PAGE 02
989-665-2202 CHICAGO MFG & DIST
15:12
0'311'312002
MSDS012
REVISION: 0
PRODUCT IDENTITY EXTREME PRESSURE LUBE #3
(AS ON LABEL): (CAS #647-42-650)
SECTIONI
Manufacturer's Name: Chicago Manutacturlng and Distribution Co., Inc.
Address: 6592 Lincoln Street
GIgttown, MI 48735
Emergency
Response
Number: gaa-885-2631
TelephoneNumber lor Information: 800-537.2956
March 2002
Data Prepared
SECTION" -Hazardous Ingredients/Identity
Information
NIOSH
Hazardous OSHA ACGIH
Component PEL REL %
OTHER
STEL
STEL TLV
PetroleumHydrocarbon:
Pennzoi!,
023-'68 oil 10mg/w 10 mg/m) 59.0
5 mg/mJ 5mg/nr
5rng/~
(CASN.Mix1ure) (mist) (mist)
(mist) (mist)
(mist)
Petroleum
Wax;
WitcoChemical
Mulli.Wax
445 2 mg/m3 14.3
2 mt;'m'
2mg/~
(CAS#63231.60.7 (fume)
(fume)
Rosin Ester; Hercules.Inc.
Slaybelite Ester ., o
(CAS# 65997.13.9) '5 mg/~ , O mglmJ 5.0
Pyrolysis:
(5 mg/ffi'1 0.1 mg/m'
(3 mg/m3
respirable respIrable as
fraction) fraction) formaldehyde
(Note 1,2)
Poiyoxyethylenedinonyl-
phenylerherphosphate;
Poly (Oxy.1.2.ethanediyl)
aIphadinonylphenyl-omega
-hydroxy.phosphate.
RHODAFACRM41OILM400,
GAFACANTAAA,Rhone.
PoulencGAFAC AMl400
(CASt 39464-84-7) Unknown Unknown Unknown Unknown Unknown (Note
3,4,5)
FragranceCompound;
Neutroline14809 Unknown Unknown Unknown Unknown Unknown
(CAS'.Mixture)
Note 1: In its pute state the dust of the materialshould be treated as a nuisanceparticulatewith a TLV (ACGIH)of 10 mg/m>,
Note 2: Acute oral LD5 0 (Rat) and LDSO (GuineaPig) >20 g/kg.
Lube N3/1
~
989-665-2202
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PAGE
Note 3: Screening studies of related compounds indIcate a rather low order of acute oral toxicity and of skin and eye irritation. The follow-
ing acute oral LDS O values have been reported;
Antara LE700 7.8 glKg
Antara LM600 12.8 g/Kg
Note4: Sub-chronic ratldog
oral studies GAF.RM indicated various
with MIX t"at levels IT'Iixture
of administered thedietinduced
into no
significant
toxicological pathologicaJ
or changes.Nootheracute chronic
or datahavebeenfound.
Note 5: Small quantitiesof severalhazardousmaterialare presentin RHOOAFAC 410/LM400:
AM
NIOSH ACGIH
OSHA
Hazardous
%
PEL STEl OTHER
STEL TLV
REL
Component
1 ppm <0.01 Class A-2
Ethylene Oxide 0.002
5ppm 1 ppm
Confirmed
CAS# 75-21-8 Carcinogen
Ceiling
Human (10 min.)
Carcinogen
(0.5ppmaction
level;STELSppm)
100 ppm 25 ppm
1 ppm 0.03
, , 4-Dioxane Class A3
CAS# 123-91-1 (per 30 min)
Phosphoric Acid
1 mg/m3
CA~ 7664.38.2 3 mg/ma
3 mg/m~ Subject
to
1 mg/m' 1
mg/mJ
Sara313
Reporting
Polyoxyethylene
Dinonylether
PhosphateCAS# N/A Unknown Sara313
Unknown Unknown Unknown Unknown
ListedToxic
SECTIONII .Hazardous Ingredients/Identity
Information(Continued)
HazardousMaterialsIdentificationSystem(HMIS)
Health Flammabili1y Personal Protection
Reactivity
2 1 O C
National Fire Protection Association Standard System for the Identification of the Fire Hazards of Materials
Health Flammability Reactivity Basis
2 1 O NFPA 704
Exposure for TotalProduct
Umit
5 mg/m3 oil mistin air
for OSHARegulation
29CFR1910.1000
5 mg/m3 for Oil Mist
TLV AmericanConferenceof Governmental
10mg/m3STELfor OilMist IndustrialHygienists(ACGIH)
SECTION III. Physica1JChemical Properties
Boiling Point, oF 246 O 1 mm.Hg. (Initial BoilingPoint)
0.3 O 200" ~
Vapor Pressure, mm.Hg.
