For Emergency Assistance involving chemicals call CHEMTREC (800) 424-9300
ICAO/IATA European Inventory of Existing Commercial Chemical The Version Date and Number for this MSDS is: 02/18/2008 - #016
Substances (EINECS) This product is on the EINECS inventory.
NOT REGULATED
CEPA - Domestic Substances List (DSL)
Additional Information PRODUCT NAME: ETHYLENE GLYCOL
All substances contained in this product are listed on the Canadian Domestic
Reportable quantity: 5,050 lb - ETHYLENE GLYCOL
MSDS NUMBER: DZ30478
Substances List (DSL) or are not required to be listed.
This information is not intended to convey all specific regulatory or opera-
DATE ISSUED: 1/14/2008
tional requirements/information relating to this product. Additional transporta-
16. Other Information SUPERSEDES: 11/30/2005
tion system information can be obtained through an authorized sales or cus-
tomer service representative. It is the responsibility of the transporting organ- Hazard Rating System ISSUED BY: 001719
ization to follow all applicable laws, regulations and rules relating to the
NFPA Health Fire Reactivity
transportation of the material.
1 1 0
Material Safety Data Sheet
Recommended Uses and Restrictions
15. Regulatory Information 1. Product and Company Identification Birth Defects/Developmental Effects: Based on animal studies,
For industrial use. It is recommended that you use this product in a manner
ingestion of very large amounts of ethylene glycol appears to be the major
consistent with the recommended use.
OSHA Hazard Communication Standard Product Name
and possibly only route of exposure to produce birth defects. Exposures by
This product is a "Hazardous Chemical" as defined by the OSHA Hazard ETHYLENE GLYCOL inhalation or skin contact, the primary routes of occupational exposure, had
Legend minimal effect on the fetus, in animal studies.
Communication Standard, 29 CFR 1910.1200.
N/A Not available Reproductive Effects: Ingestion of large amounts of ethylene glycol has
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Distributed by: Univar USA Inc.
been shown to interfere with reproduction in animals.
Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 W/W Weight/Weight 17425 NE Union Hill Road
Immediate (Acute) Health Hazard Yes OEL Occupational Exposure Limit Redmond, WA 98052
3. Composition Information
Delayed (Chronic) Health Hazard Yes STEL Short Term Exposure Limit 425-889-3400
Fire Hazard No Component CAS # Amount
TWA Time Weighted Average
Reactive Hazard No
Ethylene glycol 107-21-1 > 99.0 %
ACGIH American Conference of Governmental Industrial Hygienists, Inc. 2. Hazards Identification
Sudden Release of Pressure Hazard No
DOW IHG Dow Industrial Hygiene Guideline
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Emergency Overview
4. First-aid measures
Planning and Community Right-to-Know Act of 1986) Section 313 This prod- WEEL Workplace Environmental Exposure Level Color: Colorless
uct contains the following substances which are subject to the reporting Eye Contact: Flush eyes thoroughly with water for several minutes.
Physical State: Liquid
HAZ DES Hazard Designation
requirements of Section 313 of Title III of the Superfund Amendments and Remove contact lenses after the initial 1-2 minutes and continue flushing for
Odor: Sweet
Action Level A value set by OSHA that is lower than the PEL which will
Reauthorization Act of 1986 and which are listed in 40 CFR 372. several additional minutes. If effects occur, consult a physician, preferably an
Hazards of product:
trigger the need for activities such as exposure monitoring and ophthalmologist.
Component CAS # Amount
medical surveillance if exceeded. WARNING! Harmful or fatal if swallowed. May cause eye irritation. Isolate
Ethylene glycol 107-21-1 > 99.0 % Skin Contact: Wash skin with plenty of water.
area.
Inhalation: Move person to fresh air. If not breathing, give artificial respira-
For Additional Information: OSHA Hazard Communication Standard
Pennsylvania (Worker and Community Right-To-Know Act): tion; if by mouth to mouth use rescuer protection (pocket mask, etc). If
Contact: MSDS Coordinator - Univar USA
Pennsylvania Hazardous Substances List and/or Pennsylvania Environmental This product is a "Hazardous Chemical" as defined by the OSHA Hazard breathing is difficult, oxygen should be administered by qualified personnel.
Hazardous Substance List: The following product components are cited in the Communication Standard, 29 CFR 1910.1200. Call a physician or transport to a medical facility.
