
with the manufacturer's MSDS. To ensure that the
manufacturer's MSDS complies with the HPA and CPR, sample blank MSDS Checklist (9-Section).
suppliers need to review all required information items.
= information present as required
= information inaccurate or missing
N/AP = information not applicable
N/AV = information not available
[ ]= optional information
MSDS CHECKLIST (9-SECTION)
3
SECTION 1 -- Product Information
Product Identifier [WHMIS Classification]
Product Use
Manufacturer's Name Supplier's Name
Street Address Street Address
City, Province/State, Postal/Zip Code City, Province/State, Postal/Zip Code
Emergency Telephone [Fax Number] Emergency Telephone [Fax Number]
SECTION 2 -- Hazardous Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific chemical name for each) (specify species and route) (specify species)
SECTION 3 -- Physical Data
Physical State Odour and Appearance Odour Threshold (ppm)
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
Boiling Point (?C) Freezing Point (?C) pH Coefficient of Water/Oil
Distribution
PART 3 ?Step 3: Prepare the MSDS 73
Product Identifier:
SECTION 4 -- Fire and Explosion Data
Flammability If yes, conditions identified?
Means of Extinction
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
Hazardous Combustion Products
SECTION 5 -- Reactivity Data
Chemical Stability If yes, conditions identified?
Incompatibility with Other Substances If yes, incompatible substances identified?
Reactivity, and Under What Conditions?
Hazardous Decomposition Products
SECTION 6 -- Toxicological Properties
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
Effects of Chronic Exposure to Product
Exposure Limits (value, source, date) Irritancy (if yes, explained?)
Sensitization (if yes, explained?) Carcinogenicity (if yes, explained?)
Reproductive Toxicity (if yes, explained?) Teratogenicity (if yes, explained?)
Mutagenicity (if yes, explained?) Synergistic Products (if yes, explained?)
74 PART 3 ?Step 3: Prepare the MSDS
Product Identifier:
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If any of above checked, type specified?
Engineering Controls (specified, such as ventilation, enclosed process)
Leak and Spill Procedure
Waste Disposal
Handling Procedures and Equipment
3
Storage Requirements
Special Shipping Information PIN
SECTION 8 -- First Aid Measures
Inhalation
Ingestion
Skin Contact
Eye Contact
SECTION 9 -- Preparation Information
Prepared by (group, department, etc.)
Telephone Number Preparation Date (original date or date of last review)
Completed by: Date:
PART 3 ?Step 3: Prepare the MSDS 75
CASE STUDY #6: REVIEWING A 9-SECTION MSDS
Step 1 -- Classify the Product
In Case Study #2 (page 25) and Case Study #5 (page 46),
we classified Best Brake Cleaner 123 (Step 1 in the
Best Brake Cleaner 123 is a controlled product that,
Four Steps to Compliance) and reviewed hazardous
based on its individual ingredients, falls into WHMIS
ingredients for this product (Step 2). In this case study,
hazard class:
we begin Step 3 by continuing the revision of the non-
compliant manufacturer's MSDS.
?B2 -- Flammable Liquid
?D2B -- Chronic Toxic Effects;
Skin/Eye Irritation
Step 2 -- Review Hazardous Ingredients
Best Brake Cleaner 123 contains three hazardous
ingredients:
Component CAS # % (WT)
n-Hexane 110-54-3 15?0%
Ethanol 64-17-5 5?0%
Methanol 67-56-1 15?0%
Step 3 -- Prepare a Compliant MSDS
The first step in preparing a compliant MSDS is reviewing Note that the MSDS Checklist (9-Section) uses the
the manufacturer's MSDS to identify the required following conventions:
information items.
= information present as required
This case study will show the following: = information inaccurate or missing
N/AP = information not applicable
1. The non-compliant manufacturer's MSDS for Best N/AV = information not available
Brake Cleaner 123 with revised hazardous ingredients. [ ]= optional information
2. The MSDS Checklist (9-Section) results for this
MSDS.
76 PART 3 ?Step 3: Prepare the MSDS
1. Best Brake Cleaner 123 MSDS
(non-compliant with revised hazardous ingredients section)
Best Brake Cleaner 123
Stock Number(s): B12345, B9876, B7654
Manufacturer's Name: The Best Oil Company, Inc.
Address: 789 Black Gold Road, CA 34567
N
N
N
N
Emergency Phone: 672-222-1212 or 800-222-3333
Date Printed: 07/10/99
on
on
on
on
SECTION 1 -- Material Identification and Hazard Components
Component CAS Number % (WT) OSHA PEL ACGIH TLV
-c
-c
-c
-c
1. n-Hexane 110-54-3 15?0 50 ppm 50 ppm 3
2. Ethanol 64-17-5 5?0 1000 ppm 1000 ppm
om
om
om
om
3. Methanol 67-56-1 15?0 200 ppm 200 ppm
SECTION 2 -- Physical/Chemical Characteristics
Boiling Point: 151?56?F Specific Gravity: 0.68 @ 60癋
pl
pl
pl
pl
Vapour Density: Evaporation Test: Ethyl Ether
ia
ia
ia
ia
Water Solubility: Less than 0.01 @ 77?F Vapour Pressure: Hexane: 150 mmHg
Ethanol: 51 mmHg
nt
nt
nt
nt
Methanol: 96 mmHg
SECTION 3 -- Fire and Explosion Hazard Data
Flashpoint: < 0?F Method: TCC based on Hexane
M
M
M
M
Flammable Limits in Air % by Volume at: Lower Explosion Limit: 1.8%
SD
SD
SD
SD
Upper Explosion Limit: 11.6%
Extinguishing Media: Use water fog, foam, alcohol foam, carbon dioxide, dry chemical
General Hazard: Extremely flammable. Material will readily ignite at ambient temperature. This liquid is volatile and gives
S
S
S
S
off invisible vapours. Either the liquid or vapour may settle in low areas or travel some distance along the
ground or surface to ignition sources where it may ignite or explode.
Firefighting Use water spray to cool fire exposed surfaces and to protect personnel. Shut off "fuel" to fire. If
Procedures: leak or spill has not ignited, use water spray to disperse the vapours. Either allow to burn under controlled
conditions, or extinguish with foam or dry chemical. Try to cover liquid spills with foam. Respiratory and
eye protection required for firefighting personnel.
Hazardous Combustion Products: Fumes and smoke
PART 3 ?Step 3: Prepare the MSDS 77
SECTION 4 -- Reactivity Hazard Data
Stability: Stable
Incompatibility:
Hazardous Polymerization: Unknown
Hazardous Decomposition Products: Fumes and smoke
N
N
N
N
N
SECTION 5 -- Health Hazard Data
The health effects noted below are consistent with requirements under the OSHA Hazard Communication Standard
on
on
on
on
on
(29 CFR 1910.1200).
Eye Contact: Liquid or vapour can irritate. Prolonged contact may lead to corneal damage.
Skin Contact: Contact may dry the skin. Prolonged contact may cause irritation.
-c
-c
-c
-c
-c
Inhalation: High vapour/aerosol concentrations (greater than approximately 1000 ppm) are irritating to the eyes and the
respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous
system effects, including death.
om
om
om
om
om
Ingestion: Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild
to severe pulmonary injury, possibly progressing to death. Low order of toxicity.
SECTION 6 -- Control and Protective Measures
pl
pl
pl
pl
pl
Respiratory Protection: None under normal conditions of use. Avoid breathing vapours.
Skin Protection: Where contact is likely, wear chemical-resistant/impermeable gloves.
Eye Protection: Use of safety glasses with splash guards or full face shield is recommended.
ia
ia
ia
ia
ia
Ventilation: Sufficient to prevent inhalation of solvent vapours.
Protective Clothing: None under normal use.
Hygienic Work Practices: Eye washes and safety showers in the workplace are recommended.
nt
nt
nt
nt
nt
SECTION 7 -- Precautions for Safe Handling and Storage
Steps To Be Taken if Material is Spilled or Released: Avoid breathing vapours. Ventilate area. Dike area to contain spill.
M
M
M
M
M
Remove all sources of ignition. Clean up area with absorbent material and place in closed containers for disposal.
Waste Disposal Method: Dispose of in accordance with local, state, and federal regulations. Before attempting clean-up,
refer to other sections of this MSDS for hazard caution information.
SD
SD
SD
SD
SD
Precautions To Be Taken in Handling Storage: Store and use in cool, dry, well-ventilated areas. Keep away from heat,
sparks, and open flame. If entire contents are not used, replace cap and keep tightly closed. Use adequate ventilation.
SECTION 8 -- Emergency and First Aid Procedures
S
S
S
S
S
Eye Contact: Wash immediately with large volumes of fresh water.
Skin Contact: Flush with large amounts of water. Wash with soap. Remove grossly contaminated clothing, including shoes,
and launder before reuse.
Inhalation: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Keep at
rest. Get immediate medical attention.
Ingestion: If swallowed, DO NOT induce vomiting. Keep at rest. If unconscious, do not give anything by mouth. Immediately
contact a physician.
Health Effects: Simultaneous exposure to the vapours of n-hexane and methyl ethyl ketone or n-hexane and methyl isobutyl
ketone above the recommended workplace limits increases the risk of adverse effects from n-hexane.
SECTION 9 -- Regulatory Information
EPCRA SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE (EHS).
78 PART 3 ?Step 3: Prepare the MSDS
2. Best Brake Cleaner 123 MSDS Checklist (9-Section) Results
= information present as required
= information inaccurate or missing
N/AP = information not applicable
N/AV = information not available
[ ]= optional information
MSDS CHECKLIST (9-SECTION)
SECTION 1 -- Product Information
Product Identifier [WHMIS Classification]
Best Brake Cleaner 123
Product Use
Missing 3
Manufacturer's Name Supplier's Name
Missing
Street Address Street Address
Missing
City, Province/State, Postal/Zip Code City, Province/State, Postal/Zip Code
City missing Missing
Emergency Telephone
[Fax Number] Emergency Telephone [Fax Number]
SECTION 2 -- Hazardous Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific chemical name for each) (specify species and route) (specify species)
n-Hexane Missing Missing
Ethanol Missing Missing
Methanol Missing Missing
SECTION 3 -- Physical Data
Physical State Odour and Appearance Odour Threshold (ppm)
Missing Missing Missing
Specific Gravity
Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
Missing State value for product if Rate is relative to ethyl ether.
known or use values for Actual rate is missing.
individual ingredients.
Boiling Point (?C) Freezing Point (癈) pH Coefficient of Water/Oil Distribution
Missing Missing Missing
PART 3 ?Step 3: Prepare the MSDS 79
Product Identifier: Best Brake Cleaner 123
SECTION 4 -- Fire and Explosion Data
Flammability If yes, conditions identified?
Missing
Means of Extinction
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (癈) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
Missing Missing Missing
Hazardous Combustion Products
Incorrect. Must specify what combustion products.
SECTION 5 -- Reactivity Data
Chemical Stability If yes, conditions identified?
Incompatibility with Other Substances If yes, incompatible substances identified?
Missing
Reactivity, and Under What Conditions?
Missing
Hazardous Decomposition Products
Incorrect. Hazardous decomposition products are substances resulting from aging, heating, and oxidation.
Fumes and smoke result from burning.
SECTION 6 -- Toxicological Properties
Routes of Entry
Skin Contact
Skin Absorption Eye Contact
Inhalation
Ingestion
Incomplete. Skin Absorption: Methanol has a SKIN designation from ACGIH; it can be absorbed through the
skin contributing to the overall exposure. Ingestion: "Low order of toxicity" is incorrect. Ingestion of methanol
may cause blindness and death.
Effects of Acute Exposure to Product
Incomplete. Health effects resulting from short-term exposure (single exposure or multiple exposure within a
short time, usually 24 hours) must be separated from chronic health effects.
Effects of Chronic Exposure to Product
Incomplete. Health effects resulting from repeated exposure to the product over a relatively long period of time
must be separated from acute health effects.
