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CAS

9003-42-3 94-36-0 2783-94-0 2379-74-0 10101-66-3 12001-99-9 8003-22-3 57455-37-5 13463-67-7 1309-37-1

File Name: 9003-42-3_94-36-0_2783-94-0_2379-74-0_10101-66-3_12001-99.asp

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MATERIAL SAFETY DATA SHEET CND-N-119


Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 09/15/2004


1. PRODUCT IDENTIFICATION
1.1 Product Name:

MOSAIC POWDERS
1.2 Chemical Name:
POLY (ETHYL/METHYL) METHACRYLATE COPOLYMER
1.3 Synonyms:
NA
1.4 Trade Names:
TERRA COTTA (ORANGE), SPANISH TILE (RED), QUARTZ CRYSTAL (PURPLE), JADE (GREEN), GOLDEN GLASS (YELLOW), COBALT GLASS (BLUE), BLACK
1.5 Product Use:
PROFESSIONAL OR SUNDRY USE ONLY
1.6 Manufacturer's Name:
CREATIVE NAIL DESIGN, INC.
1.7 Manufacturer's Address:
1125 JOSHUA WAY VISTA, CA USA 92081
1.8 Emergency Phone:

ROCKY MOUNTAIN POISON CONTROL CENTER: 303-623-5716
1.9 Business Phone:
800-833-NAIL (6245), 760-599-2900


2. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH OSHA OTHER
TLV STEL PEL STEL IDLH
CHEMICAL NAME(S) CAS No. RTECS No. EINECS No. % ppm ppm ppm ppm ppm
POLYETHYLMETHYL METHACRYLATE 9003-42-3 NA NA 50.0 NE NE NE NE NE
METHACRYLATE COPOLYMER NA NA NA 50.0 NE NE NE NE NE
BENZOYL PEROXIDE 94-36-0 DM8575000 202-327-6 1.0 (5) NE (5) NE NE

ADDITIONAL INGREDIENTS:
TERRA COTTA (ORANGE):
COLORANT CI 15985 2783-94-0 NA NA 2.0 NE NE NE NE NE

SPANISH TILE (RED):
COLORANT CI 73360 2379-74-0 NA 219-163-6 5.0 NE NE NE NE NE

QUARTZ CRYSTAL (PURPLE):
COLORANT CI 77742 10101-66-3 NA 233-257-4 5.0 NE NE NE NE NE

JADE (GREEN):
COLORANT CI 77289 12001-99-9 NA 215-160-9 3.0 NE NE NE NE NE

GOLDEN GLASS (YELLOW):
COLORANT CI 47000 8003-22-3 NA 232-318-2 3.0 NE NE NE NE NE

COBALT GLASS (BLUE):
COLORANT CI 77007 57455-37-5 NA 309-928-3 < 3.0 NE NE NE NE NE
TITANIUM DIOXIDE 13463-67-7 XR2275000 236-675-5 1.0 (10) NA (15) NA NA DUST

BLACK:
COLORANT CI 77499 1309-37-1 NA 215-168-2 5.0 NE NE NE NE NE
TITANIUM DIOXIDE 13463-67-7 XR2275000 236-675-5 2.0 (10) NA (15) NA NA DUST

OTHER COMPONENTS PRESENT IN LESS THAN 1% CONCENTRATION BAL THE REMAINING COMPONENTS DO NOT CONTRIBUTE
ANY SIGNIFICANT ADDITIONAL HAZARDS
NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2003 format.
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MATERIAL SAFETY DATA SHEET CND-N-119


Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 09/15/2004


3. HAZARD IDENTIFICATION
3.1 Hazard Identification:
Allergic contact dermatitis is possible with prolonged or repeated contact. The product is a fine powder, and may cause a slipping
and falling hazard if spilled.
3.2 Routes of Entry: Inhalation: YES Absorption: NO Ingestion: YES
3.3 Effects of Exposure:
EYES: Possible irritation from dust.
SKIN: Irritation. Allergic contact dermatitis is possible with prolonged or repeated contact.
INGESTION: No exposure effects are reported.
INHALATION: Considered a nuisance dust. May cause irritation of the mouth, nose, throat, and lungs.
3.4 Symptoms of Overexposure:
EYES: Redness & watering.
SKIN: Redness, itching, drying of skin.
INGESTION: No symptoms are expected.
INHALATION: Upper respiratory irritation, including coughing & sneezing.
3.5 Acute Health Effects:
EYES: Possible irritation from dust.
SKIN: Irritation. Allergic contact dermatitis is possible with prolonged or repeated contact.
INGESTION: No exposure effects are reported.
INHALATION: Considered a nuisance dust. May cause irritation of the mouth, nose, throat, and lungs.
3.6 Chronic Health Effects:
EYES: Possible irritation from dust.
SKIN: Irritation. Allergic contact dermatitis is possible with prolonged or repeated contact.
INGESTION: No exposure effects are reported.
INHALATION: Considered a nuisance dust. May cause irritation of the mouth, nose, throat, and lungs.
3.7 Target Organs:
Eyes, skin and respiratory system.


4. FIRST AID MEASURES
4.1 First Aid:
EYES: Flush eyes thoroughly with copious amounts of water for at least 15 minutes, holding eyelid(s) open to ensure complete
flushing. If irritation persists, seek immediate medical attention.
SKIN: Remove contaminated clothing and wash affected areas with soap and water. Wash all contaminated clothing
thoroughly before reuse. If irritation persists, seek prompt medical attention.
INGESTION: DO NOT INDUCE VOMITING. Contact Rocky Mountain Poison Control at 303-623-5716 or the nearest Poison Control
Center or local emergency telephone number for assistance and instructions. Seek immediate medical attention. If
vomiting occurs spontaneously, keep victim's head lowered (forward) to reduce the risk of aspiration.
INHALATION: Remove victim to fresh air at once. If breathing stops, perform artificial respiration. Seek prompt medical attention if
adverse effects continue.

HEALTH 1
4.2 Medical Conditions Aggravated by Exposure:
Preclude from exposure those individuals that are susceptible to dermatitis, asthma or
FLAMMABILITY 1
bronchitis.

REACTIVITY 2
PROTECTIVE EQUIPMENT B
EYES SKIN
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MATERIAL SAFETY DATA SHEET CND-N-119



Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 09/15/2004


5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
579 癋 (304 癈) TCC
5.2 Autoignition Temperature:
NA
5.3 Flammability Limits: Lower Explosive Limit (LEL): NA Upper Explosive Limit (UEL): NA
5.4 Fire & Explosion Hazards:
Keep away from excessive heat, open flames, sparks, and other possible sources of ignition.
5.5 Extinguishing Methods:
Carbon dioxide, dry chemical & water spray.
5.6 Firefighting Procedures:
Keep containers cool until well after the fire is out. Prevent runoff from fire control or dilution from
entering sewers, drains, drinking water supply, or any natural waterway. Firefighters should wear full
face, self-contained breathing apparatus (MSHA/NIOSH approved or the equivalent) and impervious
protective clothing.


6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., <1 gallon) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open
doors and windows). Remove spilled material with broom, vacuum or wet sponge. Dispose of properly in accordance with local,
state and federal regulations. Wash all affected areas and outside of container with plenty of warm water and soap. Remove any
contaminated clothing and wash thoroughly before reuse.
For spills 1 gallon, deny entry to all unprotected individuals. Remove spilled material with broom, vacuum (with high-efficiency
particulate filter) or wet mops. Transfer product to containers for recovery or disposal. Remove contaminated clothing promptly and
wash affected skin areas with soap and water. Keep spills and cleaning runoffs out of municipal sewers and open bodies of water.


7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Use eye protection when using this product. Wash hands thoroughly after using this product and before eating, drinking, or smoking.
7.2 Storage & Handling:
Use and store in a cool, dry, well-ventilated location (e.g., local exhaust ventilation, fans). Keep away from excessive heat, open
flames, sparks, and other possible sources of ignition. Do not store in damaged or unmarked containers or storage devices. Keep
containers securely closed when not in use.
7.3 Special Precautions:
Empty containers may retain residual amounts of product. Readily available emergency fire, first aid, and spill response equipment
and/or measures are recommended. The product is a fine powder, and may cause a slipping and falling hazard if spilled. Spilled
product should be swept or vacuumed up immediately to prevent falls.