During business hours, Pacific Time - (425) 889-3400
Pennsylvania Hazardous Substance List and/or the Pennsylvania
Potential Health Effects Ingestion: Do not induce vomiting. Seek medical attention immediately. If
Environmental Substance List, and are present at levels which require report-
person is fully conscious give 1 cup or 8 ounces (240 mL) of water. If medical
NOTICE Eye Contact: May cause slight eye irritation. Corneal injury is unlikely.
ing.
advice is delayed and if an adult has swallowed several ounces of chemical,
Vapor or mist may cause eye irritation.
Component CAS # Amount Univar USA expressly disclaims all express or implied warranties of merchan-
then give 3-4 ounces (1/3-1/2 Cup) (90-120 mL) of hard liquor such as 80
tibility and fitness for a particular purpose with respect to the product or Skin Contact: Brief contact is essentially nonirritating to skin. Prolonged
Ethylene glycol 107-21-1 > 99.0 % proof whiskey. For children, give proportionally less liquor at a dose of 0.3
information provided herein, and shall under no circumstances be liable for contact may cause slight skin irritation with local redness. Repeated contact ounce (1 1/2 tsp.) (8 ml) liquor for each 10 pounds of body weight, or 2 ml
incidental or consequential damages. may cause skin irritation with local redness.
Pennsylvania (Worker and Community Right-To-Know Act): per kg body weight (e.g., 1.2 ounce (2 1/3 tbsp.) for a 40 pound child or 36
Pennsylvania Special Hazardous Substances List: To the best of our knowl- Do not use ingredient information and/or ingredient percentages in this mL for an 18 kg child).
Skin Absorption: Prolonged skin contact is unlikely to result in absorp-
edge, this product does not contain chemicals at levels which require report- MSDS as a product specification. For product specification information refer tion of harmful amounts. Repeated skin exposure to large quantities may Notes to Physician: If several ounces (60 - 100 ml) of ethylene glycol
ing under this statute. to a Product Specification Sheet and/or a Certificate of Analysis. These can result in absorption of harmful amounts. Massive contact with damaged skin have been ingested, early administration of ethanol may counter the toxic
be obtained from your local Univar USA Sales Office. or of material sufficiently hot to burn skin may result in absorption of poten- effects (metabolic acidosis, renal damage). Consider hemodialysis or peri-
tially lethal amounts.
California Proposition 65 (Safe Drinking Water and Toxic All information appearing herein is based upon data obtained from the manu- toneal dialysis & thiamine 100 mg plus pyridoxine 50 mg intravenously every
Enforcement Act of 1986) WARNING: This product contains a facturer and/or recognized technical sources. While the information is 6 hours. If ethanol is used, a therapeutically effective blood concentration in
Inhalation: At room temperature, exposure to vapor is minimal due to low
chemical(s) known to the State of California to cause cancer. believed to be accurate, Univar USA makes no representations as to its accu- the range of 100 - 150 mg/dl may be achieved by a rapid loading dose fol-
volatility. With good ventilation, single exposure is not expected to cause
racy or sufficiency. Conditions of use are beyond Univar USA's control. lowed by a continuous intravenous infusion. Consult standard literature for
adverse effects. If material is heated or areas are poorly ventilated,
Component CAS # Amount
Therefore, users are responsible to verify this data under their own operating details of treatment. 4-Methyl pyrazole (Antizol*) is an effective blocker of
vapor/mist may accumulate and cause respiratory irritation and symptoms
Acetaldehyde 75-07-0 <= 8.0 PPM
conditions to determine whether the product is suitable for their particular alcohol dehydrogenase and should be used in the treatment of ethylene gly-
such as headache and nausea.
1,4-Dioxane 123-91-1 <= 0.25 PPM
purposes, and they assume all risks of their use, handling, and disposal of col (EG), di- or triethylene glycol (DEG, TEG), ethylene glycol butyl ether
Ingestion: Oral toxicity is expected to be moderate in humans due to eth-
the product or from the publication or use of, or reliance upon, information (EGBE), or methanol intoxication if available. Fomepizole protocol (Brent, J. et
ylene glycol even though tests with animals show a lower degree of toxicity.
