MATERIAL SAFETY DATA SHEET
Thermo Manufacturing Systems, LLC
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Thermo?#150 Rinseable Primer MSDS Date: 06/2002
COMPANY INDENTIFICATION EMERGENCY TELEPHONE NUMBERS
Thermo Manufacturing Health Emergency : 215-592-3000
301 Walnut Springs Road Spill Emergency : 215-592-3000
Lindale, TX 75771 Chemtrec : 800-424-9300
2. COMPOSITION/INFORMATION ON INGREDIENTS
No. CAS REG No. WEIGHT(%)
1 Inorganic salts Trade Secret 9-11
2 Anionic/nonionic surfactant mixture Trade Secret 1-3
3 Water 7732-18-5 87-89
See Section 8, Exposure Controls / Personal Protection
3. HAZARDS INDENTIFICATION
Primary Routes of Exposure Skin Contact
Inhalation Material can cause corrosion to the skin
Eye Contact - burns.
Skin Contact
Ingestion
Inhalation Material is harmful if swallowed.
Inhalation of vapor or mist can cause Material can cause burning and severe swelling
severe irritation of nose, throat and lungs. of the mouth, throat and digestive tract -
abdominal pain -gastrointestinal irritation -
Eye Contact nausea - vomiting -diarrhea.
Material can cause corrosion to the eyes
- corneal burns - permanent eye injury.
4. FIRST AID MEASURES
Inhalation thoroughly before reuse. Do not take clothing
Move subject to fresh air. If breathing is home to be laundered. Discard contaminated
difficult, give oxygen. Give artificial respiration if shoes, belts and other articles made of leather.
breathing has stopped. Call a physician.
Ingestion
Eye Contact DO NOT induce vomiting. Give milk or
IMMEDIATELY flush eyes with a large water to drink. IMMEDIATELY see a physician.
amount of water for at least 15 minutes. Get If vomiting occurs spontaneously, keep airway
prompt medical attention. clear. Never give anything by mouth to an
unconscious person.
Skin Contact
IMMEDIATELY get under a safety Note to Physician
shower. Remove contaminated clothing. Wash No specific antidote, treat
skin thoroughly with soap and water. Get prompt symptomatically. Corrosive material.
medical attention. Wash contaminated clothing
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MATERIAL SAFETY DATA SHEET
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Thermo Manufacturing Systems, LLC Thermo #150 Rinseable Primer
5. FIRE FIGHTING MEASURES
Flash Point Noncombustible
Auto-ignition Temperature Not Applicable
Lower Explosive Limit Not Applicable
Upper Explosive Limit Not Applicable
Unusual Hazards or equivalent) and full protective gear.
Combustion generates toxic fumes of MATERIAL IS CORROSIVE. If exposed to
carbon oxides - phosphorous oxides material as-is or mixed with run-off water during
fire-fighting, IMMEDIATELY remove all
Extinguishing Agents contaminated clothing and wash exposed skin
Use extinguishing media appropriate for areas with soap and water. See SECTION 4,
surrounding fire. First Aid Measures, for further information.
Personal Protective Equipment Special Procedures
Wear self-contained breathing Contain run-off. Remain upwind. Use
apparatus (pressure-demand NIOSH approved water spray to cool containers exposed to fire.
6. ACCIDENTIAL RELEASE MEASURES
Personal Protection Procedures
Wear compatible, chemically resistant Evacuate the spill area. Ventilate the
gloves. spill area. Floor may be slippery; use care to
Wear protective clothing including avoid falling. Contain spills immediately with
splash proof goggles and rubber overshoes. inert materials (e.g. sand, earth) Transfer liquids
MATERIAL IS CORROSIVE. If exposed and solid diking material to separate suitable
to material during clean-up operations, containers for recovery or disposal. Avoid all
IMMEDIATELY remove all contaminated contact.
clothing and wash exposed skin areas with soap WARNING: KEEP SPILLS AND CLEANING
and water. See SECTION 4, First Aid Measures RUNOFFS OUT OF MUNICIPAL SEWERS
for further information. AND OPEN BODIES OF WATER.
7. HANDLING AND STORAGE
Storage Conditions Protection, prior to handling. Wash after
Store in a well ventilated area. Store in a handling and shower at end of work period.
dry area.
