U.S. DEPARTMENT OF LABOR

              OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION

                      MATERIAL SAFETY DATA SHEET





IDENTITY: FPPF GLYCLEAN RECYCLED ANTIFREEZE COOLANT SOLUTION



NOTE: THIS IS A VALID IF THE RECYCLED PRODUCT HAS A p H of 9.5 ?10.5 by the addition of Glyclean and has a

freeze point of ?40F.





                   SECTION 1 ?IDENTIFICATION DATA

Product Name: Ethylene Glycol Antifreeze Grade 50% Solution V/V

Chemical Name: Ethylene Glycol-Glyclean Recycled Premixed Ethylene

Glycol

Chemical Family: Glycols

Formula: C2H6O2/H2O (Mixture)

Synonyms: EG; Glycol; 1,2 ?Ethanediol

CAS #: 107-21-1             1310-73-2

CAS Name: 1,2 Ethanediol Sodium Hydroxide



        SECTION 2 ?PHYSICAL DATA (Determined on typical material)

Boiling Point: 760 mmHg:                             200.5 0F +/- 100F

Freezing Point:                                            -340F

Specific Gravity (H2O = 1):                        8.82 +/- 0.5 20/200C

Vapor Pressure @ 200C                                  0.06 mm Hg

Vapor Density (Air = 1)                                 1.78 +/- 0.2

Solubility in Water by WT:                                  100

Evaporation Rate (Butyl Acetate = 1):                       0.01

Appearance & Odor: Green-Blue color, mild

odor





                                  SECTION 3 ?INGREDIENTS

                                 CAS #         OSHA PEL ACGIH                          STEL        %

                                                         TLV

Ethylene Glycol                  107-21-1      125 ppm 125 ppm                                 50-60

Sodium Hydroxide                 1310-73-2     120 ppm 120 ppm                                 1.4-5.4

Diethylene Glycol                111-46-6       None     tablished                               0-8

                                               Es-





                 SECTION 4 ?FIRE & EXPLOSION HAZARD DATA

Flash Point: (Test Methods): Not Applicable

Flammable Limits in Air: (% by volume): Not established

Extinguishing Media: Apply alcohol-type or all-purpose type foams by

manufacturers

Recommended techniques for large fires. Use CO2 dry chemical media

for small fires

Special fire fighting procedure: Do not spray pool fires directly; a solid

stream of

water or foam directed into hot burning liquid can cause frothing. Use

self-contained

breathing apparatus and protective clothing.



                   GLYCLEAN RECYCLED ANTIFREEZE 1 - 6

                     SECTION 5 ?HEALTH HAZARD DATA



TLV & SOURCE:       SEE SECTION 3



EFFECT OF SINGLE OVEREXPOSURE:



Swallowing: May cause abdominal discomfort or pain, nausea, vomiting,

dizziness, malaise, blurring of vision, irritability, lumbar pain, oliguria, urenia

and central nervous system effects, including irregular eye movements,

convulsions and coma. Cardiac failure and pulmonary eczema may

develop. Severe kidney damage follows the swallowing of large volumes

of ethylene glycol may be fatal. A few reports have been published

describing the development of weakness of the facial muscles, diminished

hearing and difficulty with swallowing, during the late stages of severe

poisoning.



Skin Absorption: No evidence of adverse effects from available

information.

Skin Contact: No evidence of adverse effects from available information.



Inhalation: May cause irritation of the nose and throat with headache,

particularly from mists. High vapor concentrations caused, for example,

by heating the material in an enclosed and poorly ventilated work place,

may produce nausea, vomiting, headache, dizziness and irregular eye

movements.



Eye Contact: Liquid, vapor and mist may cause discomfort in the eye with

persistent conjunctivitis, seen as sight excess redness of conjunctiva.

Serious corneal injury is not anticipated.



Effects of Repeated Overexposure: Inhalation of mist may produce signs of

central nervous system involvement, particularly dizziness and nystagmus.

Medical Conditions Aggravated by Overexposure: The available

toxicology information and knowledge of the physical and chemical

properties of the material suggest that overexposure is unlikely to

aggravate existing medical conditions.



Significant Laboratory Data with Possible Relevance to Human Health

Hazard Evaluation:



Ethylene Glycol has been shown to produce dose-related teratogenic

effects in rats and mice when given by lavage or in drinking water at high

concentrations or doses.