8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
General mechanical ventilation (e.g., fans) and local exhaust ventilation is recommended for use with this product.
8.2 Respiratory Protection:
Respirators are not required for use with this product. However, this product is a nuisance dust hazard. Product may cause irritation of
the mouth, nose, throat, and lungs. Accordingly, a dust mask is suggested. A respiratory protection program that meets OSHA's 29
CFR ?910.134 and ANSI Z88.2 requirements must be followed whenever a respirator is used.
8.3 Eye Protection:
As a minimum, safety glasses with side shields should be used when using this product.
8.4 Hand Protection:
None required under normal conditions of use. However, may cause skin irritation in some sensitive individuals.
When handling large quantities (e.g., 1 gallon), wear rubber or impervious plastic gloves.
8.5 Body Protection:
No apron required when handling small quantities.
When handling large quantities (e.g., 1 gallon), eye wash stations and deluge showers should be available. Upon completion of
work activities involving large quantities of this product, wash any exposed areas thoroughly with soap and water.
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MATERIAL SAFETY DATA SHEET CND-N-119


Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 09/15/2004



9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Density: NA
9.2 Boiling Point: NA
9.3 Melting Point: Approximately 200癈
9.4 Evaporation Rate: NA
9.5 Vapor Pressure: NA
9.6 Molecular Weight: NA
9.7 Appearance & Color: Metallic and colored powder with faint bland odor.
ND
9.8 Odor Threshold:

9.9 Solubility: Insoluble
9.10 pH NA
9.11 Viscosity: NA
9.12 Other Information: NA


10. STABILITY & REACTIVITY
10.1 Stability: Stable under normal conditions of use (see section 7).
10.2 Hazardous Decomposition Products: Oxides of carbon and nitrogen. May form shock, heat, and friction-sensitive by-products.
10.3 Hazardous Polymerization: Will not occur.
10.4 Conditions to Avoid: Open flames, sparks, high heat (120癋) or other ignition sources, and proximity to incompatible
substances.
10.5 Incompatible Substances: ND


11. TOXICOLOGICAL INFORMATION
11.1 Toxicity Data: This product has not been tested on animals to obtain toxicological data. There are toxicology data
for the components of this product, which are found in the scientific literature. These data have not
been presented in this document.
11.2 Acute Toxicity: See section 3.5
11.3 Chronic Toxicity: See section 3.6
11.4 Suspected Carcinogen: NE
11.5 Reproductive Toxicity: This product is not reported to produce reproductive toxicity in humans
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to produce teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to produce reproductive effects in humans.
11.6 Irritancy of Product: See Section 3.3
NE
11.7 Biological Exposure Indices:

Treat symptomatically.
11.8 Physician Recommendations:



12. ECOLOGICAL INFORMATION
12.1 Environmental Stability: This product will slowly volatilize from soil. Components of this product will slowly decompose into
organic compounds.
12.2 Effects on Plants & Animals: There is no specific data available for this product.
There is no specific data available for this product.
12.3 Effects on Aquatic Life:
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MATERIAL SAFETY DATA SHEET CND-N-119


Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 09/15/2004


13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Dispose of in accordance with all federal, state, and local regulations.
13.2 Special Considerations:
If the material is unsuitable for recycling or reclamation, enclosed璫ontrolled incineration is recommended unless otherwise
prohibited by local ordinance.


14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
NOT REGULATED
14.2 IATA (AIR):
NOT REGULATED
14.3 IMDG (OCN):
NOT REGULATED
14.4 TDGR (Canadian GND):
NOT REGULATED
14.5 ADR/RID (EU):
NOT REGULATED


15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
This product does not contain any substances with SARA reporting requirements.
15.2 SARA Threshold Planning Quantity:
This product does not contain any substances with a SARA threshold planning quantity.
15.3 TSCA Inventory Status:
All chemical substances of this product are listed on the TSCA inventory or are otherwise exempt from inventory status.
15.4 CERCLA Reportable Quantity (RQ):
This product does not contain any substances with a CERCLA reportable quantity.
15.5 Other Federal Requirements:
This product complies with the appropriate sections of the Food and Drug Administration's 21 CFR Subchapter G, (Cosmetics).
15.6 Other Canadian Regulations
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List.
15.7 State Regulatory Information:
No component if this mixture is listed in the California Proposition 65 Lists.
15.8 67/548/EEC (European Union) Requirements:
The primary component of this product is not listed in Annex I of EU Directive 67/548/EEC.
Page 6 of 7
MATERIAL SAFETY DATA SHEET CND-N-119


Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 09/15/2004


16. OTHER INFORMATION
16.1 Other Information:
Precisely follow directions and MSDS (available through your supplier) for use. Avoid skin and eye contact. Keep out of reach of
children. If redness or other signs of adverse reaction occur, discontinue use immediately and thoroughly rinse affected area.
16.2 Terms & Definitions:
See page 7 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard, 29 CFR ?910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Creative Nail Design's
knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness
are not guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein
relates only to the specific product(s). If this product(s) is combined with other materials, all component properties must be
considered. Data may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
Creative Nail Design, Inc.
1125 Joshua Way
Vista, CA 92081
800-833-NAIL (6245) phone
760-599-4005 fax
http://www.creativenaildesign.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Blvd., Suite 201
Torrance, CA 90504
310-370-3600 phone
310-370-5700 fax
http://www.shipmate.com/
Page 7 of 7
MATERIAL SAFETY DATA SHEET CND-N-119


Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 1.0 MSDS Revision Date: 09/15/2004
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION: NATIONAL FIRE PROTECTION ASSOCIATION: NFPA

CAS No. Chemical Abstract Service Number FLAMMABILITY LIMITS IN AIR:
EXPOSURE LIMITS IN AIR:
Autoignition Minimum temperature required to initiate combustion
Temperature in air with no other source of ignition
ACGIH American Conference on Governmental Industrial Hygienists
LEL Lower Explosive Limit - lowest percent of vapor in air, by
TLV Threshold Limit Value
volume, that will explode or ignite in the presence of
OSHA U.S. Occupational Safety and Health Administration
an ignition source
PEL Permissible Exposure Limit
UEL Upper Explosive Limit - highest percent of vapor in air,
IDLH Immediately Dangerous to Life and Health
by volume, that will explode or ignite in the presence of
an ignition source
FIRST AID MEASURES:

CPR Cardiopulmonary resuscitation - method in which a person HAZARD RATINGS:
whose heart has stopped receives manual chest
compressions and breathing to circulate blood and provide
0 Minimal Hazard
oxygen to the body.
1 Slight Hazard
FLAMMABILITY
2 Moderate Hazard
HMIS?br>
HAZARDOUS MATERIALS IDENTIFICATION REACTIVITY
3 Severe Hazard
SYSTEM: HMIS
4 Extreme Hazard
HEALTH
HEALTH, FLAMMABILITY & REACTIVITY RATINGS: ACD Acidic
ALK Alkaline
0 Minimal Hazard
FLAMMABILITY COR Corrosive
1 Slight Hazard
W Use No Water SPECIAL
2 Moderate Hazard HEALTH
REACTIVITY OX Oxidizer PRECAUTIONS
3 Severe Hazard
4 Extreme Hazard PERSONAL PROTECTION
TOXICOLOGICAL INFORMATION:
NCCHL44T ?NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808



PERSONAL PROTECTION RATINGS:
LD50 Lethal Dose (solids & liquids) which kills 50% of the
exposed animals s
A G
LC50 Lethal concentration (gases) which kills 50% of the
exposed animal
B H ppm Concentration expressed in parts of material per
million parts
C I TDlo Lowest dose to cause a symptom
TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or
D J TC, TCo, LClo, & LCo toxic effects
IARC International Agency for Research on Cancer
E K NTP National Toxicology Program
RTECS Registry of Toxic Effects of Chemical Substances
Consult your supervisor or S.O.P. for BCF Bioconcentration Factor
F X special handling directions. TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution

REGULATORY INFORMATION:
Face Shield &
Safety Glasses Splash Goggles Gloves
Eye Protection
WHMIS Canadian Workplace Hazardous Material Information System
DOT U.S. Department of Transportation
TC Transport Canada
Boots Dust Respirator
Synthetic Apron Full Suit EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
NDSL Canadian Non-Domestic Substance List
Full Face
Dust & Vapor Airline Hood/Mask
PSL Canadian Priority Substances List
Vapor Respirator Respirator
Respirator or SCBA
TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
Note: the dotted circle indicates that this respiratory protective
equipment is required for high concentrations or for large CPR Canadian Controlled Product Regulations
volume spills or releases of product.

