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MSDS Material Safety Data Sheet
CAS

68585-36-4 7664-38-2 123-91-1

File Name: 68585-36-4_7664-38-2_123-91.asp

                                                    MATERIAL SAFETY DATA SHEET
Revision: 1.0
06/07/2002
Page: 1 of 8
Product name: JACAAB PHOSPHOLAN PS-220



1. PRODUCT AND COMPANY IDENTIFICATION

JACAAB-PHOSPHOLAN PS-220
Product name:

Alkyl ether phosphate
Chemical name:

JACAAB LLC
Repacker:
4155 Manchester Avenue
St. Louis, MO 63110, USA


JACAAB LLC 314-652-5400
Emergency telephone
CHEMTREC (24 hours) 800-424-9300
number:


Customer Service: 800-906-9977
For MSDS, Product Safety, or
regulatory inquiries, call:




2. COMPOSITION / INFORMATION ON INGREDIENTS

COMPONENT CAS# CONCENTRATION
Alcohols, C10-14, ethoxylated, phosphate 68585-36-4 98.0 %
Phosphoric acid 7664-38-2 2.0 %
Dioxane 123-91-1 < 0.1 %




3. HAZARDS IDENTIFICATION

APPEARANCE
Liquid
Physical state
Yellow
Color
Mild
Odor
MATERIAL SAFETY DATA SHEET
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06/07/2002
Page: 2 of 8
Product name: JACAAB PHOSPHOLAN PS-220

EMERGENCY OVERVIEW
MAY BE HARMFUL IF SWALLOWED.

SEE SECTION 7 OF THE MSDS FOR INFORMATION ON TRACE 1,4-DIOXANE CONTENT.


POTENTIAL HEALTH EFFECTS

Swallowing
Acute effects
May be harmful if swallowed.

Skin absorption
Acute effects
Harmful effects are not expected from short periods of contact.

Inhalation
Acute effects
Short-term harmful health effects are not expected from vapor generated at ambient temperature.

Skin contact
Acute effects
Prolonged contact may cause irritation.

Eye contact
Acute effects
May cause irritation.


POTENTIAL ENVIRONMENTAL EFFECTS
This product is expected to be moderately toxic to aquatic organisms.


4. FIRST AID MEASURES

Swallowing
Do not induce vomiting.=Obtain medical attention immediately.=

Skin
Wash skin with soap and water.=

Inhalation
Remove to fresh air.=Give artificial respiration if not breathing.=Obtain medical attention.=

Eye contact
Immediately flush eyes with water and continue washing for at least 15 minutes.=
MATERIAL SAFETY DATA SHEET
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06/07/2002
Page: 3 of 8
Product name: JACAAB PHOSPHOLAN PS-220


5. FIRE-FIGHTING MEASURES

> 94 癈
Flash point:

Special protective equipment for firefighters
Use self-contained breathing apparatus when fighting fires in enclosed areas.

Extinguishing media
Suitable: Extinguish with:
- water fog
- dry chemical
- CO2
- alcohol resistant foam
- water spray

Unsuitable: None.




6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Wear suitable protective equipment.=

Environmental precautions
Avoid runoff to sewers or waterways.=May be harmful to aquatic life.=Product is soluble in water.=

Methods for cleaning up
Absorb on inert material such as sand, earth, vermiculite.
Contain or minimize dispersion and collect if possible.
If not possible disperse residue to reduce aquatic harm.
Report per regulatory requirements.



7. HANDLING AND STORAGE


HANDLING
Handling precautions
Do not get in eyes, on skin, on clothing. Keep drums tightly closed to prevent contamination. Wear recommended
personal protection equipment. Never use pressure to empty drums.

Other precautions
This product contains trace amounts of 1,4-dioxane, a condition which creates the potential for human exposure. If
this product is handled according to the recommendations in this MSDS, the presence of these trace amounts is not
expected to result in any short term or long term hazard.
MATERIAL SAFETY DATA SHEET
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06/07/2002
Page: 4 of 8
Product name: JACAAB PHOSPHOLAN PS-220




STORAGE
Storage requirements
Store and use with adequate ventilation. Store at ambient temperature.