Greaterthan 20
Vapor Density (Air =1.00)
Solubility in water: Nil (The product,while essentiallyinsolublein water,forms a stable emulsionof 1.15%
oil in water when mixedwith a ten-fold excessof water).
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09/19/2002 15:12 '38'3-665-2202 CHICAGO MFG & DIST 04
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Appearance and Odor: App$al'ance: Grease-Iike semi-$Olid which is darker than 8.0 on the ASTM D1500 scale.
Odor: Slight, pleasant odor.
Specific Gravity {HzO=1.00) 0.9510 t 60/60?F
Melting Point (Pour Point), oF 130
EvaporationRate
(Butyl = Acetate = 1.00) Essentially
non-volatile roomtemperature.
at
Viscosity at 1W C. cs 38.8
voc (EPA24),
weight
fraction 0.057
SECTIONIV. Fireand Explosion
HazardData
Flash Point (COC), 'F 445
700
Autoignition Temperature, of
FlammableLimits. % (vlv)
LEL Approximately (exactvaluenotavailable)
0.9
UEL Approximately (exactvaluenotavailable)
7.0
Extinguishing Methods:
Foamwaterspray(fog),dry chemical. carbondioxide vaporizing
and liquid(Halon) typeextinguishing
agentsmayall be suitable
for
extinguishing involving productdepending size,potential of fire andcircumstances
fires this on size relative thesituation,
to consult
localfire fighting authorities appropriate protection fire response
for fire and strategy.
SpecialFireFighting
Procedures
Usewatersprayto coolftre exposed surfaces, containers storage
and tanksandto protect personnel.Water, except the formof a
in
tinesprayor fog,maybe ineffectiVe fire fighting shouldnot be usedexcept coolcontainers, storage
for and to and tanksexposedto
heator flame. Improperapplication liquidwaterto burning
of liquidcan causeboilover.If a leakor spill hasnot ignited, water
use
sprayto disperse vaporsandto provide
the protection personnel
lor attempting stopthe leak. Waterspraymaybe usedto flush
to
spillsawayfromexposures. Densesmokemaybe generated whenbuming. Respirato'Y protectionmaybe required firefighting
for
personnel. contained
Self breathing apparatus be required enclosed
may in areasor whenlargequantities liquidareburning.
of
Minimize breathinggases.
vapor,fumesor decompos~ion products.
Unusual andExplosion
Fire Hazards
Hazardous products combustion the product
of of includedensesmokeandfumes, carbonmonoxide,
carbondioXide,aldehydes,
nitrogenoxides,phosphine
and/orotherdecomposItion
products organic
of phosphorus
compounds. prodl.::t
The l'eactsvigorously
withstrongoxidizing
agent$.
EmptyContainer
Waming
Empty containers contain residue (liquid and vapor) which C3n be dangerous. Do not pressurize, "cut, weld, braze, solder, drill, grind
or expose such containers to heat, flame, sparks or other sources of ignition, They may explod$ and cause injury or death. Do not
Lube #3/3
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at1empt to clean since complete removal of residue is difficult. "empty" drums snould be completely drained, properly bunged and
promptly returned to a drum reconditioner. All such containers should be disposed of in an environmentally safe manner and in accor-
dance with all relevant governmental regulations. For work on tanks refer to OSHA regulations. ANSI Z49.1 I and other governmental
and industrial references pertaining to cleaning, repairing, welding and/or other contemplated operations.