US. Toxic Substances Control Act
contained herein. This information relates only to the product designated al., New England Journal of Medicine, Feb. 8, 2001, 344:6, p. 424-9): loading
Small amounts swallowed incidentally as a result of normal handling opera-
All components of this product are on the TSCA Inventory or are exempt from herein and does not relate to its use in combination with any other material dose 15 mg/kg intravenously, follow by bolus dose of 10 mg/kg every 12
tions are not likely to cause injury; however, swallowing larger amounts may
TSCA Inventory requirements under 40 CFR 720.30 or in any other process. hours; after 48 hours, increase bolus dose to 15 mg/kg every 12 hours.
cause serious injury, even death. May cause nausea and vomiting. May cause
Continue fomepizole until serum methanol, EG, DEG, TEG or EGBE are unde-
abdominal discomfort or diarrhea. Excessive exposure may cause central
tectable. The signs and symptoms of poisoning include anion gap metabolic
nervous system effects, cardiopulmonary effects (metabolic acidosis), and
acidosis, CNS depression, renal tubular injury, and possible late stage cranial
kidney failure.
nerve involvement. Respiratory symptoms, including pulmonary edema, may
For additional copies of this MSDS, request Part No. 1-40-0035:
Effects of Repeated Exposure: Repeated excessive exposure may be delayed. Persons receiving significant exposure should be observed 24-48
Rexarc International, Inc. cause irritation of the upper respiratory tract. In humans, effects have been hours for signs of respiratory distress. Maintain adequate ventilation and oxy-
35 East Third Street l P.O. Box 7 l West Alexandria, Ohio 45381 USA reported on the following organs: Central nervous system. Observations in genation of the patient. In severe poisoning, respiratory support with
humans include: Nystagmus (involuntary eye movement). In animals, effects
Tel: 877.Rexarc.1 l Fax: 877.Rexarc.3 l www.Rexarc.com mechanical ventilation and positive end expiratory pressure may be required.
have been reported on the following organs: Kidney. Liver. If lavage is performed, suggest endotracheal and/or esophageal control.
Page 4 Page 1
Danger from lung aspiration must be weighed against toxicity when consid- 8. Exposure Controls / Personal Protection 10. Stability and Reactivity Persistence and Degradability
ering emptying the stomach. If burn is present, treat as any thermal burn, Material is readily biodegradable. Passes OECD test(s) for ready biodegrad-
Exposure Limits Stability/Instability
after decontamination. Treatment of exposure should be directed at the con- ability. Material is ultimately biodegradable (reaches > 70% mineralization in
Component List Type Value Stable under recommended storage conditions. See Storage, Section 7.
trol of symptoms and the clinical condition of the patient. OECD test(s) for inherent biodegradability). Indirect Photodegradation with OH
. Conditions to Avoid: Exposure to elevated temperatures can cause
Ethylene glycol ACGIH Ceiling 100 mg/m3 Radicals
5. Fire Fighting Measures product to decompose. Generation of gas during decomposition can cause
Aerosol. Rate Constant Atmospheric Half-life Method
pressure in closed systems.
Extinguishing Media: Water fog or fine spray. Dry chemical fire Personal Protection 8.32E-12 cm3/s 15 h Estimated
Incompatible Materials: Avoid contact with: Strong acids. Strong bases.
extinguishers. Carbon dioxide fire extinguishers. Foam. Do not use direct
Eye/Face Protection: Use safety glasses. If exposure causes eye dis- OECD Biodegradation Tests:
Strong oxidizers.
water stream. May spread fire. Alcohol resistant foams (ATC type) are pre-
comfort, use a full-face respirator. Biodegradation Exposure Time Method
ferred. General purpose synthetic foams (including AFFF) or protein foams Hazardous Polymerization
> 94 % 28 d OECD 301F Test
Skin Protection: Use protective clothing chemically resistant to this
may function, but will be less effective.
Will not occur.
material. Selection of specific items such as face shield, boots, apron, or full Theoretical Oxygen Demand: 1.29 mg/mg
Fire Fighting Procedures: Keep people away. Isolate fire and deny
body suit will depend on the task. Remove contaminated clothing immediate- Thermal Decomposition
unnecessary entry. Use water spray to cool fire exposed containers and fire ECOTOXICITY
ly, wash skin area with soap and water, and launder clothing before reuse or
Decomposition products depend upon temperature, air supply and the pres-
affected zone until fire is out and danger of reignition has passed. Fight fire
dispose of properly. When handling hot material, protect skin from thermal Material is practically non-toxic to aquatic organisms on an acute basis
ence of other materials. Decomposition products can include and are not lim-
from protected location or safe distance. Consider the use of unmanned hose
burns as well as from skin absorption.