8. EXPOSURE CONTROLS / PERSONAL PROTECTION

PERSONAL PROTECTION
Respiratory protection
If personnel exposure exceeds the exposure limits, select appropriate protective equipment in accordance with
NIOSH recommendations.

Hand protection / protective gloves
Resistant gloves

Eye protection
Safety glasses.

Industrial hygiene measures
Remove contaminated clothing and clean it.

ENGINEERING CONTROLS
Ventilation
General (mechanical) room ventilation is expected to be satisfactory for normal handling.

EXPOSURE LIMITS
Component Type Value Remark
Phosphoric acid TWA, OSHA 1.0 mg/m3

STEL, OSHA 3.0 mg/m3

TWA, ACGIH 1.0 mg/m3

STEL, ACGIH 3.0 mg/m3




9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE
Liquid
Physical state
MATERIAL SAFETY DATA SHEET
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06/07/2002
Page: 5 of 8
Product name: JACAAB PHOSPHOLAN PS-220

Yellow
Color
Mild
Odor


OTHER PROPERTIES
Decomposes
Boiling point

Not determined
Melting point

1.5 - 2.5
pH
Concentration:=
30 g/l

Density 1.02 g/cm3=at=20 癈
Negligible
Vapor pressure

Non Volatile
Vapor density (air=1)

Soluble
Solubility in water

> 94 癈
Flash point
Method:=Pensky-Martens closed cup ASTM D 93

0 %(m)
Percent volatiles




10. STABILITY AND REACTIVITY

Stability: Stable.

Stability - Conditions to avoid
Stable under normal conditions.

Incompatible materials
Strong oxidizing agents.

Hazardous combustion products
Carbon monoxide.
Carbon dioxide.
Oxides of phosphorous.

Hazardous polymerization: Will not occur.



11. TOXICOLOGICAL INFORMATION

CARCINOGENICITY
MATERIAL SAFETY DATA SHEET
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Product name: JACAAB PHOSPHOLAN PS-220

2 (HMIS) Moderate hazard
3 (HMIS) Serious hazard
4 (HMIS) Severe hazard
X (HMIS) Personal protection rating to be supplied by user depending on use conditions
MATERIAL SAFETY DATA SHEET
Revision: 1.0
06/07/2002
Page: 7 of 8
Product name: PHOSPHOLAN PS-220

Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA) requires
notification of the National Response Center of release of quantities of hazardous substances equal to or
greater than the reportable quantities (RQ's) in 40CFR302.4.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
Phosphoric acid RQ 5000 pounds 7664-38-2 2.00
for phosphoric
acid

Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency planning
based on Threshold Planning Quantities (TPQ's) and release reporting based on Reportable Quantities (RQ's)
in 40CFR355 (used for SARA 302 and 304).
Components present in this product at a level which could require reporting under the statute are:
None.

Pennsylvania Right-To-Know Hazardous Substance List--Hazardous Substances and Special Hazardous
Substances on the list must be identified when present in products.
Components present in this product at a level which could require reporting under the statute are:
Chemical name CAS# Max weight %
Phosphoric acid 7664-38-2

New Jersey Worker and Community Right-To-Know Act (Labeling Requirements)
Chemical name CAS# New Jersey TS Number
Phosphoric acid 7664-38-2
Alcohols, C10-14, ethoxylated, phosphate 68585-36-4

None
EPA Hazard Categories (SARA 311, 312):




CHEMICAL INVENTORY

United States: The ingredients of this product are on the TSCA inventory.




16. OTHER INFORMATION

RECOMMENDED USES AND RESTRICTIONS
Please consult the product and/or application information bulletins for this product.=


HMIS RATING
Health: 1 Flammability: 1 Reactivity: 0 PPI: -

LEGEND

STP Standard temperature and pressure
W/W Weight/Weight
0 (HMIS) Minimal hazard
1 (HMIS) Slight hazard
MATERIAL SAFETY DATA SHEET
Revision: 1.0
06/07/2002
Page: 8 of 8
Product name: PHOSPHOLAN PS-220

2 (HMIS) Moderate hazard
3 (HMIS) Serious hazard
4 (HMIS) Severe hazard
X (HMIS) Personal protection rating to be supplied by user depending on use conditions

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