The no-effect dose for developmental toxicity in the mouse receiving

ethylene glycol by lavage has been determined to be 150 mg/kg/day

over the period of organogenesis. Also, in a preliminary study to assess the

effects of exposure of pregnant rats and mice to aerosols at

concentrations 150, 1000, and 2500 mg/m3 for six (6) hours a day

throughout the period of organogenesis, teratogenic effects were

produced at the highest concentration, but only in mice.



                  GLYCLEAN RECYCLED ANTIFREEZE 2 ?6

The conditions of these latter experiments did not allow a conclusion as to

whether inhalation of aerosol, percutaneous absorption of ethylene glycol

from contaminated skin or swallowing of ethylene glycol as a result of

grooming the wetted coat mediated the developmental toxicity. In a

further study, comparing effects from high aerosol concentration by

whole body or nose only exposure, it was shown that nose-only exposure

resulted in maternal toxicity (1000 and 2500 mg/m3). The no-effects

concentration (based on maternal toxicity) was 500 mg/m3. Ethylene

glycol was applied to the skin of pregnant mice over the period of

organogenesis. The above observations suggest that ethylene glycol is to

be regarded as an animal teratogen; there is currently no available

information to suggest that ethylene glycol has caused birth defects in

humans. Coetaneous application of ethylene glycol is ineffective in

producing developmental toxicity; exposure to high aerosol

concentration is only minimally effective in producing developmental

toxicity; the major route for producing developmental toxicity is perorally.

Two chronic feeding studies, using rats and mice, have not produced any

evidence that ethylene glycol causes dose-related increases in tumor

incidence, or a different pattern of tumors compared to untreated

controls. The absence of a carcinogenic potential for ethylene glycol has

been supported by numerous in vitro genotoxicity studies showing that it

does not produce mutagenic or clastogenic effects.

Other Effects of Overexposure:



Repeated skin contact may, in a very small proportion of cases, cause

sensitization with the development of allergic contact dermatitis. The

incidence is significantly less than 1% with the undiluted material.



Emergency & First Aid Procedures:



Swallowing: If conscious, give two (2) glasses of water and induce

vomiting. Call a physician immediately.

Skin: Remove contaminated clothing and flush skin with water.

Inhalation: Remove to fresh air. Call a physician if discomfort persists.

Eyes: Immediately flush with water and continue washing the eyes for

several minutes.



Notes to Physician: The principal toxic effects of ethylene glycol, when

swallowed, are kidney damage and metabolic acidosis. Ethanol is

antidotal and its early administration may block the formation of

nephrotoxic met abolites of ethylene glycol in the liver. Ethanol should be

given intravenously, as a 5% solution sodium bicarbonate at a rate of

about 10ml ethanol per hour. A desired therapeutic level of ethanol in

blood is 100 mg/dl. Hermodialysis may be required. 4-Methylpyrazole, a

potent inhibitor of alcohol dehydrogenase, has been used therapeutically

to decrease the metabolic consequences of ethylene glycol poisoning

before coma, seizure, and renal failure have occurred (20 mg/kg/day).





                  GLYCLEAN RECYCLED ANTIFREEZE 3 - 6

Pulmonary edema with hypoxemia has been described in a number of

patients following poisoning with ethylene glycol. The mechanism of

production has not been elucidated, but it appears to be

noncardiogenic in origin in several cases. Respirat ory support with

mechanical ventilation and positive end-expiratory pressure may be

required.



There may be cranial nerve involvement in the late stages of toxicity from

swallowed ethylene glycol. In particular, effects have been reported

involving the seventh, eighth and ninth cranial nerves, presenting with

bilaterial facial paralysis, diminished hearing and dysphagia.





                       SECTION 6 ?REACTIVITY DATA

Stability: Stable

Conditions to Avoid: None

Incompatibility (Materials to Avoid): Explosive decomposition may occur

if combined

with strong acids or strong bases and subjected to elevated

temperatures.

Therefore, avoid strong acids and strong bases at elevated temperatures.

Avoid

Contamination with strong oxidizing agents and materials reactive wit h

hydroxyl

Compounds.

Hazardous combustion or Decomposition products: Burning can produce

carbon

Monoxide and or carbon dioxide.

Hazardous Polymerization: Will not occur

Conditions to Avoid: None





                    SECTION 7 ?SPILL OR LEAK PROCEDURES

Steps to be Taken if Material is Released or Spilled:

Wear suitable protective equipment. Small spills should be flushed with

large

Quantities of water. Larger spills should be collected for disposal.

