MATERIAL SAFETY DATA SHEET
SIGNS & SYMPTOMS OF OVEREXPOSURE:
SECTION 1 - PRODUCT AND COMPANY INFORMATION
Dryness, itching, cracking, burning, redness, and swelling are conditions
associated with excessive skin contact.
PPG Industries, Inc.
One PPG Place MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not
Pittsburgh, PA 15272 applicable.
CHRONIC OVEREXPOSURE EFFECTS
EMERGENCY PHONE NUMBERS (412) 434-4515 (U.S.) Avoid long-term and repeated contact.
(24 hours/day): Do not process this material at temperatures above 200 degrees C. At
(514) 645-1320 (Canada) these temperatures, decomposition of the dye in this product may
01-800-00-21-400 (Mexico) produce aromatic amines. Some of these aromatic amines are
0532-83889090 (China) carcinogenic. Trimethoxysilanes are capable of forming methanol if
hydrolyzed or ingested. If swallowed, methanol may be harmful or fatal or
PRODUCT SAFETY/MSDS INFORMATION: (412) 492-5555 7:00 a.m.
cause blindness. Additionally, adverse developmental effects from oral
- 4:30 p.m. EST
administration of some trimethoxysilanes have been reported in rats.
Product ID: PX70066 (0882)
The effects of long-term, low level exposures to this product have not
PRODUCT NAME: PSX 700 ORANGE F/S 12199
been determined. Safe handling of this material on a long-term basis
SYNONYMS: None
should emphasize the prevention of all contact with this material to avoid
ISSUE DATE: 12/14/2006
any effects from repetitive acute exposures. See Section 11, of this
EDITION NO.: 4
MSDS for a detailed list of chronic health effects information available on
CHEMICAL MIXTURE
individual ingredients in this product.
FAMILY:
EMERGENCY OVERVIEW:
CAUSES EYE IRRITATION. MAY CAUSE MODERATE SKIN SECTION 4 - FIRST AID MEASURES
IRRITATION. PROLONGED OR REPEATED CONTACT MAY CAUSE If ingestion, irritation, any type of overexposure or symptoms of
AN ALLERGIC SKIN REACTION.VAPOR AND/OR SPRAY MIST MAY overexposure occur during or persists after use of this product, contact a
BE HARMFUL IF INHALED.HARMFUL IF SWALLOWED.STABLE - POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN
HAZARDOUS REACTIONS POSSIBLE AT EXTREMELY HIGH immediately; have Material Safety Data Sheet information available.
TEMPERATURES/PRESSURES. This product is not expected to present EYE CONTACT:
any unusual hazards under fire or spill conditions. Read entire MSDS Remove contact lens and pour a gentle stream of warm water through the
before use. affected eye for at least 15 minutes. If irritation persists, contact a poison
control center, emergency room, or physician as further treatment may be
necessary.
SKIN CONTACT:
SECTION 2 - COMPOSITION INFORMATION
Run a gentle stream of water over the affected area for 15 minutes. A
The following ingredient(s) marked with an "x" are considered
mild soap may be used if available. Contact a poison control center,
hazardous under applicable U.S. OSHA and/or Canadian WHMIS
emergency room or physician right away as further treatment will be
regulations. If no ingredients are listed, then there are no U.S. OSHA
necessary.
and/or Canadian WHMIS hazardous ingredients in this product.
INHALATION:
Material/ Percent Hazardous
Remove from area to fresh air. If symptomatic, contact a poison control
CAS Number
PROPRIETARY SILICONE 40 - 70 X center, emergency room or physician for treatment information.
Proprietary INGESTION:
PROPRIETARY EPOXY 15 - 40 X Gently wipe or rinse the inside of the mouth with water. Sips of water
Proprietary
may be given if person is fully conscious. Never give anything by mouth
BENZIDINE PIGMENT ORANGE 5 - 10 X
to an unconscious or convulsing person. Do Not induce vomiting.
15793-73-4
Contact a poison control center, emergency room or physician right away
TITANIUM DIOXIDE 1-5 X
as further treatment will be necessary.
13463-67-7
BIS(PENTAMETHYLPIPERIDYL) 1-5 X
SEBACATE
SECTION 5 - FIRE FIGHTING MEASURES
41556-26-7
FLAMMABLE PROPERTIES
FLASHPOINT: 205 Degrees F ( 96 Degrees C)
SECTION 3 - HAZARDS IDENTIFICATION
FLASHPOINT TEST METHOD:
ACUTE OVEREXPOSURE EFFECTS Pensky-Martens Closed Cup
UEL: Not Available.