Exposure Limits (value, source, date) Irritancy (if yes, explained?)
Incomplete. None are established for the product, so
need most current exposure limits for the ingredients.
Sensitization (if yes, explained?) Carcinogenicity (if yes, explained?)
Missing Missing
Reproductive Toxicity (if yes, explained?) Teratogenicity (If yes, explained?)
Missing Missing
Mutagenicity (if yes, explained?) Synergistic Products (if yes, explained?)
Missing Missing
80 PART 3 ?Step 3: Prepare the MSDS
Product Identifier: Best Brake Cleaner 123
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If any of above checked, type specified?
Incorrect. For Gloves and Eye protection, must specify type of personal protective equipment. For Respirator
and Clothing, MSDS incorrectly indicates none required. (Note Section 6 Toxicological Properties indicates
inhalation and skin contact/absorption are potential routes of entry).
Engineering Controls (specified, such as ventilation, enclosed process)
Missing
Leak and Spill Procedure
Incomplete. Must specify how to avoid breathing vapours and the type of absorbent material to use.
Waste Disposal
3
Handling Procedures and Equipment
Incomplete. Product is classified as flammable; add information on grounding and bonding of containers when
filling or emptying containers, and state no welding or flame-cutting containers.
Storage Requirements
Special Shipping Information PIN
Missing. Must provide information on safe shipment of product. Reference Missing
should be made to the TDG Regulations.
SECTION 8 ?First Aid Measures
Inhalation
Incomplete. Administration of oxygen should be performed only by a qualified person.
Ingestion
Skin Contact
Eye Contact
Incomplete. Need to indicate time required to flush eyes.
Incorrect. Synergistic effects should be in Section 6 Toxicological Properties.
SECTION 9 ?Preparation Information
Prepared by (group, department, etc.)
Missing
Telephone Number Preparation Date (original date or date of last review)
Missing Missing
PART 3 ?Step 3: Prepare the MSDS 81
PREPARING A COMPLIANT 9-SECTION MSDS
To prepare a compliant MSDS, suppliers should start with 3. Revise the MSDS or prepare a new MSDS as required
the manufacturer's non-compliant MSDS, revised with the to meet Canadian requirements.
correct hazardous ingredients information. To ensure that
When researching problem areas, refer to these resources:
the manufacturer's MSDS complies with the HPA and
CPR, suppliers need to complete the following steps:
?The table, Sources for MSDS Information Items, on
page 229. This table identifies various sources to
1. Review the MSDS. Use the MSDS Checklist (9-
check when completing the information items
Section) to identify missing or incorrect information.
required on an acceptable Canadian MSDS. An
See the back folder of this guide for a blank MSDS
excerpt of the table is shown below:
Checklist (9-Section).
2. Research problem areas in order to:
?Find missing information
?Revise incorrect information
?Verify information (if necessary)
Sources of MSDS Information Items (excerpt)
CPR Items Where to Find the Information
Physical Data
?br>
10. Physical state By Observation, Manufacturer, Supplier
?br>
11. Odour and appearance By Observation, Harper
?br>
12. Odour threshold 3M Respirator Guide, CCOHS (CHEMINFO), NIOSH
?br>
13. Specific gravity CCOHS (CHEMINFO), CRC, Merck, Manufacturer, Physical Laboratory Testing,
(for pure substances) Professional Judgment, Sax
?Technical Information Contacts, page 213, which ?WHMIS-Related Internet Sites, which are listed on
provides details (address, telephone number, etc.) for page 218
all of the information sources listed in Sources for
MSDS Information Items
82 PART 3 ?Step 3: Prepare the MSDS
CASE STUDY #7: PREPARING A COMPLIANT 9-SECTION MSDS
In Case Study #2 (page 25) and Case Study #5 (page 46), 2. The MSDS Checklist (9-Section) results for each
we classified Best Brake Cleaner 123 (Step 1 in the MSDS section. Potential sources for finding or
Four Steps to Compliance) and reviewed hazardous verifying information are listed and can be referenced
ingredients for this product (Step 2). In Case Study #6 in the table Sources for MSDS Information Items.
(page 76) we reviewed the manufacturer's MSDS for Best Note that different sources provide similar informa-
Brake Cleaner 123. This case study will complete Step 3 tion.
of the process.
3. The revised supplier's MSDS. The supplier will have
revised the MSDS based on an information search to
Step 3 -- Prepare 9-Section MSDS ensure that the MSDS is compliant in Canada. Revised
information in the case study will be highlighted in red.
This case study will show how to prepare a compliant
MSDS for Best Brake Cleaner 123. For each of the Note that the MSDS Checklist (9-Section) uses the
nine MSDS sections, this case study will show the following conventions:
3
following items:
= information present as required
1. Each section of the manufacturer's MSDS for Best = information inaccurate or missing
Brake Cleaner 123. N/AP = information not applicable
N/AV = information not available
[ ]= optional information
PART 3 ?Step 3: Prepare the MSDS 83
Case Study #7: Section 1 -- Product Information
Manufacturer's Material Safety Data Sheet
Best Brake Cleaner 123
Stock Number(s): B12345, B9876, B7654
Manufacturer's Name: The Best Oil Company, Inc.
Address: 789 Black Gold Road, CA 34567
Emergency Phone: 672-222-1212 or 800-222-3333
Date Printed: 07/10/05
MSDS Checklist (9-Section) Results
SECTION 1 -- Product Information
Product Identifier [WHMIS Classification]
Product Use
Manufacturer's Name Supplier's Name
Street Address Street Address
City, Province/State, Postal/Zip Code City, Province/State, Postal/Zip Code
Emergency Telephone [Fax Number] Emergency Telephone [Fax Number]
Revised Material Safety Data Sheet (compliant)
SECTION 1 -- Product Information
Product Identifier WHMIS Classification (optional)
Best Brake Cleaner 123 B2, D2B
Product Use
Automotive Cleaner
Manufacturer's Name Supplier's Name
The Best Oil Company, Inc. ABC Distributors
Street Address Street Address
789 Black Gold Road 2234 Speedy Avenue
City Province City Province
Windy Bay CA, USA Toner Town BC
Postal Code Emergency Telephone Postal Code Emergency Telephone
34567 (672) 222-1212 or S2S 2S2 1-800-444-5555
800-222-3333
84 PART 3 ?Step 3: Prepare the MSDS
Case Study #7: Section 2 -- Hazardous Ingredients
Manufacturer's Material Safety Data Sheet
SECTION 1 -- Material Identification and Hazard Components
Component CAS Number % (WT) OSHA PEL ACGIH TLV
1. n-Hexane 110-54-3 15?0 50 ppm 50 ppm
2. Ethanol 64-17-5 5?0 1000 ppm 1000 ppm
3. Methanol 67-56-1 15?0 200 ppm 200 ppm
MSDS Checklist (9-Section) Results
3
SECTION 2 -- Hazardous Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific chemical name for each) (specify species and route) (specify species)
n-Hexane
sources include sources include
CCOHS (CHEMINFO, CCOHS (CHEMINFO,
RTECS), CSST, Sax* RTECS), CSST, Sax*
Ethanol sources include sources include
CCOHS (CHEMINFO, CCOHS (CHEMINFO,
RTECS), CSST, Sax* RTECS), CSST, Sax*
Methanol sources include sources include
CCOHS (CHEMINFO, CCOHS (CHEMINFO,
RTECS), CSST, Sax* RTECS), CSST, Sax*
* In this case, the supplier obtained the required information (shown below) from CSST and Sax.
Revised Material Safety Data Sheet (compliant)
SECTION 2 -- Hazardous Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific) (specify species and route) (specify species)
n-Hexane 15?0 110-54-3 15,840 mg/kg (oral, rat) 38,500 ppm/4 hrs (rat)
Ethanol 5?0 64-17-5 7060 mg/kg (oral, rat) 21,000 ppm/4 hrs (rat)
Methanol 15?0 67-56-1 5628 mg/kg (oral, rat) 64,000 ppm/4 hrs (rat)
PART 3 ?Step 3: Prepare the MSDS 85
Case Study #7: Section 3 -- Physical Data
Manufacturer's Material Safety Data Sheet
SECTION 2 -- Physical/Chemical Characteristics
Boiling Point: 151?56?F Specific Gravity: 0.68 @ 60癋
Vapour Density: Evaporation Test: Ethyl Ether
Water Solubility: Less than 0.01 @ 77?F Vapour Pressure: Hexane: 150 mmHg
Ethanol: 51 mmHg
Methanol: 96 mmHg
MSDS Checklist (9-Section) Results
SECTION 3 -- Physical Data
Physical State Odour and Appearance Odour Threshold (ppm)
Sources include Harper Sources include
Is it a gas, liquid, or solid?
Sources include (List of Terms for Scaling Odour Quality). manufacturer, NIOSH, or
manufacture or 3M Respirator Guide.
observation.
Specific Gravity
Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
Check with Relative to ethyl ether.
manufacturer. Check with manufacturer.
Boiling Point (?C) Freezing Point (?C) pH Coefficient of Water/Oil
Note CPR requires Check with Distribution
Test with pH meter/
units of measure- manufacturer. paper if applicable. Check with manufacturer.
ment; either
temperature scale
is acceptable.
Revised Material Safety Data Sheet (compliant)
SECTION 3 -- Physical Data
Physical State Odour and Appearance Odour Threshold (ppm)
Liquid Clear, colourless liquid, faint gasoline-like odour. N/AV
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
0.68 @ 60癋 2.6 103 2.8 (Ethyl Ether = 1)
Boiling Point (?C) Freezing Point (癈) pH Coefficient of Water/Oil Distribution
151?56癋 N/AV N/AP 0.7
86 PART 3 ?Step 3: Prepare the MSDS
Case Study #7: Section 4 -- Fire and Explosion Data
Manufacturer's Material Safety Data Sheet
SECTION 3 -- Fire and Explosion Hazard Data
Flashpoint: < 0?F Method: TCC based on Hexane
Flammable Limits in Air % by Volume at: Lower Explosion Limit: 1.8%
Upper Explosion Limit: 11.6%
Extinguishing Media: Use water fog, foam, alcohol foam, carbon dioxide, dry chemical.
General Hazard: Extremely flammable. Material will readily ignite at ambient temperature. This liquid is volatile and gives
off invisible vapours. Either the liquid or vapour may settle in low areas or travel some distance along the
ground or surface to ignition sources where it may ignite or explode.
3
Firefighting Use water spray to cool fire exposed surfaces and to protect personnel. Shut off "fuel" to fire. If leak or
Procedures: spill has not ignited, use water spray to disperse the vapours. Either allow to burn under controlled
conditions or extinguish with foam or dry chemical. Try to cover liquid spills with foam. Respiratory and
eye protection required for firefighting personnel.
Hazardous Combustion Products: Fumes and smoke
MSDS Checklist (9-Section) Results
SECTION 4 -- Fire and Explosion Data
Flammability If yes, conditions identified?
Check with manufacturer, by physical laboratory testing, or by observation.
Means of Extinction
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
Check with manufacturer. Check with manufacturer. Check with manufacturer.
Hazardous Combustion Products
Must specify what combustion products. Check with manufacturer. In the absence of information from the
manufacturer, check individual ingredients. Sources include CCOHS (CHEMINFO), CSST.
PART 3 ?Step 3: Prepare the MSDS 87
Revised Material Safety Data Sheet (compliant)
SECTION 4 -- Fire and Explosion Data
Flammability If yes, under which conditions?
Ignition sources, static discharge. General hazard: Extremely flammable.
Yes No
Material will readily ignite at ambient temperature. This liquid is volatile and
gives off invisible vapours. Either the liquid or vapour may settle in low areas
or travel some distance along the ground or surface to ignition sources
where it may ignite or explode.
Means of Extinction
Extinguishing Media: Use water fog, foam, alcohol foam, carbon dioxide, dry chemical.