SECTION v. Reactivity
Data
Stability .Stable; does not feact violently with water
Incompatibility (Materials to avoid) .Strong oxidizing ~gents such as oxygen ~t elev~ted pressure, liquid oxygen, riquid chlorine,
sodium hypochlorite and calcium hypochlorite.
Hazardous Decomposition by-products
or .The product reactwitho:
will agents,especially
whenheated.Thermal
and
oxidative
decomposition
prOducts
produced whencompound heatedil' air include
is oxides phosphorus,
of carbon nitrogen,
and
aldehydes,phosphine othertoxicoxides fumes.
and and
Hazardous Polymerization. will not occur.
SECTION VI- Health Hazard Data
Routes Entry
of
Inhalation mist,sprayor vapor.
of
SkinContact.
EyeContact.
Ingestion.
Injection highpressure
by greasegun,
Variability
Healthstudieshaveshownthat manypetroleumhydrocarbons synthetic
and lubricant
blendsposepotential humanhealth risks
whichmaydifferfromoneindividual another.Forthis reason,
to exposure suchmaterials the formof liquids,vapors,
to in m~ls or
fumesshouldbe minimized.
Nature Hazard Toxicity
of and Information
In accordance the currentOSHAHazard
with Communication Standard product
I',is doesnot require cancer
a warning because the
basestockfromwhichit hasbeenformulated nota mildlyhydrotreated
is Baphthenic IARChasconcluded highlyrefined
oil. that min-
eraloils aregroup3 substances, classifiable to theircarcinogenicity humans,"
.not as to basedon inadequate human inadequate
and
animalevidence.
Prolonged repeated contacttend$to remove oilsandcan leacj irritation dermatitis.Thisproduct however,
or skin skin to or is, not
judgedto be corrOSive material an irritantby OSHA
or criteria.
Contact witheyescauseseye irritation.
Theproduct a loworderof acuteanddermal
has toxicity.Aspiration mistor vaporintolungsmay,however.
of cause severeput-
monary injuryor evendeath.No datafor acuteoralLDso (rat)or acutedem,alLDs (rabbit) available the product.
o are for
SignsandSymptoms Exposure
of
EyeContact Maycauseburning,
irritation mildconjunctivl~is days).
and (1-3
Skin Contact May result in irritation of dermatitis on prolonged 0{ repeated exposure. Injection beneath skin or any other
part of the body by high pressure grease gun can cause serious delayed soft tissue damage and should
be treated immediately as a surgical emergency.
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Inhalation In a mist tom may cause local irritation, dizzim~ss,
drowsiness,pneumonia.
Maycauselocafirritation the mucous
of membiranes the mouth,
of esophagus stomach.Mayactas a
and
Ingestion
laxative.
Unknown
(noneof thecomponents the prodlJct known be human
of are to carcinogens).
Carcenogenjcity
Medical
Cond~ions
Generally
Aggravated Exposure
by
Skinirritation dermatitis
or maybe aggravated
especially individuals mayhavedeveloped highdegree hypersensitivity
in ~Iho a of as
a resultof prolonged repeated
or exposure.
Emergency FirstAid Procedures:
and
Eye Contact: If product gets in eyes, flush eyes with clear water for at least 15 minutes or longer until irritation subsides.
Call a physician immediately.
In caseof skincontact,
remove contaminatelj
all clothing.Washskinwithsoapandwater.Contaminated
Skin Contact:
clothingmustbe washed beforebeingrewom.
Inhalation: In caseof inhalation vapors,sprayor mist,remove
of exposed personto freshair immediately. breathing
If
hasstopped, startresuscitation
procedures
including
artif~ialrespiration administration oxygen
and of as
necessary. a phys~janimmediately.
Call
In case of ingestion. (ie, if material has been swallowed), do not induce vomiting. Call a physician
Ingestion:
immediately.
If injectedbeneath skin.regardless thearnount
the of injected the appearance the areaof injection.
or of
Injection;
contacta physicianimmediately.
DelaymaycalJse of the affected of the body.
loss part
SECTION VII .Precautions for Safe Handling and Use
Steps to be taken in case product is released or spilled.