EYE CONTACT: LEL: 9.7
Causes eye irritation. Redness, itching, burning sensation and visual AUTOIGNITION TEMPERATURE:
disturbances may indicate excessive eye contact. Not Available.
SKIN CONTACT: EXTINGUISHING MEDIA:
May cause moderate skin irritation. Dryness, itching, cracking, burning, Use National Fire Protection Association (NFPA) Class B extinguishers
redness, and swelling are conditions associated with excessive skin (carbon dioxide, dry chemical or universal aqueous film forming foam)
contact. designed to extinguish NFPA Class IIIB combustible liquid fires.
SKIN ABSORPTION: PROTECTION OF FIREFIGHTERS:
Skin absorption not expected to occur. Prolonged or repeated contact Water spray may be ineffective. Water spray may be used to cool closed
may cause an allergic skin reaction. containers that are exposed to extreme heat. If water is used, fog
INHALATION: nozzles are preferable. Firefighters should wear self-contained breathing
Vapor and/or spray mist may be harmful if inhaled. apparatus and full protective clothing.
INGESTION:
Harmful if swallowed.
__________________________________________________________________
Page 1 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: PX70066 (0882)
PRODUCT NAME: PSX 700 ORANGE F/S 12199
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Material not known to be explosive. May produce hazardous
Material/ Percent ACGIH TLV ACGIH OSHA PEL OSHA
decomposition products when exposed to extreme heat. Extreme heat CAS Number STEL STEL
includes, but is not limited to, flame cutting, brazing, and welding. 3 3
TITANIUM DIOXIDE 1-5 10 mg/m Not 10 mg/m Not
13463-67-7 established established
SECTION 6 - ACCIDENTAL RELEASE MEASURE
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Material/ Percent Ontario Ontario PPG IPEL PPG STEL
Provide maximum ventilation. Only personnel equipped with proper CAS Number TWA STEL
respiratory, skin, and eye protection should be permitted in the area. 10 MG/m3
TITANIUM DIOXIDE 1-5 Not Not Not
Remove all sources of ignition. Take up spilled material with sand, 13463-67-7 established established established
vermiculite, or other noncombustible absorbent material and place in
clean, empty containers for disposal. Only the spilled material and the
Key: ACGIH=American Conference of Governmental Industrial
absorbant should be placed in this container.
Hygienists; OSHA=Occupational Safety and Health Administration;
TLV=Threshold Limit Value; TWA=Time Weighted Average;
SECTION 7 - HANDLING AND STORAGE PEL=Permissible Exposure Limit (1989 Vacated values); IPEL=Internal
PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORAGE: Permissible Exposure Limit; Ceiling=TLV or PEL Ceiling Limit; STEL=TLV
If this material is part of a multiple component system, read the Material or PEL Short-Term Exposure Limit; Skin= Skin Absorption Designation.
Safety Data Sheet(s) for the other component or components before [C- Ceiling Limit; S-Potential Skin Absorption; R-Respirable Dust]
blending as the resulting mixture may have the hazards of all of its parts. Additional Information Not applicable.
STORAGE:
Do not store above 120 degrees F.(48 degress C.). Store large quantities
SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES
in buildings designed and protected for storage of NFPA Class IIIB
(FORMULA VALUES, NOT SALES SPECIFICATIONS)
combustible liquids.
SPECIFIC GRAVITY: 1.217
PHYSICAL STATE: Liquid
SECTION 8 - EXPOSURE CONTROLS & PERSONAL PROTECTION Percent Solids: 99.78
ENGINEERING CONTROLS: Percent Volatile by Volume: .310
Provide general dilution or local exhaust ventilation in volume and pattern pH: Not available.
to keep the concentration of ingredients listed in Section 8 below the ODOR THRESHOLD: Not available.
lowest suggested exposure limits, the LEL below the stated limit, and to Vapour Pressure: 4.8 mmHg
remove decomposition products during welding or flame cutting. ODOR/APPEARANCE: Viscous liquid with an odor
characteristic of the solvents listed in
Section 2.
PERSONAL PROTECTIVE EQUIPMENT
VAPOR DENSITY: HEAVIER THAN AIR
EYES:
Evaporation Rate: 33
Wear chemical-type splash goggles when possibility exists for eye
BOILING POINT OR RANGE: 96- 311Degrees F
contact due to splashing or spraying liquid, airborne particles, or vapors.
