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MSDS Material Safety Data Sheet
CAS

13472-45-2 1314-35-8 106-94-5 108-88-3 75-52-5 106-88-7

File Name: 13472-45-2_1314-35-8_106-94-5_108-88-3_75-52-5_106-88.asp

 An Illinois Tool Works Company
2901 Hamilton Boulevard
South Plainfield, NJ 07080
Tel: 908-757-8300
An Illinois Tool Works Company Fax: 908-757-9273


MATERIAL SAFETY DATA SHEET
Prepared to U.S. Standards


1. PRODUCT IDENTIFICATION

CHEMICAL NAME/CLASS: TEMPILAQG

PRODUCT: Tempilaq篏 1200F/649篊
SUPPLIER/MANUFACTURER'S NAME: TEMPIL INC.
ADDRESS: 2901 HAMILTON BLVD.
SOUTH PLAINFIELD, NJ 07080

EMERGENCY PHONE: CHEMTREC: 1-800-424-9300

BUSINESS PHONE: 1-908-757-8300


2. COMPOSITION and INFORMATION ON INGREDIENTS

CHEMICAL NAME CAS # % EXPOSURE LIMITS IN AIR
Hazardous
ACGIH OSHA
TLV STEL PEL STEL IDLH OTHER
ppm ppm Ppm ppm ppm

Sodium Tungstate 13472-45-2 15-20 1mg/cu.m NA NA NA NA

Tungstic Oxide 1314-35-8 0-5 5mg/cu.m NA NA NA NA
(as w)

n-propyl bromide 106-94-5 65-70 NE NA NE NA NA

Toluene 108-88-3 0-2 100ppm NE 100ppm NE NE

Patented Stabilizer package:

Nitromethane 75-52-5 <0.5 NA NA 100 NA NA NA

1,2 butylene Oxide 106-88-7 <0.5 NA NA NE NA NA NA




Non-Hazardous Balance

NA = Not Available, NE= Not Established




TEMPILAQG 1200F/649篊 EFFECTIVE DATE: JUNE 7, 2006
PAGE 1 OF 6
3. HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: Vapors may be irritating to eyes, skin, and respiratory tract. Harmful if inhaled. Wear
full protective equipment. Prevent contamination of soil surface, water or ground water. Solvent has no flash point,
but vapors will form flammable mixture at a concentration of 4.6% to 8.5% by volume with air.

SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE: The most significant route of over-exposure
for this product is by contact with the skin.

INHALATION: In high concentrations produces irritation to upper respiratory tract, vapors can cause
unconsciousness, headache, dizziness, nausea, vomiting or narcosis. Chronic overexposure at high levels may
cause adverse effects in the liver, respiratory system, kidney, reproductive system, and central nervous system.
Persons having pre-existing diseases of the lungs, eyes or skin may have an increased susceptibility to the hazards
of excessive exposure.

CONTACT WITH THE SKIN AND EYES: May cause pain and slight eye irritation. Vapors may irritate eyes.
Prolonged or repeated exposure may cause skin irritation. May cause drying or flaking of skin. A single prolonged
exposure is not likely to result in the material being absorbed through skin in harmful amounts.


INGESTION: may result in irritation of mouth and gastro-intestinal tract.


HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.

Persons having pre-existing diseases of the lungs, eyes or skin may have increased susceptibility to the hazards of
excessive exposure.

4. FIRST-AID MEASURES
SKIN EXPOSURE: If this product contaminates the skin, begin flushing with soap and water. Remove exposed or
contaminated clothing, taking care not to contaminate eyes. Contaminated individual must seek medical attention if
redness or irritation continues after area has been rinsed.

EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient
force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes.

INHALATION: Remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Remove
or cover gross contamination to avoid exposure to rescuers. Call a physician and/or transport to emergency facility
immediately.

INGESTION: Drink large amounts of water. Do not induce vomiting, Seek emergency medical attention.

Contaminated individual must be taken for medical attention if adverse effects occur. Rescuers should be taken for
medical attention, if necessary. Take copy of label and MSDS to physician or other health professional with
contaminated individual.




TEMPILAQG 1200F/649篊 EFFECTIVE DATE: JUNE 7, 2006
PAGE 2 OF 6
5. FIRE-FIGHTING MEASURES
FLASH POINT, (method): None (CC)
NFPA RATING
FLAMMABILITY
AUTOIGNITION TEMPERATURE: NA
0
FLAMMABLE LIMITS (in air by volume, %):
1
0
2
HEALTH REACTIVITY
Lower (LFL): 4.6
Upper (UFL): 8.5

FIRE EXTINGUISHING MATERIALS:
OTHER

Water fog: YES Carbon Dioxide: YES
Foam: YES Dry Chemical: YES


UNUSUAL FIRE AND EXPLOSION HAZARDS: Avoid contact with flames, sparks or high intensity sources. Thermal
decomposition may produce carbon monoxide, carbon dioxide, hydrogen halide and bromides.

.

SPECIAL FIRE-FIGHTING PROCEDURES: Keep people away. Isolate fire area and deny unnecessary entry.
Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Stay
upwind. Wear positive-pressure self-contained breathing appratus (SCBA) and protective fire fighting clothing. If
possible, prevent run-off water from entering storm drains, bodies of water, or other environmentally sensitive areas.

6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Clear all personnel from area. Do not breathe vapors. Ventilate area of leak or spill.
Do not breathe vapors. Ventilate area of leak or spill. Wear protective equipment including positive pressure self
contained or air supplied breathing apparatus.

Contain liquid, prevent contamination of soil, surface water or ground water. Solvent material is heavier than water
and has limited water solubility. It will collect on the lowest surface.


