MATERIAL SAFETY DATA SHEET
FILE NO.: P2V1
MSDS DATE: 11/30/2009
Product: P2 MSDS No.: P2113009
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: P2 Permanent PermaTack
PRODUCT CODES: P2QT1, P2GL1, P2GL5
COMPANY NAME: SmartAdhesives LLC
ADDRESS: San Francisco, CA 94129
EMERGENCY PHONE: Chemtrec: 1-800-424-9300
PRODUCT USE: Permanent Pressure Sensitive Adhesive
ISSUE DATE: 11-30-2009
SECTION 2: INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENT: C.A.S. No. % by Wt.
Vinyl Acetate (monomer) 108-05-4 0.1 - < 0.5%
SECTION 3: HAZARDS IDENTIFICATION
Normal physical form - liquid
EMERGENCY OVERVIEW:
IMMEDIATE HEALTH AND ENVIRONMENTAL HAZARDS
While this material is not considered as hazardous under OSHA regulations, the
MSDS contains valuable information concerning the safe handling and proper use
of the product.
No known physical hazards. Contains trace amounts of vinyl acetate monomer
remaining from production process.
POTENTIAL HEALTH EFFECTS
May cause slight irritation.
EYE CONTACT:
May cause allergic skin reaction.
SKIN CONTACT:
No known acute toxic respiratory tract effects.
INHALATION:
Not expected to be ingested under normal conditions of use. No known ingestion
INGESTION:
hazards.
MEDICAL CONDITIONS AGGREVATED BY OVEREXPOSURE
Not established.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
None.
This material contains trace amounts of vinyl acetate monomer. Vinyl acetate is
FURTHER INFORMATION:
metabolized into acetaldehyde, which has an IARC 2B classification, and thus vinyl
acetate is also listed in category 2B.
CARCINOGENICITY
Vinyl Acetate (monomer) OSHA: NO NTP: NO IARC: 2B
PAGE 1 OF 5
MATERIAL SAFETY DATA SHEET Product: P2 Revision Date: 11/30/2009
SECTION 4: FIRST AID MEASURES
Immediately flush eyes with plenty of water for at least 15 minutes. If symptoms
EYES:
occur, seek medical advice.
Wash skin with mild soap and plenty of warm water. If symptoms occur, seek
SKIN:
medical advice.
Do not induce vomiting unless directed to do so by medical personnel. If conscious,
INGESTION:
drink two glasses of water. Never give anything by mouth to an unconscious
person. If symptoms occur, seek medical attention.
Move to fresh air. No special measures required.
INHALATION:
SECTION 5: FIRE FIGHTING MEASURES
FLAMMABILITY: Combustible Liquid Class IIIB
FLAMMABLE LIMITS UPPER: not applicable
(% BY VOLUME) LOWER: not applicable
FLASH POINT: not applicable
AUTOIGNITION TEMP: not applicable
NFPA HAZARD CLASSIFICATION
HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0
HMIS HAZARD CLASSIFICATION
HEALTH: *1 FLAMMABILITY: 1 REACTIVITY: 0
EXTINGUISHING MEDIA: Use water fog, dry chemical, carbon dioxide, foam or water. Water may be used to cool
adjacent tanks and structures. Avoid spreading burning liquid with water used for cooling
purposes.
SPECIAL FIRE FIGHTING PROCEDURES:
Wear self-contained breathing apparatus and full protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
None
HAZARDOUS DECOMPOSITION PRODUCTS:
see Section 10
SECTION 6: ACCIDENTAL RELEASE MEASURES
ACCIDENTAL RELEASE MEASURES:
No action shall be taken involving any personal risk or without suitable training. If material
is released, indicate risk of slipping. Put on appropriate personal protective equipment
(see section 8). Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
For small spills, absorb with liquid binding material such as diatomaceous earth, sand,
silica gel, acid binder, universal binder, and sawdust. For large spills, pump into suitable
containers and dispose in appropriate waste disposal container. Clean up area with
plenty of water. Dispose of cleansing water and all material in accordance with Federal,
State, and local regulations.
SECTION 7: HANDLING AND STORAGE
HANDLING: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face with soap and
water before eating, drinking and smoking.
PAGE 2 OF 5
MATERIAL SAFETY DATA SHEET Product: P2 Revision Date: 11/30/2009
Spilled material increases risk of slipping. No special precautions against fire and
explosion are required. Containers of this material may be hazardous when emptied due
to product residues, including vapors.
STORAGE: Do not store below 32癋 (0癈). Keep from freezing. Store in cool, dry, ventilated area in
accordance with local regulations.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
VENTILATION : Use with adequate ventilation.
RESPIRATORY PROTECTION: Not normally required.
EYE PROTECTION: Avoid contact with eyes. Use safety glasses with side shields or indirect vented goggles.