Freezing Point or Range: Not Applicable.
SKIN/GLOVES:
Melting Point or Range(癈): Not Applicable.
Wear protective clothing to prevent skin contact. Apron and gloves
Partition coefficient (n- Not Applicable.
should be constructed of: rubber. No specific permeation/degradation
octanol/water):
testing have been done on protective clothing for this product.
WEIGHT PER GALLON: 10.14 (U.S.) / 12.1 (IMPERIAL)
Recommendations for skin protection are based on infrequent contact
with this product. For frequent contact or total immersion, contact a
manufacturer of protective clothing for appropriate chemical impervious
SECTION 10 - STABILITY AND REACTIVITY
equipment. The decision whether to clean or discard contaminated
clothing should be based on the chemicals contaminating them. Some STABILITY:
chemicals can cause skin irritation, sensitization or other health effects if This product is normally stable but may undergo hazardous reactions at
the cleaning process does not remove all traces of them. Consult a extremely high temperatures and pressures.
safety professional to determine whether clothing contaminated with this CONDITIONS TO AVOID:
product can be safely cleaned and reused. None Known.
RESPIRATOR: INCOMPATIBLE MATERIALS:
Where ventilation is inadequate, use a NIOSH- approved air purifying Avoid contact with strong alkalies, strong mineral acids, or strong
respirator with the appropriate chemical cartridges or positive- pressure, oxidizing agents.
air-supplied respirator. Read the respirator manufacturer's instructions HAZARDOUS POLYMERIZATION:
and literature carefully to determine the type of airborne contaminants None Known.
against which the respirator is effective, its limitations, and how it is to be HAZARDOUS DECOMPOSITION PRODUCTS:
properly fitted and used. Provide general dilution or local exhaust - Carbon monoxide - Carbon dioxide - Oxides of nitrogen - Chlorinated
ventilation in volume and pattern to keep the concentration of ingredients products - Hydrogen cyanide - Ammonia
listed in Section 2 below the lowest suggested exposure limits, the LEL
below the stated limit, and to remove decomposition products during
welding or flame cutting.
SECTION 11 - TOXICOLOGICAL INFORMATION
GENERAL HYGIENE - ESTABLISHED EXPOSURE LIMITS
ACUTE TOXICITY
If Threshold Limit Values (TLVs) have been established by ACGIH,
OSHA, Ontario or PPG, they will be listed below. These limits are
intended for use in the practice of industrial hygiene as guidelines or
recommendations in the control of potential workplace health hazards.
These limits are not a relative index of toxicity and should not be used by
anyone without industrial hygiene training.
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Page 2 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: PX70066 (0882)
PRODUCT NAME: PSX 700 ORANGE F/S 12199
USA-RQ Hazardous Substance None
Material/ Percent ORAL DERMAL INHALATION
CAS Number LD50 (g/kg) LD50 (g/kg) LC50 (mg/l) Threshold Ship Weight:
BENZIDINE 5 - 10 15.00 g/kg Not Available Not Available Marine Pollutant Name: None
PIGMENT ORANGE
15793-73-4
SECTION 15 - REGULATORY INFORMATION
TITANIUM DIOXIDE 1-5 10.00 g/kg Not Available Not Available
INVENTORY STATUS
13463-67-7
BIS(PENTAMETHY 1-5 3.13 g/kg Not Available Not Available U.S. TSCA: This product and/or all of its components are listed on the
LPIPERIDYL) U.S. TSCA Inventory or is otherwise exempt from TSCA Inventory
SEBACATE reporting requirements.
41556-26-7
FEDERAL REGULATIONS
US Regulations
Material/ Percent
CHRONIC TOXICITY
CAS Number CERCLA HS - SARA EHS- SARA 313
Ingredient Target Organ/Chronic Effects:
RQ (LBS) TPQ (LBS)
- Lung - Carcinogen - Embryotoxin - Teratogen
PROPRIETARY 40 - 70 Not Listed Not Listed Not Listed
SILICONE
Proprietary
Mutagenicity Toxicity:
PROPRIETARY 15 - 40 Not Listed Not Listed Not Listed
This has not been tested for this product.