Contain liquid, transfer to properly labeled closed containers. Place all spill in a suitable container and seal. Dispose
of in accordance with Federal, State and local hazardous waste disposal regulations (see Section 13, Disposal
Considerations).

7. HANDLING and USE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN
YOU. Do not eat or drink while handling chemicals.

STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it
safely. Avoid breathing material of this product. Packages of this product must be properly labeled. Store packages
in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store
away from incompatible materials (see Section 10, Stability and Reactivity). Inspect all incoming packages before
storage, to ensure they are properly labeled and not damaged.

PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out
safely. Decontaminate equipment using soapy water before maintenance begins. Collect all rinsates and dispose of
according to applicable Federal, State, or local procedures.




TEMPILAQG 1200F/649篊 EFFECTIVE DATE: JUNE 7, 2006
PAGE 3 OF 6
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Prudent practice is to ensure eyewash/safety shower stations are
available near where this product is used. Provide local exhaust ventilation to control airborne levels below the
exposure guidelines.

RESPIRATORY PROTECTION: Use an approved air-purifying or positive-pressure supplied-air respirator depending
on the potential concentration. Follow the requirements of the Federal OSHA Respiratory Protection Standard (29
CFR 1910.134), or equivalent State standards.

EYE PROTECTION: Safety glasses.

HAND PROTECTION: Wear impervious gloves.



9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): NA. Odor: Irritating odor at high concentration.
SPECIFIC GRAVITY (water = 1): NA FREEZING/MELTING POINT: Not available.
SOLUBILITY IN WATER: NA BOILING POINT: NA
VAPOR PRESSURE: NA
pH: NA.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable.

APPEARANCE AND COLOR: liquid with solvent odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance is a distinct property of this product.

10. STABILITY and REACTIVITY
STABILITY: Stable.

DECOMPOSITION PRODUCTS: None known.

HAZARDOUS POLYMERIZATION: Will not occur.

CONDITIONS TO AVOID: Avoid open flames, direct sunlight or ultraviolet sources.

11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following toxicological data are available for the components of this product:

N-Propyl bromide LD50/Rat--oral --4260 mg/Kg
Lc50/Rat, inhalation--50,291ppm/30min;14,374/4hr

Stabilizer package
Nitromethane and 1,2 butylene oxide have been classified by the NTP and/or IARC (IARC 2B-possibly carcinogenic
to humans).




RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce or eliminate exposure.




TEMPILAQG 1200F/649篊 EFFECTIVE DATE: JUNE 7, 2006
PAGE 4 OF 6
12. ECOLOGICAL INFORMATION

ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION

ENVIRONMENTAL STABILITY:

No information available

13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State,
and local regulations. This product if unaltered by use may be disposed of by treatment at a permitted facility or as
advised by your local hazardous waste regulatory authority.


14. TRANSPORTATION INFORMATION

PROPER SHIPPING NAME: Product not regulated
HAZARD CLASS NUMBER and DESCRIPTION: NA.
UN IDENTIFICATION NUMBER: NA
PACKING GROUP: NA.
DOT LABEL(S) REQUIRED: NA.

NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): NA.
MARINE POLLUTANT: NA.

TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: NA

15. REGULATORY INFORMATION
SARA REPORTING REQUIREMENTS: This product is subject to the reporting requirements of Sections 311, 312
and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows:
COMPONENT SARA 311 SARA 312 SARA 313
Toluene NA NA yes




SARA THRESHOLD PLANNING QUANTITY: NA.
TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
CERCLA REPORTABLE QUANTITY (RQ): NA.
OTHER U.S. FEDERAL REGULATIONS: NA.
STATE REGULATORY INFORMATION: The components of this product are covered under specific State
regulations, as denoted below:
Alaska - Designated Toxic and Massachusetts - Substance List: NA. Pennsylvania - Hazardous Substance
Hazardous Substances: NA. Minnesota - List of Hazardous List: NA.
California: contain chemicals known Substances: NA. Rhode Island - Hazardous Substance
to the state of California to cause Missouri - Employer Information/Toxic List: NA.
cancer, birth defects or other Substance List: NA. Texas - Hazardous Substance List:
reproductive harm. New Jersey - Right to Know NA.
Florida - Substance List: NA. Hazardous Substance List: NA. West Virginia - Hazardous Substance
Illinois - Toxic Substance List: NA. North Dakota - List of Hazardous List: NA.
Kansas - Section 302/313 List: NA. Chemicals, Reportable Quantities: Wisconsin - Toxic and Hazardous
NA. Substances: NA.




TEMPILAQG 1200F/649篊 EFFECTIVE DATE: JUNE 7, 2006
PAGE 5 OF 6
16. OTHER INFORMATION

CAUTION! MAY BE HARMFUL IF INGESTED. CONTACT WITH SKIN MAY CAUSE IRRITATION. Do not taste
or swallow. Avoid contact with skin. Use with adequate ventilation. Wash thoroughly after handling. Wear gloves
and safety goggles when using this product. FIRST-AID: In case of contact, immediately flush skin or eyes with
large amounts of water. If inhaled, move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. IN CASE OF FIRE: Use fog, foam, dry chemical or CO2. IN CASE OF SPILL: Pick-up
material and rinse area with soap and water. Refer to MSDS for additional information.




PREPARED BY: Tempil INC.
2901 Hamilton Boulevard, South Plainfield, NJ 07080
908/757/8300



This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR, 1910.1200. Other government
regulations must be reviewed for applicability to this product. To the best of Tempil's knowledge, the information contained herein is
reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type,
either express or implied, are provided. The information contained herein relates only to this specific product. If this product is combined
with other materials, all component properties must be considered. Data may be changed from time to time. Be sure to consult the latest
edition.




TEMPILAQG 1200F/649篊 EFFECTIVE DATE: JUNE 7, 2006
PAGE 6 OF 6

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