10-6234 CORVELB #91 SAGE
MSDS Number: 149999-1- 3
iHAAS Effective: 8115/03
MATERIAL SAFETY DATA SHEET Supersedes: 4/22/03 Page 1
1. CHEMICAL PRODUCT AND COMPANY INFORMATION
Product ID: 10-6234 CORVELB #91 SAGE
Generic Description: Epoxy
Product Use: Coating Powder
For customer service/technical information, contact:
HAZARD RATINGS
Morton Powder Coatinas
Corporate Center, umber 5 Commerce Dr.
I I NFPA I
I HMlS
PO Box 15240
Reading PA 19612-5240 1*
Health 1
610-775-6600
MSDS prepared by:
Reactivity
Hazard Communications
David Wienckowski, D.A.B.T.
123 N. Wacker Drive
Chicago IL 60606-1743
312-807-3422
ChemTrec Emergency
1-800-424-9300
2. COMPOSITION/INFORMATIONON INGREDIENTS
This product is considered hazardous under the OSHA Hazard Communication
Standard (29 CFR 1910.1200).
Approximate
CAS #
COMMON NAME % (w/w)
Titanium Dioxide 13463-67-7 20 - 30
Silica, amorphous 7631-86-9 1- 5
Non-hazardous and other ingredients Not Applicable Balance
below reportable levels
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: IF PRODUCT DOES NOT CONTAIN INGREDIENTS WITH ESTABLISHED
AIRBORNE EXPOSURE LIMITS, THIS MATERIAL IS CONSIDERED A NUISANCE PARTICULATE.
INGESTION MAY CAUSE PAIN, UPSET STOMACH, DIARRHEA. MAY CAUSE EYE IRRITATION.
MAY CAUSE MECHANICAL EYE IRRITATION. DO NOT SWALLOW. See sections 3, 5, & 6.
PRIMARY ROUTES OF EXPOSURE: Eye. Skin. Inhalation (breathing).
EYE CONTACT: May cause slight to mild irritation. May cause mechanical
irritation.
SKIN CONTACT: Incidental contact is not expected to cause irritation.
INHALATION (Breathing): If this product does not contain ingredients with
established airborne exposure limits (see Exposure Guidelines in section 8),
this material is considered a nuisance particulate. No effects are expected
when exposures are maintained below the following limits: OSHA PEL - 5 m g / ~ 3
(respirable particulates), 15 m g / ~ 3(total particulates); ACGIH TLV - 10 m g / ~ 3
(total particulates).
Rohm & Haas Company 123 N. Wmker Drive Chicago, IL 60606-1 743
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10-6234 CORVELB #91 SAGE
MSDS Number: 149999-1- 3
iHAAS Effective: 8115/03
MATERIAL SAFETY DATA SHEET Supersedes: 4/22/03 Page 2
INGESTION (Swallowing): Not hazardous in normal industrial use. May cause
pain and stomach upset (e.g., diarrhea).
TARGET ORGANS/CHRONIC EFFECTS: Eyes.
CONDITIONS AGGRAVATED BY EXPOSURE: Lungs and respiratory system.
CARCINOGENICITY:
ACGIH IARC NTP OSHA
Titanium Dioxide A4 No No No
Silica, amorphous No No No No
4. FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation persists.
SKIN CONTACT: Immediately flush with water. Remove contaminated clothing and
shoes. Get medical attention if irritation persists. Professionally wash
clothing and shoes before re-use.
INHALATION (Breathing): Remove to fresh air. If symptoms develop, seek
immediate medical attention. If not breathing, give artificial respiration.
INGESTION (Swallowing): Obtain immediate medical attention. Rinse mouth
thoroughly with water, and give a cupful of water to drink. If vomiting
occurs, repeat rinsing and give another cupful of water. Never give anything
by mouth to an unconscious person.
NOTES TO PHYSICIANS: Treatment should be directed at preventing absorption,
administering to symptoms (if they occur), and providing supportive therapy.
5. FIRE FIGHTING METHODS
Flash Point. . . : Not Applicable Method . . . . . . . .: Not Applicable
Explosive Lmts: LEL ( % ) 30 - 70 g/M3 UEL ( % ) Not Determined
Autoignition..: Not Determined
HAZARDOUS COMBUSTION AND DECOMPOSITION PRODUCTS: Smoke, soot, and
toxic/irritating fumes (i.e., carbon dioxide, carbon monoxide, etc.).
FIRE AND EXPLOSION HAZARDS: Bulk powder in storage or being transferred in
closed containers has an HMIS/NFPA flammability rating of 1. If this material
is transferred into a process or dispersed in a powder coating operation where
concentrations can reach the explosive limit, the HMIS/NFPA flammability
rating is 4. Dusts at sufficient concentrations can form explosive mixtures
with air. During a fire, irritating and toxic gases may be generated during
combustion or decomposition.