(LC50/EC50 >100 mg/L in the most sensitive species tested).
ited to: Aldehydes. Ketones. Organic acids.
holders or monitor nozzles. Immediately withdraw all personnel from the area
Hand protection: If hands are cut or scratched, use gloves chemically
in case of rising sound from venting safety device or discoloration of the con- Fish Acute & Prolonged Toxicity
resistant to this material even for brief exposures. Use gloves with insulation
tainer. Burning liquids may be extinguished by dilution with water. Do not use
LC50, rainbow trout (Oncorhynchus mykiss), static, 96 h: 18,000 - 46,000
11. Toxicological Information
for thermal protection, when needed. Examples of preferred glove barrier
direct water stream. May spread fire. Move container from fire area if this is
mg/L
materials include: Butyl rubber. Natural rubber ("latex"). Neoprene.
possible without hazard. Burning liquids may be moved by flushing with Acute Toxicity
Nitrile/butadiene rubber ("nitrile" or "NBR"). Polyethylene. Ethyl vinyl alcohol Aquatic Invertebrate Acute Toxicity
water to protect personnel and minimize property damage.
Ingestion
laminate ("EVAL"). Polyvinyl alcohol ("PVA"). Polyvinyl chloride ("PVC" or
LC50, water flea Daphnia magna, static, 48 h: 46,300 - 51,100 mg/L
Special Protective Equipment for Firefighters: Wear positive-
"vinyl"). NOTICE: The selection of a specific glove for a particular application For ethylene glycol: Lethal Dose, Human, adult 3 Ounces
pressure self-contained breathing apparatus (SCBA) and protective fire fight- Aquatic Plant Toxicity
and duration of use in a workplace should also take into account all relevant LD50, Rat 6,000 - 13,000 mg/kg
ing clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If
workplace factors such as, but not limited to: Other chemicals which may be EC50, green alga Selenastrum capricornutum, biomass growth inhibition, 96
Skin Absorption
protective equipment is not available or not used, fight fire from a protected
handled, physical requirements (cut/puncture protection, dexterity, thermal h: 9,500 - 13,000 mg/L
location or safe distance LD50, Rabbit > 22,270 mg/kg
protection), potential body reactions to glove materials, as well as the
Toxicity to Micro-organisms
Unusual Fire and Explosion Hazards: Container may rupture from instructions/specifications provided by the glove supplier. Inhalation
EC50, OECD 209 Test; activated sludge, respiration inhibition, 30 min: 225
gas generation in a fire situation. Violent steam generation or eruption may
Respiratory Protection: Atmospheric levels should be maintained LC50, 7 h, Aerosol, Rat > 3.95 mg/L mg/L
occur upon application of direct water stream to hot liquids.
below the exposure guideline. When respiratory protection is required for cer-
Repeated Dose Toxicity
Hazardous Combustion Products: During a fire, smoke may contain tain operations, use an approved air-purifying respirator. The following should
13. Disposal Considerations
Repeated excessive exposure may cause irritation of the upper respiratory
the original material in addition to combustion products of varying composi- be effective types of air-purifying respirators: Organic vapor cartridge with a
tract. In humans, effects have been reported on the following organs: Central
tion which may be toxic and/or irritating. Combustion products may include particulate pre-filter. DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF
nervous system. Observations in humans include: Nystagmus (involuntary
and are not limited to: Carbon monoxide. Carbon dioxide. WATER. All disposal practices must be in compliance with all Federal,
Ingestion: Use good personal hygiene. Do not consume or store food in
eye movement). In animals, effects have been reported on the following State/Provincial and local laws and regulations. Regulations may vary in dif-
the work area. Wash hands before smoking or eating.
organs: Kidney. Liver.
6. Accidental Release Measures ferent locations. Waste characterizations and compliance with applicable
Engineering Controls
laws are the responsibility solely of the waste generator. WE HAVE NO CON-
Chronic Toxicity and Carcinogenicity
Steps to be Taken if Material is Released or Spilled: Contain
Ventilation: Provide general and/or local exhaust ventilation to control air- TROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESS-
spilled material if possible. Collect in suitable and properly labeled contain- Ethylene glycol did not cause cancer in long-term animal studies.
borne levels below the exposure guidelines. ES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION
ers. Small spills: Absorb with materials such as: Cat litter. Sand. Sawdust. Developmental Toxicity PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS
Vermiculite. Zorb-all*. Hazorb*. Large spills: Dike area to contain spill. Pump
INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition
Based on animal studies, ingestion of very large amounts of ethylene glycol
into suitable and properly labeled containers. See Section 13, Disposal
9. Physical and Chemical Properties Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred
appears to be the major and possibly only route of exposure to produce birth
Considerations, for additional information.
options include sending to a licensed, permitted: Recycler. Reclaimer.
defects. Exposures by inhalation or skin contact, the primary routes of occu-
Physical State Liquid
Ignition Sources Removal: Keep away from sources of ignition. Incinerator or other thermal destruction device. As a service to our cus-
pational exposure, had minimal effect on the fetus, in animal studies.