Firefighting Procedures: Use water spray to cool fire exposed surfaces and to protect personnel. Shut off "fuel"
to fire. If leak or spill has not ignited, use water spray to disperse the vapours. Either allow to burn under
controlled conditions or extinguish with foam or dry chemical. Try to cover liquid spills with foam. Respiratory
and eye protection required for firefighting personnel.
Flashpoint (癈) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
-21.7癈 (TCC based on hexane) 11.6% 1.8%
Autoignition Temperature (癈) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
266癈 No Material can accumulate static charges,
which can cause an electrical
discharge. Bond and ground containers
when pouring. DO NOT cut, weld, braze,
solder, drill, grind, or expose containers
to heat, sparks, static electricity, or other
sources of ignition. They may explode
and cause injury or death.
Hazardous Combustion Products
Carbon monoxide, carbon dioxide, and formaldehyde
88 PART 3 ?Step 3: Prepare the MSDS
Case Study #7: Section 5 -- Reactivity Data
Manufacturer's Material Safety Data Sheet
SECTION 4 -- Reactivity Hazard Data
Stability: Stable
Incompatibility:
Hazardous Polymerization: Unknown
Hazardous Decomposition Products: Fumes and smoke
MSDS Checklist (9-Section) Results
3
SECTION 5 -- Reactivity Data
Chemical Stability If yes, conditions identified?
Incompatibility with Other Substances If yes, incompatible substances identified?
Since this product is flammable, the MSDS should indicate "strong oxidizing agent." Check with manufacturer.
In the absence of information from the manufacturer, check individual ingredients. Sources include CCOHS
(CHEMINFO), CSST.
Reactivity, and Under What Conditions?
Check with manufacturer. In the absence of information from the manufacturer, check individual ingredients.
Sources include CCOHS (CHEMINFO), CSST.
Hazardous Decomposition Products
Hazardous decomposition products are substances as a result of aging, heating, and oxidation. Fumes and
smoke result from burning. Check with manufacturer. In the absence of information from the manufacturer,
check individual ingredients. Sources include CCOHS (CHEMINFO), CSST.
Revised Material Safety Data Sheet (compliant)
SECTION 5 -- Reactivity Data
Chemical Stability If no, under which conditions?
Stable. Yes No
Incompatibility with Other Substances If yes, which ones?
Keep away from strong oxidizing agents
Yes No
Reactivity, and Under What Conditions?
N/AP
Hazardous Decomposition Products
None
PART 3 ?Step 3: Prepare the MSDS 89
Case Study #7: Section 6 -- Toxicological Properties
Manufacturer's Material Safety Data Sheet
SECTION 5 -- Health Hazard Data
The health effects noted below are consistent with requirements under the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Eye Contact: Liquid or vapour can irritate. Prolonged contact may lead to corneal damage.
Skin Contact: Contact may dry the skin. Prolonged contact may cause irritation.
Inhalation: High vapour/aerosol concentrations (greater than approximately 1000 ppm) are irritating to the eyes and the
respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and other central nervous
system effects, including death.
Ingestion: Small amounts of this product aspirated into the respiratory system during ingestion or vomiting may cause mild
to severe pulmonary injury, possibly progressing to death. Low order of toxicity.
MSDS Checklist (9-Section) Results
SECTION 6 -- Toxicological Properties
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Note: The reference to OSHA standards is not required. Skin Absorption: Methanol has a SKIN designation
from ACGIH; it can be absorbed through the skin contributing to the overall exposure. Ingestion: "Low order of
toxicity" is incorrect. Ingestion of methanol may cause blindness and death. Check with manufacturer. In the
absence of information from the manufacturer, check individual ingredients. Sources include: CCOHS
(CHEMINFO), CSST, Provincial/Territorial OH&S Requirements.
Effects of Acute Exposure to Product
Health effects resulting from short- term exposure (single exposure or
multiple exposure within a short time, usually 24 hours) should be separated from chronic health effects.
Effects of Chronic Exposure to Product Health effects resulting from repeated exposure to the product over a
relatively long period of time. Check with manufacturer. In the absence of information from the manufacturer,
check individual ingredients. Sources include: CCOHS (CHEMINFO), CSST.
Exposure Limits (value, source, date) Irritancy (if yes, explained?)
Identify most current values. Use exposure limits
for the ingredients. Check ACGIH.
Sensitization (if yes, explained?) Carcinogenicity (if yes, explained?)
In the absence of information from the manufacturer, In the absence of information from the manufacturer,
check individual ingredients. Sources include: check individual ingredients. Sources include:
CCOHS (CHEMINFO), CSST, Patty's. CCOHS (CHEMINFO), CSST.
Reproductive Toxicity (if yes, explained?) Teratogenicity (if yes, explained?)
In the absence of information from the manufacturer, In the absence of information from the manufacturer,
check individual ingredients. Sources include: check individual ingredients. Sources include:
CCOHS (CHEMINFO), CSST, Patty's. CCOHS (CHEMINFO), CSST, Patty's.
Mutagenicity (if yes, explained?) Synergistic Products (if yes, explained?)
In the absence of information from the manufacturer, Check with manufacturer (Note Section 8 -- First Aid
check individual ingredients. Sources include: Measures in this case study).
CCOHS (CHEMINFO), CSST.
90 PART 3 ?Step 3: Prepare the MSDS
Revised Material Safety Data Sheet (compliant)
SECTION 6 -- Toxicological Properties
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
Eye Contact: Liquid or vapour can irritate. Prolonged contact may lead to corneal damage.
Skin Contact: Contact may dry the skin. Prolonged contact may cause irritation.
Inhalation: High vapour/aerosol concentrations (greater than approximately 1000 ppm) are irritating to the eyes
and the respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconsciousness, and
other central nervous system effects, including death.
Ingestion: Ingestion of methanol may cause blindness and death. Small amounts of this product aspirated into
the respiratory system during ingestion or vomiting may cause mild to severe pulmonary injury, possibly
progressing to death.
Effects of Chronic Exposure to Product
3
Long-term exposure may result in muscular weakness or "wrist-drop syndrome," a peripheral neuropathy, from
n-hexane, and possible liver and kidney injuries.
Exposure Limits (value, source, date) Irritancy (if yes, explain)
n-hexane: 50 ppm (skin) ACGIH, TWA 2005 Can be irritating to eyes, skin,
Yes No
methanol: 200 ppm (skin) ACGIH, TWA 2005 and respiratory tract.
ethanol: 1000 ppm ACGIH, TWA 2005
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)
Yes No Yes No
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
None known
Yes No Yes No
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
Exposure to vapours of n-hexane
Yes No Yes No
and methyl ethyl ketone or methyl
isobutyl ketone will increase the
risk of the adverse health effects
from n-hexane.
PART 3 ?Step 3: Prepare the MSDS 91
Case Study #7: Section 7 -- Preventive Measures
Manufacturer's Material Safety Data Sheet
SECTION 6 -- Control and Protective Measures
Respiratory Protection: None under normal conditions of use. Avoid breathing vapours.
Skin Protection: Where contact is likely, wear chemical-resistant/impermeable gloves.
Eye Protection: Use of safety glasses with splash guards or full face shield is recommended.
Ventilation: Sufficient to prevent inhalation of solvent vapours.
Protective Clothing: None under normal use.
Hygienic Work Practices: Eye washes and safety showers in the workplace are recommended.
SECTION 7 -- Precautions for Safe Handling and Storage
Steps To Be Taken if Material is Spilled or Released: Avoid breathing vapours. Ventilate area. Dike area to contain spill.
Remove all sources of ignition. Clean up area with absorbent material and place in closed containers for disposal.
Waste Disposal Method: Dispose of in accordance with local, state, and federal regulations. Before attempting clean-up,
refer to other sections of this MSDS for hazard caution information.
Precautions To Be Taken in Handling Storage: Store and use in cool, dry, well-ventilated areas. Keep away from heat,
sparks, and open flame. If entire contents are not used, replace cap and keep tightly closed. Use adequate ventilation.
MSDS Checklist (9-Section) Results
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If any of above checked, type specified?
For Gloves and Eye protection, must specify type of PPE. For Respirator and Clothing, MSDS incorrectly
indicates none required (Note Section 6 -- Toxicological Properties indicates inhalation and skin contact/
absorption are potential routes of entry). Check with manufacturer.
Engineering Controls (specified, such as ventilation, enclosed process)
Must specify the engineering controls to be used. Check with manufacturer.
Leak and Spill Procedure
Must specify how to avoid breathing vapours and the type of absorbent material to use. Check with manufacturer.
Waste Disposal
Handling Procedures and Equipment
This product is classified as flammable; add information on grounding and bonding of containers when filling
or emptying containers, and state no welding or flame-cutting containers. Check with manufacturer.
Storage Requirements
Special Shipping Information PIN
Must provide information on safe shipment of product. Reference should be
made to the TDG Regulations. Sources include CANUTEC or TDG Regulations.
92 PART 3 ?Step 3: Prepare the MSDS
Revised Material Safety Data Sheet (compliant)
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type
Respiratory Protection: Avoid breathing vapours. Wear NIOSH-approved, supplied air respirator. (In confined
spaces, use NIOSH-approved, self-contained breathing apparatus.)
Skin Protection: Neoprene gloves.
Eye Protection: Use of safety glasses with splash guards or full face shield is recommended.
Protective Clothing: Rubber apron.
Engineering Controls (specify, such as ventilation, enclosed process)
Ventilation: Local exhaust ventilation (explosion-proof).
Leak and Spill Procedure
Steps to be taken if material is spilled or released: Emergency response personnel must wear NIOSH-
3
approved, self-contained breathing apparatus and neoprene gloves. Ventilate area. Dike area to contain spill.
Remove all sources of ignition including heat, sparks, and flames. Absorb with sand and place in a tightly
sealed container for disposal.
Waste Disposal
Dispose of in accordance with local, state/provincial or territorial, and federal regulations. Before attempting
clean-up, refer to other sections of this MSDS for hazard caution information.
Handling Procedures and Equipment
Store and use in cool, dry, well-ventilated areas. Ground and bond containers when filling or emptying to avoid
electrical discharge. Do not weld or flame-cut the containers. Keep away from heat, sparks, and open flame.
Storage Requirements
If entire contents are not used, replace cap and keep tightly closed. Use adequate ventilation (local exhaust
ventilation).
Special Shipping Information PIN
Flammable liquids (NOS), UN1993, Class 3, Packing group I 1993
PART 3 ?Step 3: Prepare the MSDS 93
Case Study #7: Section 8 -- First Aid Measures
Manufacturer's Material Safety Data Sheet
SECTION 8 -- Emergency and First Aid Procedures
Eye Contact: Wash immediately with large volumes of fresh water.
Skin Contact: Flush with large amounts of water. Wash with soap. Remove grossly contaminated clothing, including shoes,
and launder before reuse.
Inhalation: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Keep at
rest. Get immediate medical attention.
Ingestion: If swallowed, DO NOT induce vomiting. Keep at rest. If unconscious, do not give anything by mouth. Immediately
contact a physician.
Health Effects: Simultaneous exposure to the vapours of n-hexane and methyl ethyl ketone or n-hexane and methyl isobutyl
ketone above the recommended workplace limits increases the risk of adverse effects from n-hexane.
MSDS Checklist (9-Section) Results
SECTION 8 -- First Aid Measures
Inhalation
Administration of oxygen should be performed only by a qualified person
Ingestion
Skin Contact
Eye Contact
Need to indicate time required to flush eyes
Synergistic effects should be in Section 6 -- Toxicological Properties
Revised Material Safety Data Sheet (compliant)
SECTION 8 -- First Aid Measures
Inhalation
Remove to fresh air. Administer oxygen if needed. Administration of oxygen should be performed only by a
qualified person. Apply artificial respiration if breathing has stopped. Keep at rest. Get immediate medical
attention.
Ingestion
If swallowed, DO NOT induce vomiting. Keep at rest. If unconscious, do not give anything by mouth.
Immediately contact a physician.
Skin Contact
Flush with large amounts of water. Wash with soap. Remove grossly contaminated clothing, including shoes,
and launder before reuse.