EXTINGUISHING MEDIA: SMALL FIRES: Foam, carbon dioxide, dry chemical, water
spray. LARGE FIRES: Foam, water spray, or fog.
FIRE FIGHTING PROCEDURES/EQUIPMENT: Fire fighters and others who may be
exposed to the products of combustion should be equipped with NIOSH-approved
positive pressure self-contained breathing apparatus (SCBA) and full
protective clothing.
6. ACCIDENTAL RELEASE MEASURES
Rohm & Haas Company 123 N. Wmker Drive Chicago, IL 60606-1 743
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10-6234 CORVELB #91 SAGE
MSDS Number: 149999-1- 3
iHAAS Effective: 8115/03
MATERIAL SAFETY DATA SHEET Supersedes: 4/22/03 Page 3
EVACUATION: Isolate hazard area. Keep unnecessary and unprotected personnel
from entering. Eliminate all sources of ignition.
CONTAINMENT: Safely stop discharge. Contain material, as necessary, with a
dike or barrier. Stop material from contaminating soil, or from entering
sewers or bodies of water.
CLEAN-UP/PERSONALPROTECTION EQUIPMENT: Appropriate safety measures and
protective equipment should be used.
COLLECTION AND DISPOSAL: Shovel or vacuum material and place in chemical
waste containers. Use non-sparking tools and/or explosion-proof equipment.
Dispose of according to applicable local, state and federal regulations.
REPORTING: Spills of this material in excess of a component's RQ must be
reported to the National Response Center (1-800-424-8802) and to the
appropriate state and local emergency response organizations.
No regulated ingredients.
7. HANDLING AND STORAGE
STORAGE CONDITIONS: Store in cool, dry, well ventilated area away from heat,
ignition sources, and direct sunlight. Keep containers tightly closed.
TRANSFER: No special precautions are needed. Follow good manufacturing and
handling practices.
PERSONAL HYGIENE: wash thoroughly after handling, especially before eating,
drinking, smoking, and using restroom facilities. wash contaminated goggles
faceshield, and gloves. Professionally launder contaminated clothing before
re-use.
EMPTY CONTAINER PRECAUTIONS: Attention! This container can be hazardous when
empty. Follow label warnings even after container is emptied since empty
containers may retain product residues. Do not reuse empty container without
professional cleaning for food, clothing, or products for human or animal
consumption or where skin contact can occur.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE GUIDELINES:
ACGIH TLV
-
Titanium Dioxide 10 mg/M3
Silica, amorphous 10 mg/M3 Total
dust
OSHA PEL
-
Titanium Dioxide 10 mg/M3
Silica, amorphous mg/M3 Total
6
dust
ENGINEERING CONTROLS/VENTILATION: Local exhaust ventilation is recommended
when dusts can be released in excess of established airborne exposure limits
(TLVs or PELS). Explosion-proof exhaust ventilation is recommended when
excessive levels of dusts are generated. Ventilation equipment, baghouse and
cyclone dust collection system should be explosion proof and grounded. Curing
Rohm & Haas Company 123 N. Wmker Drive Chicago, IL 60606-1 743
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10-6234 CORVELB #91 SAGE
MSDS Number: 149999-1- 3
iHAAS Effective: 8115/03
MATERIAL SAFETY DATA SHEET Supersedes: 4/22/03 Page 4
ovens should be properly vented to prevent fumes from entering the workplace.
EYE PROTECTION: An eye wash facility should be readily available. Dust-proof
goggles are recommended for use in areas containing particulate matter.
Safety glasses are recommended for general industrial use.
SKIN PROTECTION: Wear protective clothing and appropriate impervious gloves.
Because a variety of protective gloves exist, consult glove manufacturer to
determine the proper type for a specific operation.
RESPIRATORY PROTECTION: Avoid breathing dust. Industrial hygiene consultation
is recommended because airborne exposure levels vary depending on the nature
of the operation performed. Use NIOSH/MSHA approved respirator equipped with
a HEPA filter or an appropriate respiratory device for particulates and fumes.
Determine the appropriate type by consulting the respirator manufacturer.
High airborne concentrations may necessitate the use of self-contained
breathing apparatus (SCBA) or a supplied air respirator. Respiratory
protection programs must be in compliance with 29 CFR 1910.134.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance . . . .: Odor . . . . . . . . . .:
See Section 1 Slight, if any
Solubility . . . .:
Physical State: Fine powder Negligible
pH . . . . . . . . . . . . : ~ r e e z e / ~ e. .t :
l. 104F - 176F 40C 80C
Not Applicable -
VOC Material..: Not Determined Specific Grvty: Not Determined
. > 99
on-~ol (w/w) :
NOTE: The physical data presented above are typical values and should
not be construed as a specification.