Waste Disposal Method: Incinerate in a furnace where permitted under

appropriate

Federal, State or Local regulations. At a very low concentration in water,

Ethylene

Glycol is readily biodegradable in a biological waste water treatment

plant.





                    SECTION 8 ?SPECIAL PRECAUTIONS

Precautions to be Taken in Handling & Storage:

               DANGER: HARMFUL OR FATAL IF SWALLOWED:









                GLYCLEAN RECYCLED ANTIFREEZE 4 - 6

               SECTION 8 ?SPECIAL PRECAUTIONS CON'T.

?Prolonged or repeated breathing of mist or vapor harmful.

  Causes eye irritation.

?br>
  May cause kidney and nervous system damage.

?br>
  Causes birth defects in laboratory animals.

?br>
  Do not swallow.

?br>
  Do not breathe mist from spray.

?br>
  Avoid prolonged or repeated breathing of vapor.

?br>
  Avoid contact with eyes.

?br>
  Keep container closed.

?br>
  Use with adequate ventilation.

?br>
  Wash thoroughly after handling.

?br>
                          For Industrial Use Only.

Other precautions: None known.





                  SECTION 9 ?REGULATORY INFORMATION



Status on Substance Lists: The concentrations shown are maximum or

ceiling levels (weight - %) to be used for calculations for regulations. Trade

Secrets are indicated by "TS".



Federal EPA: Comprehensive Environmental Response, compensation,

and Liability Act of 1980 (CERCLA) requires notification of the Natl.

Response Center of release of quantities of Hazardous Substances equal

to or greater than the reportable quantities (RQ's) in 40 CFR 302.4.

Components present in this product at a level which could require

reporting under the statute are: Chemical: Dioxane; CAS # 123-91-1;

Upper Bound Concentration (%): .0004.



Superfunds Amendments & Reauthorization A ct of 1986 (SARA/Title III):

Requires emergency planning based on Threshold Planning Quantities

(TPQ's) and release reporting based on Reportable Quantities (RQ's) in 40

CFR 355 (Used for SARA 302, 304,311 and 31200) Components present in

this product at t his level which could require reporting under the statute

are: **NONE**.



Superfund Amendments & Reauthorization Act of 1986 (SARA Title III):



Requires submission of annual reports of release of toxic chemicals that

appear in 40 CFR 372 (for SARA 313). T his information must be included in

all MSDS's that are copied and distributed for this material. Components

present in this product are:

              Chemical:                               CAS #:

Ethylene Glycol                        107-21-1

Sodium                             1310-733-2

Upper Bound Concentration % 70.0=5.4



                 GLYCLEAN RECYCLED ANTIFREEZE 5 ?6



State "Right to Know":                      California Proposition 65:



This product contains trace levels of Dioxane that the State of California

has found to cause cancer, birth defects or other reproductive harm.



State "Right to Know":                      Massachusetts:



Right to Know. Substance List (MSL) Hazardous Substances and

Extraordinarily Hazardous Substances on the MSL must be identified when

present in products. Components present in this product at a level that

could require reporting under the statute are:



      Chemical                 CAS #          Upper Bound Concentration

                                              (%)

Dioxane                123-91-1                         .0004

Methanol               67-56-1                          .0024

Ethylene Glycol        107-21-1                          92.0

Sodium Hydroxide       1310-73-2                          5.4

Hazardous Substances (=>1%)



State "Right to Know":                            Pennsylvania:



Right to Know. Hazardous Substance List Hazardous Substances and

Special Hazardous Substances on the MSL must be identified when

present in products.



Components present in this product at a level that could require reporting

under the statute are:



      Chemical                 CAS #          Upper Bound Concentration

                                              (%)

Ethylene Glycol          107-21-1                       92.00

Diethylene Glycol        111-46-6                        8.00

Sodium Hydroxide         1310-73-2                       5.4



Toxic Substances Control Act (TSCA) Status:



      The ingredients of this product are on the TSCA Inventory.

California SSCAQMD Rule 443.1 VOC's: Not presently available.









FPPF CHEMICAL COMPANY, INC.

                                   Effective date: 9/22/2001

117 West Tupper Street

                                    Revision date: 4/1/ 2008

Buffalo, NY 14201-2193



                 GLYCLEAN RECYCLED ANTIFREEZE 6-6