Eye Contact
Flush immediately with large amounts of water for at least 20 minutes. Immediately contact a physician.
94 PART 3 ?Step 3: Prepare the MSDS
Case Study #7: Section 9 -- Preparation Information
Manufacturer's Material Safety Data Sheet
SECTION 9 -- Regulatory Information
EPCRA SECTION 302 EXTREMELY HAZARDOUS SUBSTANCE (EHS)
MSDS Checklist (9-Section) Results
SECTION 9 -- Preparation Information
Prepared by (group, department, etc.)
3
Telephone Number Preparation Date (original date or date of last review)
Revised Material Safety Data Sheet (compliant)
SECTION 9 -- Preparation Information
Prepared by (group, department, etc.) Telephone Number Preparation Date
A. Nother (672) 222-1212 07/10/05
PART 3 ?Step 3: Prepare the MSDS 95
ADDITIONAL EXERCISE
Review a 9-Section MSDS
1. Use a photocopy of the blank MSDS Checklist 2. Using the checklist, review the following MSDS to
(9-Section) that is in the back folder of this guide. determine if it meets Canadian WHMIS requirements.
MATERIAL SAFETY DATA SHEET
Section 1: Product Information
Emergency Telephone: (604) 999-7777
Product Name: Super Wax Remover
Date: 02/12/05
Description of Use: Wax stripper
Small Manufacturing Company
39800 Clean Street
Soapy Harbor, BC V1V 1V1
Section 2: Hazardous Ingredients
Monoethanolamine CAS #: 141-343-5 > 10%
Ethylene glycol monobutyl ether CAS #: 111-76-2 > 10%
Ethylenediamine tetra-acetic acid,
tetra sodium CAS #: 64-02-8 > 10%
NFPA Rating: Health 3; Fire 2; Reactivity 0 WHMIS Classification: B3, D2B, E
Section 3: Toxicological Information
Acute Effects of Overexposure: May irritate eyes and mucous membranes. Skin contact may produce irritation depending
on length of contact time. Overexposure by inhalation may cause respiratory irritation. Ingredients in this product may
aggravate existing skin, eye, or respiratory disorders.
Chronic Effects of Overexposure: Repeated or prolonged exposure of skin can produce chronic dermatitis characterized
by redness, scaling, and blistering. Repeated exposure to spray mists may lead to chronic eye inflammation, chronic
respiratory tract irritation, or lung damage.
Section 4: First Aid Procedures
Skin: Immediately flush contaminated skin with plenty of water for at least 15 minutes. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting upper and lower lids. Get
medical attention at once.
Inhale: Move exposed person to fresh air. Get immediate medical attention.
Ingest: If swallowed, do not induce vomiting. If vomiting occurs, keep head below hip level. Immediately contact a physician.
96 PART 3 ?Step 3: Prepare the MSDS
Section 5: Physical Data
Boiling Point: 100 deg C. Freezing Point: -5 deg C.
Specific Gravity: % Volatile: 1.013
Appearance and Odour: Transparent and ammonia odour
Vapour Density: Physical State: Liquid
pH: Alkaline Evaporation Rate: n/d
Vapour Pressure:
Section 6: Preventative Measures
Special Protection Information:
Protective Clothing: Wear chemical-resistant gloves Eye Protection: Recommended
3
Respiratory Protection: Recommended Ventilation: Recommended
Spill and Disposal Procedures: Observe safety precautions in section 6 during cleanup. Absorb spill on inert absorbent
material. Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
Waste Disposal Method: Unusable material should be properly drummed. Consult local, provincial, and federal agencies
for proper methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
Special Precautions: Do not breathe spray mists or vapours. Clothing or shoes that become contaminated with substance
should be removed promptly and not reworn until thoroughly cleaned. Keep product away from skin and eyes. Keep out of
reach of children.
Section 7: Fire and Explosion Data
Flashpoint: n/a Conditions of Flammability: None
Autoignition Temperature: n/d Flammable Limits: n/a
Hazardous Combustion Products: Carbon dioxide, carbon monoxide, and toxic/corrosive fumes as oxides of phosphorus
Explosion Data: n/d
Section 8: Reactivity Data
Stability: Stable Incompatibility: Strong acids and oxidizing agents
Section 9: Preparation Information
Prepared By: Small Technical Department Phone: (604) 999-8888
PART 3 ?Step 3: Prepare the MSDS 97
Answer:
= information present as required
= information inaccurate or missing
N/AP = information not applicable
N/AV = information not available
[ ]= optional information
MSDS CHECKLIST (9-SECTION)
SECTION 1 -- Product Information
Product Identifier [WHMIS Classification]
Super Wax Remover B3, D2B, E
Product Use
Manufacturer's Name Supplier's Name
Street Address Street Address
City, Province/State, Postal/Zip Code City, Province/State, Postal/Zip Code
Emergency Telephone [Fax Number] Emergency Telephone [Fax Number]
SECTION 2 -- Hazardous Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific chemical name for each) (specify species and route) (specify species)
Monoethanolamine
Monobutyl Ether
Ethylene Glycol
EDTA
SECTION 3 -- Physical Data
Physical State Odour and Appearance Odour Threshold (ppm)
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
Boiling Point (?C) Freezing Point (?C) pH Coefficient of Water/Oil Distribution
Must specify value
98 PART 3 ?Step 3: Prepare the MSDS
Product Identifier: Super Wax Remover
SECTION 4 -- Fire and Explosion Data
Flammability If yes, conditions identified?
Product is B3 (combustible). Conditions of flammability should be listed.
Means of Extinction
Flashpoint (癈) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
Hazardous Combustion Products
SECTION 5 -- Reactivity Data 3
Chemical Stability If yes, conditions identified?
Incompatibility with Other Substances If yes, incompatible substances identified?
Reactivity, and Under What Conditions?
Hazardous Decomposition Products
SECTION 6 -- Toxicological Properties
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
Product is Class E -- Corrosive, yet no mention that it could cause burns
Effects of Chronic Exposure to Product
Product is Class B3, D2B, and E, but no mention of toxic effects
Exposure Limits (value, source, date) Irritancy (if yes, explained?)
Sensitization (if yes, explained?) Carcinogenicity (if yes, explained?)
Reproductive Toxicity (if yes, explained?) Teratogenicity (If yes, explained?)
Mutagenicity (if yes, explained?) Synergistic Products (if yes, explained?)
PART 3 ?Step 3: Prepare the MSDS 99
Product Identifier: Super Wax Remover
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If any of above checked, type specified?
Not specific
Engineering Controls (specified, such as ventilation, enclosed process)
Not specific
Leak and Spill Procedure
Waste Disposal
Handling Procedures and Equipment
Storage Requirements
Special Shipping Information PIN
SECTION 8 -- First Aid Measures
Inhalation
Ingestion
Skin Contact
Eye Contact
SECTION 9 -- Preparation Information
Prepared by (group, department, etc.)
Telephone Number Preparation Date (original date or date of last review)
Comments: Verify the classification with the manufacturer by obtaining missing information (such as %, flammability,
and toxicological properties).
100 PART 3 ?Step 3: Prepare the MSDS
THE 16-SECTION MSDS ?If the 16-heading format is used, state in the Regula-
tory Information section:
Basic Information ?This product has been classified in accordance
with the hazard criteria of the Controlled Prod-
The following statements summarize the requirements for
ucts Regulations (CPR) and the MSDS contains
both 9- and 16-section MSDSs:
all of the information required by the CPR.
?The CPR specifies that an MSDS in Canada should
?If sections are combined, the section heading must
contain nine sections. However, American and
clearly indicate that both CPR sections are included,
European MSDSs that have 16 sections instead of
and the sections must have some commonality. For
nine are also acceptable.
example,
?Canada accepts the International Labour Organization,
?"Health Hazards and First Aid Measures" but not
International Standards Organization or European
Union 16-section MSDS. ?"First Aid Measures and Fire and Explosion Data"
3
?The 9-section headings must be similar to those ?The 16-section format is only acceptable if all informa-
specified in the CPR. tion items are included, if available. A 16-section
MSDS with the required items highlighted follows this
?The 16-section headings must be similar to those
page. A description of the information items can be
specified in the following acceptable standards:
found on pages 58?2). Suppliers can use the MSDS
Checklist (16-Section) to review a 16-section MSDS
?American National Standards Institute (ANSI)
and ensure it contains all required information. See
Standard Z400.1-1998
the back folder of this guide for a blank MSDS
?European Economic Community (EEC) Directive Checklist (16-Section).
91/155/EEC and 93/112/EEC
?International Standards Organization (ISO)
11014-1:1994(E)
PART 3 ?Step 3: Prepare the MSDS 101
16-Section MSDS with Information Items Highlighted
MATERIAL SAFETY DATA SHEET -- 16 SECTIONS
SECTION 1 -- Chemical Product and Company Identification
Product Identifier [WHMIS Classification]
[1]
Product Use
[2]
Manufacturer's Name Supplier's Name
[3] [4]
Street Address Street Address
City Province City Province
Postal Code Emergency Telephone Postal Code Emergency Telephone
Date MSDS Prepared MSDS Prepared by Phone Number
[53] [54]
SECTION 2 -- Composition/Information on Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific) (specify species and route) (specify species)
[5] [6] [7] [8] [9]
SECTION 3 -- Hazards Identification
Routes of Entry
[34] Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
[Emergency Overview]
[WHMIS Symbols]
[Potential Health Effects]
SECTION 4 -- First Aid Measures
Skin Contact
[52]
Eye Contact
[52]
Inhalation
[52]
Ingestion
[52]
102 PART 3 ?Step 3: Prepare the MSDS
Product Identifier:
SECTION 5 -- Firefighting Measures
Flammability If yes, under which conditions?
[21] Yes No
Means of Extinction
[22]
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
[23] [24] [25]
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
[26] [28] [29]
Hazardous Combustion Products
3
[27]
[NFPA]
SECTION 6 -- Accidental Release Measures
Leak and Spill Procedures
[47]
SECTION 7 -- Handling and Storage
Handling Procedures and Equipment
[49]
Storage Requirements
[50]
SECTION 8 -- Exposure Control/Personal Protection
Exposure Limits
ACGIH TLV OSHA PEL Other (specify)
[37]
Specific Engineering Controls (such as ventilation, enclosed process)
[46]
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
[45]
If checked, specify type
PART 3 ?Step 3: Prepare the MSDS 103
Product Identifier:
SECTION 9 -- Physical and Chemical Properties
Physical State Odour and Appearance Odour Threshold (ppm)
[10] [11] [12]
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg)
[13] [14] [15]
Evaporation Rate Boiling Point (癈) Freezing Point (?C)
[16] [17] [18]
pH Coefficient of Water/Oil Distribution [Solubility in Water]
[19] [20]
SECTION 10 -- Stability and Reactivity
Chemical Stability If no, under which conditions?
[30] Yes No
Incompatibility with Other Substances If yes, which ones?
[31] Yes No
Reactivity, and Under What Conditions?
[32]
Hazardous Decomposition Products
[33]
SECTION 11 -- Toxicological Information
Effects of Acute Exposure
[35]
Effects of Chronic Exposure
[36]
Irritancy of Product
[38]
Skin Sensitization Respiratory Sensitization
[39] [39]
Carcinogenicity -- IARC Carcinogenicity -- ACGIH
[40] [40]
Reproductive Toxicity Teratogenicity
[41] [42]
Embryotoxicity Mutagenicity
[42] [43]
Name of Synergistic Products/Effects
[44]
104 PART 3 ?Step 3: Prepare the MSDS
Product Identifier:
SECTION 12 -- Ecological Information
[Aquatic Toxicity]
SECTION 13 -- Disposal Considerations
Waste Disposal
[48]
3
SECTION 14 -- Transport Information
Special Shipping Information PIN
[51]
TDG [DOT]
[IMO] [ICAO]
SECTION 15 -- Regulatory Information
[WHMIS Classification] [OSHA]
[SERA] [TSCA]
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
SECTION 16 -- Other Information
PART 3 ?Step 3: Prepare the MSDS 105
REVIEWING A 16-SECTION MSDS
To prepare a compliant MSDS, suppliers should start with Suppliers can use the MSDS Checklist (16-Section) to
the manufacturer's MSDS. To ensure that the manufactur- identify missing or incorrect information. See below for a
sample blank MSDS Checklist (16-Section).
er's MSDS complies with the HPA and CPR, suppliers
need to review the MSDS to make sure all information
items are present as required.
