Material Safety Data Sheet
Revision Date: 04/05/2005 Issue date: 04/06/2005
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Hysol 1C Varian Epoxy Adhesive Item No. : 83187_RESIN
Product type: Epoxy Resin Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Epichlorohydrin-4,4'-isopropylidene 30-60 None None None
diphenol resin
25068-38-6
Tremolite 10-30 1 mg/m?TWA as Fe = 0.1 f/cc TWA see None
14567-73-8 1910.1001
Antigorite 10-30 None None None
12135-86-3
Talc 10-30 2 mg/m?TWA respirable = 20 mppcf TWA 50 ppm
14807-96-6 fraction, particulate matter
containing no asbestos
and < 1% crystalline silica
Anthophyllite 1-5 None 0.1 fiber/cc TWA fibers None
17068-78-9 longer than 5 祄
1.0 fiber/cc Excursion
Limit 30 min. Cancer and
lung disease hazard - see
29 CFR 1910.1001 - does
not include non-
asbestiform actinolite,
tremolite or anthophylite
Titanium dioxide 1-5 10 mg/m?TWA 15 mg/m?TWA total dust None
13463-67-7
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
HMIS:
Physical state: Viscous liquid HEALTH: 2*
Color: White FLAMMABILITY: 1
Odor: None PHYSICAL HAZARD: 1
Personal Protection: See Section 8
WARNING: MAY CAUSE ALLERGIC SKIN REACTION.
MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact
Potential Health Effects
Item No. : 83187_RESIN Product name: Hysol 1C Varian Epoxy Adhesive
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Inhalation: May cause irritation to nose and throat. Mild respiratory tract irritation. Coughing.
Skin contact: Allergic skin reaction. Moderate skin irritation. Itching. Redness.
Eye contact: Moderate eye irritation. Redness.
Ingestion: Not expected under normal conditions of use.
Existing conditions aggravated by Skin disorders. Skin allergies. Respiratory disorders. Eye disorders.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get
medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Get medical attention if symptoms occur.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Get
medical attention if symptoms develop and persist.
Notes to physician: None.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 93篊 (200篎) Pensky Martens closed cup
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: In the event of fire, cool tanks with water spray. Closed containers may rupture (due to build up of
pressure) when exposed to extreme heat.
Hazardous combustion products: Oxides of carbon. Irritating organic fragments. Acids. Aldehydes.
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as much material
as possible. Clean residue with soap and water. Store in a closed container until ready for disposal.
Item No. : 83187_RESIN Product name: Hysol 1C Varian Epoxy Adhesive
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7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Do not breathe mist or vapors. Keep container closed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Storage: Store in original container until ready to use. Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.
Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits
exists.
Skin protection: Chemical resistant, impermeable gloves.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Viscous liquid
Color: White
Odor: None
Vapor pressure: Nil
pH: Not applicable
Boiling point/range: Greater than 260癈 (500癋)
Melting point/range: Not available
Specific gravity: 1.57
Vapor density: Not available
Evaporation rate: Not available
Solubility in water: Insoluble
Partition coefficient (n-octanol/water): Not available
VOC content: < 0.05% (value for resin and hardener together) (estimated)
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous polymerization: Will not occur.
Hazardous decomposition products: None
Incompatability: Strong acids. Strong bases. Strong oxidizers. Amines. Water.
Conditions to avoid: Excessive heat. Storage with incompatible materials.
11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Item No. : 83187_RESIN Product name: Hysol 1C Varian Epoxy Adhesive
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Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Epichlorohydrin-4,4'-isopropylidene No No No
diphenol resin
25068-38-6
Tremolite No Group 1 Yes
14567-73-8
Antigorite No No No
12135-86-3
Talc No No No
14807-96-6
Anthophyllite Known Carcinogen No Yes
17068-78-9
Titanium dioxide No No No
13463-67-7
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Epichlorohydrin-4,4'-isopropylidene Allergen, Irritant
diphenol resin
25068-38-6
Tremolite Lung, Mutagen, Carcinogen
14567-73-8
Antigorite Lung, Some evidence of carcinogenicity, Mutagen
12135-86-3
Talc Some evidence of carcinogenicity, Lung, Irritant
14807-96-6
Anthophyllite Carcinogen, Mutagen, Lung
17068-78-9
Titanium dioxide Irritant, Respiratory
13463-67-7
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose according to EPA and local governmental regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be
different for bulk packaging.