ADDITIONAL INFORMATION: Measured volatiles are absorbed water (per EPA
Reference Method 24 {ASTM D-2369-861).
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under normal conditions of use.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: High temperatures.
INCOMPATIBILITY WITH OTHER MATERIALS: Oxidizers. Acids.
11. TOXICITY INFORMATION
PRODUCT:
Prolonged breathing of dust can lead to particulate deposition within the
lungs.
COMPONENTS:
Titanium Dioxide:
In a 2-year study in rats, an increase in benign and malignant lung tumors was
observed at 250 m g / ~ 3respirable dust level. This level is 50 times the
current occupational exposure level and is not expected to correlate to human
exposures.
Silica, amorphous:
Repeated exposure to dusts can lead to particulate deposition in the lungs
Rohm & Haas Company 123 N. Wmker Drive Chicago, IL 60606-1 743
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10-6234 CORVELB #91 SAGE
MSDS Number: 149999-1- 3
iHAAS Effective: 8115/03
MATERIAL SAFETY DATA SHEET Supersedes: 4/22/03 Page 5
e., pneumoconiosis).
(i.
Oral LD50 Rat
12. ECOLOGICAL INFORMATION
No data are available on this product.
13. DISPOSAL CONSIDERATIONS
DISPOSAL: Dispose in accordance with all local, state, and federal
regulations.
GENERAL STATEMENTS: Federal regulations may apply to empty container. State
and/or local regulations may be different.
GENERAL RECOMMENDATIONS: Of the methods of disposal currently available, it
is recommended that an alternative be selected according to the following
order of preference, based upon environmental acceptability: (1) recycle-or
rework, if feasible; (2) incinerate at an authorized facility; or (3) treat at
an acceptable waste treatment facility.
SPECIAL INSTRUCTIONS: Be sure to contact the appropriate government
environmental agencies if further guidance is required.
14. TRANSPORT INFORMATION
49 CFR IATA IMO
Weight (lb) Shipping Name
Non-regulated Y Y Y
DOT Label . . . . . : Not applicable UN/NA Id Num..: Not Applicable
DOT Label No..: L199
15. REGULATORY INFORMATION
FEDERAL:
SARA Title I11 Section 311/312 - Hazard Categories:
-
N - Fire Hazard
N - Sudden Release of Pressure Hazard
N - Reactivity Hazard
N - Immediate (acute) Health Hazard
Y - Delayed (chronic) Health Hazard
Ozone-Depleting Chemicals No regulated ingredients.
-
SARA Section 302 Extremely Hazardous Mat No regulated ingredients.
-
SARA Section 313 Toxic Chemicals No regulated ingredients.
-
TSCA Section 12(b) Export Notification
Polychlorinated biphenyls
STATE RIGHT-TO-KNOW:
Pennsylvania - New Jersey R -T -K
Titanium Dioxide 13463-67-7 20 - 30
7631-86-9 1 - 5
Silica, amorphous
Non-hazardous trade secret ingredient(s) Proprietary Balance
California California Proposition 65 No regulated ingredients.
- -
Rohm & Haas Company 123 N. Wmker Drive Chicago, IL 60606-1 743
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10-6234 CORVELB #91 SAGE
MSDS Number: 149999-1- 3
iHAAS Effective: 8115/03
MATERIAL SAFETY DATA SHEET Supersedes: 4/22/03 Page 6
CONEG No data available.
-
CANADA:
This is a "controlled productM under the Canadian Workplace Hazardous
.
Materials Information System (WHMIS)
Class D Division 2 Sub-division B
CEPA NPRI No regulated ingredients.
- -
16. OTHER INFORMATION
USERS RESPONSIBILITY: A bulletin such as this cannot be expected to cover all
possible individual situations. As the user has the responsibility to provide
a safe workplace, all aspects of an individual operation should be examined to
determine if, or where, precautions - in addition to those described herein -
are required. Any health hazard and safety information herein should be
passed on to your customers or employees, as the case may be.
DISCLAIMER OF LIABILITY: The information contained herein is, to the best of
our knowledge and belief, accurate. However, since the conditions of handling
and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. All chemicals may
present unknown health hazards and should be used with caution. Although
certain hazards are described herein, we cannot guarantee that these are the
only hazards which exist. Final determination of suitability of the chemical
is the sole responsibility of the user. No representations or warranties,
either expressed or implied, of merchantability, fitness for a particular
purpose or any other nature are made hereunder with respect to the information
contained herein or the chemical to which the information refers. It is the
responsibility of the user to comply with all applicable federal, state and
local laws and regulations.
End of Material Safety Data Sheet
Rohm & Haas Company 123 N. Wmker Drive Chicago, IL 60606-1 743
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