MSDS Checklist (16-Section)
= information present as required
= information inaccurate or missing
N/AP = information not applicable
N/AV = information not available
[ ]= optional information
SECTION 1 -- Chemical Product and Company Identification
Product Identifier [WHMIS Classification]
Product Use
Manufacturer's Name Supplier's Name
Street Address Street Address
City, Province/State, Postal/Zip Code City, Province/State, Postal/Zip Code
Emergency Telephone [Fax Number] Emergency Telephone [Fax Number]
Date MSDS Prepared MSDS Prepared by Phone Number
SECTION 2 -- Composition/Information on Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific chemical name for each) (specify species and route) (specify species)
SECTION 3 -- Hazards Identification
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
[Emergency Overview]
[WHMIS Symbols]
[Potential Health Effects]
106 PART 3 ?Step 3: Prepare the MSDS
Product Identifier:
SECTION 4 -- First Aid Measures
Skin Contact
Eye Contact
Inhalation
Ingestion
SECTION 5 -- Firefighting Measures
Flammability If yes, conditions identified?
3
Yes No
Means of Extinction
Flashpoint (癈) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (癈) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
Hazardous Combustion Products
[NFPA]
SECTION 6 -- Accidental Release Measures
Leak and Spill Procedures
SECTION 7 -- Handling and Storage
Handling Procedures and Equipment
Storage Requirements
PART 3 ?Step 3: Prepare the MSDS 107
Product Identifier:
SECTION 8 -- Exposure Control/Personal Protection
Exposure Limits
ACGIH TLV OSHA PEL Other (specify)
Specific Engineering Controls (such as ventilation, enclosed process)
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, type specified?
SECTION 9 -- Physical and Chemical Properties
Physical State Odour and Appearance Odour Threshold (ppm)
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg)
Evaporation Rate Boiling Point (?C) Freezing Point (癈)
pH Coefficient of Water/Oil Distribution [Solubility in Water]
SECTION 10 -- Stability and Reactivity
Chemical Stability If no, conditions identified?
Yes No
Incompatibility with Other Substances If yes, incompatible substances identified?
Yes No
Reactivity, and Under What Conditions?
Hazardous Decomposition Products
108 PART 3 ?Step 3: Prepare the MSDS
Product Identifier:
SECTION 11 -- Toxicological Information
Effects of Acute Exposure
Effects of Chronic Exposure
Irritancy of Product
Skin Sensitization (if yes, explained?) Respiratory Sensitization (if yes, explained?)
3
Carcinogenicity -- IARC (if yes, explained?) Carcinogenicity -- ACGIH (if yes, explained?)
Reproductive Toxicity (if yes, explained?) Teratogenicity (if yes, explained?)
Embryotoxicity (if yes, explained?) Mutagenicity (if yes, explained?)
Name of Synergistic Products/Effects
SECTION 12 -- Ecological Information
[Aquatic Toxicity]
SECTION 13 -- Disposal Considerations
Waste Disposal
SECTION 14 -- Transport Information
Special Shipping Information PIN
TDG [DOT]
[IMO] [ICAO]
PART 3 ?Step 3: Prepare the MSDS 109
Product Identifier:
SECTION 15 -- Regulatory Information
[WHMIS Classification] [OSHA]
[SERA] [TSCA]
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
SECTION 16 -- Other Information
Completed by: Date:
110 PART 3 ?Step 3: Prepare the MSDS
COMPARISON OF 16-SECTION AND 9-SECTION FORMATS
16-Section MSDS 9-Section MSDS
(ANSI, EEC, ISO) (Canada)
1. Chemical Product and Company Identification 1. Product Information
(Note: ISO -- Product and Company Identification) 9. Preparation Information
2. Composition/Information on Ingredients 2. Hazardous Ingredients
3. Hazards Identification 6. Toxicological Properties
4. First Aid Measures 8. First Aid Measures
5. Firefighting Measures 4. Fire and Explosion Data
6. Accidental Release Measures 7. Preventive Measures
7. Handling and Storage 7. Preventive Measures
3
8. Exposure Controls/Personal Protection 6. Toxicological Properties
7. Preventive Measures
13. Disposal Considerations 7. Preventive Measures
9. Physical and Chemical Properties 3. Physical Data
10. Stability and Reactivity 5. Reactivity Data
11. Toxicological Information 6. Toxicological Properties
12. Ecological Information Not required under WHMIS
14. Transport Information 7. Preventive Measures (Not all of the information in the
16-section MSDS is required/available under WHMIS)
15. Regulatory Information 2. Product Information (Not all of the information in the
16-section is required/available under WHMIS)
16. Other Information Not required under WHMIS
PART 3 ?Step 3: Prepare the MSDS 111
CASE STUDY #8: CONVERTING A 9-SECTION
MSDS TO A 16-SECTION MSDS
2. Show the section(s) of the compliant 9-section MSDS
Suppliers who supply products to various countries may
that contain corresponding information. (See previous
wish to prepare 16-section MSDSs.
page for comparison table).
The best approach is to start with a compliant 9-section
3. Give the MSDS Checklist (16-Section) results, which
MSDS, and reformat it into 16 sections. See Preparing a
should be used to double-check that all information
Compliant 9-Section MSDS, page 83, for details and a
required under the CPR is included.
case study on preparing a compliant 9-section MSDS.
4. Show 16-section MSDS.
This case study will show how a compliant 9-section
MSDS can be converted into a 16-section MSDS compli-
Note that the MSDS Checklist (16-Section) indicates:
ant in Canada and other countries. For each of the 16
MSDS sections, the case study will: = information present as required
= information inaccurate or missing
1. Show the compliant 9-section MSDS for Super Wax
N/AP = information not applicable
Remover
N/AV = information not available
[ ]= optional information
COMPLIANT 9-SECTION MATERIAL SAFETY DATA SHEET
Product Identifier: Super Wax Remover
SECTION 1 -- Product Information
Product Identifier WHMIS Classification (optional)
Super Wax Remover B3, D2B, E
Product Use
Wax Stripper
Manufacturer's Name Supplier's Name
Small Manufacturing Company Albert's Cleaning Supplies
Street Address Street Address
39800 Clean Street 5454 Mop Road
City Province City Province
Soapy Harbour BC Blue Sky AB
Postal Code Emergency Telephone Postal Code Emergency Telephone
V1V 1V1 (604) 999-7777 Y2Y 2Y2 (780) 888-4444
SECTION 2 -- Hazardous Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific) (specify species and route) (specify species)
Monoethanolamine 10?0 141-43-5 1720 mg/kg (oral, rat) N/AV
Ethylene glycol
monobutyl ether 30?0 111-76-2 560 mg/kg (oral, rat) 486 ppm/4 hrs (rat)
Ethylenediamine tetra-
acetic acid, tetra sodium 1? 64-02-8 3030 mg/kg (oral, rat) N/AV
112 PART 3 ?Step 3: Prepare the MSDS
Product Identifier: Super Wax Remover
SECTION 3 -- Physical Data
Physical State Odour and Appearance Odour Threshold (ppm)
Liquid Transparent; ammonia odour N/AV
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
1.013 4.07 0.67 0.1 (n-butyl acetate = 1)
Boiling Point (?C) Freezing Point (癈) pH Coefficient of Water/Oil Distribution
100 deg. C -5 deg. C 12.5?3.0 2.5
SECTION 4 -- Fire and Explosion Data
Flammability If yes, under which conditions?
Combustible Keep away from strong oxidizing agents, heat, sparks, and flames
Yes No
Means of Extinction
3
Carbon dioxide, fog, and foam
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
60 deg. C (closed cup) 10.6% 1.1%
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
244 deg. C None N/AV
Hazardous Combustion Products
Carbon dioxide, carbon monoxide, and toxic/corrosive fumes as oxides of phosphorus
NFPA: Health 3; Fire 2; Reactivity 0
SECTION 5 -- Reactivity Data
Chemical Stability If no, under which conditions?
Stable Yes No
Incompatibility with Other Substances If yes, which ones?
Strong acids and oxidizing agents
Yes No
Reactivity, and Under What Conditions?
None
Hazardous Decomposition Products
None
SECTION 6 -- Toxicological Properties (excerpt)
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
May cause burns to eyes and skin. Damage to respiratory tract. Ingredients in this product may aggravate
existing skin, eye, or respiratory disorders.
Effects of Chronic Exposure to Product
Repeated or prolonged exposure of skin can cause burns. Repeated exposure to spray mists may lead to
chronic eye inflammation, chronic respiratory tract irritation, or lung damage. Potential for liver, kidney, or red
blood cell damage.
Exposure Limits (value, source, date) Irritancy (if yes, explain)
2005 ACGIH TLVs: Yes No
Monoethanolamine: 3 ppm (TWA)
Ethylene glycol monobutyl ether: 20 ppm, skin (TWA)
Ethylenediamine tetra-acetic acid, tetra sodium: N/AV
PART 3 ?Step 3: Prepare the MSDS 113
Product Identifier: Super Wax Remover
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)
Yes No Yes No
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
None known None known
Yes No Yes No
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
None known None
Yes No Yes No
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type
Protective Gloves: Wear chemical-resistant gloves such as nitrile gloves
Respiratory Protection: Wear NIOSH-approved respirator for organic vapour
Eye Protection: Splash-proof safety goggles
Engineering Controls (specify, such as ventilation, enclosed process)
Use local exhaust ventilation (explosion-proof) to keep concentration of vapours below exposure limits.
Leak and Spill Procedure
Emergency personnel should wear NIOSH-approved organic vapour respirator, nitrile gloves, and splash-proof
safety goggles. Observe safety precautions in Section 7 during clean-up. Absorb spill on inert absorbent material.
Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
Waste Disposal
Unusable material should be properly drummed. Consult local, provincial, and federal agencies for proper
methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
Handling Procedures and Equipment
Do not breathe spray mists or vapours. Keep away from skin and eyes. Use local exhaust ventilation. Clothing
or shoes that become contaminated with substance should be removed promptly and not be worn until
thoroughly cleaned. Keep away from sources of ignition such as heat, sparks, and flames. Bond and ground
containers when pouring. Do not cut or weld empty container.
Storage Requirements
Store in cool, dry, well-ventilated area, away from strong oxidizing agents.
Special Shipping Information PIN
Transportation of Dangerous Goods (TDG) shipping name: 1760
Corrosive liquid NOS (monoethanolamine)
Hazard Class: 8, 9.2, TDG ID Number: UN 1760, TDG label/placard: Corrosive
SECTION 8 -- First Aid Measures
Inhalation
Move exposed person to fresh air. Get immediate medical attention.
Ingestion
If swallowed, DO NOT INDUCE VOMITING. Immediately contact a physician.
Skin Contact
Immediately flush contaminated skin with plenty of water for at least 15 minutes. Get medical attention if
irritation develops.
Eye Contact
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower lids. Get medical
attention at once.