SKIN PROTECTION: Any liquid tight vinyl or rubber gloves.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
If splashing might occur, wear protective clothing such as an apron, lab coat, coveralls or
other appropriate clothing to cover skin. Facilities storing or utilizing this material should
be equipped with eye wash fountains
EXPOSURE GUIDELINES:
Organization Type Limit
Vinyl Acetate (monomer) ACGIH (TLV) TWA 10 ppm
STEL 15 ppm
OSHA (PEL) not regulated
ACGIH: American Conference of Governmental Industrial Hygienists
OSHA: Occupational Safety and Health Administration
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
COLOR & APPEARANCE: white liquid VAPOR PRESSURE (mmHg): 18.6 at 70癋 (21癈)
ODOR THRESHOLD: slightly sweet VAPOR DENSITY (AIR=1): not available
PHYSICAL FORM: liquid SPECIFIC GRAVITY (H2O=1): 1.02
FLAMMABLE LIMITS EVAPORATION RATE: not available
LEL: not applicable
UEL: not applicable
SOLUBILITY IN WATER: moderately soluble
BOILING POINT: 212癋 (100癈)
AUTOIGNITION TEMP: not available VISCOSITY: 7,000 ?200 cP
FLASH POINT: not applicable VOLATILE ORGANIC COMPOUNDS (VOC)
(Pensky-Martens Closed Cup ASTM D 93) VOC: NA
VOC less H2O & Exempt Solvent: NA
pH AS SUPPLIED: 4.3
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Material is stable.
MATERIALS AND CONDITIONS TO AVOID (STABILITY):
Keep from freezing.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
Carbon dioxide. Carbon monoxide. Hydrocarbons. Aldehydes. Acetic Acid.
HAZARDOUS POLYMERIZATION: Cannot occur.
PAGE 3 OF 5
MATERIAL SAFETY DATA SHEET Product: P2 Revision Date: 11/30/2009
SECTION 11: TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION:
Vinyl Acetate (monomer) - Acute Toxicity
Acute oral LD50: >2,000 mg/kg (rat)
Experience with humans during manufacture and use: No information on damage to health.
SECTION 12: ECOLOGICAL INFORMATION
ECOLOGICAL INFORMATION:
Information on Elimination: Not readily biodegradable. Polymer component is eliminated by adsorption to activated
sludge. Separation by flocculation is possible.
Ecotoxicity: Carp (Cyprinus carpio) LC50 (96 hr.) >1,000 mg/L
No expected damaging effects to aquatic organisms
Sludge EC10 (0.5 hr.) <1,000 mg/L (bacteria toxicity: respiration/reproduction inhibition)
According to current knowledge, no expected adverse effects on water purification plants
Prevent material from entering surface waters and soil. Do not introduce into water purification plants unless in
diluted state. No environmental problems are expected if handled and treated in accordance with standard industrial
practices and local regulations. The ecological results were obtained from tests on similar products.
SECTION 13: DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of product in accordance with regulations by incineration in a special waste
incinerator. Small quantities may be disposed of by incineration in an approved facility.
After chemical deflocculation, can be stored with domestic waste. Disposal of this
product, solutions and any by-products should at all times comply with Federal, State and
local regulations.
RCRA HAZARD CLASS: none
SECTION 14: TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (49 CFR)
PROPER SHIPPING NAME: Not a DOT controlled material
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA)
PROPER SHIPPING NAME: Not subject to IATA regulations
WATER TRANSPORTATION (IMO/IMDG)
PROPER SHIPPING NAME: Not subject to IMDG code
SECTION 15: REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA (Toxic Substance Control Act)
All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. No TSCA 12(b)
Export Notification chemicals are present in this product.
311/312 HAZARD CATEGORIES:
Chronic: yes Reactivity: no Acute: no
SECTION 313: (Toxic chemicals subject to reporting requirements of that section and 40 CFR part 372 (EPCRA))
Vinyl Acetate (monomer) upper limit by wt.: 0.4%
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION, AND LIABILITY ACT):
Vinyl Acetate (monomer) 108-54-4 RQ: 5,000 lbs. upper limit by wt.: 0.4%
PAGE 4 OF 5
MATERIAL SAFETY DATA SHEET Product: P2 Revision Date: 11/30/2009
STATE REGULATIONS
California Prop. 65: Carcinogen: Acetaldehyde (CAS 75-07-0); 1,4-Dioxane (123-91-1); Ethylene Oxide (75-21-8)
Reproductive: Ethylene Oxide (75-21-8)
SECTION 16: OTHER INFORMATION
OTHER INFORMATION:
HMIS Rating
Health *1
Flammability 0
Reactivity 0
NFPA Rating
Health 1
Flammability 0
Reactivity 0
PREPARATION INFORMATION:
DISCLAIMER: The material in this Material Safety Data Sheet (MSDS) is, to the best of our knowledge, accurate as of the
date issued. However, neither SmartAdhesives nor any of its subsidiaries or agents assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole
responsibility of the user. Compliance with all applicable federal, state, and local laws and regulations remains the
responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain
hazards are described herein, we cannot guarantee that these are the only hazards that may exist. Given the quantity of
variables that affect use and application of our products, many of which are within the user's control and unique to each
user's knowledge, SMARTADHESIVES MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING BUT NOT
LIMITED TO ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR
COURSE OF PERFORMANCE OR USAGE OF TRADE.
PAGE 5 OF 5
|