Collectlargespillswithshovel,drysandor oil absorbentmaterials.Cleanspillareawithaqueousdetergent solutions.Provide ade-
quateventilation
duringclean-up prevent
to exceeding recommended
the exposure for oil, mistor fumeor build-up explosive
limit of
concentrations vaporin air. Keepproduct of sewersandwatercoursElSdikingor impounding.
of out by Adviseauthorities product
if
hasentered mayhaveentered
or sewers,
watercourses extensive areas. Minimize contact.Assure
or land skin conformity with
applicable
governmental regulations.
WasteDiSposal
Method
Wastematerial
shouldbe disposed by incineration a suitable
of in combu6tion
systemcapable handling
of grease-Iike
products,
Usedproduct
maybe suitablefor reclamation re-refining notcontaminated.
or if
Disposal
mustcomplywithall applicable
governmental regulations.
Precautions to be taken in handling and storing
Store in sealed containers away from heat. open flame and oxidizing matElrials. Appropriate fire extinguishing agents must be kept
readily available and personnel must be trained in their proper use. Dry san~ or oil absorbent material should be kept readily available
and personnel must be trained in their proper use in case of spillage.
See NFPA 30 and OSHA 1910.106 -Flammable and Combustible Uquids.
Lube *3/5
15:12 989-665-2202
0911912002 CHICAGO MFG & DIST 07
PAGE
Othet Precautions
Donottransfer unmarked
to containers.
Follow Department Transportation
of regulations
during
transpol1. further
For informationrelative
to spillsresulting transportation
from incidents, to latestDep~rtment Transportation
refer of Emergency Response Guidebook Hazardous
for
Materials Incidents, DOTp 5800.3.When using product a highpressure
with grease be especially
gun careful avoidinjection the
to of
product beneath skinor Intoanyotherpartof 1he
the body.
SECTIONVIII. Control Measures
RespiratoryProtection
Normally needed ambient
not at temperatures undernormal
and conditions; product
of use. If product handled a manner
is in whichpro-
duces
vapor,
spray mistthefollowing
or respiratory
protection
measure
should taken:
be
LowConcentrationsvapor,
01 spray mist:
or
Usepartial full-face
or respirator NIOSH
with approved
organic
v~)r canister.
HignConcentrations:
Uselult-face
piecesupplied breathing
air apparatus.
Either
self.contained air-line
or breathing
apparatus be usedprovided is of a NIOSH
may it approved
type.
Donotusecompressed
oxygensystems hydrocarbon
in atmospheres,
Ventilation
Uselocalexhaust capture
to vapor, mIsts.
sprayand/orfumes, necessary.
if Provide
greaterthan60 ft/minhoodfacevelocity confined
for
space$.Provide ventilation
sufficient prevent
to exceeding recommended
the exposure foroil mistor fumeor build-up explosive
lImIt of
concentrationsvaporin air. In confined
of areasexplosion
proofequipment be required. smoking openlights
n,ay No or should permit-
be
tedin presence the product.
of
Protective Gloves
Use chemicalresistantsynthetic rubberprotectivegloves, if neededto avoilj prolonged repeatedskin contact.
or
Eye Protection
Usesplash
goggles faceshield
or wheneyecontact occur.
may
Other
Protective
Clothing Equipment
or
Usechemicalresistant
apronor otherimpervious
clothing, required. prEIVent
if to contamination regular
of clothing
whichcouldresult
in
prolonged repeated contact.
or skin
Work Practices
Keepcontainers
closedwhennot in use. Donothandle storenearheat,sparks,
or flame oxidizing
or agents.Whenusingproduct a
w~h
highpressure
grease gun,avoidinjection theproduct
of beneath or intoelny
skin other of thebody.
part
Hygiene Practices
Minimize breathing vapor,
of mist,spray fumes.Avoid
or prolonged fepeatod
Of contact skin. Remove
with contaminated
clothing.
Launder
or dry-clean
beforereuse.Remove contaminated
shots andthOfOllghly before
cJean, reuse.Discard oil-soaked.
if Cleanse thoroughly
skin
aftercontact,
beforebreaks meals, at endof ever)'workperiod.Product be removed tlseof waterless deanersfol.
and and may by hand
lowed thorough
by washing soapandwatef.
with
Lube *3/6
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