SECTION 9 -- Preparation Information
Prepared by (group, department, etc.) Telephone Number Preparation Date
Mr. Albert (780) 888-5555 04/22/05
114 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 1 -- Chemical Product and Company Identification
9-Section Material Safety Data Sheet (compliant)
SECTION 1 -- Product Information
Product Identifier WHMIS Classification (optional)
Super Wax Remover B3, D2B, E
Product Use
Wax Stripper
Manufacturer's Name Supplier's Name
Small Manufacturing Company Albert's Cleaning Supplies
Street Address Street Address
39800 Clean Street 5454 Mop Road
City Province City Province
3
Soapy Harbour BC Blue Sky AB
Postal Code Emergency Telephone Postal Code Emergency Telephone
V1V 1V1 (604) 999-7777 Y2Y 2Y2 (780) 888-4444
SECTION 9 -- Preparation Information
Prepared by (group, department, etc.) Telephone Number Preparation Date
Mr. Albert (780) 888-5555 04/22/05
MSDS Checklist (16-Section) Results
SECTION 1 -- Chemical Product and Company Identification
Product Identifier [WHMIS Classification]
Product Use
Manufacturer's Name Supplier's Name
Street Address Street Address
City, Province/State, Postal/Zip Code City, Province/State, Postal/Zip Code
Emergency Telephone [Fax Number] Emergency Telephone [Fax Number]
Not required Not required
MSDS Prepared by
Date MSDS Prepared Phone Number
PART 3 ?Step 3: Prepare the MSDS 115
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 1 -- Chemical Product and Company Identification
Product Identifier [WHMIS Classification]
Super Wax Remover B3, D2B, E
Product Use
Wax Stripper
Manufacturer's Name Supplier's Name
Small Manufacturing Company Albert's Cleaning Supplies
Street Address Street Address
39800 Clean Street 5454 Mop Road
City Province City Province
Soapy Harbour BC Blue Sky AB
Postal Code Emergency Telephone Postal Code Emergency Telephone
V1V 1V1 (604) 999-7777 Y2Y 2Y2 (780) 888-4444
Date MSDS Prepared MSDS Prepared by Phone Number
04/22/05 Mr. Albert (780) 888-5555
116 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 2 -- Composition and Information on Ingredients
9-Section Material Safety Data Sheet (compliant)
SECTION 2 -- Hazardous Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific) (specify species and route) (specify species)
Monoethanolamine 10?0 141-43-5 1720 mg/kg (oral, rat) N/AV
Ethylene glycol
monobutyl ether 30?0 111-76-2 560 mg/kg (oral, rat) 486 ppm/4 hrs (rat)
Ethylenediamine tetra-
acetic acid, tetra sodium 1? 64-02-8 3030 mg/kg (oral, rat) N/AV
3
MSDS Checklist (16-Section) Results
SECTION 2 -- Composition/Information on Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific chemical name for each) (specify species and route) (specify species)
Monoethanolamine
Ethylene glycol
monobutyl ether
Ethylenediamine
tetra-acetic acid,
tetra sodium
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 2 -- Composition/Information on Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific) (specify species and route) (specify species)
Monoethanolamine 10?0 141-43-5 1720 mg/kg (oral, rat) N/AV
Ethylene glycol
monobutyl ether 30?0 111-76-2 560 mg/kg (oral, rat) 486 ppm/4 hrs (rat)
Ethylenediamine tetra-
acetic acid, tetra sodium 1? 64-02-8 3030 mg/kg (oral, rat) N/AV
PART 3 ?Step 3: Prepare the MSDS 117
Case Study #8: Section 3 -- Hazards Identification
9-Section Material Safety Data Sheet (compliant)
SECTION 6 -- Toxicological Properties
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
May cause burns to eyes and skin. Damage to respiratory tract. Ingredients in this product may aggravate
existing skin, eye, or respiratory disorders.
Effects of Chronic Exposure to Product
Repeated or prolonged exposure of skin can cause burns. Repeated exposure to spray mists may lead to
chronic eye inflammation, chronic respiratory tract irritation, or lung damage. Potential for liver, kidney, or red
blood cell damage.
Exposure Limits (value, source, date) Irritancy (if yes, explain)
2005 ACGIH TLVs: Yes No
Monoethanolamine: 3 ppm (TWA)
Ethylene glycol monobutyl ether: 20 ppm, skin (TWA)
Ethylenediamine tetra-acetic acid, tetra sodium: N/AV
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)
Yes No Yes No
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
None known None known
Yes No Yes No
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
None known None
Yes No Yes No
MSDS Checklist (16-Section) Results
SECTION 3 -- Hazards Identification
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
[Emergency Overview]
Not required under WHMIS
[WHMIS Symbols]
[Potential Health Effects]
Not required under WHMIS
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 3 -- Hazards Identification
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
[Emergency Overview]
Combustible, corrosive
[WHMIS Symbols]
[Potential Health Effects]
May cause burns to eyes, skin, and respiratory tract
118 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 4 -- First Aid Measures
9-Section Material Safety Data Sheet (compliant)
SECTION 8 -- First Aid Measures
Inhalation
Move exposed person to fresh air. Get immediate medical attention.
Ingestion
If swallowed, DO NOT INDUCE VOMITING. Immediately contact a physician.
Skin Contact
Immediately flush contaminated skin with plenty of water for at least 15 minutes. Get medical attention if
irritation develops.
Eye Contact
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower lids. Get medical
3
attention at once.
MSDS Checklist (16-Section) Results
SECTION 4 -- First Aid Measures
Skin Contact
Eye Contact
Inhalation
Ingestion
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 4 -- First Aid Measures
Skin Contact
Immediately flush contaminated skin with plenty of water for at least 15 minutes. Get medical attention if
irritation develops.
Eye Contact
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower lids. Get medical
attention at once.
Inhalation
Move exposed person to fresh air. Get immediate medical attention.
Ingestion
If swallowed, DO NOT INDUCE VOMITING. Immediately contact a physician.
PART 3 ?Step 3: Prepare the MSDS 119
Case Study #8: Section 5 -- Firefighting Measures
9-Section Material Safety Data Sheet (compliant)
SECTION 4 -- Fire and Explosion Data
Flammability If yes, under which conditions?
Combustible Keep away from strong oxidizing agents, heat, sparks, and flames
Yes No
Means of Extinction
Carbon dioxide, fog, and foam
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
60 deg. C (closed cup) 10.6% 1.1%
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
244 deg. C None N/AV
Hazardous Combustion Products
Carbon dioxide, carbon monoxide, and toxic/corrosive fumes as oxides of phosphorus
NFPA: Health 3; Fire 2; Reactivity 0
MSDS Checklist (16-Section) Results
SECTION 5 -- Firefighting Measures
Flammability If yes, conditions identified?
Yes No
Means of Extinction
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (癈) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
Hazardous Combustion Products
[NFPA]
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 5 -- Firefighting Measures
Flammability If yes, under which conditions?
Combustible Keep away from strong oxidizing agents, heat, sparks, and flames
Yes No
Means of Extinction
Carbon dioxide, fog, and foam
Flashpoint (?C) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
60?C (closed-cup) 10.6% 1.1%
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
244癈 None N/AV
Hazardous Combustion Products
Carbon dioxide, carbon monoxide, and toxic/corrosive fumes as oxides of phosphorus
[NFPA]
Heath 3; Fire 2; Reactivity 0
120 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 6 -- Accidental Release Measures
9-Section Material Safety Data Sheet (compliant)
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type
Protective Gloves: Wear chemical-resistant gloves such as nitrile gloves
Respiratory Protection: Wear NIOSH-approved respirator for organic vapour
Eye Protection: Splash-proof safety goggles
Engineering Controls (specify, such as ventilation, enclosed process)
Use local exhaust ventilation (explosion-proof) to keep concentration of vapours below exposure limits.
Leak and Spill Procedure
Emergency personnel should wear NIOSH-approved organic vapour respirator, nitrile gloves, and splash-proof 3
safety goggles. Observe safety precautions in Section 7 during clean-up. Absorb spill on inert absorbent material.
Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
Waste Disposal
Unusable material should be properly drummed. Consult local, provincial, and federal agencies for proper
methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
Handling Procedures and Equipment
Do not breathe spray mists or vapours. Keep away from skin and eyes. Use local exhaust ventilation. Clothing
or shoes that become contaminated with substance should be removed promptly and not be worn until
thoroughly cleaned. Keep away from sources of ignition such as heat, sparks, and flames. Bond and ground
containers when pouring. Do not cut or weld empty container.
Storage Requirements
Store in cool, dry, well-ventilated area, away from strong oxidizing agents.
Special Shipping Information PIN
Transportation of Dangerous Goods (TDG) shipping name: 1760
Corrosive liquid NOS (monoethanolamine)
Hazard Class: 8, 9.2, TDG ID Number: UN 1760, TDG label/placard: Corrosive
MSDS Checklist (16-Section) Results
SECTION 6 -- Accidental Release Measures
Leak and Spill Procedures
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 6 -- Accidental Release Measures
Leak and Spill Procedures
Emergency personnel should wear NIOSH-approved, organic vapour respirator, nitrile gloves, and splash-proof
safety goggles. Observe safety precautions in Section 7 during clean-up. Absorb spill on inert absorbent material.
Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
PART 3 ?Step 3: Prepare the MSDS 121
Case Study #8: Section 7 -- Handling and Storage
9-Section Material Safety Data Sheet (compliant)
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type
Protective Gloves: Wear chemical-resistant gloves such as nitrile gloves
Respiratory Protection: Wear NIOSH-approved respirator for organic vapour
Eye Protection: Splash-proof safety goggles
Engineering Controls (specify, such as ventilation, enclosed process)
Use local exhaust ventilation (explosion-proof) to keep concentration of vapours below exposure limits.
Leak and Spill Procedure
Emergency personnel should wear NIOSH-approved organic vapour respirator, nitrile gloves, and splash-proof
safety goggles. Observe safety precautions in Section 7 during clean-up. Absorb spill on inert absorbent material.
Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
Waste Disposal
Unusable material should be properly drummed. Consult local, provincial, and federal agencies for proper
methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
Handling Procedures and Equipment
Do not breathe spray mists or vapours. Keep away from skin and eyes. Use local exhaust ventilation. Clothing
or shoes that become contaminated with substance should be removed promptly and not be worn until
thoroughly cleaned. Keep away from sources of ignition such as heat, sparks, and flames. Bond and ground
containers when pouring. Do not cut or weld empty container.
Storage Requirements
Store in cool, dry, well-ventilated area, away from strong oxidizing agents.
Special Shipping Information PIN
Transportation of Dangerous Goods (TDG) shipping name: 1760
Corrosive liquid NOS (monoethanolamine)
Hazard Class: 8, 9.2, TDG ID Number: UN 1760, TDG label/placard: Corrosive
MSDS Checklist (16-Section) Results
SECTION 7 -- Handling and Storage
Handling Procedures and Equipment
Storage Requirements
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 7 -- Handling and Storage
Handling Procedures and Equipment
Do not breathe spray mists or vapours. Keep away from skin and eyes. Use local exhaust ventilation. Clothing
or shoes that become contaminated with substance should be removed promptly and not be worn until
thoroughly cleaned. Keep away from sources of ignition such as heat, sparks, and flames. Bond and ground
containers when pouring. Do not cut or weld empty container.
Storage Requirements
Store in cool, dry, well-ventilated area, away from strong oxidizing agents.
122 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 8 -- Exposure Controls/Personal Protection
9-Section Material Safety Data Sheet (compliant)
SECTION 6 -- Toxicological Properties (excerpt)
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
May cause burns to eyes and skin. Damage to respiratory tract. Ingredients in this product may aggravate
existing skin, eye, or respiratory disorders.
Effects of Chronic Exposure to Product
Repeated or prolonged exposure of skin can cause burns. Repeated exposure to spray mists may lead to
chronic eye inflammation, chronic respiratory tract irritation, or lung damage. Potential for liver, kidney, or red
blood cell damage.
3
Exposure Limits (value, source, date) Irritancy (if yes, explain)
2005 ACGIH TLVs: Yes No
Monoethanolamine: 3 ppm (TWA)
Ethylene glycol monobutyl ether: 20 ppm, skin (TWA)
Ethylenediamine tetra-acetic acid, tetra sodium: N/AV
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)
Yes No Yes No
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
None known None known
Yes No Yes No
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
None known None
Yes No Yes No
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type
Protective Gloves: Wear chemical-resistant gloves such as nitrile gloves
Respiratory Protection: Wear NIOSH-approved respirator for organic vapour
Eye Protection: Splash-proof safety goggles
Engineering Controls (specify, such as ventilation, enclosed process)
Use local exhaust ventilation (explosion-proof) to keep concentration of vapours below exposure limits.