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
International Air Transportation (ICAO/IATA):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
WaterTransportation (IMO/IMDG):
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None
Marine pollutant: None known
Item No. : 83187_RESIN Product name: Hysol 1C Varian Epoxy Adhesive
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15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None above reporting de minimus.
CERCLA/SARA Section 311/312: Immediate Health Hazard, Delayed Health Hazard
CERCLA/SARA 313: None above reporting de minimus.
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: First issue.
Prepared by: Gary Pierson, Sr. Product Safety and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
Item No. : 83187_RESIN Product name: Hysol 1C Varian Epoxy Adhesive
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Material Safety Data Sheet
Revision Date: 03/30/2005 Issue date: 03/30/2005
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: Hysol 1C Varian Item No. : 83187_HARDENER
Product type: Epoxy Hardener Region: United States
Company address: Contact Information:
Henkel Corporation Telephone: 860.571.5100
1001 Trout Brook Crossing Emergency telephone: 860.571.5100
Rocky Hill, Connecticut 06067 Internet: www.loctite.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components % ACGIH TLV OSHA PEL OTHER
Epoxy resin/Curing agent 10-30 None None None
68610-56-0
Tremolite 10-30 1 mg/m?TWA as Fe = 0.1 f/cc TWA see None
14567-73-8 1910.1001
Silica, quartz 10-30 0.05 mg/m?TWA 0.1mg/m?TWA None
14808-60-7 respirable fraction (respirable)
Antigorite 10-30 None None None
12135-86-3
Talc 10-30 2 mg/m?TWA respirable = 20 mppcf TWA 50 ppm
14807-96-6 fraction, particulate matter
containing no asbestos
and < 1% crystalline silica
Diethylene triamine 10-30 1 ppm TWA None None
111-40-0 (skin)
Anthophyllite 1-5 None 0.1 fiber/cc TWA fibers None
17068-78-9 longer than 5 祄
1.0 fiber/cc Excursion
Limit 30 min. Cancer and
lung disease hazard - see
29 CFR 1910.1001 - does
not include non-
asbestiform actinolite,
tremolite or anthophylite
4,4`-Isopropylidenediphenol 1-5 None None None
80-05-7
3. HAZARDS IDENTIFICATION
Item No. : 83187_HARDENER Product name: Hysol 1C Varian
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EMERGENCY OVERVIEW
HMIS:
Physical state: Viscous liquid HEALTH: 3*
Color: Tan FLAMMABILITY: 1
Odor: Strong, Ammoniacal PHYSICAL HAZARD: 0
Personal Protection: See Section 8
DANGER: CAUSES EYE AND SKIN BURNS.
MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION.
MAY CAUSE RESPIRATORY TRACT IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
Relevant routes of exposure: Eye contact, Ingestion, Inhalation, Skin contact
Potential Health Effects
Inhalation: Allergic respiratory reaction. May cause respiratory tract irritation. May cause irritation to nose and
throat.
Skin contact: May cause skin burns. Allergic skin reaction. Rash. Redness.
Eye contact: Burns. Severe eye irritation. Redness. Tissue damage.
Ingestion: May be harmful if swallowed. May cause burns of mouth and throat if swallowed.
Existing conditions aggravated by Skin disorders. Skin allergies. Respiratory disorders. Eye disorders.
exposure:
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove contaminated clothing
and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if
symptoms occur.
Eye contact: Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.
Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Keep individual calm. Get
medical attention immediately.
Notes to physician: None.
5. FIRE-FIGHTING MEASURES
Flash point: Greater than 101.6篊 (215篎) (estimated)
Autoignition temperature: Not available
Flammable/Explosive limits-lower %: Not available
Flammable/Explosive limits-upper %: Not available
Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.
Special fire fighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
Unusual fire or explosion hazards: In the event of fire, cool tanks with water spray.
Hazardous combustion products: Oxides of carbon. Oxides of nitrogen. Irritating organic fragments.
Item No. : 83187_HARDENER Product name: Hysol 1C Varian
2 of 5
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Prevent product from entering drains or open waters.
Clean-up methods: Remove all ignition sources. Immediately contact emergency personnel. Scrape up as much material
as possible. Clean residue with soap and water. Store in a closed container until ready for disposal.
7. HANDLING AND STORAGE
Handling: Keep away from heat, spark and flame. Do not breathe mist or vapors. Keep container closed. Avoid
contact with eyes, skin and clothing. Wash thoroughly after handling.
Storage: Store in original container until ready to use. Keep in a cool, well ventilated area away from heat,
sparks and open flame. Keep container tightly closed until ready for use.
Incompatible products: Refer to Section 10.