Color Colorless tomers, we can provide names of information resources to help identify
Dust Control: Not applicable. Reproductive Toxicity
waste management companies and other facilities which recycle, reprocess
Odor Sweet
Personal Precautions: Isolate area. Keep unnecessary and unprotected Ingestion of large amounts of ethylene glycol has been shown to interfere or manage chemicals or plastics, and that manage used drums. Please con-
personnel from entering the area. Use appropriate safety equipment. For Flash Point - Closed Cup 116 deg C (241 deg F) ASTM D56 with reproduction in animals. tact our Customer Information Group (telephone number in Section 1 of this
additional information, refer to Section 8, Exposure Controls and Personal
document) for further details.
Flammable Limits In Air Lower: 3.2 % (V) Literature Genetic Toxicology
Protection. Refer to Section 7, Handling, for additional precautionary meas-
ures. In vitro genetic toxicity studies were negative. Animal genetic toxicity studies
Upper: 15.2 % (V) Literature
14. Transport Information
were negative.
Environmental Precautions: Prevent from entering into soil, ditches, Autoignition Temperature 427 deg C (801 deg F) Literature
DOT Non-Bulk
sewers, waterways and/or groundwater. See Section 12, Ecological
Vapor Pressure 0.06 mmHg @ 20 C Literature NOT REGULATED
Information.
12. Ecological Information
Boiling Point (760 mmHg) > 197 deg C (> 387 F) Literature DOT Bulk
CHEMICAL FATE
7. Handling and Storage Proper Shipping Name: OTHER REGULATED SUBSTANCES, LIQUID, NOS
Vapor Density (air = 1) 2.1 Literature
Movement & Partitioning
Technical Name: CONTAINS ETHYLENE GLYCOL
Handling Specific Gravity (H20 = 1) 1.115 20 deg C/20 C Literature
Bioconcentration potential is low (BCF < 100 or log Pow < 3). Potential for
Hazard Class: 9 ID Number: NA3082 Packing Group: PG III
General Handling: Do not swallow. Avoid contact with eyes. Wash thor-
Freezing Point -13 C (9 F) Literature mobility in soil is very high (Koc between 0 and 50). Given its very low
oughly after handling. Spills of these organic materials on hot fibrous insula- IMDG
Henry's constant, volatilization from natural bodies of water or moist soil is
Melting Point Not applicable
tions may lead to lowering of the autoignition temperatures possibly resulting
Proper Shipping Name: OTHER REGULATED SUBSTANCES, LIQUID, NOS
not expected to be an important fate process.
in spontaneous combustion. See Section 8, EXPOSURE CONTROLS AND PER- Solubility in Water (by weight) 100 % Literature Technical Name: CONTAINS ETHYLENE GLYCOL
Henrys Law Constant (H): 8.05E-09 atm*m3/mole; 25 C Estimated Partition
SONAL PROTECTION.
pH 9 Literature coefficient, n-octanol/water (log Pow): -1.36 Measured Partition coefficient, Hazard Class: 9 ID Number: NA3082 Packing Group: PG III
Storage
soil organic carbon/water (Koc): 1 Estimated Distribution in Environment: Marine pollutant.: No
Molecular Weight 62 g/mol Literature
Do not store near food, foodstuffs, drugs or potable water supplies. Additional Mackay Level 1 Fugacity Model:
THIS SHIPMENT IS MARKED, LABELED AND/OR PLACARDED AND DESCRIBED
Octanol/Water Partition -1.36 Measured Coefficient
storage and handling information on this product may be obtained by calling
Air Water. Biota Soil Sediment IN ACCORDANCE WITH US DOT REGULATIONS AND IS NOT REGULATED BY
your sales or customer service contact. Ask for a product brochure.
Evaporation Rate (Butyl Acetate = 1) 0.01 Literature 2.1% 98 % <0.01% <0.01% <0.01% IMDG.
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