Leak and Spill Procedure
Emergency personnel should wear NIOSH-approved, organic vapour respirator, nitrile gloves, and splash-proof
safety goggles. Observe safety precautions in Section 7 during clean-up. Absorb spill on inert absorbent material.
Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
Waste Disposal
Unusable material should be properly drummed. Consult local, provincial, and federal agencies for proper
methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
Handling Procedures and Equipment
Do not breathe spray mists or vapours. Keep away from skin and eyes. Use local exhaust ventilation. Clothing
or shoes that become contaminated with substance should be removed promptly and not be worn until
thoroughly cleaned. Keep away from sources of ignition such as heat, sparks, and flames. Bond and ground
containers when pouring. Do not cut or weld empty container.
PART 3 ?Step 3: Prepare the MSDS 123
Storage Requirements
Store in cool, dry, well-ventilated area, away from strong oxidizing agents.
Special Shipping Information PIN
Transportation of Dangerous Goods (TDG) shipping name: 1760
Corrosive liquid NOS (monoethanolamine)
Hazard Class: 8, 9.2, TDG ID Number: UN 1760, TDG label/placard: Corrosive
MSDS Checklist (16-Section) Results
SECTION 8 -- Exposure Control/Personal Protection
Exposure Limits
ACGIH TLV OSHA PEL Other (specify)
Specific Engineering Controls (such as ventilation, enclosed process)
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, type specified?
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 8 -- Exposure Control/Personal Protection
Exposure Limits
ACGIH TLV OSHA PEL Other (specify)
Monoethanolamine: 3 ppm (TWA)
Ethylene glycol monobutyl ether: 20 ppm, skin (TWA) 2005
Ethylenediamine tetra-acetic acid, tetra sodium: N/AV
Specific Engineering Controls (such as ventilation, enclosed process)
Use local exhaust ventilation (explosion-proof) to keep concentration of vapours below exposure limits
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type?
Protective Gloves: Wear chemical-resistant gloves such as nitrile gloves
Respiratory Protection: Wear NIOSH-approved respirator for organic vapour
Eye Protection: Splash-proof safety goggles
124 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 9 -- Physical and Chemical Properties
9-Section Material Safety Data Sheet (compliant)
SECTION 3 -- Physical Data
Physical State Odour and Appearance Odour Threshold (ppm)
Liquid Transparent; ammonia odour N/AV
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg) Evaporation Rate
1.013 4.07 0.67 0.1 (n-butyl acetate = 1)
Boiling Point (癈) Freezing Point (癈) pH Coefficient of Water/Oil Distribution
100 deg. C -5 deg. C 12.5?3.0 2.5
MSDS Checklist (16-Section) Results
3
SECTION 9 -- Physical and Chemical Properties
Physical State Odour and Appearance Odour Threshold (ppm)
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg)
Evaporation Rate Boiling Point (癈) Freezing Point (?C)
pH Coefficient of Water/Oil Distribution [Solubility in Water]
Not required
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 9 -- Physical and Chemical Properties
Physical State Odour and Appearance Odour Threshold (ppm)
Liquid Transparent; ammonia odour N/AV
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg)
1.013 4.07 0.67
Evaporation Rate Boiling Point (癈) Freezing Point (?C)
0.1 (n-butyl acetate = 1) 100 deg. C -5 deg. C
pH Coefficient of Water/Oil Distribution [Solubility in Water]
12.5?3.0 2.5 N/AV
PART 3 ?Step 3: Prepare the MSDS 125
Case Study #8: Section 10 -- Stability and Reactivity
9-Section Material Safety Data Sheet (compliant)
SECTION 5 -- Reactivity Data
Chemical Stability If no, under which conditions?
Stable Yes No
Incompatibility with Other Substances If yes, which ones?
Strong acids and oxidizing agents
Yes No
Reactivity, and Under What Conditions?
None
Hazardous Decomposition Products
None
MSDS Checklist (16-Section) Results
SECTION 10 -- Stability and Reactivity
Chemical Stability If no, conditions identified?
Yes No
Incompatibility with Other Substances If yes, incompatible substances identified?
Yes No
Reactivity, and Under What Conditions?
Hazardous Decomposition Products
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 10 -- Stability and Reactivity
Chemical Stability If no, under which conditions?
Stable Yes No
Incompatibility with Other Substances If yes, which ones?
Strong acids and oxidizing agents
Yes No
Reactivity, and Under What Conditions?
None
Hazardous Decomposition Products
None
126 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 11 -- Toxicological Information
9-Section Material Safety Data Sheet (compliant)
SECTION 6 -- Toxicological Properties
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
Effects of Acute Exposure to Product
May cause burns to eyes and skin. Damage to respiratory tract. Ingredients in this product may aggravate
existing skin, eye, or respiratory disorders.
Effects of Chronic Exposure to Product
Repeated or prolonged exposure of skin can cause burns. Repeated exposure to spray mists may lead to
chronic eye inflammation, chronic respiratory tract irritation, or lung damage. Potential for liver, kidney, or red
blood cell damage.
3
Exposure Limits (value, source, date) Irritancy (if yes, explain)
2005 ACGIH TLVs: Monoethanolamine: 3 ppm (TWA) Yes No
Ethylene glycol monobutyl ether: 20 ppm, skin (TWA)
Ethylenediamine tetra-acetic acid, tetra sodium: N/AV
Sensitization (if yes, explain) Carcinogenicity (if yes, explain)
Yes No Yes No
Reproductive Toxicity (if yes, explain) Teratogenicity (if yes, explain)
None known None known
Yes No Yes No
Mutagenicity (if yes, explain) Synergistic Products (if yes, explain)
None known None
Yes No Yes No
MSDS Checklist (16-Section) Results
SECTION 11 -- Toxicological Information
Effects of Acute Exposure
Effects of Chronic Exposure
Irritancy of Product
Skin Sensitization (if yes, explained?) Respiratory Sensitization (if yes, explained?)
Carcinogenicity -- IARC (if yes, explained?) Carcinogenicity -- ACGIH (if yes, explained?)
Reproductive Toxicity (if yes, explained?) Teratogenicity (if yes, explained?)
Embryotoxicity (if yes, explained?) Mutagenicity (if yes, explained?)
Name of Synergistic Products/Effects
PART 3 ?Step 3: Prepare the MSDS 127
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 11 -- Toxicological Information
Effects of Acute Exposure
May cause burns to eyes and skin. Damage to respiratory tract. Ingredients in this product may aggravate
existing skin, eye, or respiratory disorders.
Effects of Chronic Exposure
Repeated or prolonged exposure of skin can cause burns. Repeated exposure to spray mists may lead to
chronic eye inflammation, chronic respiratory tract irritation, or lung damage. Potential for liver, kidney, or red
blood cell damage.
Irritancy of Product
Irritates respiratory tract
Skin Sensitization Respiratory Sensitization
No No
Carcinogenicity -- IARC Carcinogenicity -- ACGIH
No No
Reproductive Toxicity Teratogenicity
None known None known
Embryotoxicity Mutagenicity
None known None known
Name of Synergistic Products/Effects
None
128 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 12 -- Ecological Information
9-Section Material Safety Data Sheet (compliant)
Not required under WHMIS
MSDS Checklist (16-Section) Results
SECTION 12 -- Ecological Information
[Aquatic Toxicity]
Not required under WHMIS
Converted into 16-Section Material Safety Data Sheet (compliant) 3
SECTION 12 -- Ecological Information
[Aquatic Toxicity]
Not available
PART 3 ?Step 3: Prepare the MSDS 129
Case Study #8: Section 13 -- Disposal Considerations
9-Section Material Safety Data Sheet (compliant)
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type
Protective Gloves: Wear chemical-resistant gloves such as nitrile gloves
Respiratory Protection: Wear NIOSH-approved respirator for organic vapour
Eye Protection: Splash-proof safety goggles
Engineering Controls (specify, such as ventilation, enclosed process)
Use local exhaust ventilation (explosion-proof) to keep concentration of vapours below exposure limits.
Leak and Spill Procedure
Emergency personnel should wear NIOSH-approved organic vapour respirator, nitrile gloves, and splash-proof
safety goggles. Observe safety precautions in Section 7 during clean-up. Absorb spill on inert absorbent material.
Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
Waste Disposal
Unusable material should be properly drummed. Consult local, provincial, and federal agencies for proper
methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
Handling Procedures and Equipment
Do not breathe spray mists or vapours. Keep away from skin and eyes. Use local exhaust ventilation. Clothing
or shoes that become contaminated with substance should be removed promptly and not be worn until
thoroughly cleaned. Keep away from sources of ignition such as heat, sparks, and flames. Bond and ground
containers when pouring. Do not cut or weld empty container.
Storage Requirements
Store in cool, dry, well-ventilated area, away from strong oxidizing agents.
Special Shipping Information PIN
Transportation of Dangerous Goods (TDG) shipping name: 1760
Corrosive liquid NOS (monoethanolamine)
Hazard Class: 8, 9.2, TDG ID Number: UN 1760, TDG label/placard: Corrosive
MSDS Checklist (16-Section) Results
SECTION 13 -- Disposal Considerations
Waste Disposal
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 13 -- Disposal Considerations
Waste Disposal
Unusable material should be properly drummed. Consult local, provincial, and federal agencies for proper
methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
130 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 14 -- Transport Information
9-Section Material Safety Data Sheet (compliant)
SECTION 7 -- Preventive Measures
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, specify type
Protective Gloves: Wear chemical-resistant gloves such as nitrile gloves
Respiratory Protection: Wear NIOSH-approved respirator for organic vapour
Eye Protection: Splash-proof safety goggles
Engineering Controls (specify, such as ventilation, enclosed process)
Use local exhaust ventilation (explosion-proof) to keep concentration of vapours below exposure limits.
Leak and Spill Procedure
3
Emergency personnel should wear NIOSH-approved organic vapour respirator, nitrile gloves, and splash-proof
safety goggles. Observe safety precautions in Section 7 during clean-up. Absorb spill on inert absorbent material.
Pick up and place residue in a designated waste container. Wash area thoroughly with a detergent solution.
Waste Disposal
Unusable material should be properly drummed. Consult local, provincial, and federal agencies for proper
methods of disposal. Do not contaminate water supply when disposing of wastes or containers.
Handling Procedures and Equipment
Do not breathe spray mists or vapours. Keep away from skin and eyes. Use local exhaust ventilation. Clothing
or shoes that become contaminated with substance should be removed promptly and not be worn until
thoroughly cleaned. Keep away from sources of ignition such as heat, sparks, and flames. Bond and ground
containers when pouring. Do not cut or weld empty container.
Storage Requirements
Store in cool, dry, well-ventilated area, away from strong oxidizing agents.