EPOXY
Reproductive Toxicity:
Proprietary
This has not been tested for this product. BENZIDINE 5 - 10 Not Listed Not Listed Not Listed
PIGMENT ORANGE
15793-73-4
SUPPLEMENTAL HEALTH INFORMATION:
TITANIUM DIOXIDE 1-5 Not Listed Not Listed Not Listed
Material/ Percent
13463-67-7
CAS Ingredient Specific Animal Data:
BIS(PENTAMETHY 1-5 Not Listed Not Listed Not Listed
Number
LPIPERIDYL)
TITANIUM 1-5 This product contains titanium dioxide. Animals inhaling
SEBACATE
DIOXIDE massive quantities of titanium dioxide dust in a long-term
41556-26-7
13463-67-7 study developed lung tumors. Studies with humans
involved in manufacture of this pigment indicate no
increased risk of cancer from exposure.
SARA 311/312
Health (acute): Yes
SECTION 12 - ECOLOGICAL INFORMATION Health (chronic): Yes
POTENTIAL ENVIRONMENTAL EFFECTS Fire (flammable): No
Ecotoxicity: No Information Available. Pressure: No
Reactivity: No
WHMIS HAZARD CLASS: - Class D, Division 2, Subdivision A - Class
ENVIRONMENTAL FATE
D, Division 2, Subdivision B
Mobility: No information available.
Biodegradation: No information available.
STATE/PROVINCIAL REGULATIONS
Bioaccumulation: No Information Available.
CALIFORNIA PROP. 65: WARNING: This product contains a chemical
known to the State of California to cause cancer.
PHYSICAL/CHEMICAL Additional Information
Percent
Material/
Hydrolysis: No information available.
CAS Number IARC IARC IARC ACGIH NTP OSHA
Photolysis: No information available.
Group Group 2B ( Carc. Known Carc.
1(Kno 2A Suspec Carc.
SECTION 13 - DISPOSAL CONSIDERATIONS wn (Proba ted
Human ble Carc.)
Provide maximum ventilation, only personnel equipped with proper
Carc.) Carc.)
respiratory and skin and eye protection should be permitted in the area.
1-5
TITANIUM DIOXIDE N N Y N N N
Take up spilled material with sawdust, vermiculite, or other absorbent
13463-67-7
material and place in containers for disposal.
Waste material must be disposed of in accordance with federal, state,
provincial and local environmental control regulations. Empty containers Key: IARC- International Agency on the Research of Cancer; ACGIH-
should be recycled by an appropriately licensed reconditioner/salvager or American Conference of Governmental Industrial Hygienists; NTP-
disposed of through a permitted waste management facility. Additional National Toxicology Program *Denotes chemical as NTP Known
disposal information is contained on the Environmental Data Sheet for Carcinogen; + Denotes NTP Possible Carcinogen; OSHA-
this product, which can be obtained from your PPG representative. Occupational Safety and Health Administration.
SECTION 14 - TRANSPORTATION INFORMATION SECTION 16 - OTHER INFORMATION
Proper Shipping Name: Paint- Non-Regulated Goods
NOS Technical Name: None Hazard Rating Systems
Hazard Class: None NFPA Rating: 2 11
Subsidiary Class(es): None HMIS Rating: 2*11
UN Number: None
Packing Group: None Rating System: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe,
*=Chronic Effects.
USA - RQ Hazardous Substances: None
__________________________________________________________________
Page 3 of 4
_______________________________________________________________________________________________________________
PPG Industries, Inc.
One PPG Place
Pittsburgh, PA 15272
Product ID: PX70066 (0882)
PRODUCT NAME: PSX 700 ORANGE F/S 12199
HMIS=Hazardous Materials Identification System; NFPA=National Fire
Protection Association;
Safe handling of this product requires that all of the information on the
MSDS be evaluated for specific work environments and conditions of use.
PREPARED BY: Product Safety Department
REASON FOR REVISION: Section 2 has been updated. Changes to this
section may also result in changes in sections 8, 11 and/or 15. Date.
Edition.
Updated MSDS
format.
This Material Safety Data Sheet has been prepared in accordance with
Canada's Workplace Hazardous Materials Information System (WHMIS)
and the OSHA Hazard Communication Standard (29 CFR 1910.1200),
the supplier notification requirements of SARA Title III, Section 313 and
other applicable right-to-know regulations.
Additional environmental information is contained on the Environmental
Data Sheet for this product, which can be obtained from your PPG
representative.
PX70066 000002 (00439011.001)(12/13/06)
061212, 000, 0882
*** END OF MSDS ***
__________________________________________________________________
Page 4 of 4
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