EC INFORMATION:
OTHER STANDARD ABBREVIATIONS:
NA Not Available
NR No Results
NE Not Established
ND Not Determined
ML Maximum Limit C E F N O T+ Xi Xn
SCBA Self-Contained Breathing Apparatus
Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful

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1309-60-0_84-74-2_68611-50-7_108-88-3_13463-67-7_108171-26-2.asp 1309-60-0 84-74-2 68611-50-7 108-88-3 13463-67-7 108171-26-2
65996-69-2_1305-78-8_14808-60-7_13463-67.asp 65996-69-2 1305-78-8 14808-60-7 13463-67-7
39382-25-7_12001-26-2_111-87-5_25852-47-5_18268-70-7_9002-84-0.asp 39382-25-7 12001-26-2 111-87-5 25852-47-5 18268-70-7 9002-84-0 68909-20-6 80-15-9 13463-67-7
2921-88-2_67-64-1_500-00-0_67-56-1_95-48-7_94-75-7_72-43-5_139-13-9.asp 2921-88-2 67-64-1 500-00-0 67-56-1 95-48-7 94-75-7 72-43-5 139-13-9 78-92-2 1310-73-2
109-16-0_94-36-0_65997-17-3_7631-86-9_13463-67-7_1309-37-1.asp 109-16-0 94-36-0 65997-17-3 7631-86-9 13463-67-7 1309-37-1
1344-28-1_12136-45-7_13463-67-7.asp 1344-28-1 12136-45-7 13463-67-7
7647-14-5_68917-18-0_13463-67-7_63231-67-4_25446-78-0_7732-18.asp 7647-14-5 68917-18-0 13463-67-7 63231-67-4 25446-78-0 7732-18-5
13463-67-7_7732-18-5_57-55-6.asp 13463-67-7 7732-18-5 57-55-6
25068-38-6_100-51-6_14807-96-6_13463-67-7_1317-61-9_1332-37-2.asp 25068-38-6 100-51-6 14807-96-6 13463-67-7 1317-61-9 1332-37-2 51274-00-1 1308-38-9
12001-26-2_13463-67-7_1309-37-1_18282-10-5.asp 12001-26-2 13463-67-7 1309-37-1 18282-10-5
142-82-5_85-68-7_13463-67-7.asp 142-82-5 85-68-7 13463-67-7
25852-47-5_9004-96-0_81-07-2_80-15-9_67-56-1_112945-52-5_613-48-9.asp 25852-47-5 9004-96-0 81-07-2 80-15-9 67-56-1 112945-52-5 613-48-9 13463-67-7
7727-43-7_13463-67-7_6358-31-2.asp 7727-43-7 13463-67-7 6358-31-2
14807-96-6_65997-11-7_67-63-0_13463-67-7_14808-60-7.asp 14807-96-6 65997-11-7 67-63-0 13463-67-7 14808-60-7
9003-42-3_94-36-0_2783-94-0_2379-74-0_10101-66-3_12001-99.asp 9003-42-3 94-36-0 2783-94-0 2379-74-0 10101-66-3 12001-99-9 8003-22-3 57455-37-5 13463-67-7 1309-37-1
63231-60-7_8002-74-2_8015-86-9_8006-40-4_555-43-1_8050-09-7.asp 63231-60-7 8002-74-2 8015-86-9 8006-40-4 555-43-1 8050-09-7 13463-67-7 546-93-0 7782-42-5 8042-47-5 8009-03-8 8001-31-8 8006-54-0 8006-44-8
1317-65-3_7732-18-5_14808-60-7_13463-67-7_9003-20-7_108-05-4.asp 1317-65-3 7732-18-5 14808-60-7 13463-67-7 9003-20-7 108-05-4 34375-28-5
65997-15-1_14808-60-7_13463-67-7.asp 65997-15-1 14808-60-7 13463-67-7


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