Keep container tightly closed when not Other
in use. CONTAINERS HAZARDOUS WHEN
EMPTY. Since emptied containers retain
Handling Procedures product residue (vapors and/or liquid) follow all
This material is corrosive. See MSDS and label warnings even after container
SECTION 8, Exposure Controls / Personal is emptied.
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MATERIAL SAFETY DATA SHEET
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Thermo Manufacturing Systems, LLC Thermo #150 Rinseable Primer
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Limit Information
No. CAS REG No. WEIGHT(%)
1 Inorganic salts Trade Secret 9-11
2 Anionic/nonionic surfactant mixture Trade Secret 1-3
3 Water 7732-18-5 87-89
Comp. OSHA ACGIH
No. Units TWA STEL TWA STEL
1 None None None None
2 None None None None
3 None None None None
Respiratory Protection Gloves should be removed and replaced
A respiratory protection program immediately if there is any indication of
meeting OSHA 1910.134 and ANSI Z88.2 degradation or chemical breakthrough.
requirements or equivalent must be followed Rinse and remove gloves immediately
whenever workplace conditions warrant a after use. Wash hands with soap and water.
respirator's use. None required under normal
operating conditions. Where vapors and/or mists Other Protection
may occur, wear a properly fitted NIOSH Use chemically resistant apron or other
approved (or equivalent) half-mask, air-purifying impervious clothing to avoid prolonged or
respirator. Air-purifying respirators should be repeated skin contact. Where splashing is
equipped with NIOSH approved (or equivalent) possible, full chemically resistant protective
organic vapor cartridges and N95 filters. If oil clothing (e.g. acid suit) and boots are required.
mist is present, use R95 or P95 filters.
Engineering Controls (Ventilation)
Eye Protection Use local exhaust ventilation with a
Use chemical splash goggles and face minimum capture velocity of 100 ft/min.
shield (ANSI Z87.1 or approved equivalent). Eye (0.5m/sec.) at the point of vapor evolution. Refer
protection must be compatible with respiratory to the current edition of Industrial Ventilation: A
protection system employed. Manual of Recommended Practice published by
the American Conference of Governmental
Hand Protection Industrial Hygienists for information on the
Chemical-resistant gloves should be design, installation, use, and maintenance of
worn whenever this material is handled. exhaust systems.
Glove permeation data does exist for
this material. The following glove(s) should be Other Protective Equipment
used for splash protection only: Facilities storing and utilizing this
-Neoprene material should be equipped with an eyewash
-Butyl rubber facility and a safety shower.
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MATERIAL SAFETY DATA SHEET
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Thermo Manufacturing Systems, LLC Thermo #150 Rinseable Primer
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear
Color Light Pink
State Liquid
Odor Characteristic Mild Odor
pH 13 to 13.5
Viscosity No Data
Vapor Density (Air=1) < 1 Water
Vapor Pressure 17 mmHg @ 20'C/68'F
Water
Melting Point 0'C/32'F Water
Boiling Point 100'C/212'F Water
Solubility in Water Completely soluble
Percent Volatility 87 to 89% Water
Evaporation Rate (BAc=1) < 1 Water
The physical and chemical data given in Section 9 are typical values for this product and are not intended
to be product specifications.
See Section 5, Fire Fighting Measures
10. STABILITY AND REACTIVITY
Instability Incompatibility
This material is considered stable. Avoid contact with strong oxidizers -
strong reducing agents - strong bases - strong
Hazardous Polymerization acids - strong mineral acids - aluminum - tin -
Product will not undergo hazardous zinc
polymerization.
11. TOXICOLOGICAL INFORMATION
Acute Data Toxicity data for component number 1:
No toxicity data are available for this
material. Oral LD50-rat: 800 mg/kg
Skin irritation-rabbit: severe irritation
The information shown in SECTION 3, Hazards
Identification, is based on toxically profiles of Toxicity data for component number 2:
similar materials or on the components present
in this material. Oral LD50-rat: 707mg/kg
Inhalation LC50-rat: >21.5 mg/L
12. ECOLOGICAL INFORMATION
Environmental Toxicity
Fish, 96 Hour LC50: 120 to 220 mg/l;
Daphnia magna, 48 Hour EC50: >100mg/l
Fish, 96 Hour LC50: 7 to 9 mg/l
Algae, 96 Hour EC50: 0.2 mg/l
Footnote 1: Data is for component 1.