For information on product shelf life contact Henkel Customer Service at (800) 243-4874.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Use local exhaust ventilation to maintain airborne concentrations below established exposure limits.
Respiratory protection: Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits
exists.
Skin protection: Chemical resistant, impermeable gloves. Use chemical resistant, impermeable clothing including
gloves and either an apron or body suit to prevent skin contact.
Eye/face protection: Chemical splash goggles or safety glasses with side shields.
See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Viscous liquid
Color: Tan
Odor: Strong, Ammoniacal
Vapor pressure: <1 mmHg @ 20癈 (68癋)
pH: Not applicable
Boiling point/range: 207癈 (404癋)
Melting point/range: Not available
Specific gravity: 1.65
Vapor density: 3.5
Evaporation rate: Not available
Solubility in water: Slightly soluble
Partition coefficient (n-octanol/water): Not available
VOC content: <0.1% (value for resin and hardener together)
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous polymerization: Polymerization is a highly exothermic reaction and may generate sufficient heat to cause thermal
decomposition and/or rupture containers.
Hazardous decomposition products: None
Incompatability: Strong acids. Strong bases. Strong oxidizers. Amines. Water.
Conditions to avoid: Temperatures above 37.8癈 (100癋). Excessive heat. Storage with incompatible materials. Avoid
mixing resin (Part A) and curing agent (Part B) in batches greater than 2 pound (.9 kg) unless you plan
to use immediately. Failure to observe these precautions may result in excessive heat build-up causing
an exotherm.
Item No. : 83187_HARDENER Product name: Hysol 1C Varian
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11. TOXICOLOGICAL INFORMATION
Carcinogen Status
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen
Epoxy resin/Curing agent No No No
68610-56-0
Tremolite No Group 1 Yes
14567-73-8
Silica, quartz Known Carcinogen Group 1 Yes
14808-60-7
Antigorite No No No
12135-86-3
Talc No No No
14807-96-6
Diethylene triamine No No No
111-40-0
Anthophyllite Known Carcinogen No Yes
17068-78-9
4,4`-Isopropylidenediphenol No No No
80-05-7
Literature Referenced Target Organ & Other Health Effects
Hazardous components Health Effects/Target Organs
Epoxy resin/Curing agent No data
68610-56-0
Tremolite Lung, Mutagen, Carcinogen
14567-73-8
Silica, quartz Some evidence of carcinogenicity, Lung, Immune system
14808-60-7
Antigorite Lung, Some evidence of carcinogenicity, Mutagen
12135-86-3
Talc Some evidence of carcinogenicity, Lung, Irritant
14807-96-6
Diethylene triamine Allergen, Eyes, Irritant
111-40-0
Anthophyllite Carcinogen, Mutagen, Lung
17068-78-9
4,4`-Isopropylidenediphenol Allergen, Blood, Irritant, Kidney, Spleen, Reproductive
80-05-7
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Dispose according to EPA and local governmental regulations.
EPA hazardous waste number: Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be
different for bulk packaging.
U.S. Department of Transportation Ground (49 CFR):
Proper shipping name: Diethylenetriamine solution
Hazard class or division: 8
Identification number: UN 2079
Packing group: II
Exceptions: (Not more than 1 Liter) Consumer Commodity ORM-D
Item No. : 83187_HARDENER Product name: Hysol 1C Varian
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International Air Transportation (ICAO/IATA):
Proper shipping name: Diethylenetriamine solution
Hazard class or division: 8
Identification number: UN2079
Packing group: II
WaterTransportation (IMO/IMDG):
Proper shipping name: Diethylenetriamine solution
Hazard class or division: 8
Identification number: UN2079
Packing group: II
Marine pollutant: None known
15. REGULATORY INFORMATION
United States Regulatory Information
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory.
TSCA 12 (b) Export Notification: None.
CERCLA/SARA Section 302 EHS: None.
CERCLA/SARA Section 311/312: Immediate Health Hazard
CERCLA/SARA 313: None above reporting de minimus.
California Proposition 65: This product contains a chemical known to the State of California to cause cancer.
Canada Regulatory Information
CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Domestic Substances List.
WHMIS hazard class: E, D.2.A, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: Corrected information in Section(s) 14.
Prepared by: Gary Pierson, Sr. Product Safety and Regulatory Affairs Specialist
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation
does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the
user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular
purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be
involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically
disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale
or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of
any kind, including lost profits.
Item No. : 83187_HARDENER Product name: Hysol 1C Varian
5 of 5
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