Special Shipping Information PIN
Transportation of Dangerous Goods (TDG) shipping name: 1760
Corrosive liquid NOS (monoethanolamine)
Hazard Class: 8, 9.2, TDG ID Number: UN 1760, TDG label/placard: Corrosive
MSDS Checklist (16-Section) Results
SECTION 14 -- Transport Information
Special Shipping Information PIN
TDG [DOT]
Not required under WHMIS
[IMO] [ICAO]
Not required under WHMIS Not required under WHMIS
PART 3 ?Step 3: Prepare the MSDS 131
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 14 -- Transport Information
Special Shipping Information PIN
1760
TDG [DOT]
Transportation of Dangerous Goods (TDG) shipping
name: Corrosive liquid NOS (monoethanolamine)
Hazard Class: 8, 9.2, TDG ID Number: UN 1760
TDG label/placard: Corrosive
[IMO] [ICAO]
132 PART 3 ?Step 3: Prepare the MSDS
Case Study #8: Section 15 -- Regulatory Information
9-Section Material Safety Data Sheet (compliant)
SECTION 1 -- Product Information
Product Identifier WHMIS Classification (optional)
Super Wax Remover B3, D2B, E
Product Use
Wax Stripper
Manufacturer's Name Supplier's Name
Small Manufacturing Company Albert's Cleaning Supplies
Street Address Street Address
39800 Clean Street 5454 Mop Road
City Province City Province
3
Soapy Harbour BC Blue Sky AB
Postal Code Emergency Telephone Postal Code Emergency Telephone
V1V 1V1 (604) 999-7777 Y2Y 2Y2 (780) 888-4444
MSDS Checklist (16-Section) Results
SECTION 15 -- Regulatory Information
[WHMIS Classification] [OSHA]
Not required under WHMIS
[TSCA]
[SERA]
Not required under WHMIS Not required under WHMIS
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 15 -- Regulatory Information
[WHMIS Classification] [OSHA]
B3, D2B, E Not available
[SERA] [TSCA]
Not available Not available
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
PART 3 ?Step 3: Prepare the MSDS 133
Case Study #8: Section 16 -- Other Information
9-Section Material Safety Data Sheet (compliant)
Not required under WHMIS
MSDS Checklist (16-Section) Results
SECTION 16 -- Other Information
Not required under WHMIS
Converted into 16-Section Material Safety Data Sheet (compliant)
SECTION 16 -- Other Information
Not available
134 PART 3 ?Step 3: Prepare the MSDS
ADDITIONAL EXERCISE
Review a 16-Section MSDS
Use a photocopy of the blank MSDS Checklist (16-Section) in the back of this guide to review the following MSDS.
Determine if it meets Canadian WHMIS requirements; if any of the required information items are missing, the MSDS
needs to be revised.
MATERIAL SAFETY DATA SHEET
Product: Stop Slide
1. Chemical Product and Company Identification
Manufacturer: Slippery Slope Chemicals Emergency Phone Number: (888) 565-6767
Address: Information Phone Number: (312) 999-9999
2000 Millennium Town
3
Greenville, IL, 20202
Prepared: 01/22/01 by Mr. Tread
Revised: 01/25/05 by Mr. Tread
2. Composition/Information on Ingredients
Hazardous Components CAS # OSHA PEL ACGIH TLV Other Limits %
2.5 mg/m3 2.0 mg/m3
Graphite, Natural (as respirable dust) 7782-42-5 None Prop.
Silica, Crystalline Quartz (as respirable
0.1 mg/m3 0.1 mg/m3
dust) 14808-60-7 None N/D
Mineral Spirits 8052-41-3 100 ppm 100 ppm None Prop.
Tests performed on natural graphite have shown quartz levels ranging from 2% to 10%.
3. Hazards Identification
Route(s) of Entry: Inhalation: Yes Skin: Yes Ingestion: Yes
Health Hazards (acute and chronic):
Acute: Eye, skin, and respiratory system irritant. Breathing high concentrations may result in dizziness, headache,
respiratory irritation, convulsions, or loss of consciousness.
Chronic: None expected when good hygiene practices are employed.
Carcinogenicity: NTP: No IARC Monographs: YES OSHA Regulated: No
Silica as quartz: Animal sufficient evidence, human sufficient evidence.
Signs and Symptoms of Exposure:
Inhalation: Respiratory irritation, dizziness, headache, nausea, fatigue, drowsiness, impaired co-ordination, and
eye-watering.
Skin: Contact may dry the skin; prolonged contact may cause irritation. Can be absorbed through the skin. Solvent
action can dry and de-fat the skin causing skin to crack, leading to dermatitis.
Eyes: Liquid or vapour can irritate the eyes.
Ingestion: May cause cramps and diarrhea. Small amounts aspirated into the respiratory system during ingestion or from
vomiting may cause bronchopneumonia or pulmonary edema, a possibly fatal condition.
Medical Conditions Generally Aggravated by Exposure: None known.
PART 3 ?Step 3: Prepare the MSDS 135
4. First Aid Measures
Eyes: Flush thoroughly with water for 15 minutes. Get medical attention.
Skin: Wash exposed skin with soap and water. If irritation persists, get medical attention. Launder severely
contaminated clothing before reuse.
Ingestion: Do not induce vomiting. Get medical attention.
Inhalation: Remove to fresh air. Administer oxygen if needed. Apply artificial respiration if breathing has stopped. Get
medical attention.
5. Firefighting Measures
Flashpoint: (method) TCC 105癋 Flammable Limits: LEL: 0.9, UEL: 7.0
Extinguishing Media: Foam, carbon dioxide, water spray (fog), and dry chemical
Special Firefighting Procedures: Water may be ineffective as an extinguishing medium, but can be used to keep containers
cool. Wear a NIOSH-approved, self-contained breathing apparatus to fight a fire involving this product.
Unusual Fire and Explosion Hazards: Combustible liquid. Keep away from heat, sparks, open flame, and electrical
equipment. Closed containers may explode when exposed to extreme heat. On burning, overexposure to decomposition
products may cause a health hazard. Symptoms may not be immediately apparent. Seek medical attention.
NFPA Hazard Rating: Health 2 Flammability 2 Reactivity 0
6. Accidental Release Measures
Spill/Leak Procedures: Avoid breathing vapours. Ventilate area. Remove all sources of ignition. Clean up area with rags
and/or other absorbent material and place in closed containers for solid waste disposal. Prevent from entering sewers or
waterways if possible.
7. Handling and Storage
Handling and Storage Precautions: Store and use in cool, dry, well-ventilated areas. Do not store above 120癋. Do not take
internally. Handle carefully to prevent spills. Keep containers tightly closed when not in use.
Work/Hygienic Practices: Wear eye protection. Wash hands and face after handling this product.
8. Exposure Controls/Personal Protection
Respiratory Protection (specify type): None under normal use. Avoid breathing vapours. In confined areas, use NIOSH-
approved, vapour canister respirator. Self-contained breathing apparatus or supplied-air hose mask is required for vapour
concentrations above PEL/TLC limits.
Local Exhaust: Required Mechanical (general): Required Special: None Other: None
Eye/Face Protection: Goggles, safety glasses, or face shield. Eye wash station should be available.
Skin Protection: Chemical-resistant gloves. Safety shower should be available.
9. Physical/Chemical Characteristics
Physical State: Liquid Boiling Point: 305?48?F Appearance: Black/Grey Melting Point: N/A
Odour: Petroleum Solvent Vapour Pressure (mmHg): 2 @ 68癋 Specific Gravity (H2O = 1): 1.2
Vapour Density (air = 1): 4.7 Water Solubility: Negligible Evaporation Rate (Butyl Acetate = 1): 0.2
136 PART 3 ?Step 3: Prepare the MSDS
10. Stability and Reactivity
Stability: Material is stable.
Incompatibility (materials to avoid): Strong oxidizing agents, acids, and alkalis.
Hazardous Decomposition Products: On burning, may release carbon dioxide and carbon monoxide.
Hazardous Polymerization: Will not occur.
11. Toxicological Information
None available.
12. Ecological Information
None available.
13. Disposal Considerations
3
Dispose of in accordance with local, state, and federal regulations.
14. Transport Information
Proper Shipping Name: Flammable liquid, NOS (contains mineral spirits), 3, UN1993, PGIII.
15. Regulatory Information
All components of this product are on the TSCA inventory.
16. Other Information
Disclaimer: The information contained herein is based on data available. However, no warranty is expressed or implied
regarding the accuracy of the data or the results obtained from the use thereof. Because the information contained herein
may be applied under conditions beyond our control, we assume no responsibility for its use. Unk. = Unknown; N/A = Not
applicable; Nav = Not available; N/D = Not determined; N/E = Not established.
PART 3 ?Step 3: Prepare the MSDS 137
Answer:
MSDS Checklist (16-Section)
= information present as required
= information inaccurate or missing
N/AP = information not applicable
N/AV = information not available
[ ]= optional information
SECTION 1 -- Chemical Product and Company Identification
Product Identifier [WHMIS Classification]
Stop Slide Not required
Product Use
Anti-slip lubricant
Manufacturer's Name Supplier's Name
Street Address Street Address
City, Province/State, Postal/Zip Code City, Province/State, Postal/Zip Code
Emergency Telephone [Fax Number] Emergency Telephone [Fax Number]
Date MSDS Prepared MSDS Prepared by Phone Number
SECTION 2 -- Composition/Information on Ingredients
Hazardous Ingredients % CAS Number LD50 of Ingredient LC50 of Ingredient
(specific chemical name for each) (specify species and route) (specify species)
Graphite, Natural
Silica,
Crystalline Quartz
Mineral Spirits
SECTION 3 -- Hazards Identification
Routes of Entry
Skin Contact Skin Absorption Eye Contact Inhalation Ingestion
[Emergency Overview]
[WHMIS Symbols]
[Potential Health Effects]
138 PART 3 ?Step 3: Prepare the MSDS
Product Identifier: Stop Slide
SECTION 4 -- First Aid Measures
Skin Contact
Eye Contact
Inhalation
Administer oxygen (by qualified personnel)
Ingestion
SECTION 5 -- Firefighting Measures
Flammability If yes, conditions identified?
3
Yes No
Means of Extinction
Flashpoint (癈) and Method Upper Flammable Limit (% by volume) Lower Flammable Limit (% by volume)
Autoignition Temperature (?C) Explosion Data -- Sensitivity to Impact Explosion Data -- Sensitivity to Static Discharge
Hazardous Combustion Products
[NFPA]
SECTION 6 -- Accidental Release Measures
Leak and Spill Procedures
SECTION 7 -- Handling and Storage
Handling Procedures and Equipment
Storage Requirements
PART 3 ?Step 3: Prepare the MSDS 139
Product Identifier: Stop Slide
SECTION 8 -- Exposure Control/Personal Protection
Exposure Limits
ACGIH TLV
OSHA PEL
Other (specify)
(Note MSDS Section 2)
Specific Engineering Controls (such as ventilation, enclosed process)
Personal Protective Equipment
Gloves Respirator Eye Footwear Clothing Other
If checked, type specified?
Non-specific
SECTION 9 -- Physical and Chemical Properties
Physical State Odour and Appearance Odour Threshold (ppm)
Specific Gravity Vapour Density (air = 1) Vapour Pressure (mmHg)
Evaporation Rate Boiling Point (?C) Freezing Point (癈)
pH Coefficient of Water/Oil Distribution [Solubility in Water]
SECTION 10 -- Stability and Reactivity
Chemical Stability If no, conditions identified?
Yes No
Incompatibility with Other Substances If yes, incompatible substances identified?
Yes No
Reactivity, and Under What Conditions?
Hazardous Decomposition Products
Hazardous combustion products listed
140 PART 3 ?Step 3: Prepare the MSDS
Product Identifier: Stop Slide
SECTION 11 -- Toxicological Information
Effects of Acute Exposure
(in MSDS Section 3)
Effects of Chronic Exposure
Irritancy of Product
Skin Sensitization (if yes, explained?) Respiratory Sensitization (if yes, explained?)
3
Carcinogenicity -- IARC (if yes, explained?) Carcinogenicity -- ACGIH (if yes, explained?)
Unclear
Reproductive Toxicity (if yes, explained?) Teratogenicity (if yes, explained?)
Embryotoxicity (if yes, explained?) Mutagenicity (if yes, explained?)
Name of Synergistic Products/Effects
SECTION 12 -- Ecological Information
[Aquatic Toxicity]
SECTION 13 -- Disposal Considerations
Waste Disposal
SECTION 14 -- Transport Information
Special Shipping Information PIN
TDG [DOT]
[IMO] [ICAO]
PART 3 ?Step 3: Prepare the MSDS 141
Product Identifier: Stop Slide
SECTION 15 -- Regulatory Information
[WHMIS Classification] [OSHA]
[SERA] [TSCA]
This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
SECTION 16 -- Other Information
142 PART 3 ?Step 3: Prepare the MSDS
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