Footnote 2: Data is for component 2.
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MATERIAL SAFETY DATA SHEET
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Thermo Manufacturing Systems, LLC Thermo #150 Rinseable Primer
13. DISPOSAL CONSIDERATIONS
Procedure
Incinerate liquid and contaminated solids in accordance with local, state, and federal regulations.
(See 40 CFR 268)
14. TRANSPORT INFORMATION
US DOT Hazard Class NONREGULATED
15. REGULATORY INFORMATION
Workplace Classification Center (1-800-424-8802) and to the appropriate
This product is considered hazardous state and local emergency response
under the OSHA Hazard Communication organizations. D002, 100lbs.
Standard (29CFR 1910.1200).
This product is a controlled product Waste Classification
under the Canadian Workplace Hazardous When a decision is made to discard this
Materials Information System (WHMIS). material as supplied, it is classified as a RCRA
hazardous waste with the characteristic of
SARA TITLE 3: SECTION 311/312 corrosivity and toxicity, hazardous waste
Categorizations (40CFR 370) numbers: D002
This product is a hazardous chemical
under 29CFR 1910.1200, and is categorized as United States
an immediate health hazard. All components of this product are in
compliance with the Inventory listing
SARA TITLE 3: Section 313 Information (40CFR requirements of the U.S. Toxic Substances
372) Control Act (TSCA) Chemical Substance
This product does not contain a Inventory.
chemical which is listed in Section 313 at or
above de minimis concentrations. California (Proposition 65)
This product contains trace levels of a
CERCLA Information (40CFR 302.4) component or components known to the state of
This material has a reportable quantity California to cause cancer:
under the Comprehensive Environmental -1,4-Dioxane (123-91-1)
Response, Compensation, and Liability Act
(CERCLA) and the Superfund Amendments and This product contains trace levels of a
Reauthorization Act (SARA) Title III Section 304. component or components known to the state of
The material's hazardous waste number and California to cause cancer and birth defects or
reportable quantity is listed below. Releases of other reproductive harm:
this material in excess of its reportable quantity -Ethylene oxide (75-21-8)
must be reported to the National Response
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MATERIAL SAFETY DATA SHEET
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Thermo Manufacturing Systems, LLC Thermo #150 Rinseable Primer
16. OTHER INFORMATION
Thermo Manufacturing
Scale
Hazard Rating
Toxicity 3 4=EXTREME
Fire 0 3=HIGH
Reactivity 0 2=MODERATE
Special C 1=SLIGHT
0=INSIGNIFICANT
C=CORROSIVE
Ratings are based on Thermo Manufacturing guidelines, and are intended for internal use.
HMIS Hazard Ratings
HMIS Hazard Ratings: HEALTH=3, FLAMMABILITY=0, REACTIVITY=0.
PERSONAL PROTECTION: See Section 8, Exposure Controls / Personal Protection for
recommended handling of material as supplied; check with supervisor for your actual use condition.
Scale: 0=Minimal, 1=Slight, 2=Moderate, 3=Serious, 4=Severe *=Chronic Effects
(See Section 3, Hazardous Identification)
HMIS is a registered trademark of the National Paint and Coatings Association.
ABBREVIATIONS:
ACGIH American Conference of Governmental Industrial Hygienists
OSHA Occupational Safety and Health Administration
TLV Threshold Limit Value
PEL Permissible Exposure Limit
TWA Time Weighted Average
STEL Short-Term Exposure Limit
BAc Butyl acetate
| Bar denotes a revision from previous MSDS in this area.
The information contained herein relates only to the specific material identified. Thermo Manufacturing believes that such
information is accurate and reliable as of the date of this material safety date sheet, but no representation, guarantee or warranty,
expressed or implied is made as to the accuracy, reliability, or completeness of the information. Thermo Manufacturing urges
persons receiving this information to make their own determination as to the information's suitability and completeness for their
particular application.
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